首页 | 本学科首页   官方微博 | 高级检索  
文章检索
  按 检索   检索词:      
出版年份:   被引次数:   他引次数: 提示:输入*表示无穷大
  收费全文   2839篇
  免费   126篇
  国内免费   1069篇
安全科学   220篇
废物处理   147篇
环保管理   197篇
综合类   1768篇
基础理论   444篇
污染及防治   892篇
评价与监测   124篇
社会与环境   110篇
灾害及防治   132篇
  2024年   4篇
  2023年   47篇
  2022年   131篇
  2021年   114篇
  2020年   90篇
  2019年   86篇
  2018年   98篇
  2017年   143篇
  2016年   118篇
  2015年   141篇
  2014年   226篇
  2013年   269篇
  2012年   227篇
  2011年   235篇
  2010年   204篇
  2009年   185篇
  2008年   190篇
  2007年   186篇
  2006年   161篇
  2005年   129篇
  2004年   85篇
  2003年   118篇
  2002年   86篇
  2001年   69篇
  2000年   84篇
  1999年   81篇
  1998年   67篇
  1997年   75篇
  1996年   93篇
  1995年   72篇
  1994年   60篇
  1993年   50篇
  1992年   38篇
  1991年   16篇
  1990年   19篇
  1989年   11篇
  1988年   3篇
  1987年   6篇
  1986年   5篇
  1985年   3篇
  1984年   3篇
  1983年   1篇
  1982年   3篇
  1981年   1篇
  1976年   1篇
排序方式: 共有4034条查询结果,搜索用时 15 毫秒
1.
Zhu  Rong  Wang  Shixin  Srinivasakannan  C.  Li  Shiwei  Yin  Shaohua  Zhang  Libo  Jiang  Xiaobin  Zhou  Guoli  Zhang  Ning 《Environmental Chemistry Letters》2023,21(3):1611-1626
Environmental Chemistry Letters - The demand for lithium is growing rapidly with the increase in electric vehicles, batteries and electronic equipments. Lithium can be extracted from brines, yet...  相似文献   
2.
Huang  Ying  Jiang  Qiongji  Yu  Xubiao  Gan  Huihui  Zhu  Xia  Fan  Siyi  Su  Yan  Xu  Zhirui  He  Cunrui 《Environmental science and pollution research international》2021,28(37):51251-51264
Environmental Science and Pollution Research - Trace copper ion (Cu(II)) in water and wastewater can trigger peroxymonosulfate (PMS) activation to oxidize organic compounds, but it only works under...  相似文献   
3.
生态足迹影响因子的定量分析   总被引:2,自引:0,他引:2  
人口的膨胀和人类工业化进程的加剧,使得人类向自然界获取越来越多的资源,同时向环境源源不断的输入废弃物,已经严重超过了自然生态系统的供给能力和环境容量,生态环境日益恶化,水土流失、草场退化、植被消亡、生物多样性锐减、全球变暖等情况已经严重到难以遏制的地步,危及到人类自身的生存。在和平与发展成为世界两大主题的今天,人们越来越关注可持续发展的问题。在现有资料的基础上,利用主成分分析方法,定量地讨论了中国各省(区市)1999年生态足迹大小与其影响因子间的关系。结果表明,生态足迹的大小是各省(区市)的大中型企业个数、全社会固定生产投资等众多因子共同作用的结果,其中总人口和GDP是生态足迹大小的主要影响因子,其因子载荷量分别达到了0.940和0.913。值得一提的是非农业人口与生态足迹的相关系数超过了农业人口,这说明由于消费模式和生活水平等的差异,非农业人口对生态足迹的影响大于农业人口对生态足迹的影响。在此基础上建立了生态足迹影响因子的多元线性回归模型,以期为生态足迹在进行区域可持续发展评价的方法上提供新的思路。  相似文献   
4.
Urban agglomeration of the Yangtze Delta (UAYD), one of the most developed regions of China, has witnessed an increasing prevalence in building ecological cities when the ecological cities are pursued by many modem cities, and great achievements have been made in this regard. It is inevitable, however, that certain problems exist during the construction of ecological city, which include but not limited to non-harmonious development of urban complex ecosystem, and the difficulty in quantifying eco-city construction or incomplete quantification in assessing the construction of present and future eco-city. Based on the analysis on social-economic conditions and regional conditions of the UAYD, this paper attempts to set up an index system of eco-cities combining with local characteristics, and to adopt the indices of eco-city, urban harmony, and eco-city colligate to evaluate the ecological level, urban harmonious development and eco-city construction of cities within the UAYD. Results indicate that among 15 cities in UAYD, Suzhou City ranks the highest in terms of eco-city construction, whereas Nantong ranks relatively lower; sustainable eco-city construction is possible only when cities are developed in every respect of harmony.  相似文献   
5.
