首页 | 本学科首页   官方微博 | 高级检索  
文章检索
  按 检索   检索词:      
出版年份:   被引次数:   他引次数: 提示:输入*表示无穷大
  收费全文   3481篇
  免费   220篇
  国内免费   1339篇
安全科学   302篇
废物处理   168篇
环保管理   263篇
综合类   2304篇
基础理论   559篇
污染及防治   983篇
评价与监测   181篇
社会与环境   138篇
灾害及防治   142篇
  2024年   15篇
  2023年   76篇
  2022年   206篇
  2021年   168篇
  2020年   157篇
  2019年   132篇
  2018年   133篇
  2017年   189篇
  2016年   156篇
  2015年   201篇
  2014年   263篇
  2013年   359篇
  2012年   286篇
  2011年   298篇
  2010年   264篇
  2009年   232篇
  2008年   238篇
  2007年   209篇
  2006年   191篇
  2005年   151篇
  2004年   91篇
  2003年   128篇
  2002年   104篇
  2001年   75篇
  2000年   92篇
  1999年   88篇
  1998年   70篇
  1997年   79篇
  1996年   91篇
  1995年   71篇
  1994年   58篇
  1993年   53篇
  1992年   41篇
  1991年   16篇
  1990年   19篇
  1989年   11篇
  1988年   4篇
  1987年   5篇
  1986年   5篇
  1985年   3篇
  1984年   5篇
  1983年   1篇
  1982年   3篇
  1981年   1篇
  1978年   1篇
  1976年   1篇
排序方式: 共有5040条查询结果,搜索用时 46 毫秒
1.
Zhu  Rong  Wang  Shixin  Srinivasakannan  C.  Li  Shiwei  Yin  Shaohua  Zhang  Libo  Jiang  Xiaobin  Zhou  Guoli  Zhang  Ning 《Environmental Chemistry Letters》2023,21(3):1611-1626
Environmental Chemistry Letters - The demand for lithium is growing rapidly with the increase in electric vehicles, batteries and electronic equipments. Lithium can be extracted from brines, yet...  相似文献   
2.
Huang  Ying  Jiang  Qiongji  Yu  Xubiao  Gan  Huihui  Zhu  Xia  Fan  Siyi  Su  Yan  Xu  Zhirui  He  Cunrui 《Environmental science and pollution research international》2021,28(37):51251-51264
Environmental Science and Pollution Research - Trace copper ion (Cu(II)) in water and wastewater can trigger peroxymonosulfate (PMS) activation to oxidize organic compounds, but it only works under...  相似文献   
3.
生态足迹影响因子的定量分析   总被引:2,自引:0,他引:2  
人口的膨胀和人类工业化进程的加剧,使得人类向自然界获取越来越多的资源,同时向环境源源不断的输入废弃物,已经严重超过了自然生态系统的供给能力和环境容量,生态环境日益恶化,水土流失、草场退化、植被消亡、生物多样性锐减、全球变暖等情况已经严重到难以遏制的地步,危及到人类自身的生存。在和平与发展成为世界两大主题的今天,人们越来越关注可持续发展的问题。在现有资料的基础上,利用主成分分析方法,定量地讨论了中国各省(区市)1999年生态足迹大小与其影响因子间的关系。结果表明,生态足迹的大小是各省(区市)的大中型企业个数、全社会固定生产投资等众多因子共同作用的结果,其中总人口和GDP是生态足迹大小的主要影响因子,其因子载荷量分别达到了0.940和0.913。值得一提的是非农业人口与生态足迹的相关系数超过了农业人口,这说明由于消费模式和生活水平等的差异,非农业人口对生态足迹的影响大于农业人口对生态足迹的影响。在此基础上建立了生态足迹影响因子的多元线性回归模型,以期为生态足迹在进行区域可持续发展评价的方法上提供新的思路。  相似文献   
4.
