湿式电除尘器伏安特性的实验研究

伏安特性是分析电除尘放电特性和运行状况的基本方法。深入研究电除尘伏安特性,有助于提高除尘效率,为微细颗粒物控制提供了理论基础。实验研究了不同电场风速、雾滴粒径和喷水量下湿式电除尘的伏安特性。结果表明:当电场风速为1.0～1.2m/s、喷嘴压力为0.3～0.4MPa、喷水流量为0.24m3/h,湿式电除尘器处于最佳工作状态,通过对该状态下的除尘效率的测定,验证了该参数组合的正确性。     

湿式电除尘器极配改进及性能测定

极配形式作为电除尘器的核心组成部分,对电晕放电特性的影响十分重要。电除尘器极配系统电晕放电性能可用伏安特性曲线来描述和判断。通过实验研究了电场风速、雾滴粒径和喷水量对湿式电除尘器电晕放电特性的影响。结果表明:电场风速对起晕电压和火花放电电压的影响不大;在相同的试验条件下,随着电场风速的增大,伏安特性曲线向下偏移;在相同的电压下,雾滴粒径越大,电晕电流越大,但火花放电电压却降低;在一定的电场风速下,随着喷水量的增大,伏安特性曲线有向上偏移的趋势,但火花放电电压比不喷水时要低得多。     

板式电除尘器多物理场耦合数值分析

为理解电除尘器除尘机理,文章采用Fluent软件对实验室板式电除尘器进行仿真模拟,分析了多场耦合作用下流体流动特性和粉尘运动过程。电场特性考虑了电晕放电过程,并研究了电流体动力学(EHD)流对流场的影响。结果显示:电晕放电后阴极线附近形成电晕区,电势在两电极间形成了一个交联的等势场,阴极线之间电场强度迅速减弱,连线中点处形成一个黑影区,电场强度几乎为零;在低流速下EHD流改变了流体湍流运动,当电场断面风速增加到1 m/s时,EHD流的影响可以忽略;在湍流扩散的影响下,粉尘运动距离增加,湍流剧烈;当电场断面风速越小、粒径越大、施加电压越大时,除尘效率越高,对粒径为6.9μm的粉尘最大捕集效率可以达到99.4%。     

电除尘器中水雾雾化特性及对除尘性能的影响

湿式电除尘器将水雾除尘与电除尘技术相结合,可以有效地对细颗粒物进行收集,抑制了二次扬尘的发生。通过研究电除尘器喷淋系统的雾化特性,以及不同供水压力对水雾荷电的影响,并测得其分级效率。研究结果表明:在供水压力为0.4 MPa时,湿式电除尘器的除尘效率大于99.5%;在喷雾粒径为100μm时,对10μm以下的细颗粒物除尘效率大于92%。通过分析,为湿式除尘器喷淋系统设计提供了依据。     

长芒刺电除尘器性能研究

提出一种新型长芒刺电除尘器,理论与实验研究结果表明,长芒刺电除尘器的场强、伏安特性和除尘效率等性能均高于普通线板式电除尘器。     

烟气温度对电除尘器性能影响的数值模拟

采用计算流体动力学（CFD）软件对电除尘器进行三维数值模拟研究,通过自定义函数（UDF）实现电场、流场、颗粒场和温度场的4场耦合,研究烟气温度对电除尘器电场特性、流场特性和除尘效率的影响.结果显示：入口烟气质量流量相同时,当烟气温度从20℃上升到400℃时,平均电场强度从4.9×10⁵V/m减小到1.4×10⁵V/m,平均板电流密度从0.971mA/m²降至0.261mA/m²,但板电流密度分布的均匀性逐渐变好;烟气温度上升平均湍流强减小,离子风效应也随之减小.当入口烟气体积流量相同时,随着烟气温度的增加,颗粒运动轨迹线拉长,整体的颗粒捕集效率减低.降低烟气温度可以有效提高电除尘器的除尘效率.     

