Phosphorus transport pathways to streams in tile-drained agricultural watersheds

Agriculture is a major nonpoint source of phosphorus (P) in the Midwest, but how surface runoff and tile drainage interact to affect temporal concentrations and fluxes of both dissolved and particulate P remains unclear. Our objective was to determine the dominant form of P in streams (dissolved or particulate) and identify the mode of transport of this P from fields to streams in tile-drained agricultural watersheds. We measured dissolved reactive P (DRP) and total P (TP) concentrations and loads in stream and tile water in the upper reaches of three watersheds in east-central Illinois (Embarras River, Lake Fork of the Kaskaskia River, and Big Ditch of the Sangamon River). For all 16 water year by watershed combinations examined, annual flow-weighted mean TP concentrations were >0.1 mg L(-1), and seven water year by watershed combinations exceeded 0.2 mg L(-1). Concentrations of DRP and particulate P (PP) increased with stream discharge; however, particulate P was the dominant form during overland runoff events, which greatly affected annual TP loads. Concentrations of DRP and PP in tiles increased with discharge, indicating tiles were a source of P to streams. Across watersheds, the greatest DRP concentrations (as high as 1.25 mg L(-1)) were associated with a precipitation event that followed widespread application of P fertilizer on frozen soils. Although eliminating this practice would reduce the potential for overland runoff of P, soil erosion and tile drainage would continue to be important transport pathways of P to streams in east-central Illinois.     

Tile water quality following liquid swine manure application into standing corn

The quality of water draining fields fertilized with liquid swine (Sus scrofa) manure (LSM) sidedressed into standing corn (Zea mays L.) at rates ranging from 0 to 94 m(3) ha(-1), either topdressed (TD) onto the surface, or injected (INJ) into the soil once annually for each of three consecutive years was evaluated. Liquid swine manure application rate was a critical driver of preferential flow of LSM to tile as detected by turbidity, concentrations of NH(4)(+)-N, dissolved reactive phosphorus (DRP), and the presence of enteric bacteria (Escherichia coli). Contaminant movement to drains occurred immediately after 75 and 94 m(3) LSM ha(-1) were injected (e.g., 2.5 mg DRP L(-1), 3-yr average). With injection of 56 m(3) ha(-1) or less, drainage water was not turbid and concentrations of NH(4)(+)-N, DRP, and enteric bacteria were dramatically lower than with the higher rates, even when tiles flowed freely during manure application. Application method also affected tile water quality. With TD applications (37 and 56 m(3) ha(-1)), nutrients and bacteria did not move to tiles at the time of application, but with rains that fell within 3 d after application, concentrations increased (e.g., 0.1 mg DRP L(-1)), although less than with INJ. Overall, sidedress injection rates that supplied adequate crop nutrients did not compromise drainage water quality.     

REGIONAL ASSESSMENT OF NLEAP NO3-N LEACHING INDICES1

ABSTRACT: Nonpoint source ground water contamination by nitrate nitrogen (NO₃-N) leached from agricultural lands can be substantial and increase health risks to humans and animals. Accurate and rapid methods are needed to identify and map localities that have a high potential for contamination of shallow aquifers with NO₃-N leached from agriculture. Evaluation of Nitrate Leaching and Economic Analysis Package (NLEAP) indices and input variables across an irrigated agricultural area on an alluvial aquifer in Colorado indicated that all leaching indices tested were more strongly correlated with aquifer NO₃-N concentration than with aquifer N mass. Of the indices and variables tested, the NO₃-N Leached (NL) index was the NLEAP index most strongly associated with groundwater NO₃-N concentration (r² values from 0.37 to 0.39). NO₃-N concentration of the leachate was less well correlated with ground water NO₃-N concentration (r² values from 0.21 to 0.22). Stepwise regression analysis indicated that, although inorganic and organic/inorganic fertilizer scenarios had similar r² values, the Feedlot Indicator (proximity) variable was significant over and above the NO₃-N Leached index for the inorganic scenario. The analysis also showed that combination of either Movement Risk Index (MIRI) or NO₃-N concentration of the leachate with the NO₃-N Leached index leads to an improved regression, which provides insight into area-wide associations between agricultural activities and ground water NO₃-N concentration.     