江元汝  黄琼玉 《环境化学》1996,15(2):118-126
本文对用硫化亚铁处理含砷废水时,在气相、液相和固相中砷的形态进行了研究结果表明,在气相中无AaH3,但在As(V)废水的液相中有As(V)和As(Ⅲ)共同存在,在固相中有As(0),FeAsO4(FeAsO3),As2S3(As2S5)和吸附砷,砷的形态变化表明,硫化亚铁处理含砷废水能取得良好的效果,是沉淀、沉淀转化、氧化还原、吸附共沉淀和中和五种反应共同作用的结果。  相似文献   
6.
Five biochars derived from lotus seedpod(LSP) were applied to examine and compare the adsorption capacity of 17β-estradiol(E2) from aqueous solution.The effect of KOH activation and the order of activation steps on material properties were discussed.The effect of contact time,initial concentration,p H,ionic strength and humic acid on E2 adsorption were investigated in a batch adsorption process.Experimental results demonstrated that the pseudo second-order model fitted the experimental data best and that adsorption equilibrium was reached within 20 hr.The efficiency of E2 removal increased with increasing E2 concentration and decreased with the increase of ionic strength.E2 adsorption on LSP-derived biochar(BCs) was influenced little by humic acid,and slightly affected by the solution p H when its value ranged from 4.0 to 9.0,but considerably affected at p H 10.0.Low environmental temperature is favorable for E2 adsorption.Chemisorption,π–π interactions,monolayer adsorption and electrostatic interaction are the possible adsorption mechanisms.Comparative studies indicated that KOH activation and the order of activation steps had significant impacts on the material.Post-treated biochar exhibited better adsorption capacity for E2 than direct treated,pretreated,and raw LSP biochar.Pyrolyzed biochar at higher temperature improved E2 removal.The excellent performance of BCs in removing E2 suggested that BCs have potential in E2 treatment and that the biochar directly treated by KOH would be a good choice for the treatment of E2 in aqueous solution,with its advantages of good efficiency and simple technology.  相似文献   
7.
Inhaled atmospheric fine particulate matter(PM_(2.5)) includes soluble and insoluble fractions,and each fraction can interact with cells and cause adverse effects.PM_(2.5) samples were collected in Jinan,China,and the soluble and insoluble fractions were separated.According to physiochemical characterization,the soluble fraction mainly contains watersoluble ions and organic acids,and the insoluble fraction mainly contains kaolinite,calcium carbonate and some organic carbon.The interaction between PM_(2.5) and model cell membranes was examined with a quartz crystal microbalance with dissipation(QCM-D) to quantify PM_(2.5) attachment on membranes and membrane disruption.The cytotoxicity of the total PM_(2.5) and the soluble and insoluble fractions,was investigated.Negatively charged PM_(2.5) can adhere to the positively charged membranes and disrupt them.PM_(2.5)also adheres to negatively charged membranes but does not cause membrane rupture.Therefore,electrostatic repulsion does not prevent PM_(2.5) attachment,but electrostatic attraction induces remarkable membrane rupture.The human lung epithelial cell line A549 was used for cytotoxicity assessment.The detected membrane leakage,cellular swelling and blebbing indicated a cell necrosis process.Moreover,the insoluble PM_(2.5) fraction caused a higher cell mortality and more serious cell membrane damage than the soluble fraction.The levels of reactive oxygen species(ROS) enhanced by the two fractions were not significantly different.The findings provide more information to better understand the mechanism of PM_(2.5) cytotoxicity and the effect of PM_(2.5) solubility on cytotoxicity.  相似文献   
8.
Methylglyoxal(CH_3COCHO,MG),which is one of the most abundant α-dicarbonyl compounds in the atmosphere,has been reported as a major source of secondary organic aerosol(SOA).In this work,the reaction of MG with hydroxyl radicals was studied in a 500 L smog chamber at(293±3) K,atmospheric pressure,(18±2)% relative humidity,and under different NOx and SO_2.Particle size distribution was measured by using a scanning mobility particle sizer(SMPS) and the results showed that the addition of SO_2 can promote SOA formation,while different NOx concentrations have different influences on SOA production.High NOx suppressed the SOA formation,whereas the particle mass concentration,particle number concentration and particle geometric mean diameter increased with the increasing NOx concentration at low NOx concentration in the presence of SO_2.In addition,the products of the OH-initiated oxidation of MG and the functional groups of the particle phase in the MG/OH/SO_2 and MG/OH/NOx/SO_2 reaction systems were detected by gas chromatography mass spectrometry(GC-MS) and attenuated total reflection fourier transformed infrared spectroscopy(ATR-FTIR) analysis.Two products,glyoxylic acid and oxalic acid,were detected by GC-MS.The mechanism of the reaction of MG and OH radicals that follows two main pathways,H atom abstraction and hydration,is proposed.Evidence is provided for the formation of organic nitrates and organic sulfate in particle phase from IR spectra.Incorporation of NOx and SO_2 influence suggested that SOA formation from anthropogenic hydrocarbons may be more efficient in polluted environment.  相似文献   
9.
