首页 | 本学科首页   官方微博 | 高级检索  
文章检索
  按 检索   检索词:      
出版年份:   被引次数:   他引次数: 提示:输入*表示无穷大
  收费全文   3029篇
  免费   186篇
  国内免费   912篇
安全科学   265篇
废物处理   175篇
环保管理   244篇
综合类   1714篇
基础理论   470篇
污染及防治   655篇
评价与监测   207篇
社会与环境   216篇
灾害及防治   181篇
  2024年   8篇
  2023年   52篇
  2022年   174篇
  2021年   134篇
  2020年   128篇
  2019年   116篇
  2018年   157篇
  2017年   140篇
  2016年   118篇
  2015年   161篇
  2014年   232篇
  2013年   246篇
  2012年   226篇
  2011年   228篇
  2010年   212篇
  2009年   191篇
  2008年   177篇
  2007年   186篇
  2006年   160篇
  2005年   90篇
  2004年   124篇
  2003年   120篇
  2002年   145篇
  2001年   144篇
  2000年   115篇
  1999年   83篇
  1998年   57篇
  1997年   37篇
  1996年   41篇
  1995年   31篇
  1994年   29篇
  1993年   13篇
  1992年   6篇
  1991年   17篇
  1990年   4篇
  1989年   8篇
  1988年   5篇
  1987年   3篇
  1986年   1篇
  1984年   1篇
  1983年   2篇
  1982年   3篇
  1981年   1篇
  1976年   1篇
排序方式: 共有4127条查询结果,搜索用时 78 毫秒
1.
Environmental Science and Pollution Research - A mechanical harvesting technology based on coupling flocculation with a rotary drum filter (RDF, 35-μm) was applied to remove cyanobacterial...  相似文献   
2.
可持续旅游是 80年代中期以后提出的关于旅游业发展的新思想。经过十多年的不断拓展深化 ,已经得到世界各国的广泛认同 ,并作为跨世纪旅游业发展的战略指导思想。本文从可持续旅游的由来和对可持续旅游内涵实质的界定角度出发 ,结合可持续旅游实现途径的探讨 ,以井冈山风景名胜区为例 ,对风景区旅游业可持续发展进行了深入的探讨 ,为景区的发展规划提出了战略性构想 ,以期能对井冈山风景名胜区旅游资源的可持续利用和旅游业的可持续发展起到抛砖引玉的作用  相似文献   
3.
Urban agglomeration of the Yangtze Delta (UAYD), one of the most developed regions of China, has witnessed an increasing prevalence in building ecological cities when the ecological cities are pursued by many modem cities, and great achievements have been made in this regard. It is inevitable, however, that certain problems exist during the construction of ecological city, which include but not limited to non-harmonious development of urban complex ecosystem, and the difficulty in quantifying eco-city construction or incomplete quantification in assessing the construction of present and future eco-city. Based on the analysis on social-economic conditions and regional conditions of the UAYD, this paper attempts to set up an index system of eco-cities combining with local characteristics, and to adopt the indices of eco-city, urban harmony, and eco-city colligate to evaluate the ecological level, urban harmonious development and eco-city construction of cities within the UAYD. Results indicate that among 15 cities in UAYD, Suzhou City ranks the highest in terms of eco-city construction, whereas Nantong ranks relatively lower; sustainable eco-city construction is possible only when cities are developed in every respect of harmony.  相似文献   
4.
Pollution due to persistent pesticides is not a regional but a global problem. Organochlorine pesticides are persistent chemicals, stored and accumulated in the tissues of a wide variety of invertebrates and vertebrates including marine species. In the present study the organochlorine residues HCHs, DDTs and PCBs were measured in different trophic groups of birds (scavengers, inland piscivores, coastal piscivores, insectivores, granivores and omnivores) collected from Tamil Nadu Coast, India. The residue accumulation as a function of sex did not depict distinct variation. However, females had lower residue levels than males in terms of their mean weight and feeding habits. A continuous monitoring programme is recommended to establish the studied organisms as indicator species.  相似文献   
5.