Hydrologic Controls on Nitrogen and Phosphorous Dynamics in Relict Oxbow Wetlands Adjacent to an Urban Restored Stream

Although wetlands are known to be sinks for nitrogen (N) and phosphorus (P), their function in urban watersheds remains unclear. We analyzed water and nitrate (NO₃^?) and phosphate (PO₄^3?) dynamics during precipitation events in two oxbow wetlands that were created during geomorphic stream restoration in Baltimore County, Maryland that varied in the nature and extent of connectivity to the adjacent stream. Oxbow 1 (Ox1) received 1.6‐4.2% and Oxbow 2 (Ox2) received 4.2‐7.4% of cumulative streamflow during storm events from subsurface seepage (Ox1) and surface flow (Ox2). The retention time of incoming stormwater ranged from 0.2 to 6.7 days in Ox1 and 1.8 to 4.3 days in Ox2. Retention rates in the wetlands ranged from 0.25 to 2.74 g N/m²/day in Ox1 and 0.29 to 1.94 g N/m²/day in Ox2. Percent retention of the NO₃^?‐N load that entered the wetlands during the storm events ranged from 64 to 87% and 23 to 26%, in Ox1 and Ox2, respectively. During all four storm events, Ox1 and Ox2 were a small net source of dissolved PO₄^3? to the adjacent stream (i.e., more P exited than entered the wetland), releasing P at a rate of 0.23‐20.83 mg P/m²/day and 3.43‐24.84 mg P/m²/day, respectively. N and P removal efficiency of the oxbows were regulated by hydrologic connectivity, hydraulic loading, and retention time. Incidental oxbow wetlands have potential to receive urban stream and storm flow and to be significant N sinks, but they may be sources of P in urban watersheds.     

SPRING RUNOFF AND DRAINAGE N AND P LOSSES FROM HOG-MANURED CORN1

ABSTRACT: A two-year study was conducted to assess the effect of hog manure on the losses of nitrogen and phosphorus in runoff and drainage from grain-corn (Zea mays L.) plots, and the importance of spring versus annual loads. Treatments consisted of mineral N-P-K fertilizer applied at rates of 152 kg N ha^-1, 35 kg P ha^-1, and 86 kg K ha^-1; and hog (Sus scrofa domestica L.) manure applied preplant or post-emergence (six-to-eight leaf stage), at 152 kg N ha^-1, 39 kg P ha^-1, and 112 kg K ha^-1. The plots were rototilled (7 cm depth) in spring to incorporate fertilizer and preplant hog manure, and fall chisel-plowed (15 cm depth) to incorporate chopped corn residues. They were arranged in a completely randomized plot design. Flow volumes and nutrient levels in runoff and drainage waters were monitored year round but occurred mainly during the snowmelt (March 25-April 9), and post.snowmelt (April 10-May 13) periods. Of the total amount of water lost during snowmelt, 90 percent was in runoff, while 92 percent occurred as drainage in the post-snowmelt period. Sixty-five percent of the total annual volume of water lost was lost during these two periods as runoff and drainage. Treatments did not affect the annual snowmelt or post-snowmelt N and P loads. Total annual loads averaged 8.0 kg TKN ha^-1, 1.8 kg NH₄-N ha^-1, 43 kg NO₃-N ha^-1, 0.4 kg TP ha^-1, and 0.15 kg PO₄-P ha^-1. Spring (snowmelt and ost-snowmelt) runoff and drainage loads averaged 2.9 kg TKN ha^-1, 1.2 kg NH₄-N ha^-1, 18 kg NO₃-N ha^-1, 0.25 kg TP ha^-1, and 0.04 kg PO₄-P ha^-1, which were 40 percent to 70 percent of the yearly nutrient loads. Therefore, the hog manure management systems examined were of no greater threat to the environment than mineral fertilizers. However, spring N and P losses do represent an important part of the annual nutrient loss budget, even with conservation practices.     

