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作为新兴生物燃料,大分子醇类燃料在低压下的火灾安全基础迫切需要得到深入研究。热解过程作为火灾过程的初始阶段直接控制着火过程,火灾中碳烟颗粒的产生也依赖于热解反应,因此可燃物的低压热解研究在其低压火灾基础研究中具有重要意义。利用同步辐射真空紫外光电离质谱方法研究了异戊醇在0.2atm下的流动反应器热解,探测到了20余种热解产物,包括烯丙基自由基和C_4H_8O、C_5H_8、C_6H_6等同分异构体,并测量了其摩尔分数。基于实验结果,对燃料分解路径和主要产物的生成及消耗路径进行了探讨。与本组之前正戊醇热解实验的对比表明,由于存在支链结构,异戊醇在热解中比正戊醇更容易产生戊烯、丁烯和丙烯,但更少地产生乙烯。此外,异戊醇在热解中能够生成更多的丙炔和丙二烯等环状化合物前驱体,令其苯和1,3-环戊二烯的生成量更高,表明异戊醇比正戊醇更易于生成多环芳烃和碳烟。 相似文献
34.
虚拟耕地是指隐含在农产品贸易中,生产这些农产品过程中所必需占用的土地资源,有意识的在国际农产品贸易中实施虚拟耕地战略,对于平衡国内耕地赤字、保障粮食安全,发挥我国农产品在国际市场上的竞争优势具有重要的理论指导意义。首先介绍了虚拟耕地的定义及其量化方法,接着分析计算了我国谷物、油籽、棉花等几类主要农产品单位重量的虚拟耕地含量,在此基础上,对当前农产品进出口贸易中虚拟耕地的交易现状及未来发展趋势作了分析和预测。结果显示:近10 a来虚拟耕地净进口量出现持续增长,2006年,通过农产品国际贸易净进口虚拟耕地16602903.1 hm2,约占当年全国耕地总面积的12.77%。同时,虚拟耕地净进口量在今后若干年仍将保持增长态势。 相似文献
35.
Environmental assessment of garden waste management in the Municipality of Aarhus, Denmark 总被引:1,自引:0,他引:1
An environmental assessment of six scenarios for handling of garden waste in the Municipality of Aarhus (Denmark) was performed from a life cycle perspective by means of the LCA-model EASEWASTE. In the first (baseline) scenario, the current garden waste management system based on windrow composting was assessed, while in the other five scenarios alternative solutions including incineration and home composting of fractions of the garden waste were evaluated. The environmental profile (normalised to Person Equivalent, PE) of the current garden waste management in Aarhus is in the order of −6 to 8 mPE Mg−1 ww for the non-toxic categories and up to 100 mPE Mg−1 ww for the toxic categories. The potential impacts on non-toxic categories are much smaller than what is found for other fractions of municipal solid waste. Incineration (up to 35% of the garden waste) and home composting (up to 18% of the garden waste) seem from an environmental point of view suitable for diverting waste away from the composting facility in order to increase its capacity. In particular the incineration of woody parts of the garden waste improved the environmental profile of the garden waste management significantly. 相似文献
36.
Ling R. Zeng Li H. Shi Xin G. Meng J. Xu Gui F. Jia T. Gui 《Journal of environmental science and health. Part. B》2019,54(4):317-325
This study evaluated the hydrolysis and photolysis kinetics of pyraclostrobin in an aqueous solution using ultra-high-performance liquid chromatography–photodiode array detection and identified the resulting metabolites of pyraclostrobin by hydrolysis and photolysis in paddy water using high-resolution mass spectrometry coupled with liquid chromatography. The effect of solution pH, metal ions and surfactants on the hydrolysis of pyraclostrobin was explored. The hydrolysis half-lives of pyraclostrobin were 23.1–115.5?days and were stable in buffer solution at pH 5.0. The degradation rate of pyraclostrobin in an aqueous solution under sunlight was slower than that under UV photolysis reaction. The half-lives of pyraclostrobin in a buffer solution at pH 5.0, 7.0, 9.0 and in paddy water were less than 12?h under the two light irradiation types. The metabolites of the two processes were identified and compared to further understand the mechanisms underlying hydrolysis and photolysis of pyraclostrobin in natural water. The extracted ions obtained from paddy water were automatically annotated by Compound Discoverer software with manual confirmation of their fragments. Two metabolites were detected and identified in the pyraclostrobin hydrolysis, whereas three metabolites were detected and identified in the photolysis in paddy water. 相似文献
37.
