Development and analysis of high-performance green concrete in the urban infrastructure

Cement production accounts for approximately 5% of total global CO₂ emissions from all human activities. In addition, the consumption of virgin aggregates for concrete infrastructure has created virgin material scarcity issues in many areas of the USA. High-performance green concrete (HPGC) with fly ash and recycled aggregates can help reduce the demand for material inputs and reduce pollution outputs associated with bulk material flow of urban concrete. Structural and durability tests showed that HPGC containing fly ash and 50% recycled aggregate (100% of the coarse aggregate fraction) performed equally or better than 100% ordinary Portland cement concrete with the same cementitious content. Durability improvements were more significant with Class F than Class C fly ash. For both Class F and Class C fly ash, greater per cent replacement of Portland cement with fly ash led to slower and lower strength gain, but still within acceptable strength criteria for Colorado Department of Transportation Class B concrete. This paper quantifies the sustainability of HPGC in urban infrastructure by addressing structural performance, environmental, economic and resource depletion impacts.     

Valuable utilisation of spray dryer ash and its performance in structural concrete

This paper focuses on the valuable utilisation of spray dryer ash (SDA) and investigates its performance in concrete for structural applications. Based on the challenges associated with the disposal of coal combustion products (including SDA) and the economic costs linked to cement production, this research seeks to provide an environmentally friendly and more cost-effective concrete product by utilising SDA in partial replacement of cement in concrete. With the exception of a relatively high-sulphur content, SDA exhibits very useful properties that are closely related to Class C fly ash and Portland cement.

Experimental tests were carried out to determine the effect of SDA replacement of Portland cement (ranging from 0 to 50% replacement) on the compressive strength, bond strength, freeze-thaw performance and corrosion resistance of concrete. The addition of SDA in non-air entrained concrete provided a general increase in its strength with optimal limits ranging between 25 and 35% replacement. The addition of SDA produced a negligible effect on the freeze-thaw durability of the concrete (air entrained). Results for corrosion performance were not as definitive, but indicate that the use of SDA does not significantly change the likelihood of reinforcing bar corrosion.     

Recovery and characterisation of carbon fibres from waste CFRP using supercritical n-butanol

ABSTRACT

The high-performance carbon fibres can be recycled from waste carbon fibre/epoxy resin composites by supercritical n-butanol. Recycling experiment designed by response surface method was used to investigate quantitative relation between degradation rate of epoxy resin and process parameters. Thus, the optimum process parameters could be obtained, and effects of process parameters and layers on degradation rate and mechanical performance of the recycled carbon fibres were analysed. The tensile strength of the recycled carbon fibre under the optimum process parameters was 94.53% of that of the original carbon fibre, tensile modulus was 93.57% of that of the original carbon fibre and interfacial shear strength was 90% of that of the original carbon fibre.     

Mechanical performance and capillary water absorption of sewage sludge ash concrete (SSAC)

Disposal of sewage sludge from waste water treatment plants is a serious environmental problem of increasing magnitude. Waste water treatment generates as much as 70 g of dry solids per capita per day. Although one of the disposal solutions for this waste is through incineration, still almost 30% of sludge solids remain as ash. This paper presents results related to reuse of sewage sludge ash in concrete. The sludge was characterised for chemical composition (X-ray flourescence analysis), crystalline phases (X-ray diffraction analysis) and pozzolanic activity. The effects of incineration on crystal phases of the dry sludge were investigated. Two water/cement (W/C) ratios (0.55 and 0.45) and three sludge ash percentages (5%, 10% and 20%) per cement mass were used as filler. The mechanical performance of sewage sludge ash concrete (SSAC) at different curing ages (3, 7, 28 and 90 days) was assessed by means of mechanical tests and capillary water absorption. Results show that sewage sludge ash leads to a reduction in density and mechanical strength and to an increase in capillary water absorption. Results also show that SSAC with 20% of sewage sludge ash and W/C = 0.45 has a 28 day compressive strength of almost 30 MPa. SSAC with a sludge ash contents of 5% and 10% has the same capillary water absorption coefficient as the control concrete; as for the concrete mixtures with 20% sludge ash content, the capillary water absorption is higher but in line with C20/25 strength class concretes performance.     