为研究近年来福建省SO2污染的时空动态特征,利用臭氧观测仪(ozone monitoring instrument,OMI)卫星遥感反演的PBL(planetary boundary layer,大气边界层)SO2柱含量数据,分析了2005-2017年福建省PBL SO2柱含量的时空间分布特征.结果表明:①在长时间尺度上,PBL SO2柱含量的变化趋势可分为2个时段,其中,2005-2011年PBL SO2柱含量呈逐渐上升趋势,6 a增加了约0.027 DU,增长率约为6.12%;2011-2017年PBL SO2柱含量呈下降趋势,7 a减少了约0.018 DU,下降率约为3.89%.②PBL SO2柱含量呈明显的周期性变化特征,最小值和最大值分别出现在6月和12月,多年平均值分别约为0.383和0.555 DU.③PBL SO2柱含量的3个高值区分别出现在沿海的福州市,厦门市、漳州市东部和泉州市西部,三明市和南平市部分地区,这3个高值区多年平均PBL SO2柱含量分别约为0.505、0.495和0.485 DU.从城市尺度上来看,PBL SO2柱含量最大值出现在厦门市,其多年平均值为(0.486±0.015)DU;其次为福州市,PBL SO2柱含量多年平均值为(0.465±0.026)DU;最低值出现在漳州市,PBL SO2柱含量多年平均值为(0.429±0.020)DU.④福建省PBL SO2柱含量变化趋势在空间分布上存在明显的差异,不同时期、不同区域变化趋势不一致.2005-2011年PBL SO2柱含量的变化范围为-0.13~0.18 DU,变化率范围为-25%~50%,PBL SO2柱含量出现增长的区域主要是在高值区,如龙岩市西部、厦门市北部以及三明市东部等区域;2011-2017年PBL SO2柱含量的变化范围为-0.13~0.15 DU,变化率范围为-29%~34%.2011-2017年福州市和厦门市PBL SO2柱含量下降最为明显,减少了约0.10 DU,下降率约为25%.研究显示,卫星遥感估算的PBL SO2柱含量具有一定的可靠性,可以用于区域SO2污染的研究.   相似文献   
10.
人工智能技术对长江流域水污染治理的思考   总被引:1,自引:0,他引:1       下载免费PDF全文
随着经济的快速发展和城市化进程的不断加速,促使水污染严重的长江流域需从污染物去除过程的建模与优化、污水处理过程的优化控制、水污染监测系统的构建开展水污染治理研究.传统的水污染处理技术存在污染物去除效率预测精度较低、污水优化控制成本较高、水污染监测滞后效应严重的问题.人工智能技术能够有效克服上述问题,因此通过梳理国内外学者利用人工智能技术在污水污染物去除过程的建模与优化、污水处理过程的优化控制及水污染监测系统的构建等方面的研究成果,为全面加强长江流域水污染治理能力提供科学可靠的技术指导.结果表明:①利用人工神经网络技术(径向基神经网络、多层前馈网络-人工神经网络、多层感知器神经网络)对污水污染物去除过程进行建模与优化,为精确预测长江流域重金属(Cr、Cu)、营养盐(TN、TP)、持久性有机污染物〔PBDEs(多溴二苯醚)、HCH(六氯环己烷)〕的去除率提供重要参考价值.②采用污水处理的自动控制技术与人工智能技术(递归神经网络、支持向量机、模糊神经网络等)构建污水智能控制系统,为长江流域实现高效节能的污水优化控制提供重要的技术指导.③利用在线监测仪器和人工智能技术(小波神经网络、多元线性回归-人工神经网络、叠层去噪自动编码器等)建立水污染智能监测系统,为解决长江流域水污染监测响应滞后问题提供有力的技术支持.因此,人工智能技术对长江流域提高污水污染物去除率,降低污水优化控制成本,提升水污染监测时效性具有重要的推广价值.   相似文献   
设为首页 | 免责声明 | 关于勤云 | 加入收藏

Copyright©北京勤云科技发展有限公司  京ICP备09084417号