Mass,energy and material balances of SRF production process. Part 2: SRF produced from construction and demolition waste

In this work, the fraction of construction and demolition waste (C&D waste) complicated and economically not feasible to sort out for recycling purposes is used to produce solid recovered fuel (SRF) through mechanical treatment (MT). The paper presents the mass, energy and material balances of this SRF production process. All the process streams (input and output) produced in MT waste sorting plant to produce SRF from C&D waste are sampled and treated according to CEN standard methods for SRF. Proximate and ultimate analysis of these streams is performed and their composition is determined. Based on this analysis and composition of process streams their mass, energy and material balances are established for SRF production process. By mass balance means the overall mass flow of input waste material stream in the various output streams and material balances mean the mass flow of components of input waste material stream (such as paper and cardboard, wood, plastic (soft), plastic (hard), textile and rubber) in the various output streams of SRF production process. The results from mass balance of SRF production process showed that of the total input C&D waste material to MT waste sorting plant, 44% was recovered in the form of SRF, 5% as ferrous metal, 1% as non-ferrous metal, and 28% was sorted out as fine fraction, 18% as reject material and 4% as heavy fraction. The energy balance of this SRF production process showed that of the total input energy content of C&D waste material to MT waste sorting plant, 74% was recovered in the form of SRF, 16% belonged to the reject material and rest 10% belonged to the streams of fine fraction and heavy fraction. From the material balances of this process, mass fractions of plastic (soft), paper and cardboard, wood and plastic (hard) recovered in the SRF stream were 84%, 82%, 72% and 68% respectively of their input masses to MT plant. A high mass fraction of plastic (PVC) and rubber material was found in the reject material stream. Streams of heavy fraction and fine fraction mainly contained non-combustible material (such as stone/rock, sand particles and gypsum material).     

Performance of a low cost MBT prior to landfilling: study of the biological treatment of size reduced MSW without mechanical sorting

In France, the interest in Mechanical Biological Treatment (MBT) prior to landfilling is actually growing. In the absence of acceptance criteria for the waste to be landfilled, an alternative to the intensive, high-technology MBT can only find its place in the French context if it shows substantial benefits from an environmental, economic or operational point of view. This paper presents an experiment of low-cost MBT of size reduced MSW without material splitting. The performance of an experimental, pilot-scale mechanical and biological treatment process has been studied on 37.5 Mg of raw municipal solid waste. The mechanical process has been kept simple with only coarse shredding and no material recovery. The biological treatment, which was a low-cost forced aeration process, was monitored for 25 weeks. The biogas production potential of the waste was reduced by 90% to 19 NL kgDM(-1). The initial AT4 index of 82.9 mg O2 gDM(-1) decreased to 16.0 mg O2 gDM(-1). After 25 weeks of aerobic treatment, the dry mass loss reached 37%, while the mass of waste going to landfill was reduced by 28%. The average performances of the process were explained by the biological process itself, which was not optimal, and also by the characteristics of the input waste. The high particle size of the treated waste and the high content of slowly biodegradable matter (such as paper and cardboard) may both be significant drawbacks for the biological stabilisation of waste.     

Mass,energy and material balances of SRF production process. Part 1: SRF produced from commercial and industrial waste

This paper presents the mass, energy and material balances of a solid recovered fuel (SRF) production process. The SRF is produced from commercial and industrial waste (C&IW) through mechanical treatment (MT). In this work various streams of material produced in SRF production process are analyzed for their proximate and ultimate analysis. Based on this analysis and composition of process streams their mass, energy and material balances are established for SRF production process. Here mass balance describes the overall mass flow of input waste material in the various output streams, whereas material balance describes the mass flow of components of input waste stream (such as paper and cardboard, wood, plastic (soft), plastic (hard), textile and rubber) in the various output streams of SRF production process. A commercial scale experimental campaign was conducted on an MT waste sorting plant to produce SRF from C&IW. All the process streams (input and output) produced in this MT plant were sampled and treated according to the CEN standard methods for SRF: EN 15442, EN 15443. The results from the mass balance of SRF production process showed that of the total input C&IW material to MT waste sorting plant, 62% was recovered in the form of SRF, 4% as ferrous metal, 1% as non-ferrous metal and 21% was sorted out as reject material, 11.6% as fine fraction, and 0.4% as heavy fraction. The energy flow balance in various process streams of this SRF production process showed that of the total input energy content of C&IW to MT plant, 75% energy was recovered in the form of SRF, 20% belonged to the reject material stream and rest 5% belonged with the streams of fine fraction and heavy fraction. In the material balances, mass fractions of plastic (soft), plastic (hard), paper and cardboard and wood recovered in the SRF stream were 88%, 70%, 72% and 60% respectively of their input masses to MT plant. A high mass fraction of plastic (PVC), rubber material and non-combustibles (such as stone/rock and glass particles), was found in the reject material stream.     