STREAM NITRATE-N LOADS IN RELATION TO VARIATIONS IN ANNUAL AND SEASONAL RUNOFF REGIMES1

ABSTRACT: The calculation of stream nutrient loads from a sampling period of one year or, at most, a few years may provide an inaccurate estimate of average seasonal or annual loads due to considerable year-to-year variations in hydrological regime. The number of years of record required to give a reliable estimate of long-term average NO₃-N loads was analyzed for E. Duffin Creek and the Nottawasaga River in Ontario, Canada. Nitrate load rating relationships were used in combination with a continuous stream discharge record for 22 years (E. Duffin Creek) and 34 years (Nottawasaga River) to simulate long-term seasonal and annual variation in NO₃.N loads. The errors involved in calculating average loads were examined by comparing the loads derived from sampling periods of one or more consecutive years duration with the estimated long-term average load for the two rivers. Annual NO₃-N loads for a single year deviated from the long-term average load by ± 20 to 53 percent in 8 out of 22 years in E. Duffin Creek and in 13 of 34 years in the Nottawasaga River. Six consecutive years of record would be required for both rivers to ensure that an error of > ± 20 percent would occur in only 5 percent of these observation periods. February-April NO₃-N loads for a single year could deviate by up to +90 percent or -61 percent from the long-term average spring period load for the two rivers. A sampling period of at least 6–7 years would be needed to estimate average NO₃-N loads for the spring runoff season with an error <± 20 percent.     

Nitrate transport in shallow groundwater at the stream–riparian interface in an urbanizing catchment

Drive point peizometers were installed at the stream–riparian interface in a small urbanizing southern Ontario catchment to measure the effect of buffers (presence/ absence) and land use (urban/agricultural) on the movement of NO^? ₃-N in shallow groundwater from the riparian area to the stream. Mean NO^? ₃-N concentrations ranged from 1.0 to 1.3 mg L^?1 with maximum values of 9.4 mg L^?1. Holding land use constant, there was no significant difference (p>0.05) in NO^? ₃3-N concentration between buffered and unbuffered sites. Nitrate-N levels were not significantly different (p>0.05) as a function of land use. The lack of difference between sites as a function of buffer absence/presence and land use is probably due to the placement of some peizometers in low conductivity materials that limited groundwater flow from the riparian zone to the stream. Subsurface factors controlling the hydraulic gradient are important in defining buffer effectiveness and buffer zones should not be used indiscrim inately as a management tool in urban and agricultural landscapes to control nitrate-N loading in shallow groundwater to streams without detailed knowledge of the hydrogeo logic environment.     

Factors affecting nitrate distribution in shallow groundwater under a beef farm in South Eastern Ireland

Groundwater contamination was characterised using a methodology which combines shallow groundwater geochemistry data from 17 piezometers over a 2 yr period in a statistical framework and hydrogeological techniques. Nitrate–N (NO₃-N) contaminant mass flux was calculated across three control planes (rows of piezometers) in six isolated plots. Results showed natural attenuation occurs on site although the method does not directly differentiate between dilution and denitrification. It was further investigated whether NO₃-N concentration in shallow groundwater (<5 m below ground level) generated from an agricultural point source on a 4.2 ha site on a beef farm in SE Ireland could be predicted from saturated hydraulic conductivity (K_sat) measurements, ground elevation (m Above Ordnance Datum), elevation of groundwater sampling (screen opening interval) (m AOD) and distance from a dirty water point pollution source. Tobit regression, using a background concentration threshold of 2.6 mg NO₃-N L⁻¹ showed, when assessed individually in a step wise procedure, K_sat was significantly related to groundwater NO₃-N concentration. Distance of the point dirty water pollution source becomes significant when included with K_sat in the model. The model relationships show areas with higher K_sat values have less time for denitrification to occur, whereas lower K_sat values allow denitrification to occur. Areas with higher permeability transport greater NO₃-N fluxes to ground and surface waters. When the distribution of Cl⁻ was examined by the model, K_sat and ground elevation had the most explanatory power but K_sat was not significant pointing to dilution having an effect. Areas with low NO₃ concentration and unaffected Cl⁻ concentration points to denitrification, low NO₃ concentration and low Cl⁻ chloride concentration points to dilution and combining these findings allows areas of denitrification and dilution to be inferred. The effect of denitrification is further supported as mean groundwater NO₃-N was significantly (P < 0.05) related to groundwater N₂/Ar ratio, redox potential (Eh), dissolved O₂ and N₂ and was close to being significant with N₂O (P = 0.08). Calculating contaminant mass flux across more than one control plane is a useful tool to monitor natural attenuation. This tool allows the identification of hot spot areas where intervention other than natural attenuation may be needed to protect receptors.     