Design of a novel comfort liner for a motorcycle helmet

Natural fibres are nowadays increasingly being employed for producing protective clothing and sportswear. Due to economic and/or environmental considerations they are replacing synthetic materials. The present work provides an insight into the design and development of a novel comfort liner for a motorcycle helmet. The liner is produced from wool and Tunisian alfa fibre. The plant of the alfa fibre is abundantly available in Tunisia. Furthermore, we describe a design concept for a liner that uses these natural fibres and phase change material to improve sweat absorption and perception of thermal comfort. The raw material, the processes involved and the solution to use the phase change material are analysed. The novel comfort liner can facilitate breathability and evaporative transfer of heat in the safety helmet. In addition, it increases comfort, well-being, and provides an indirect message to use natural fibres for textile support to preserve our environment.     

Effect of cement content and recycled rubber particle size on the performance of rubber-modified concrete

According to the Rubber Manufacturer’s Association, the United States generated 3664 thousand metric tons of scrap tires in 2015. While most waste tires are repurposed, approximately 409.5 thousand metric tons were disposed in landfills. This study investigates an alternative use of the waste tires as a replacement of natural aggregates in concrete mixtures. This study investigated fresh concrete properties and compressive strength. Different coarse and fine aggregate rubber particle sizes were evaluated: 19-mm tire chips (TCs) and 30-mesh crumb rubber (CR). TCs were used to replace coarse aggregates, while CR was used to replace fine aggregate in the concrete mixtures in increments of 10% by volume. Concrete strength loss was reduced with a fine aggregate replacement with CR as opposed to greater losses of strength exhibited by a coarse aggregate replacement with TCs. Adequate strengths were achieved at replacement levels as high as 40% by volume with CR, whereas satisfactory strengths were achieved with only a 10% replacement of coarse aggregates with TCs. Acceptable strengths were obtained from mixtures utilizing a combination of the two rubber sizes. Cement content was observed to have greater influence on rubberized concrete compressive strength at lower rubber contents than higher levels.     

A Framework for Assessing Carbon Flow in Indian Wood Products

This paper uses a lifecycle analysis to trace the fate of carbon bound in wood products until most of the carbon is released back into the atmosphere. A sensitivity analysis has been carried out to find the effect of change in terminal use (recycling, land filling and burning of discarded products), half-life of wood products and decay rate of carbon in landfills. Of the total carbon harvested from forests in India, about 90% is released into the atmosphere in the first year, due to burning of fuelwood; at the end of 100 years, about 0.8% still remains in the wood products. The sensitivity analysis shows that the length of the lifespan of wood products has only a marginal effect on the amount of carbon sequestered but has significant effect on the amount of carbon in products in use. Thus an important conclusion from this scenario is that by increasing the durability of the wood products, carbon can be locked over a period equal to the time needed to grow the timber for these products. Further, the carbon storage is affected more significantly by the decay rate of carbon in landfills than the proportion of products recycled. The study also shows that wood products can be important stores of carbon, but only if they can substitute for a unit of carbon emitted by burning fossil fuels. Such a lifecycle analysis has the potential to account completely for carbon stock changes in the wood products, where and when they are occurring, and explain how they are occurring.     

An experimental study on shrinkage of earth plaster with natural fibres for straw bale buildings

In this paper, a series of laboratory tests on shrinkage of plaster materials are presented. The plaster materials consist of cohesive soil, sand and different natural fibres. Three types of fibres, wheat straw, barley straw and wood shavings, were used as reinforcement in the tests. The shrinkage behaviour of earth plasters was studied by laboratory tests for different compositions and under different curing conditions. The specimens of plaster material were dried under a constant temperature of 30, 50 and 70°C, respectively. The effect of the following factors on shrinkage was investigated: temperature, soil composition, fibre type and fibre content. It was established that shrinkage crack formation decreases with increasing fibre content and increases with increasing soil content. In general, it was also found that lower curing temperature and higher fibre content are to be preferred to improve the performance of earth plasters.     

