浅谈制浆造纸工业水污染处理技术

造纸行业是我国水污染的主要行业。本文分析了我国造纸工业水污染及其治理现状，论述了造纸工业水污染控制对策，提出了造纸工业中中段水采用物化十生化处理、废纸脱墨废水处理采用PE膜处理或气浮＋好氧处理等工艺方法。     

沉淀——吸附法处理果胶工艺废水

利用果胶废水中的Al（Ⅲ）和石灰乳沉淀,并用炉渣、活性碳脱色的方法,处理盐板法提取果胶的工艺废水。通过正效实验,研究了最佳工艺条件。该工艺处理后的废水,Al（Ⅲ）去除率96.8％,CODCr去除率为92.7％,SO4^2－去除率为61.5％,且废渣产出量少。     

市场机制在白色污染物回收处置中的应用探讨——以上海一次性塑料餐具废弃物为例

近10年来上海城市生活垃圾组分中,以塑料为代表的包装废物的组分份额上升趋势尤为显著;上海GDP持续高速增长,但单位GDP城市废弃物清运量的下降率却显著低于GDP的年均增长率,一定程度上说明环卫行业的投资渠道较为单一,缺乏竞争和优化配置的市场机制;上海各类废弃塑料主要流向江浙一带,进行小规模低技术层次的加工处理,容易形成隐蔽的废品交易暗流;造成“白色污染”屡禁不止的重要原因是忽视了基于生产者责任的市场调控机制,社会化的回收体系薄弱;上海从2000年10月起,对一次性塑料餐具的回收处置建立了基于生产者责任的市场机制,由于一次性塑料饭盒的区域回收网络建设滞后,实施的效果有效但仍有限.     

To enhance the reproduction of Phanerochaete chrysosporium by adding natural lixiviums in liquid medium

Great promotion to the reproduction of white rot fungus Phanerochaete chrysosporlum by adding natural lixiviums such as from wood, maize core and potato in liquid medium was found in this research. Incubated in the liquid medium contained 10 mg/L glucose as carbon source with natural lixiviums for three days, the production of myeelium pellet reaches more than 80 g/L, which is 5 times more than that of without natural lixiviums. Incubated in the liquid medium contained 5 mg/L glucose as carbon source with natural lixiviums for three days, the production of myeelium pellet can reach 69.5 g/L, while the production in the medium without natural lixiviums is very low. When the liquid medium contained 1-20 g/L glucose as carbon source, the production of myeelium pellet in 3 d can only reach 12.5 g/L to 14.5 g/L. The fungus in the medium with potato lixiviums are easily contaminated by other microorganisms and in the medium with maize core lixiviums are easily bulking, while in the medium with wood lixiviums are neither easily contaminated nor bulking. Medium with wood lixiviums can produce more pellet than other medium, endure contamination and keep better sedimentation capacity. So that, wood lixivium is borer additive to the culture of white rot fungi in liquid medium. Addition of the mixture of wood, maize core and potato lixiviums is of advantage to the productian of mycelium pellet. The difference of the production in the medium with different amount of wood lixiviums showed little in the first 3 d, while it esnanded after 3 d. Wood lixiviums stimulate the growth of P. chrysosporium instead of supply organies which fungi need.     

白腐真菌细胞色素P450的诱导及检测方法研究

以CO结合差光谱为基本检测法,研究了白腐真菌黄孢原毛平革菌中细胞色素P450的诱导和适宜的分离检测方法.结果表明,正己烷对该真菌P450有显著的诱导作用,P450诱导量受正己烷浓度和诱导时间的影响,每小时投加正己烷2μL/mL、诱导6 h可使该真菌微粒体P450比浓度高达140~160 pmol/mg.在此基础上,本研究优化了分离P450时破碎细胞的方法以及光谱法检测P450的条件.破碎细胞时,采用高速分散结合玻璃研磨,比采用玻璃研磨、超声破碎和珠磨等方法分离的微粒体P450含量高1~5倍,是更为适宜的破碎方法.检测CO结合差光谱时,通气和还原条件对P450检测值有显著影响,较适宜的条件为:样品池和对照池分别通入等量的CO和N2,通气流量为3 mL/min(300μL样本),通气时间40 s;通气后投加还原剂低亚硫酸钠,投加浓度为0.4 mol/L.     

