生物强化技术处理难降解有机污染物的研究进展

阐述了生物强化技术的原理，概括了旧内外有关生物强化技术处理难降解有机污染物的应用实例及效果。介绍了生物强化技术应用中有关高效降解菌和生物强化菌剂的研究与开发现状，进一步讨论了应用生物强化技术的主要控制参数，展望了生物强化技术的发展方向。     

有机固体废物生物法制氢的研究进展

综述了利用有机固体废物生物法制氢的原理和研究现状。城市有机固体废物、农业有机废物、工业有机废物是生物法制氢的主要原料。暗发酵制氢是利用有机废物厌氧消化的产酸阶段而产氢，pH、温度、水力停留时间、氢气分压、原料性质、微量元素含量、产甲烷微生物抑制剂等均影响氢气产率。光发酵制氢是利用光合厌氧细菌将挥发性有机酸转化为氢气和二氧化碳。暗发酵和光发酵制氢时，生物固定化有利于高速连续产氢。在有机废物处理和生物法制氢方面，暗发酵一光发酵、暗发酵一微生物燃料电池的组合工艺是具有前景的技术。今后的研究方向是原料的预处理技术、选育高效产氢菌株、发明高效反应器、优化处理工艺和处理条件等。     

高效菌处理难降解有机工业废水研究进展

总结了高效菌在造纸、印染、化丁、农药、制药等工业有机废水处理中的研究现状;认为大力开展和加强高效菌的选育和应用工艺研究,是生物强化技术领域今后的发展方向。     

5G、物联网、云技术时代固体废物全生命周期监管体系创新

当前的固体废物监管模式已满足不了自动化、智能化固体废物监管和无废城市建设的要求。物联网技术、云技术和5G通信技术的相互融合和有机统一,必将会为固体废物环境管理提供新的机遇和新的技术手段。基于我国固体废物监管现状,分析了物联网技术、云技术和5G通信技术在固体废物监管体系创新应用研究中的关键难点,并提出建设性方案和设想。     

油气开采钻井固体废物处理与利用研究现状

对比分析了我国部分地区油气开采钻井固体废物的污染特征,对普通钻井固体废物和含油钻井固体废物的无害化处理与资源化利用技术分别进行梳理和分析,主要包括固化处理技术、生物处理技术、不落地处理技术、资源化利用技术、萃取技术、热解析技术和组合处理技术等。结合当前存在的主要问题针对性地提出了4条对策建议:加强源头控制,减少钻井固体废物产生量;对钻井固体废物进行分质分级区别处理和利用;开发高效、低成本、低能耗的钻井固体废物处理技术,发展联合处理工艺;制定相关政策和标准,加强油气田污染治理的事中事后监管。     

工业园区固体废物资源化技术研究

工业园区固体废物资源化是实施循环经济、建设生态文明的关键一环,但在实施过程中遇到诸多问题.以工业园区固体废物外延的重新界定为起点,从3个方面分析了工业园区固体废物资源化技术:固体废物生态产业链构建与运行维护、回收与分类技术、再利用与循环技术,并就固体废物资源化方面存在的问题提出了相应的解决建议.     

漆酶的固定化技术与应用研究进展

酶固定化技术的应用有效提高了漆酶的稳定性和可重复利用性，为其大规模使用提供了条件。载体材料的选择对固定化漆酶的性能至关重要。本文介绍了当前固定化漆酶的3种载体材料（高分子材料、无机纳米材料、有机-无机杂化材料），总结了固定化漆酶在废水处理、固体废物处理、生物传感器制造等方面的研究进展。指出未来的研究方向应集中于：开发新技术或优化现有工艺以降低漆酶生产成本，研发新的载体材料和固定化方法以提高漆酶的长期活性，利用基因工程提高漆酶的稳定性和回收潜力。     

制定固体废物鉴别标准的方法探讨

首先,分析了我国固体废物鉴别状况,阐述了现行鉴另导则具有重要地位,鉴剐在固体废物管理中发挥着重要技术支持作用,同时也详细论述了鉴别导则存在的不足,提出我国建立固体废物鉴别标准的必要性.其次,概括性地总结了国外固体废物鉴别的情况,国外没有建立专门的固体废物鉴别制度和技术导则,也没有专门鉴别机构,以欧美为代表,通过相关法规建立固体废物定义、列名分类以及豁免排除,当遇有是否属于固体废物纠纷时通过法院进行裁决.最后,重点介绍了制定固体废物鉴别标准的技术难点、需要解决的问题以及拟采取的技术方法,提出了编制鉴别标准的框架内容和基本理由.对制定出我国固体废物鉴别标准具有积极意义.     