Environment, Development and Sustainability - The recent growth of agriculture, industry and urban areas in Vietnam requires a large amount of water consumption as a production factor. This paper...  相似文献   
6.
有色可溶性有机物(CDOM)作为溶解性有机物的重要组分,影响着水体中污染物质的形态特征和迁移转化过程.本研究运用紫外-可见光谱技术(UV-vis)以及三维荧光光谱(EEMs)技术结合平行因子分析法(PARAFAC),对岗南水库自入库河口到坝前主库区四季演变过程中沉积物间隙水CDOM的分布、光谱特征以及来源进行解析.结果表明,岗南水库沉积物间隙水CDOM的相对浓度a_(254)、a_(260)、a_(280)和a_(355)存在显著的季节差异,并且相对浓度大小为夏季春季秋季冬季;沉积物间隙水CDOM的E2/E3、E3/E4、E4/E6以及S_R存在显著的季节差异,呈现冬季高夏季低的特征;秋冬季的E2/E3以及E3/E4明显高于春夏季,并且秋冬季的E3/E4大部分均大于3.5,表明秋冬季沉积物间隙水CDOM具有更小的分子量和更低的腐殖化程度;三维荧光光谱通过PARAFAC解析出3种组分,分别为类酪氨酸(C1)、短波类富里酸(C2)和降解的腐殖类物质(C3),并且3种荧光组分间具有显著的正相关性(P0.001);岗南水库沉积物间隙水的CDOM总荧光强度和各荧光组分荧光强度呈现显著的季节差异,总荧光强度以及各组分的荧光强度呈现春季的最高、秋冬季次之、夏季最低的分布特征;秋冬季各个荧光组分占比不存在显著差异,春夏季各个荧光组分占比不存在显著差异,秋冬季与春夏季各个荧光组分占比存在显著差异;秋冬季沉积物间隙水CDOM生物源指数(BIX)和荧光指数(FI)均高于春夏季,表明秋冬季CDOM的自生源强于春夏季,与腐殖程度指标(HIX)的结果相吻合;PCA结合Adonis分析显示沉积物间隙水CDOM的光谱特征呈现显著的季节差异(P0.001);并且组分C1、C2、C3以及水质参数[氨氮、硝氮、亚硝氮、溶解性总氮以及溶解性总磷]均有很好的线性回归方程.综上,通过对岗南水库沉积物间隙水CDOM光谱特征进行研究,可以为分析岗南水库有机物污染特征和水质管理提供技术支持.  相似文献   
7.
氨基改性生物炭负载纳米零价铁去除水中Cr(VI)   总被引:7,自引:3,他引:4  
以聚乙烯亚胺(PEI)为功能单体,玉米秸秆生物炭为载体,制备了氨基改性生物炭负载型纳米零价铁(nZVI@PEI-HBC),并利用扫描电镜(SEM)、红外光谱(FTIR)和X射线光电子能谱(XPS)等手段对材料进行了表征,分析了溶液pH、温度、材料投加量等因素对其去除Cr(VI)的影响及其去除机理.结果表明:在投加量为0.5 g·L-1,温度为20℃,pH值为5,Cr(VI)初始浓度为20 mg·L-1条件下,各材料对Cr(VI)的去除率大小为nZVI@PEI-HBC > nZVI > PEI-HBC > HBC.SEM显示nZVI颗粒较均匀地分散在生物炭表面,FTIR分析表明PEI改性后材料表面增加了氨基等重金属配位基团,这可能是nZVI@PEI-HBC去除Cr(VI)效果更好的原因.影响因素研究表明,材料具有较好稳定性,老化28 d后其Cr(VI)去除性能变化不大;酸性环境、升温、增大材料投加量均有利于nZVI@PEI-HBC对Cr(VI)的去除.机理研究发现,水中溶解氧加速了nZVI的腐蚀和Fe(II)的释放,促进Cr(VI)还原为Cr(III),然后通过共沉淀作用和氨基等基团的吸附作用被去除.  相似文献   
8.