Investigations of biological processes in Austrian MBT plants

Mechanical biological treatment (MBT) of municipal solid waste (MSW) has become an important technology in waste management during the last decade. The paper compiles investigations of mechanical biological processes in Austrian MBT plants. Samples from all plants representing different stages of degradation were included in this study. The range of the relevant parameters characterizing the materials and their behavior, e.g. total organic carbon, total nitrogen, respiration activity and gas generation sum, was determined. The evolution of total carbon and nitrogen containing compounds was compared and related to process operation. The respiration activity decreases in most of the plants by about 90% of the initial values whereas the ammonium release is still ongoing at the end of the biological treatment. If the biogenic waste fraction is not separated, it favors humification in MBT materials that is not observed to such extent in MSW. The amount of organic carbon is about 15% dry matter at the end of the biological treatment.     

A complete mass balance of a complex combined anaerobic/aerobic municipal source-separated waste treatment plant

In this study a combined anaerobic/aerobic full-scale treatment plant designed for the treatment of the source-separated organic fraction of municipal solid waste (OFMSW) was monitored over a period of one year. During this period, full information was collected about the waste input material, the biogas production, the main rejects and the compost characteristics. The plant includes mechanical pre-treatment, dry thermophilic anaerobic digestion, tunnel composting system and a curing phase to produce compost. To perform the monitoring of the entire plant and the individual steps, traditional chemical methods were used but they present important limitations in determining the critical points and the efficiency of the stabilization of the organic matter. Respiration indices (dynamic and cumulative) allowed for the quantitative calculation of the efficiency of each treatment unit. The mass balance was calculated and expressed in terms of Mgy(-1) of wet (total) matter, carbon, nitrogen and phosphorus. Results show that during the pre-treatment step about 32% of the initial wet matter is rejected without any treatment. This also reduces the biodegradability of the organic matter that continues to the treatment process. About 50% of the initial nitrogen and 86.4% of the initial phosphorus are found in the final compost. The final compost also achieves a high level of stabilization with a dynamic respiration index of 0.3±0.1g O(2) per kg of total solids per hour, which implies a reduction of 93% from that of the raw OFMSW, without considering the losses of biodegradable organic matter in the refuse (32% of the total input). The anaerobic digestion process is the main contributor to this stabilization.     

Fate of metals contained in waste electrical and electronic equipment in a municipal waste treatment process

In Japan, waste electrical and electronic equipment (WEEE) that is not covered by the recycling laws are treated as municipal solid waste. A part of common metals are recovered during the treatment; however, other metals are rarely recovered and their destinations are not clear. This study investigated the distribution ratios and substance flows of 55 metals contained in WEEE during municipal waste treatment using shredding and separation techniques at a Japanese municipal waste treatment plant. The results revealed that more than half of Cu and most of Al contained in WEEE end up in landfills or dissipate under the current municipal waste treatment system. Among the other metals contained in WEEE, at least 70% of the mass was distributed to the small-grain fraction through the shredding and separation and is to be landfilled. Most kinds of metals were concentrated several fold in the small-grain fraction through the process and therefore the small-grain fraction may be a next target for recovery of metals in terms of both metal content and amount. Separate collection and pre-sorting of small digital products can work as effective way for reducing precious metals and less common metals to be landfilled to some extent; however, much of the total masses of those metals would still end up in landfills and it is also important to consider how to recover and utilize metals contained in other WEEE such as audio/video equipment.     