进口旧机电固体废物属性鉴别体系研究

随着我国工业化水平发展和环境保护工作的强化,我国对于固体废物的管理日趋严格。2020年,《中华人民共和国固体废物污染环境防治法》进行了修订,根据该法律要求,我国于2021年全面禁止进口固体废物,固体废物属性鉴别的工作要求进一步加强。为更准确地把握进口旧机电固体废物属性鉴别的评判标准,统一评判尺度,分析了进口旧机电固体废物属性鉴别工作的特殊性和面临的困难;提出了口岸对进口旧机电的查验流程,明确了口岸初筛快速查验技术要点;结合《禁止进口旧机电目录》及机电产品维修再制造等机电产品口岸管理特殊要求,研究了机电产品实验室固废鉴别的流程和关键技术要点,提出了基于机电产品的功能特点、开展关键缺陷评估以完成固废属性鉴别的思路。     

进口初级产物类物品的固体废物属性鉴别研究

利用红外光谱、气相色谱/质谱联用、液相色谱/质谱联用、核磁共振波谱、原子发射光谱、凝胶渗透色谱、X-射线荧光光谱等多种分析方法,剖析了申报进口的一个未知有机物品的组分、含量和理化指标;阐述了进口物品的产生来源,探讨了其固体废物属性。结果表明,样品不属于固体废物。呈现了一个以回收物料为原料加工的未知有机初级产物固体废物属性鉴别的全过程,为从事进口固体废物相关的人员提供参考,另外,初级产物固体废物属性鉴别非常复杂,建议制定详细的鉴别标准。     

浅议碳排放与废钢铁的节能减排功效

二氧化碳是导致全球气候变暖、人类生存环境恶化的主要原因。简要介绍世界钢铁工业二氧化碳排放情况,针对我国钢铁工业碳排放的具体情况,提出发展我国废钢产业,提高废钢铁的供应能力,是我国钢铁工业摆脱危机,实现低碳发展、绿色发展的主要途径。     

Synthesis and identification of graft copolymers of wood pulp and styrene

Based on the graft copolymerization reactions of lignin and vinyl monomers, a series of graft copolymers of wood pulp and styrene (1-phenylethene) has been synthesized. The wood pulps used in this research are unbleached products produced by chemical, thermal, and mechanical pulping. All of them contain a high content of lignin (25–29 wt%). The grafting reaction is a free radical polymerization coinitiated by calcium chloride, hydrogen peroxide, and wood pulp in dimethylsulfoxide at 30°C. The effect of reaction temperature, reaction time, and the amount of the reactants on the conversion of monomer, yield of product, weight increase of pulp, and grafting efficiency of monomer has been studied. The grafted wood pulp was separated from homopolystyrene formed during the reaction by extraction of the reaction product with benzene in a Soxhlet apparatus for at least 48 h. The results show that after the reaction, the weight of all wood pulps was significantly increased and the weight increase of very high yield sodium bisulfite pulp (VHYS) was 333%. This proves that a part of the polymerized styrene was chemically bound to the wood pulp. The Fourier transform infrared (FTIR) spectra of the extracted products show absorbance peaks characteristic of both wood and polystyrene and, thus, provide strong proof of grafting. Grafting has completely changed the surface properties of the starting wood pulp from hydrophilic to hydrophobic, and under ordinary thermal compression conditions, thermoplastic composite objects of good uniformity can be made directly from reaction products which contain up to 52 wt% wood pulp.     

Fate and effect of linuron and metribuzin on the co-composting of green waste and sewage sludge

The fate and effect of the herbicides linuron and metribuzin on the co-composting of sewage sludge and green waste were addressed in this work. The experiments were conducted in metal cubic containers of 1.0 m³ volume simulating a windrow composting system. A mixture of sludge and green waste was prepared at a ratio of 1:5 v/v. The mixture was split in four equal parts and the two herbicides were added, using a pressure sprayer, as sole or mixed pollutant in each of the three mixtures. The forth mixture was composted without any addition of herbicide, to serve as control. Temperature, physicochemical characteristics, herbicide concentration, carbon dioxide emission, methane emission and microbiological parameters were measured either daily or every time the mixtures were turned, for a period of 80 days. Both herbicides’ concentration decreased significantly resulting in removal efficiencies of 99.1–99.7% and 95.8–96.0% for linuron and metribuzin, respectively. Incubation of microbiologically inactive mixtures at a temperature schedule following the spontaneous temperature evolution in the composters resulted in very little (1–11%) decomposition for both herbicides. Comparison of the variation of physicochemical parameters and microbial populations during composting indicated that both herbicides did not affect the composting process.     