Green Composites as Panacea? Socio-Economic Aspects of Green Materials

Much academic research and industrial development explores new ways to create greener and environmentally friendlier chemicals and materials for a variety of applications. A significant part of this work focuses on the development, processing and manufacturing, recycling and disposal of green plastics, adhesives, polymer composites, blends and many other industrial products from renewable resources. Natural fibres offer the potential to deliver greater added value, sustainability, renewability and lower costs especially in the automotive industry. Further research involves the fibre crop production. The ever-increasing volume of scientific literature refers with enthusiasm to the potential of natural fibres in technological, economic and ecological terms. This enthusiasm tends to also expand to the areas of human life and socio-economic development for the fibre crop growers and their communities. However, there is very little debate or evidence to support statements about the assumed advantages for the affected population in rural areas. We argue that despite the predicted new boom in the demand of natural fibres, it is unlikely that this will represent a real improvement in the quality of life of crop fibre growers and their communities. This paper examines the experience of Mexico as a case study and argues that only through consistent political will and co-operation between governments, industry, scientists, consumer groups and local communities, as well as a suitable economic strategy such as local subsidies, a truly sustainable economic development, social equity and improved environmental quality will be achieved for tens of thousands of natural fibre growers.     

A review of steel slag usage in construction industry for sustainable development

Use of by-products from the steelmaking process can play an important role in achieving sustainable development. The available literature suggests that the use of iron and steel industry slags as mineral admixture or partial replacement of cement improves the microstructure of the concrete as well as its mechanical and durability characteristics. This paper reviews utilization of steel slag (SS) in the construction industry by considering current and possible future utilization fields, advantages of SS usage, and problems associated with its use. Strength and durability evolution of concretes or mortars containing SS in different ratios as aggregate or cement replacement material, combined use of ground granulated blast furnace slag with SS, and some relatively new fields of utilization of SS are also addressed. Improvements in and results of SS utilization in cement and concrete are discussed by addressing its beneficial effects. This article could help researchers to understand the recent developments in evaluation of SS in the construction industry.     

Environmental goods collection and children’s schooling: evidence from Kenya

This paper presents an empirical study of schooling attendance and collection of environmental resources using cross-sectional data from Kiambu District of Kenya. Because the decision to collect environmental resources and attend school is jointly determined, we used a bivariate probit method to model the decisions. In addition, we corrected for the possible endogeneity of resource-collection work in the school attendance equation by using instrumental variable probit estimation. One of the key findings is that being involved in resource collection reduces the likelihood of a child attending school. The result supports the hypothesis of a negative relationship between children working to collect resources and the likelihood that they will attend school. The results further show that a child’s mother’s involvement in resource collection increases school attendance. In addition, although there is no school attendance discrimination against girls, they are overburdened by resource-collection work. The study recommends immediate policy interventions focusing on the provision of public amenities, such as water and fuelwood.     

Media Storms and Policy Expertise: How Environmental Beat Journalists Gained Influence During a Shale Gas Controversy

This article examines the conditions under which environmental beat journalists can gain credibility as expert informants. It shows that media storms foster a particular dynamic that can add to this credibility. Comparing a media storm over shale gas development in Quebec with regular coverage of the same issue in British Columbia, this article shows that the coverage space given to environmental beat journalists during a media storm can render their alliance with protest groups mutually beneficial. Beat journalists can benefit from the willingness of these groups to participate in their stories, while the groups benefit from increased visibility. Beat journalists also benefit by being perceived as expert informants in policy networks, a role that they use to encourage policy-makers to take the concerns of protest groups seriously. This dynamic also increases the negativity of the news coverage. The article makes a contribution to knowledge on the role of environmental journalists in policy-making processes.     

An empirical research on the determinants of Chinese college students’ carbon label cognition and interpersonal communication willingness

Carbon labels are innovative medium and tools for climate change communication and low-carbon marketing. This study aims at examining how college students are aware of low-carbon and carbon labels, whether they are more willing to communicate low-carbon ideas, and also the determinants affecting their interpersonal communication of carbon labels. The multiple regression analysis shows that Chinese college students’ willingness of interpersonal communication of carbon labels are significantly influenced by their awareness of climate change crisis, the perceived value of carbon labels, the consideration of product environmental attributes, the preferences of carbon labels, the household background, and their educational background. In response to these factors, this paper proposes, in a public perspective, the strategies to enhance the dissemination of carbon labels.     