Pretreatment of municipal solid waste prior to landfilling

An outdoor pilot-scale study was undertaken to pretreat municipal solid waste by windrow composting. The raw waste was introduced to active composting without any source separation or pulverization. Pretreatment indicators were developed and used as a tool to measure the optimum level of sorting and waste stabilization. The moisture content of the waste dropped from 68% to 61% and the pile attained a thermophilic temperature in one week. It was observed that the C/N ratio, pH profile and temperature gradients were comparable to that of traditional windrow composting. Within one week of active bulk composting, the easily degradable organic matter was consumed and there was a significant reduction in the bulk volume of the mixed waste. The pre-composted wastes were then sorted into four fractions. Compared to the initial untreated waste, the pretreated waste showed greater sorting efficiency and reduced volatile solids. A 1-m³ cage was used to study pile settlement and volume reduction. The results indicate that pretreatment by bulk composting could reduce by ≈40% the total mass of waste hauled to landfill sites in developing countries.     

Comparison of aerobic and anaerobic stability indices through a MSW biological treatment process

A complex mechanical-biological waste treatment plant designed for the processing of mixed municipal solid wastes (MSW) and source-selected organic fraction of municipal solid wastes (OFMSW) has been studied by using stability indices related to aerobic (respiration index, RI) and anaerobic conditions (biochemical methane potential, BMP). Several selected stages of the plant have been characterized: waste inputs, mechanically treated wastes, anaerobically digested materials and composted wastes, according to the treatment sequence used in the plant. Results obtained showed that the main stages responsible for waste stabilization were the two first stages: mechanical separation and anaerobic digestion with a diminution of both RI and BMP around 40% and 60%, respectively, whereas the third stage, composting of digested materials, produced lesser biological degradation (20-30%). The results related to waste stabilization were similar in both lines (MSW and OFMSW), although the indices obtained for MSW were significantly lower than those obtained for OFMSW, which demonstrated a high biodegradability of OFMSW. The methodology proposed can be used for the characterization of organic wastes and the determination of the efficiency of operation units used in mechanical-biological waste treatment plants.     

Evaluating the biogas potential of the dry fraction from pretreatment of food waste from households

At the waste handling company NSR, Helsingborg, Sweden, the food waste fraction of source separated municipal solid waste is pretreated to obtain a liquid fraction, which is used for biogas production, and a dry fraction, which is at present incinerated. This pretreatment and separation is performed to remove impurities, however also some of the organic material is removed. The possibility of realising the methane potential of the dry fraction through batch-wise dry anaerobic digestion was investigated. The anaerobic digestion technique used was a two-stage process consisting of a static leach bed reactor and a methane reactor. Treatment of the dry fraction alone and in a mixture with structural material was tested to investigate the effect on the porosity of the leach bed. A tracer experiment was carried out to investigate the liquid flow through the leach beds, and this method proved useful in demonstrating a more homogenous flow through the leach bed when structural material was added. Addition of structural material to the dry fraction was needed to achieve a functional digestion process. A methane yield of 98 m³/ton was obtained from the dry fraction mixed with structural material after 76 days of digestion. This was in the same range as obtained in the laboratory scale biochemical methane potential test, showing that it was possible to extract the organic content in the dry fraction in this type of dry digestion system for the production of methane.     

Mass and element balance in food waste composting facilities

The mass and element balance in municipal solid waste composting facilities that handle food waste was studied. Material samples from the facilities were analyzed for moisture, ash, carbon, nitrogen, and the oxygen consumption of compost and bulking material was determined.Three different processes were used in the food waste composting facilities: standard in-vessel composting, drying, and stand-alone composting machine. Satisfactory results were obtained for the input/output ash balance despite several assumptions made concerning the quantities involved. The carbon/nitrogen ratio and oxygen consumption values for compost derived only from food waste were estimated by excluding the contribution of the bulking material remaining in the compost product. These estimates seemed to be suitable indices for the biological stability of compost because there was a good correlation between them, and because the values seemed logical given the operating conditions at the facilities.     