电除尘器对高比电阻粉尘收集的研究

电除尘器收集高比电阻粉尘易产生反电晕,除尘效率较低。通过增湿降低比电阻,调节风速、电压改善除尘器性能。研究表明:实验设备在风速为0.27m/s,电压为65kV,含湿量为3%时,除尘效率最高达到99.7%。     

湿式电除尘器用于生物质气化燃气除尘的实验研究

生物质粉尘是生物质气化燃气中主要的杂质之一,其清除效果对生物质气化发电机组的安全运行有着重要的影响。以湿式电除尘装置作为试验平台,研究了生物质粉尘的特性和不同影响因素下湿式电除尘器的除尘效率,并对干法、湿法除尘效率进行对比。研究结果表明:生物质粉尘主要含C、O、Mg、Al、Si、K、Ca、Fe等元素,中位径为26.05μm。在相同条件下,除尘效率随着水压的增大而逐渐增大,当增加到0.4 MPa以后,无较大变化,除尘效率随着电场风速、焦油浓度的增加而减少,在洗涤水中添加少量的碱液有利于除尘。采用极配型式为RS二刺芒刺线配480C型板,当水压为0.4 MPa、电场风速为1.0 m/s,除尘效率可达99.21%。     

表面活性剂协同荷电水雾增效除尘实验研究

为研究湿式电除尘效率和应用范围的拓展特性,设计了针对铁矿粉尘的表面活性剂协同荷电水雾除尘实验装置,采用表面活性剂增效润湿、水膜捕尘、荷电捕尘理论,探究了风速、电压、喷雾压力和格栅目数对除尘性能的影响.实验中优选复配表面活性剂溶液,选取了0.3%LAB SA/0.5%X-100、0.3%LAB SA/0.5%AES、0.5%X-100/0.5%AES三种复配溶液进行荷电水雾除尘实验.结果表明:复合电除尘可以在提高处理风量的同时增加除尘效率,风速在0.8m/s以前与除尘效率正相关;复配溶液在水压为6MPa时都达到除尘效率最大,其中以0.3%LABSA/0.5%AES表现最为突出,其除尘效率相较于水提升达到15.36%,不同水压的平均除尘效率提高也达到了11.73%;复合电除尘除尘效率与电压在40kV之前正相关,超过后会发生电晕放电,降低除尘效率;当格栅孔径大小为40目时除尘效率最大,其中复配溶液0.3%LABSA/0.5%AES达到了96.74%的除尘效率,继续减小孔径反而会减小除尘效率;对粉尘润湿性越强的表面活性剂参与除尘后对除尘效率提升越大.     

宽间距电除尘器在回转烘干机上的应用

宽间距电除尘器是我国“七五”期间开发的高效除尘设备。它优于常规电除尘器,适应粉尘浓度大、比电阻高的烟尘,可捕集10~1～10~4(Ω·cm)的粉尘微粒。当粉尘比电阻为10~(11)(Ω·cm)时,单机除尘效率大于99％,对于0.01μm的粉尘微粒,除尘效率可达90～98％。该种除尘器首次在韶钢应用,取得很好的环境和经济效益。     

EDTA-enhanced phytoremediation of lead contaminated soil by Bidens maximowicziana

Phytoremediation is a potential cleanup technology for the removal of heavy metals from contaminated soils.Bidens maximowicziana is a new Pb hyperaccumulator,which not only has remarkable tolerance to Pb but also extraordinary accumulation capacity for Pb.The maximum Pb concentration was 1509.3 mg/kg in roots and 2164.7 mg/kg in overground tissues.The Pb distribution order in the B. maximowicziana was:leaf>stem>root.The effect of amendments on phytoremediation was also studied.The mobility of soil Pb and the Pb concentrations in plants were both increased by EDTA application.Compared with CK(control check),EDTA application promoted translocation of Pb to overground parts of the plant.The Pb concentrations in overground parts of plants was increased from 24.23-680.56 mg/kg to 29.07-1905.57 mg/kg.This research demonstrated that B.maximowicziana appeared to be suitable for phytoremediation of Pb contaminated soil,especially,combination with EDTA.     

Distribution and ecological effect of mercury in Laogang landfill, Shanghai, China

Laogang landfill near Shanghai is the largest landfill in China, and receives about 10000 t of daily garbage per day, Samples of topsoil and plants were analyzed to evaluate mercury pollution from the landfill. For topsoil samples, there were significant correlations among total mercury （HgT）, combinative mercury （Hgc） and gaseous mercury （HgG）, and content of total organic carbon （TOC）, but, no significantly relationship was found between Hg content and filling time. Hg content changes in vertical profiles with time showed that the average Hgv of profiles 1992, 1996, and 2000 was similar, but their average HgG was quite different. HgT was significantly correlated with Hgc in profile 1992 and 2000, and Hgv was significantly correlated with Hg6 in profile 1996. HgG/Hgv ratio in profile samples decreased in the order of （HgG,/HgT）1992〉（HgG/HgT）1996〉〉（HgG/HgT）2000. A simple outline of Hg release in landfill could be drawn： with increasing of filling time, degradation undergoes different biodegradation, accordingly, gaseous mercury goes through small, more, and small proportion to total mercury. Distribution of Hg in plants was inhomogeneous, following the order of leaf〉root〉stem. The highest value of leaf may be associated with higher atmospheric Hg from landfill. Ligneous plants （e.g. Phyllostachys glanca, Prunus salicina and Ligustrum lucidum） are capable of enriching more Hg than herbaceous plants.     

