Environmental Chemistry Letters - The demand for lithium is growing rapidly with the increase in electric vehicles, batteries and electronic equipments. Lithium can be extracted from brines, yet... 相似文献
It is known that globalization has led first- and second-tier cities’ urban restructuring trajectories, excreted pressures, and caused tremendous socioeconomic volatility. This resulted in marginalized communities in dire of social empowerment, employment structure variance, and industry sectoral adjustment. Moreover, recent successive climate and health crisis unfolded and affirmed the state of our urban incompetence to sustain socioeconomic resilience or otherwise; lacking swift responses in providing critical management and services, cites are facing multifaceted challenges. Urban well-being and resilience are at stake. Although the environmental and health dimensional effects are apparent, this study ascertains that the transept multi-scalar analysis within the urban socioeconomic structure is crucial in sustaining core resilience to foster health and well-being of the community. As an integral part of the investigation, the revised DPSIR assessment framework is applied to evaluate the sectoral shift; spatial structure disarray and urban codependence degree are examined within the Taipei metropolitan area (TMA), a medium size but densely populated metropolitan area in Taiwan. The place-based DPSIR analysis ascertained the states and impacts in TMA: (1) A population decline speeded the restructuring of the urban core, while the impact of demographic aging and shrinkage rate mandates proper management and planning responses to the decline process; (2) the socioeconomic state effect is determined but does not critically affect the periphery zone, while an uneven demographic shift within the urban core necessitates dynamic adjustment responses to appropriately provide intergenerational services; (3) the uneven sector redistribution stimulated the core’s spatial and structural inter-dependency with peripheral zones, requiring governance with tighter cross-administration cooperation among respective public sectors; and (4) facing the sector/temporal and demographic pressure, urban cohesiveness in the TMA is greatly affected, which in turn disrupts the resilience pathway toward a cohesion. The study ascertained that the revised DPSIR framework could provide cities facing pressing socioeconomic drivers with effective analysis to allocate pressures, states, and impacts and formulate the necessary responses. To assure the socioeconomic resilience and urban cohesiveness, planning policy should carefully monitor and evaluate socio-demographic and sector redistribution factors to promote the urban resilience.
Environmental Science and Pollution Research - Trace copper ion (Cu(II)) in water and wastewater can trigger peroxymonosulfate (PMS) activation to oxidize organic compounds, but it only works under... 相似文献
Carbon–silica materials with hierarchical pores consisting of micropores and mesopores were prepared by introducing nanocarbon microspheres derived from biomass sugar into silica gel channels in a hydrothermal environment.The physicochemical properties of the materials were characterized by nitrogen physical adsorption(BET),scanning electron microscopy(SEM),and thermogravimetric(TG),and the adsorption properties of various organic waste gases were investigated.The results showed that microporous carbon materials were introduced successfully into the silica gel channels,thus showing the high adsorption capacity of activated carbon in high humidity organic waste gas,and the high stability and mechanical strength of the silica gel.The dynamic adsorption behavior confirmed that the carbon–silica material had excellent adsorption capacity for different volatile organic compounds(VOCs).Furthermore,the carbon–silica material exhibited excellent desorption characteristics:adsorbed toluene was completely desorbed at 150℃,thereby showing superior regeneration characteristics.Both features were attributed to the formation of hierarchical pores. 相似文献
Inhaled atmospheric fine particulate matter(PM_(2.5)) includes soluble and insoluble fractions,and each fraction can interact with cells and cause adverse effects.PM_(2.5) samples were collected in Jinan,China,and the soluble and insoluble fractions were separated.According to physiochemical characterization,the soluble fraction mainly contains watersoluble ions and organic acids,and the insoluble fraction mainly contains kaolinite,calcium carbonate and some organic carbon.The interaction between PM_(2.5) and model cell membranes was examined with a quartz crystal microbalance with dissipation(QCM-D) to quantify PM_(2.5) attachment on membranes and membrane disruption.The cytotoxicity of the total PM_(2.5) and the soluble and insoluble fractions,was investigated.Negatively charged PM_(2.5) can adhere to the positively charged membranes and disrupt them.PM_(2.5)also adheres to negatively charged membranes but does not cause membrane rupture.Therefore,electrostatic repulsion does not prevent PM_(2.5) attachment,but electrostatic attraction induces remarkable membrane rupture.The human lung epithelial cell line A549 was used for cytotoxicity assessment.The detected membrane leakage,cellular swelling and blebbing indicated a cell necrosis process.Moreover,the insoluble PM_(2.5) fraction caused a higher cell mortality and more serious cell membrane damage than the soluble fraction.The levels of reactive oxygen species(ROS) enhanced by the two fractions were not significantly different.The findings provide more information to better understand the mechanism of PM_(2.5) cytotoxicity and the effect of PM_(2.5) solubility on cytotoxicity. 相似文献