Factors that affect the quality of the bio-waste fraction of selectively collected solid waste in Catalonia

The present study determines the composition of the bio-waste fraction of waste and establishes correlations between the quality of this fraction and socio-economic/demographic variables. According to the Catalan Waste Agency [Agència de Residus de Catalunya (2004). Statistical data. Available from: ], the quantities of glass, paper/cardboard, light packaging and biodegradable material (those components of municipal waste that can be recovered, and have a separate collection) that were selectively collected in 2004 represent 25.6% by weight of the total municipal waste generated. There is a large spread of values from different cities. It is important to bear in mind that this percentage was calculated using the total weights of all of the materials present in the different bins used for selective solid waste collection, without taking account of the fact that many of these bins contain a certain amount of other, undesirable waste. In order to be able to determine the actual quantities that are recovered, it is necessary to establish the quality of the waste collected. To establish the quality of the waste collected, 350 samples were analysed, corresponding to the bins for the bio-waste fraction of solid waste in 193 different cities in Catalonia. Seven levels of quality were established for the study, depending on the amount of undesirable waste present. The results show certain correlations between the socio-economic/demographic factors studied and the percentage of undesirable waste present in the samples. The correlations presented here are not intended to be predictive, but rather indicative of a tendency, which should help us gain a better understanding of the behaviour of the society studied with respect to the separation of solid household waste at origin.     

Research on solid waste management system: to improve existing situation in Corlu Town of Turkey

Over the past decades, uncontrolled population growth and rapid urbanization and industrialization have resulted in environmental problems in Corlu Town, Turkey. One of the most important problems is solid waste due to inadequate management practices. Nowadays, increasing public awareness of the environment compels local authorities to define and to adopt new solutions for waste management. This paper presents a general overview of current solid waste management practices in Corlu Town and principles of the recommended municipal solid waste (MSW) management system. In Corlu, 170 tonnes of municipal solid waste are generated each day, or 1.150 kg per capita per day. Approximately one-half of the municipal solid waste generated is organic material and 30% of the MSW consists of recyclable materials. The recommended system deals with maximizing recycling and minimizing landfilling of municipal solid waste, and consists of separation at source, collection, sorting, recycling, composting and sanitary landfilling. This study also analyzed the recommended system with respect to feasibility and economics. To evaluate whether the suggested system is cost effective or not, the operating cost of the recommended system and market prices of recyclable materials were compared, and the results show that the recommended system will reduce required landfill volume up to 27% of compared to the present situation. The profit of the recommended system is estimated to be about 80 million US dollars.     

Proximate composition of household waste and applicability of waste management technologies by source separation in Hanoi,Vietnam

The organic fraction of municipal solid wastes in Southeast Asia, which has a high moisture content, accounts for a large proportion of total waste. Local governments need to pay adequate attention to the composition of wastes to determine alternative waste management technologies. This study proposed the use of a triangle diagram to describe changes in proximate composition and rates of successful source separation of municipal solid waste and to identify technical challenges about alternative waste management technologies such as incineration, composting, and refuse-derived fuel production based on physical and proximate composition analysis of household waste sampled in Hanoi, Vietnam, as a case study. The analysis indicated the effectiveness of different types of source separation as well as different levels of successful achievement of source separation as an adjustment mechanism for the proximate composition of waste. Proper categorization of wastes for source separation is necessary for the appropriate use of alternative waste management technologies. The results showed that, at a source separation rate of just greater than 0.52 in a three-way separation scheme, the waste separated as combustible waste would be suitable for incineration with energy recovery. Based on well-designed schemes of source separation, alternative waste management technologies can be applied.     