Toxic effects of acetochlor, methamidophos and their combination on nifH gene in soil

Toxic effects of two agrochemicals on nifH gene in agricultural black soil were investigated using denaturing gradient gel electrophoresis （DGGE） and sequencing approaches in a microcosm experiment. Changes of soil nifH gene diversity and composition were examined following the application of acetochlor, methamidophos and their combination. Acetochlor reduced the nifH gene diversity （both in gene richness and diversity index values） and caused changes in the nifH gene composition. The effects of acetochlor on nifH gene were strengthened as the concentration of acetochlor increased. Cluster analysis of DGGE banding patterns showed that nifH gene composition which had been affected by low concentration of acetochlor （50 mg/kg） recovered firstly. Methamidophos reduced nifH gene richness that except at 4 weeks. The medium concentration of methamidophos （150 mg/kg） caused the most apparent changes in nifH gene diversity at the first week while the high concentration of methamidophos （250 mg/kg） produced prominent effects on nifH gene diversity in the following weeks. Cluster analysis showed that minimal changes of nifH gene composition were found at 1 week and maximal changes at 4 weeks. Toxic effects of acetochlor and methamidophos combination on nifH gene were also apparent. Different nifH genes （bands） responded differently to the impact of agrochemicals： four individual bands were eliminated by the application of the agrochemicals, five bands became predominant by the stimulation of the agrochemicals, and four bands showed strong resistance to the influence of the agrochemicals. Fifteen prominent bands were partially sequenced, yielding 15 different nifH sequences, which were used for phylogenetic reconstructions. All sequences were affiliated with the alpha- and beta-proteobacteria, showing higher similarity to eight different diazotrophic genera.     

Enzymatic oxidation of aqueous pentachlorophenol

The influence of the nonionic surfactant Tween 80 on pentachlorophenol （PCP） oxidation catalyzed by horseradish peroxidase was studied. The surfactant was tested at concentrations below and above its critical micelle concentration （CMC）. Enhancement of PCP removal was observed at sub-CMCs. The presence of Tween 80 in the reaction mixture reduced enzyme inactivation which occurred through a combination of free radical attack and sorption by precipitated products. A simple first-order model was able to simulate time profiles for enzyme inactivation in the presence or absence of Tween 80. At supra-CMCs, the surfactant caused noticeable reductions in PCP removal, presumably through micelle partitioning of PCP which precluded the hydrophobic PCP molecule from interacting with the enzyme.     

Decomposition of alachlor by ozonation and its mechanism

Decomposition and corresponding mechanism of alachlor, an endocrine disruptor in water by ozonation were investigated. Results showed that alachlor could not be completely mineralized by ozone alone. Many intermediates and final products were formed during the process, including aromatic compounds, aliphatic carboxylic acids, and inorganic ions. In evoluting these products, some of them with weak polarity were qualitatively identified by GC-MS. The information of inorganic ions suggested that the dechlorination was the first and the fastest step in the ozonation of alachlor.     

Arsenic uptake by arbuscular mycorrhizal maize （Zea mays L.） grown in an arsenic-contaminated soil with added phosphorus

The effects of arbuscular mycorrhizal (AM) fungus (Glomus mosseae) and phosphorus (P) addition (100 mg/kg soil) on arsenic (As) uptake by maize plants (Zea mays L.) from an As-contaminated soil were examined in a glasshouse experiment.Non-mycorrhizal and zero-P addition controls were included.Plant biomass and concentrations and uptake of As,P,and other nutrients,AM colonization,root lengths,and hyphal length densities were determined.The results indicated that addition of P significantly inhibited root colonization and development of extraradical mycelium.Root length and dry weight both increased markedly with mycorrhizal colonization under the zero-P treatments,but shoot and root biomass of AM plants was depressed by P application.AM fungal inoculation decreased shoot As concentrations when no P was added,and shoot and root As concentrations of AM plants increased 2.6 and 1.4 times with P addition,respectively.Shoot and root uptake of P,Mn,Cu,and Zn increased,but shoot Fe uptake decreased by 44.6%,with inoculation, when P was added.P addition reduced shoot P,Fe,Mn,Cu,and Zn uptake of AM plants,but increased root Fe and Mn uptake of the nonmycorrhizal ones.AM colonization therefore appeared to enhance plant tolerance to As in low P soil,and have some potential for the phytostabilization of As-contaminated soil,however,P application may introduce additional environmental risk by increasing soil As mobility.     