混合碳减排制度设计研究

碳减排是减缓气候变暖的必由之路,国际社会正在积极推动全球碳减排。我国已向国际社会承诺了碳减排目标,并正在大力开展相关政策的研究和制定。碳税和碳交易是多年来各国激励碳减排最主要的两大机制。这两种机制各有优缺点,它们适当的混合机制可扬长避短,创造出更优越的机制。我们认为,碳税和碳交易机制之间最大的差别在于碳税机制有较低的制度成本(包括建立者一机制所需要的人力物力的投入,以及监管成本等),在操作性上更简便;而在对市场条件和信息的变化上没有碳交易机制的灵活性强,但从另一方面,这种灵活性也恰恰是风险产生的根源之一,它增加了企业在碳排放决策方面的风险和难度;此外,碳税相对于碳交易是间接的碳减排激励机制,碳交易机制的减排效果更直接。基于这些观察,我们设计出一种混合碳减排机制,它是碳税和碳交易机制的有机结合。该混合机制包含两个部分:首先是累进制碳税制度,小企业只缴纳碳税;其次,碳交易制度,建立碳交易市场并对于大企业确定初始碳排放权,对于大企业的超排,将按照高起点的碳税税率加以惩罚。这一混合机制,既考虑了不同企业之间在碳排放权上的公平性,又考虑了机制的效率,并在保障机制效率的条件下尽可能降低企业在碳排放决策上的风险。这些正是这一混合机制的优越性所在。我们还探讨了这一混合机制在我国实施的可行性,并提出了在具体实施过程中所应注意的若干重要事项,并给出了相关的政策建议。本文的探讨可以为政府碳排放政策制定部门提供参考。     

Fibre reinforced polymers in the sports industry – Life Cycle Engineering methodology applied to a snowboard using anisotropic layer design

Technological development has had huge impacts in sports performance throughout the years, fostering the development of specific materials and manufacturing processes for sports-related products. Within this context, a new technology for snowboards was developed taking advantage of the internal coupling effects of Fibre Reinforced Plastics (FRP) using an anisotropic layer design. This work deals with the technical, economic and environmental evaluation of a snowboard made of three alternative materials, namely carbon, glass and flax fibre reinforced plastics. It shows how a life cycle analysis can support the design and development of products by applying a Life Cycle Engineering methodology to the design process of a snowboard using an innovative technology. In this case, both the material choice and the fiber placement angles have a significant impact on the stiffness of the resulting FRP and thus in the three dimensions of analysis - cost, environmental and technical. The natural fiber is the most sustainable option environmentally, the glass fiber is the best one economically and the carbon fibre is the best in terms of technical performance. Therefore, the importance attributed to each dimension of analysis is pondered and traded-off to allow an aggregated analysis of the alternatives and a well-informed decision-making.     

Properties of alkali-activated fly ash: high performance to lightweight

Alkali ash material (AAM) concrete is a unique material that is sustainable and cost-effective because it utilises waste fly ash, and has properties superior to other concrete products. The AAM concrete described here is produced from the addition of inexpensive chemicals to fly ash. AAM can be used to create a wide range of materials including high performance concrete (HPC-AAM) and lightweight (LW-AAM). The high performance AAM provides rapid strength gain along with high ultimate strengths of more than 110 MPa (16000 psi). LW-AAM can produce materials with densities ranging from 1200 to 2200 kg/m³ and compressive strengths from 2 (290 psi) to 65 MPa (9500 psi). Both HPC-AAM and LW-AAM have far better environmental resistance than Portland cement concrete, resisting attack from sulphuric acid (H₂SO₄), hydrochloric acid (HCl) and organic acids. AAMs resists freeze–thaw attack and high abrasion, possesses low chloride permeability and does not exhibit alkali silica reactivity.     

城乡居民食物碳消费变化与差异分析——以安徽省为例

经济的快速发展和居民人口的不断增长,给社会和生态环境带来了巨大压力,不可持续的居民食物碳消费是造成全球环境问题的重要原因之一。居民食物碳消费是环境碳循环研究和可持续消费的重要内容。采用政府宏观统计数据,研究了1985~2007年安徽省城乡居民食物碳消费结构和食物碳消费的变化趋势和影响因素,并对城乡差异进行了分析比较,结果表明：(1)城市居民家庭食物碳消费结构转变较农村显著,城市居民食物碳消费从以“粮食碳消费为主”的比较单一的消费模式转变为以“粮食、肉类、食用植物油碳消费为主”的多元消费模式;而农村居民食物碳消费从以“粮食碳消费为主”转变为以“粮食、食用植物油碳消费为主”的多元消费模式;(2)城市居民人均、户均食物碳消费量均呈下降趋势,但食物消费总量却呈上升趋势,加剧了食物碳消费的环境影响;农村人均和户均食物碳消费和碳消费总量呈下降趋势,但人均、户均食物碳消费仍高于城市,农村居民食物碳消费的生态压力依然较大。(3)Pearson乘积相关分析表明,影响城市居民人均食物碳消费的主要因素是恩格尔系数和人均可支配收入,而影响农村居民人均食物碳消费的主要因素是农村人均纯收入。研究结果对进一步探索可持续的居民消费模式和减轻环境影响具有重要的现实意义。
     