Fate of pharmaceuticals and personal care products in wastewater treatment plants - Conception of a database and first results 总被引:1,自引:0,他引:1
C. Miège J.M. Choubert L. Ribeiro M. Eusèbe M. Coquery 《Environmental pollution (Barking, Essex : 1987)》2009,157(5):1721-1726
We created a database in order to quantitatively assess the occurrence and removal efficiency of pharmaceuticals and personal care products (PPCPs) in wastewater treatment plants (WWTPs). From 117 scientific publications, we compiled 6641 data covering 184 PPCPs. Data included the concentrations of PPCPs in WWTP influents and effluents, their removal efficiency and their loads to the aquatic environment. The first outputs of our database allowed to identify the most investigated PPCPs in WWTPs and the most persistent ones, and to obtain reliable and quantitative values on their concentrations, frequency of detection and removal efficiency in WWTPs. We were also able to compare various processes and pointed out activated sludge with nitrogen treatment and membrane bioreactor as the most efficient ones. 相似文献
38.
Part V—sorption of pharmaceuticals and personal care products 总被引:5,自引:0,他引:5
Background, aim, and scope Pharmaceuticals and personal care products (PPCPs) including antibiotics, endocrine-disrupting chemicals, and veterinary pharmaceuticals
are emerging pollutants, and their environmental risk was not emphasized until a decade ago. These compounds have been reported
to cause adverse impacts on wildlife and human. However, compared to the studies on hydrophobic organic contaminants (HOCs)
whose sorption characteristics is reviewed in Part IV of this review series, information on PPCPs is very limited. Thus, a
summary of recent research progress on PPCP sorption in soils or sediments is necessary to clarify research requirements and
directions.
Main features We reviewed the research progress on PPCP sorption in soils or sediments highlighting PPCP sorption different from that of
HOCs. Special function of humic substances (HSs) on PPCP behavior is summarized according to several features of PPCP–soil
or sediment interaction. In addition, we discussed the behavior of xenobiotic chemicals in a three-phase system (dissolved
organic matter (DOM)–mineral–water). The complexity of three-phase systems was also discussed.
Results Nonideal sorption of PPCPs in soils or sediments is generally reported, and PPCP sorption behavior is relatively a more complicated
process compared to HOC sorption, such as the contribution of inorganic fractions, fast degradation and metabolite sorption,
and species-specific sorption mechanism. Thus, mechanistic studies are urgently needed for a better understanding of their
environmental risk and for pollution control.
Discussion Recent research progress on nonideal sorption has not been incorporated into fate modeling of xenobiotic chemicals. A major
reason is the complexity of the three-phase system. First of all, lack of knowledge in describing DOM fractionation after
adsorption by mineral particles is one of the major restrictions for an accurate prediction of xenobiotic chemical behavior
in the presence of DOM. Secondly, no explicit mathematical relationship between HS chemical–physical properties, and their
sorption characteristics has been proposed. Last but not least, nonlinear interactions could exponentially increase the complexity
and uncertainties of environmental fate models for xenobiotics. Discussion on proper simplification of fate modeling in the
framework of nonlinear interactions is still unavailable.
Conclusions Although the methodologies and concepts for studying HOC environmental fate could be adopted for PPCP study, their differences
should be highly understood. Prediction of PPCP environmental behavior needs to combine contributions from various fractions
of soils or sediments and the sorption of their metabolites and different species.
Recommendations and perspectives More detailed studies on PPCP sorption in separated soil or sediment fractions are needed in order to propose a model predicting
PPCP sorption in soils or sediments based on soil or sediment properties. The information on sorption of PPCP metabolites
and species and the competition between them is still not enough to be incorporated into any predictive models. 相似文献
39.
The objectives of this study were to quantitatively estimate the distribution of arsenic with its speciation and to identify potential pathways for transformation of arsenic species from samples of water, sediments, and plants in the ecosystem affected by the Cheongog Spring, where As(V) concentration reached levels up to 0.270 mg L−1. After flowing about 100 m downstream, the arsenic level showed a marked reduction to 0.044 mg L−1 (about 84% removal) without noticeable changes in major water chemistry. The field study and laboratory hydroponic experiments with the dominant emergent plants along the creek (water dropwort and thunbergian smartweed) indicated that arsenic distribution, reduction, and speciation appear to be controlled by, (i) sorption onto stream sediments in exchangeable fractions, (ii) bioaccumulation by and possible release from emergent plants, and (iii) transformation of As(V) to As(III) and organic species through biological activities. 相似文献
40.