张晓  胡春  张丽丽  石宝友 《环境科学学报》2020,40(11):3895-3904
采用醇助水热法制备了新型生物质炭修饰的α-FeOOH类芬顿催化剂(BC-FeOOH),并通过扫描电子显微镜(SEM)、透射电子显微镜(TEM)、X射线衍射(XRD)、傅里叶变换红外光谱(FTIR)对催化剂进行了表征,证明生物质炭(BC)成功引入到α-FeOOH中.以罗丹明B(RhB)为目标污染物,考察了BC修饰量、催化剂及H2O2投加量对其催化效率的影响.结果表明,BC的引入可以极大地提高FeOOH的类芬顿催化性能.在pH中性、催化剂投加量0.6 g·L-1、H2O2初始浓度10 mmol·L-1的条件下,BC-FeOOH(22.2% BC)对RhB的降解率可达到90%,重复利用5次活性仍可保持在80%左右,且铁离子溶出浓度仅为0.08 mg·L-1.进一步通过ESR在不同体系中的测试结果表明,BC的引入不仅可促进H2O2有效还原分解产生更多的羟基自由基(·OH),而且增强了催化剂与污染物RhB的相互作用,促使污染物失电子氧化降解,从而提高了FeOOH的催化活性及催化稳定性.  相似文献   
9.
To clarify the aerosol hygroscopic growth and optical properties of the Pearl River Delta(PRD)region,integrated observations were conducted in Heshan City of Guangdong Province from October 19 to November 17,2014.The concentrations and chemical compositions of PM_(2.5),aerosol optical properties and meteorological parameters were measured.The mean value of PM_(2.5) increased from less than 35(excellent) to 35-75 μg/m~3(good) and then to greater than 75 μg/m~3(pollution),corresponding to mean PM_(2.5) values of 24.9,51.2,and 93.3 μg/m~3,respectively.The aerosol scattering hygroscopic growth factor(f(RH = 80%)) values were 2.0,2.12,and 2.18 for the excellent,good,and pollution levels,respectively.The atmospheric extinction coefficient(σext)and the absorption coefficient of aerosols(σ_(ap)) increased,and the single scattering albedo(SSA)decreased from the excellent to the pollution levels.For different air mass sources,under excellent and good levels,the land air mass from northern Heshan had lower f(RH) and σ_(sp) values.In addition,the mixed aerosol from the sea and coastal cities had lower f(RH) and showed that the local sources of coastal cities have higher scattering characteristics in pollution periods.  相似文献   
10.
Silver nanoparticles(AgNPs) have been widely used in many fields,which raised concerns about potential threats to biological sewage treatment systems.In this study,the phosphorus removal performance,enzymatic activity and microbial population dynamics in constructed wetlands(CWs) were evaluated under a long-term exposure to Ag NPs(0,50,and 200 μg/L) for 450 days.Results have shown that Ag NPs inhibited the phosphorus removal efficiency in a short-term exposure,whereas caused no obviously negative effects from a long-term perspective.Moreover,in the coexisting CW system of Ag NPs and phosphorus,competition exhibited in the initial exposure phase,however,cooperation between them was observed in later phase.Enzymatic activity of acid-phosphatase at the moderate temperature(10–20°C) was visibly higher than that at the high temperature(20–30℃) and CWs with Ag NPs addition had no appreciable differences compared with the control.High-throughput sequencing results indicated that the microbial richness,diversity and composition of CWs were distinctly affected with the extension of exposure time at different Ag NPs levels.However,the phosphorus removal performance of CWs did not decline with the decrease of polyphosphate accumulating organisms(PAOs),which also confirmed that adsorption precipitation was the main way of phosphorus removal in CWs.The study suggested that Ag NPs and phosphorus could be removed synergistically in the coexistence system.This work has some reference for evaluating the influences of Ag NPs on the phosphorus removal and the interrelation between them in CWs.  相似文献   
设为首页 | 免责声明 | 关于勤云 | 加入收藏

Copyright©北京勤云科技发展有限公司  京ICP备09084417号