The effect of storage and mechanical pretreatment on the biological stability of municipal solid wastes

Modern mechanical–biological waste treatment plants for the stabilization of both the source-separated organic fraction of municipal solid wastes (OFMSW) and the mixed stream of municipal solid wastes (MSW) include a mechanical pretreatment step to separate recyclable materials such as plastics, glass or metals, before biological treatment of the resulting organic material. In this work, the role of storage and mechanical pretreatment steps in the stabilization of organic matter has been studied by means of respiration techniques. Results have shown that a progressive stabilization of organic matter occurs during the pretreatment of the source-separated OFMSW, which is approximately 30% measured by the dynamic respiration index. In the case of mixed MSW, the stabilization occurring during the reception and storage of MSW is compensated by the effect of concentration of organic matter that the pretreatment step provokes on this material. Both results are crucial for the operation of the succeeding biological process. Finally, respiration indices have been shown to be suitable for the monitoring of the pretreatment steps in mechanical–biological waste treatment plants, with a strong positive correlation between the dynamic respiration index and the cumulative respiration index across all samples tested.     

Evaluation of an organic soil amendment generated from municipal solid waste seeded with activated sewage sludge

This study investigated the feasibility of using fresh activated sewage sludge as inoculum for the microbial valorization of segregated municipal solid waste and evaluated the quality of organic soil amendment generated. Organic fraction of municipal solid waste, which consisted of vegetative (vegetable, fruit and flower) wastes was seeded with activated sewage sludge and processed by rapid aerobic microbial treatment. Efficacy of microbial valorization process and quality of final product were assessed by physico-chemical analysis. Suitability of final product was assessed with regard to heavy metal content, pesticide residues, microbiological quality and phytotoxicity. Quality of the soil amendment generated was compared with the control product generated with a commercial microbial inoculum. Phytotoxicity experiments indicated the stimulatory effect of sewage sludge seeded soil amendment on plant growth but inhibition was observed in closed growth test due to the evolution of gaseous phytotoxic agents. The study suggests that segregated municipal solid waste can be effectively valorized with activated non-dewatered sewage sludge as inoculum and the quality of soil amendment generated was comparable to compost intended for unrestricted applications.     

Metals, non-metals and PCB in electrical and electronic waste--actual levels in Switzerland

The chemical composition of waste of small electrical and electronic equipment (s-WEEE), a rapidly growing waste stream, was determined for selected metals (Cu, Sb, Hg etc.) and non-metals (Cl, Br, P) and PCBs. During a 3-day experiment, all output products and the s-WEEE input mass flows in a WEEE recycling plant were measured. Only output products were sampled and analyzed. Material balances were established, applying substance flow analysis (SFA). Transfer coefficients for the selected substances were also determined. The results demonstrate the capability of SFA to determine the composition of the highly heterogeneous WEEE for most substances with rather low uncertainty (2 sigma +/- 30%). The results confirm the growing importance of s-WEEE regarding secondary resource metals and potential toxic substances. Nowadays, the thirty times smaller s-WEEE turns over larger flows for many substances, compared to municipal solid waste. Transfer coefficient results serve to evaluate the separation efficiency of the recycling process and confirm--with the exception of PCB and Hg--the limitation of hand-sorting and mechanical processing to separate pollutants (Cd, Pb, etc.) out of reusable fractions. Regularly applied SFA would serve to assess the efficacy of legislative, organizational and technical measures on the WEEE.     

Volatilisation and oxidation of aluminium scraps fed into incineration furnaces

Ferrous and non-ferrous metal scraps are increasingly recovered from municipal solid waste incineration bottom ash and used in the production of secondary steel and aluminium. However, during the incineration process, metal scraps contained in the waste undergo volatilisation and oxidation processes, which determine a loss of their recoverable mass. The present paper evaluates the behaviour of different types of aluminium packaging materials in a full-scale waste to energy plant during standard operation. Their partitioning and oxidation level in the residues of the incineration process are evaluated, together with the amount of potentially recoverable aluminium. About 80% of post-consumer cans, 51% of trays and 27% of foils can be recovered through an advanced treatment of bottom ash combined with a melting process in the saline furnace for the production of secondary aluminium. The residual amount of aluminium concentrates in the fly ash or in the fine fraction of the bottom ash and its recovery is virtually impossible using the current eddy current separation technology. The average oxidation levels of the aluminium in the residues of the incineration process is equal to 9.2% for cans, 17.4% for trays and 58.8% for foils. The differences between the tested packaging materials are related to their thickness, mechanical strength and to the alloy.     