Degradation of metabolites accumulated of benzo[a]pyrene by coupling Penicillium Chrysogenum with KMnO4

Several main metabolites of benzo[a]pyrene （BaP） formed by Penicillium chrysogenum, Benzo[a]pyrene-1,6-quinone （BP 1,6- quinone）, trans-7,8-dihydroxy-7,8-dihydrobenzo[a]pyrene （BP 7,8-diol）, 3-hydroxybenzo[a]pyrene （3-OHBP）, were identified by high-performance liquid chromatography （HPLC）. The three metabolites were liable to be accumulated and were hardly further metabolized because of their toxicity to microorganisms. However, their further degradation was essential for the complete degradation of BaP. To enhance their degradation, two methods, degradation by coupling Penicillium chrysogenum with KMnO4 and degradation only by Penicillium chrysogenum, were compared; Meanwhile, the parameters of degradation in the superior method were optimized. The results showed that （1） the method of coupling Penicillium chrysogenum with KMnO4 was better and was the first method to be used in the degradation of BaP and its metabolites; （2） the metabolite, BP 1,6-quinone was the most liable to be accumulated in pure cultures; （3） the effect of degradation was the best when the concentration of KMnO4 in the cultures was 0.01% （w/v）, concentration of the three compounds was 5 mg/L and pH was 6.2. Based on the experimental results, a novel concept with regard to the bioremediation of BaP-contaminated environment was discussed, considering the influence on environmental toxicity of the accumulated metabolites.     

Impact of atrazine and nitrogen fertilizers on the sorption of chlorotoluron in soil and model sorbents

Sorption of chlorotoluron in ammonium sulfate, urea and atrazine multi-solutes system was investigated by batch experiments. The results showed application of nitrogen fertilizers to the soil could affect the behavior of chlorotoluron. At the same concentration of N, sorption of chlorotoluron decreased as the concentration of atrazine increased on the day 0 and 6 in soil, respectively. The sorption of chlorotoluron increased from 0 to 6 d when soils were preincubated with deionized water, ammonium sulfate and urea solution for 6 d. That indicated incubation time was one of the most important factors for the sorption of chlorotoluron in nitrogen fertilizers treatments. The individual sorption isotherms of chlorotoluron in rubbery polymer and silica were strictly linear in single solute system, but there were competition sorption between pesticides or between pesticides and nitrogen fertilizers. That indicated the sorption taken place by concurrent solid-phase dissolution mechanism and sorption on the interface of water-organic matter or water-mineral matter.     

基于综合水质标识指数和对应分析法的校园河道水质评价

以三峡大学的校园河道求索溪为研究对象,利用综合水质标识指数法确定求索溪水质类别,分析其水质时空变化规律,并利用对应分析法得出求索溪中不同监测点的主要污染因子.研究结果表明:求索溪整体的综合水质标识指数为7.423,整体水质为劣V类(地表水环境质量标准GB 3838-2002)且黑臭.从时间变化来看,求索溪4月份的水质最差,5月份次之,4、5月份所有监测点的水质都劣于V类且黑臭;8月份水质最好,水质为Ⅳ类;从空间分布来看,8个监测点综合水质标识指数均超过6.0,水质为劣V类,其中6号监测点的水质相对最好,监测点3号的水质相对最差;对应分析法得出求索溪的整体水体污染程度受总氮因子的影响最大,其次为总磷.该研究拟为求索溪及类似校园河道的水环境治理研究提供基础依据和参考.     

Effects of chitosan on growth of an aquatic plant (Hydrilla verticillata) in polluted waters with different chemical oxygen demands

Effects of chitosan on a submersed plant, Hydrilla verticillata, were investigated. Results indicated that H. venicillata could prevent ultrastructure phytotoxicities and oxidativereaction from polluted water with high chemical oxygen demand (COD). Superoxide dismutase (SOD) activity and malondialdehyde (MDA) contents in H. verticillata treated with 0.1% chitosan in wastewater increased with high COD (980 mg/L) and decreased with low COD (63 mg/L), respectively. Ultrastructural analysis showed that the stroma and grana of chloroplast basically remained normal. However, plant cells from the control experiment (untreated with chitosan) were vacuolated and the cell interval increased. The relict of protoplast moved to the center, with cells tending to disjoint. Our findings indicate that wastewater with high COD concentration can cause a substantial damage to submersed plant, nevertheless, chitosan probably could alleviate the membrane lipid peroxidization and ultrastructure phytotoxicities, and protect plant cells from stress of high COD concentration polluted water.