Urban agglomeration of the Yangtze Delta (UAYD), one of the most developed regions of China, has witnessed an increasing prevalence in building ecological cities when the ecological cities are pursued by many modem cities, and great achievements have been made in this regard. It is inevitable, however, that certain problems exist during the construction of ecological city, which include but not limited to non-harmonious development of urban complex ecosystem, and the difficulty in quantifying eco-city construction or incomplete quantification in assessing the construction of present and future eco-city. Based on the analysis on social-economic conditions and regional conditions of the UAYD, this paper attempts to set up an index system of eco-cities combining with local characteristics, and to adopt the indices of eco-city, urban harmony, and eco-city colligate to evaluate the ecological level, urban harmonious development and eco-city construction of cities within the UAYD. Results indicate that among 15 cities in UAYD, Suzhou City ranks the highest in terms of eco-city construction, whereas Nantong ranks relatively lower; sustainable eco-city construction is possible only when cities are developed in every respect of harmony.  相似文献   
5.
本文应用灰色关联分析方法研究了青岛地区主导工业对资源的依赖状态及不同工业行业之产出对各类资源投入的反应程度,以灰关联树反映工业经济与资源复合系统之整体及不同层次子系统的耦合关系,定量揭示工业经济效益主导变量与各类资源变量的动态联系,从资源高效利用的角度探讨了青岛工业产业结构调整和优化的方向及区域经济与环境效益相协调的可能途径。  相似文献   
6.
江元汝  黄琼玉 《环境化学》1996,15(2):118-126
本文对用硫化亚铁处理含砷废水时,在气相、液相和固相中砷的形态进行了研究结果表明,在气相中无AaH3,但在As(V)废水的液相中有As(V)和As(Ⅲ)共同存在,在固相中有As(0),FeAsO4(FeAsO3),As2S3(As2S5)和吸附砷,砷的形态变化表明,硫化亚铁处理含砷废水能取得良好的效果,是沉淀、沉淀转化、氧化还原、吸附共沉淀和中和五种反应共同作用的结果。  相似文献   
7.
通过紫外吸收光谱(UV-vis)和三维荧光光谱(3D-EEMs),研究典型富营养化湖泊巢湖沉积物溶解性有机质(DOM)光谱时空分布特征.结果表明,巢湖表层沉积物DOM的a(254)含量为13.1~101.7 m-1,平均值为(32.2±16.2)m-1.其中,夏季沉积物a(254)的含量((46.6±25.6)m-1)要显著高于其它季节,且湖心区a(254)平均值和变异性均小于湖滨区.表层沉积物DOM的S275~295值从春季到冬季上随时间呈明显上升趋势.沉积物DOM荧光强度在夏季最高,在垂直剖面上总体呈下降趋势.DOM组分以酪氨酸类蛋白质和溶解性微生物产物为主,各组分在空间分布上无明显差异.巢湖沉积物DOM荧光指数(FI)为2.56~4.89,腐殖化指数(HIX)为0.57~6.78,生物源指数(BIX)为0.31~1.54.巢湖沉积物DOM主要来自于生物源,藻的生长循环会显著影响富营养化湖泊沉积物DOM的来源和性质.  相似文献   
8.
Five biochars derived from lotus seedpod(LSP) were applied to examine and compare the adsorption capacity of 17β-estradiol(E2) from aqueous solution.The effect of KOH activation and the order of activation steps on material properties were discussed.The effect of contact time,initial concentration,p H,ionic strength and humic acid on E2 adsorption were investigated in a batch adsorption process.Experimental results demonstrated that the pseudo second-order model fitted the experimental data best and that adsorption equilibrium was reached within 20 hr.The efficiency of E2 removal increased with increasing E2 concentration and decreased with the increase of ionic strength.E2 adsorption on LSP-derived biochar(BCs) was influenced little by humic acid,and slightly affected by the solution p H when its value ranged from 4.0 to 9.0,but considerably affected at p H 10.0.Low environmental temperature is favorable for E2 adsorption.Chemisorption,π–π interactions,monolayer adsorption and electrostatic interaction are the possible adsorption mechanisms.Comparative studies indicated that KOH activation and the order of activation steps had significant impacts on the material.Post-treated biochar exhibited better adsorption capacity for E2 than direct treated,pretreated,and raw LSP biochar.Pyrolyzed biochar at higher temperature improved E2 removal.The excellent performance of BCs in removing E2 suggested that BCs have potential in E2 treatment and that the biochar directly treated by KOH would be a good choice for the treatment of E2 in aqueous solution,with its advantages of good efficiency and simple technology.  相似文献   
9.