微波辅助白腐真菌煤炭脱硫试验研究

将微波技术与生物技术相结合用于煤炭脱硫,采用微波功率1 000 W、辐照时间80 s对煤样进行辐照处理后,考察了初始pH值、煤粉粒径和煤浆浓度对微波辅助白腐真菌脱硫效果的影响,以及脱硫过程中硫化物的转化规律。研究结果表明,微波辐照作用能够缩短脱硫周期,提高有机硫的脱除率。在初始pH值为4.5,煤粉粒径为80～120目,煤浆浓度为10%,浸出时间为3 d的条件下,煤中的全硫、无机硫和有机硫脱除率分别达到52.06%、51.61%和54.22%。     

白泥海水脱硫示范工程的中试研究

对黄岛发电厂3#机组白泥海水脱硫示范工程进行了中试研究。试验结果表明:以白泥做吸收剂,脱硫效率可达到90%以上,并能产生较好的经济效益,脱硫过程中可以直接消耗白泥,从而达到以废治废的目的。     

开放体系下产酸白腐菌连续处理造纸黑液研究

研究了产酸白腐菌CoriolusSp.S1在开放环境下连续曝气处理造纸黑液。在连续50d处理过程中,产酸白腐菌可以稳定的连续处理黑液,与进水相比,出水中COD降幅最高达到53.73%,脱色率平均可以达到73.74%,木质素去除率达到45.66%,为白腐菌应用于造纸黑液的治理提供了一定的基础。     

Distribution of White Whales (Delphinapterus leucas) in the White Sea and the Southeastern Region of the Barents Sea during the Ice Season

The habitats, relative occurrence, and distribution of the white whale in the White Sea and the southeastern Barents sea in every month of the ice season have been studied using the results of an aerial ice survey along standard routes from 1970–1991. In these seas, white whales have been found in each month of the ice season, with single animals, groups, schools or gams, herds, and large congregations of several hundred animals accounting for 10, 22.8, 47.2, 12.9, and 7% of all aggregations of white whales observed, respectively. The relative occurrence of white whales in the White Sea is higher in March and May (32.5 and 30%, respectively) and lower in February, January, and November (15, 10, and 7.5%, respectively); in December and April, the whales are observed very seldom (2.5% in both months). In the southeastern Barents Sea, the relative occurrence of white whales is highest in May (53.3%) and considerably lower in December and February (16.7 and 10%); only a few animals are found during the remaining ice season. Regarding different habitats, the relative occurrences of white whales in open water, in water openings in the ice, near the edge of pack ice, and in ice packs with different degrees of closeness are 21.5, 11.4, 45.7, and 21.4%, respectively.     

白腐真菌对染料脱色及降解过程机理和影响因素

许多白腐真菌对染料具有广谱的脱色和降解能力 ,其脱色及降解作用可能主要是由于其在次生代谢阶段产生的木质素过氧化酶LiPs和锰过氧化酶MnPs所致。培养条件对白腐真菌脱色及降解活性有较大的影响 ,在培养基中加入藜芦醇和二价锰等能够显著提高木质素过氧化酶的产生 ;富氮培养基会抑制LiPs的生成 ;硫脲、叠氮化物、氰化物等均能明显地抑制白腐真菌的脱色及降解活性 ;缓冲液的选择对维持稳定的 pH值和菌丝的形态有一定作用 ,从而影响其脱色效果 ;富氧环境是一切白腐真菌对染料进行脱色和降解的必要条件 ;适度的搅拌混合有利于反应时的物质之间传递 ;一般地 ,在培养时间达到 3天以后白腐真菌才能达到较高的脱色与降解活性。染料分子大小和结构及其基团的位置对脱色及降解效果有明显影响。使用特殊填料极大地提高处理系统中的生物量以克服真菌生长速度相对较慢、提高处理能力是该技术今后的研究重点。