Perceived Influence of Proenvironmental Testimonials

Recommendations for communicators to make environmental issues more concrete in public align with the tenets of exemplification theory. Audiences may also engage with messages that they perceive as influencing them more than others, an outcome that aligns with the third-person effects framework. What is not well known is how these two areas of research intersect, namely, how exemplars about environmental issues may impact perceived message influence on the self-relative to others. This study examines the effects of testimonials on the perceived influence of environmental messages. Two experiments, each conducted simultaneously in Singapore and the Midwestern US, suggest that university students perceive themselves to be more influenced than others by proenvironmental messages. The second experiment shows that this perceptual bias is related to message desirability and individuals’ environmental values. Both experiments reveal location-specific effects, which is useful for understanding how to communicate environmental problems to global audiences.     

基于多行业DSGE模型的中国碳减排政策效应

碳达峰和碳中和目标的提出,标志着中国低碳减排进入新的阶段,从国家层面的宏观政策包括各个行业的行业政策都在推行各种低碳减排政策,从行业异质性视角动态分析碳减排政策的效应具有重要的学术和实践意义。为此,构建一个包含环境外部性和碳减排政策的多行业动态随机一般均衡模型,研究许可证交易和碳税两种政策情景下,行业技术冲击、税收政策和减排政策调整冲击对宏观经济、环境和行业排放的动态效应。模拟发现:许可证交易政策情景下,行业技术冲击具有明显的结构性效应,覆盖行业企业减排率上升,排放下降,而未覆盖行业排放随产出上升而上升,而在碳税政策情景下,这种差异并不明显。政府采用盯住总排放波动的碳减排政策能够有效地减少冲击带来的福利损失,提高对维持排放水平的关注程度能够减少相应的福利损失。建议政府有效地权衡经济增长和改善环境二者之间的关系,在不造成大的负面经济影响的前提下,加大减排政策力度,推广和扩大碳交易试点范围,尽快在全国建立统一的碳市场。制定碳减排政策时,考虑碳减排政策收入的返还机制,配以减税的财政政策以刺激经济,缓和减排政策的负面影响。政府应根据排放水平顺周期地动态调整碳减排政策的强度,适当提高对维持排放水平的关注程度。     

Emission of ammonia from indoor concrete wall and assessment of human exposure

Addition of urea-based antifreeze admixtures during cement mixing can make it possible to produce concrete cement in construction of buildings in cold weather; this, however, has led to increasing indoor air pollution due to continuous transformation and emission from urea to gaseous ammonia in indoor concrete wall. It is believed that ammonia is harmful to human body and exposure to ammonia can cause some serious symptoms such as headaches, burns, and even permanent damage to the eyes and lungs. In order to understand the emission of ammonia from indoor concrete wall in civil building and assess the health risk of people living in these buildings, the experimental pieces of concrete wall were first prepared by concreting cement and urea-based antifreeze admixtures to simulate the indoor wall in civil building in this work. Then environmental chamber was adopted for studying the effect of temperature, relative humility and air exchange rate on emission of ammonia from experimental pieces of concrete wall. Also the field experiment was made at selected rooms in given civil buildings. Exposure and potential dose of adult and children exposed to indoor/outdoor ammonia in summer and in winter are calculated and evaluated by using Scenario Evaluation Approach. The results indicated that high air exchange rate leads to decreased ammonia concentration, and elevation of temperature causes increasing ammonia concentration and volatilizing rate in chamber. The complete emission of ammonia from the wall containing urea-based antifreeze admixtures needs more than 10 years in general. Ventilating or improving air exchange can play a significant role in reducing ammonia concentration in actual rooms in field experiments. Urea-based antifreeze admixtures in concrete wall can give rise to high exposure and potential dose, especially in summer. Generally, adults have a high potential dose than children, while children have personal average dose rate beyond adults in the same conditions.