基于人工神经网络的居民生活垃圾可燃成分热值预测

研究采用BP、RBF和自适应神经模糊推理系统(ANFIS)对生活垃圾可燃成分的热值进行预测。结果表明,BP神经网络模型的预测准确率为93.36%,RBF模型为96.87%,ANFIS模型为91.06%,3种模型均可用于可燃成分热值预测,但RBF模型的预测准确率相对较高,更适用于可燃垃圾的热值预测。     

催化湿式氧化法处理垃圾渗滤液

以北京某垃圾转运站的垃圾渗滤液原液为研究对象,采用催化湿式氧化技术进行实验研究。实验以Fe2+为催化剂,H2O2为氧化剂,在反应釜中高温高压处理转运站的渗滤液。同时,实验分别研究了反应温度、反应时间、催化剂种类和添加量等几种因素对渗滤液处理效果的影响。结果表明,当反应温度达到120℃,反应60 min时,在Fe2+催化条件下,按初始COD和Fe2+质量比为6投加催化剂,初始COD和H2O2当量比为1投加氧化剂,反应出水的COD去除率达到91%。     

叠式空气隙膜蒸馏组件膜污染实验研究

采用一种具有旋流结构的多层层叠式空气隙膜蒸馏膜组件,以20 g/L氯化钠盐水为热工质,考察在70℃条件下膜污染情况,实验结果表明,一个周期的连续运行和间歇性操作膜表面在高温下较快进入膜污染,8个周期后膜通量下降为初始通量的42%。膜表面有大量黄色附着物,电镜SEM分析显示,膜表面被不均匀堆积的颗粒状污染物及长方体结晶物覆盖,能谱EDS分析,污染物有极少量NaCl结晶的Na、Cl元素,还有O、C、Mg、Cu和Fe等元素。污染膜经5%盐酸溶液清洗后无机垢沉淀被去除,表观效果较好。     

Mass-transfer processes of chromium(VI) adsorption onto guava seeds

The chromium(VI) biosorption onto guava seeds, as an alternative method for Cr⁶⁺ removal from aqueous solutions, was investigated. The parameters affecting kinetics and equilibrium of Cr⁶⁺ adsorption onto guava seeds were studied. An external mass-transfer diffusion coefficient k and intra-particle diffusion coefficient k_i were determined to measure the rate-limiting step of adsorption. A single external mass-transfer diffusion model and intra-particle diffusion models were used. The effects of initial pH, sorbent mass, and initial Cr⁶⁺ concentrations on mass-transfer coefficients were investigated. The external mass-transfer coefficient has an average value of 7.2×10^-3 cm s^-1, while the intra-particle mass-transfer diffusion coefficient was 0.34 mg g^-1 min^-0.5. This indicates that external diffusion to the guava seeds surface and intra-particle diffusion are both involved in the sorption process. The isotherm equilibrium data were well fitted by the Langmuir and Freundlich models with an average correlation coefficient R²=0.98. The maximum removal of Cr⁶⁺ was obtained at pH 1 (about 100% for adsorbent dose of 15 g l^-1 and 25 mg l^-1 initial concentration of Cr⁶⁺). The results indicated that the guava seeds exhibit acceptable sorption capacity.     

高原湿地剑湖湖滨带功能作用的定量研究

采用野外采样与室内分析的方法，从水质和底泥两个方面定量研究剑湖湖滨带的功能作用。结果表明，湖滨带在水质净化和拦截泥沙等方面效果显著，特别是对水中总氮与总磷的平均去除率分别高达66．28％和45．73％，其拦截作用表现为：迎水面的泥层厚度是背水面的1．5倍；底泥的各项指标（除pH值），湖滨带背水面均比迎水面高，速效磷和全氮的增加量最为明显，其含量分别是迎水面的3．30和2．61倍，这主要与湖滨植物带大量吸收入湖矿质营养用于自身生长，其残体在背水面沉积有关，从另一角度体现了湖滨带的吸附、净化功能。因此，要重视并保护湖滨带，从而使其功能得到有效发挥。     

Photosensitized Oxidation of Cyanide in Aqueous Solutions of Photoactive Modified Hydroxyethylcellulose

Novel water-soluble polymeric photosensitizers based on a natural polymer, naphthalene-modified hydroxyethylcellulose (HENC), were obtained and used for the photooxidation of cyanide. The reaction leads to the formation of cyanate. The process occurs via photoinduced electron transfer from CN⁻ to the naphthalene or naphthoquinone polymeric chromophores. The kinetics of the reaction depend on the degree of substitution of HENC, its concentration, and pH of the solution. The polymers can be easily removed after reaction as prolonged irradiation leads to their photodegradation.     

Prenatal diagnosis of septal agenesis with normal pituitary function

Septal agenesis is a rare brain malformation that is characterized by partial or complete absence of the septum pellucidum, either isolated or associated with other brain anomalies. We report a case presenting with septal agenesis and normal optic chiasm and pituitary function in a fetus at 19 weeks of gestation. Copyright © 2006 John Wiley & Sons, Ltd.     

欧洲污染物排放与转移登记制度简介

污染物排放与转移登记制度（简称PRTR制度）,是发达国家为了对化学污染物质进行更严格的管理而实行的一种管理制度。该制度起源于1984年,最早实行的是荷兰,其后美国、欧盟、澳大利亚、加拿大、韩国、日本等国家也相继实施了PRTR制度。本文着重介绍了欧盟污染物排放与转移登记制度的发展历史,并就EPER和E—PRTR进行了简单的比较。     

基于综合主成分及径向基网络的环境质量评价

运用综合主成分分析对监测数据进行处理,集成径向基函数人工神经网络(RBF-ANN),参考国家环境质量评价标准设定RBF的学习样本,从而构建区域环境质量综合评价模型,对安徽省合肥市新站综合开发试验区进行环境质量综合评价。实例分析结果表明,运用综合主成分法可以精准的统计出一个区域的环境综合数据,而且在matlab环境下运用RBF-ANN模型既可以准确,客观的评定环境质量的等级,又可以表现其环境污染的具体程度,能在同一评价等级内对不同环境质量的评价对象进行更加细微的污染程度的比较。结果表明,合肥市新站综合开发试验区环境综合质量介于轻度污染和中度污染的标准极限值之间,属于中度污染。     

我国原油流动的空间格局研究

运用平衡方程式分析了我国各省区的原油生产消费与输入输出状况,并根据自给率,将我国26个原油流动省区划分为基本自给型、半自给型、净输出型和净补给型4种原油产需平衡类型。根据流动比率,26个省区可划归为输出中心、输入中心和交流中心3种原油流动职能类型;在分布格局上,输出中心为直角三角形,输入中心为直角梯形区,交流中心则为钝角三角形。以主要源地为标准,我国原油流动可划分为北部、西北、华东和华南四大流场,其中北部、西北属于全国性流场。我国原油流动路径可分为五大密集区,各区路径的空间结构不同：东北区为树状网络结构,华北区为单枝二叉树状结构,西北区为"X"形结构,华东区为多中心"Ⅲ"形结构,华南区则为"Y"形结构。流动路径之间还广泛存在并联与串联,充分发挥多种通道的综合流动效益。研究原油流动空间格局为我国石油空间组织的优化奠定了基础。〖