Stabilisation of biodried municipal solid waste fine fraction in landfill bioreactor

The biodrying process of solid waste is a pre-treatment for the bio-stabilisation of the municipal solid waste. This study aims to investigate the fate of the municipal solid waste fine fraction (MSWFF) resulting from a biodrying treatment when disposed in landfills that are operated as bioreactors. Biodried MSWFF was apparently stable due to its low moisture content that slows down the microbial activity. The lab-scale anaerobic bioreactors demonstrated that a proper moisture content leads to a complete biodegradation of the organic matter contained in the biodried MSWFF. Using a pilot-scale landfill bioreactor (LBR), MSWFF stabilisation was achieved, suggesting that the leachate recirculation could be an effective approach to accomplish the anaerobic biodegradation and biostabilisation of biodried MSWFF after landfilling. The biostabilisation of the material resulting from the LBR treatment was confirmed using anaerobic and aerobic stability indices. All anaerobic and aerobic indices showed a stability increase of approximately 80% of the MSWFF after treatment in the LBR. The similar values of OD7 and BMP stability indices well agree with the relationship between the aerobic and anaerobic indices reported in literature.     

Biostabilization of municipal solid waste

A mechanical-biological process for municipal solid waste (MSW) treatment was monitored for one year. Mechanical pre-treatment provided two fractions. The oversize fraction (diameter > 50 mm) (yield of 600 g kg(-1) ww) (46 Mg day(-1)) was used for refuse derived fuel production, after undergoing a mechanical refining processes, because of low moisture content (200-250 g kg(-1)) and high calorific value (2500-2800 kcal kg ww(-1)). The undersize fraction (diameter < 50 mm) (yield 400 g kg(-1) ww) (30 Mg day(-1)) contained about 800 g kg(-1) of the MSW organic matter. This fraction was biologically treated using an aerobic process with an organic waste fraction from separate collection (77 Mg day(-1)) and recycled stabilized material (62 Mg day(-1)) obtained from end-product sieve (diameter < 20 mm) used as bulking agent. A retention time of three weeks was sufficient to obtain stabilized products in agreement with up-dated rules of the Lombardy Region (North Italy) regarding biostabilization and composting processes. Dynamic Respiration Index (DRI), such as required by both Lombardy Region rules and suggested by the European Community, was chosen in preference to other indices in order to assess the degree of biological stability of the end products. A mean DRI value of 1164 mg O2 kg SV(-1) h(-1) was obtained and is in agreement with the proposed limit of 1000+/-200 mg O2 kg SV(-1) h(-1). Self-heating test, potential biogas production and fermentable volatile solids were also used as parameters to describe the potential impact of treated waste, providing further useful information. Nevertheless, all of these methods revealed analytical or interpretative limits. A complete mass balance of the biological treatment section showed that, from a net input of 107 Mg day(-1), only 250 g kg(-1) (27 Mg day(-1)) of the waste needed to be landfilled, with 750 g kg(-1) (80 Mg day(-1)) being lost as CO2 and H2O.     

Characterization and mass balance of dioxin from a large-scale municipal solid waste incinerator in China

The input and output samples from existing large-scale municipal solid waste incinerator (MSWI) were collected and analyzed for polychlorinated dibenzo-р-dioxins and dibenzofurans (PCDD/Fs) in this study, aiming to evaluate PCDD/F characteristic and the corresponding mass balance through the whole system. The grate-type MSWI is equipped with semi-dry scrubber, activated carbon injection, and bag filter as air pollutant control devices (APCDs). Results showed that on the output side, the stack gas, bottom ash and fly ash presented their mean dioxin levels of 0.078 ng I-TEQ/Nm(3), 12.94 ng I-TEQ/kg and 858 ng I-TEQ/kg, respectively, and showed large similarities in congener profiles. Instead, on the input side, the municipal solid waste (MSW) presented a mean dioxin level of 15.56 ng I-TEQ/kg and a remarkable difference in congener profiles compared with those of the output. The dioxin mass balance demonstrated that the annual dioxin input value was around 5.38 g I-TEQ/yr, lower than the total output value (7.62 g I-TEQ/yr), signifying a positive dioxin balance of about 2.25 g I-TEQ/yr.