资源循环科学与工程专业课程体系优化与教学内容创新实践的探索

针对资源循环科学与工程本科专业课程教学,以西安建筑科技大学该专业课程体系为案例,通过对毕业生和专业研讨会调研,分析了课程体系建设的现状和存在的问题。借鉴其他高校资源专业的课程体系和教学内容,通过梳理各门专业课程的教学内容和相互联系,构建了资源专业课程体系课程群,探索了课程体系优化的方法和增加创新实践环节的具体措施。     

Photo-oxidation and Photo-toxicity of Crude and Refined Oils

The fate and effects of an oil spill are effected by solar radiation through the action of photo-oxidation and photo-toxicity. Photo-oxidation, an important process in the weathering of oil, produces a variety of oxidized compounds, including aliphatic and aromatic ketones, aldehydes, carboxylic acids, fatty acids, esters, epoxides, sulfoxides, sulfones, phenols, anhydrides, quinones and aliphatic and aromatic alcohols. Some of these compounds contribute to the marine biota toxicity observed after an oil spill. Photo-toxicity occurs when uptake of certain petroleum compounds, e.g. certain polycyclic aromatic hydrocarbons and benzothiophenes, is followed by solar exposure which results in much greater toxicity than after dark uptake. The mechanism of PAH photo-toxicity includes absorbance of solar radiation by the PAH which produces a free radical and this free radical in turn reacts with oxygen to produce reactive oxygen species that can damage DNA and other cellular macromolecules. While most studies on photo-toxicity have been carried out in the laboratory, there are studies showing that water from an oil spill is photo-toxic to bivalve embryos for at least a few days after the spill. Other studies have found that oil contaminated sediments are photo-toxic to several marine invertebrates. More studies are required to determine if marine fauna at an oil spill site are effected by the action of photo-toxicity and photo-oxidation.     

我国废旧电子电器产品拆解技术、设备应用现状及改进建议

从我国废旧电子电器回收行业基本情况、专业技术人才情况、相关企业拆解技术设备情况等方面，阐述了我国废旧电子电器产品拆解技术、设备应用现状，并提出相关改进提升建议。     

电子废弃物的再循环利用:企业、政府与公众的角色和责任

电子废弃物不仅种类繁多,而且成分复杂,含有多种有毒、有害物质,已成为固体废物中最大的重金属污染源.长期以来,由于对电子废弃物问题缺乏足够认识和有效管理,电子废弃物对人体健康及生活环境可能构成的危害常常被忽视.实现电子废弃物的再循环利用,关键是明确企业、政府和公众在电子产品设计、生产、消费、回收、处置和再利用整个过程中的相关责任.因此,解决电子废弃物的问题,首先要对相关行为主体的角色进行准确定位.     

TEMPO-Mediated Oxidation of Norway Spruce and Eucalyptus Pulps: Preparation and Characterization of Nanofibers and Nanofiber Dispersions

This study deals with 2,2,6,6-tetramethylpiperidine-1-oxyl (TEMPO)-mediated oxidation of cellulose. Softwood and hardwood pulp fibers were suspended in water and oxidized to various extents at pH 10 and 22 °C using sodium hypochlorite in the presence of TEMPO radical and sodium bromide. This reaction system is known to be the most efficient one for the introduction of both surface carboxyl and aldehyde groups. Important relationships between formation of these functional groups and the fibrillation yield, light transmittance of the water dispersions and degree of polymerization of the oxidized softwood and hardwood pulps were established in the present study. A birefringence test confirmed the presence of nanofibers which according to atomic force microscopy analyses had diameters in the 1.6–3.8 nm range.     

炼油废水处理的现状、问题及对策

针对原油性质日趋恶劣、排放标准日益严格的形势,介绍了炼油废水的处理现状,分析了炼油废水在达标排放、处理回用、运行成本等方面面临的主要问题,提出了从源头挖掘节水减排潜力、实施装置排水分级控制与高浓度废水预处理、对废水处理场进行适度改造和补充完善、开发含盐废水处理技术等对策。     

火电厂灰渣浸溶特性及冲灰过程中铬、铅的迁移转化规律研究

通过对电厂除灰系统结构、冲灰用水种类、灰水比的调查，对除尘器下干灰进行标准和模拟浸溶试验，研究灰渣浸溶特性和六价铬、铅在冲灰过程中的迁移转化规律，从而为进一步开展重金属污染防治和减小灰场灰水对周围环境的影响提供理论依据。