Inhaled atmospheric fine particulate matter(PM_(2.5)) includes soluble and insoluble fractions,and each fraction can interact with cells and cause adverse effects.PM_(2.5) samples were collected in Jinan,China,and the soluble and insoluble fractions were separated.According to physiochemical characterization,the soluble fraction mainly contains watersoluble ions and organic acids,and the insoluble fraction mainly contains kaolinite,calcium carbonate and some organic carbon.The interaction between PM_(2.5) and model cell membranes was examined with a quartz crystal microbalance with dissipation(QCM-D) to quantify PM_(2.5) attachment on membranes and membrane disruption.The cytotoxicity of the total PM_(2.5) and the soluble and insoluble fractions,was investigated.Negatively charged PM_(2.5) can adhere to the positively charged membranes and disrupt them.PM_(2.5)also adheres to negatively charged membranes but does not cause membrane rupture.Therefore,electrostatic repulsion does not prevent PM_(2.5) attachment,but electrostatic attraction induces remarkable membrane rupture.The human lung epithelial cell line A549 was used for cytotoxicity assessment.The detected membrane leakage,cellular swelling and blebbing indicated a cell necrosis process.Moreover,the insoluble PM_(2.5) fraction caused a higher cell mortality and more serious cell membrane damage than the soluble fraction.The levels of reactive oxygen species(ROS) enhanced by the two fractions were not significantly different.The findings provide more information to better understand the mechanism of PM_(2.5) cytotoxicity and the effect of PM_(2.5) solubility on cytotoxicity.  相似文献   
10.
Methylglyoxal(CH_3COCHO,MG),which is one of the most abundant α-dicarbonyl compounds in the atmosphere,has been reported as a major source of secondary organic aerosol(SOA).In this work,the reaction of MG with hydroxyl radicals was studied in a 500 L smog chamber at(293±3) K,atmospheric pressure,(18±2)% relative humidity,and under different NOx and SO_2.Particle size distribution was measured by using a scanning mobility particle sizer(SMPS) and the results showed that the addition of SO_2 can promote SOA formation,while different NOx concentrations have different influences on SOA production.High NOx suppressed the SOA formation,whereas the particle mass concentration,particle number concentration and particle geometric mean diameter increased with the increasing NOx concentration at low NOx concentration in the presence of SO_2.In addition,the products of the OH-initiated oxidation of MG and the functional groups of the particle phase in the MG/OH/SO_2 and MG/OH/NOx/SO_2 reaction systems were detected by gas chromatography mass spectrometry(GC-MS) and attenuated total reflection fourier transformed infrared spectroscopy(ATR-FTIR) analysis.Two products,glyoxylic acid and oxalic acid,were detected by GC-MS.The mechanism of the reaction of MG and OH radicals that follows two main pathways,H atom abstraction and hydration,is proposed.Evidence is provided for the formation of organic nitrates and organic sulfate in particle phase from IR spectra.Incorporation of NOx and SO_2 influence suggested that SOA formation from anthropogenic hydrocarbons may be more efficient in polluted environment.  相似文献   
设为首页 | 免责声明 | 关于勤云 | 加入收藏

Copyright©北京勤云科技发展有限公司  京ICP备09084417号