Nutrient transport through a Vegetative Filter Strip with subsurface drainage

The transport of nutrients and soil sediments in runoff has been recognized as a noteworthy environmental issue. Vegetative Filter Strips (VFS) have been used as one of the best management practices (BMPs) for retaining nutrients and sediments from surface runoff, thus preventing the pollutants from reaching receiving waters. However, the effectiveness of a VFS when combined with a subsurface drainage system has not been investigated previously. This study was undertaken to monitor the retention and transport of nutrients within a VFS that had a subsurface drainage system installed at a depth of 1.2 m below the soil surface. Nutrient concentrations of NO₃-N (Nitrate Nitrogen), PO₄⁻ (Orthophosphorus), and TP (Total Phosphorus) were measured in surface water samples (entering and leaving the VFS), and subsurface outflow. Soil samples were collected and analyzed for plant available Phosphorus (Bray P1) and NO₃-N concentrations. Results showed that PO₄⁻, NO₃-N, and TP concentrations decreased in surface flow through the VFS. Many surface outflow water samples from the VFS showed concentration reductions of as much as 75% for PO₄⁻ and 70% for TP. For subsurface outflow water samples through the drainage system, concentrations of PO₄⁻ and TP decreased but NO₃-N concentrations increased in comparison to concentrations in surface inflow samples. Soil samples that were collected from various depths in the VFS showed a minimal buildup of nutrients in the top soil profile but indicated a gradual buildup of nutrients at the depth of the subsurface drain. Results demonstrate that although a VFS can be very effective in reducing runoff and nutrients from surface flow, the presence of a subsurface drain underneath the VFS may not be environmentally beneficial. Such a combination may increase NO₃-N transport from the VFS, thus invalidating the purpose of the BMP.     

Simulation of Daily Flow Pathways,Tile‐Drain Nitrate Concentrations,and Soil‐Nitrogen Dynamics Using SWAT

Tile drainage significantly alters flow and nutrient pathways and reliable simulation at this scale is needed for effective planning of nutrient reduction strategies. The Soil and Water Assessment Tool (SWAT) has been widely utilized for prediction of flow and nutrient loads, but few applications have evaluated the model's ability to simulate pathway‐specific flow components or nitrate‐nitrogen (NO₃‐N) concentrations in tile‐drained watersheds at the daily time step. The objectives of this study were to develop and calibrate SWAT models for small, tile‐drained watersheds, evaluate model performance for simulation of flow components and NO₃‐N concentration at daily intervals, and evaluate simulated soil‐nitrogen dynamics. Model evaluation revealed that it is possible to meet accepted performance criteria for simulation of monthly total flow, subsurface flow (SSF), and NO₃‐N loads while obtaining daily surface runoff (SURQ), SSF, and NO₃‐N concentrations that are not satisfactory. This limits model utility for simulating best management practices (BMPs) and compliance with water quality standards. Although SWAT simulates the soil N‐cycle and most predicted fluxes were within ranges reported in agronomic studies, improvements to algorithms for soil‐N processes are needed. Variability in N fluxes is extreme and better parameterization and constraint, through use of more detailed agronomic data, would also improve NO₃‐N simulation in SWAT. Editor's note : This paper is part of the featured series on SWAT Applications for Emerging Hydrologic and Water Quality Challenges. See the February 2017 issue for the introduction and background to the series.     

Sample intake position and loading rates from nonpoint source pollution

Paired water samples were simultaneously activated from two different vertical positions within the approach section of a flow-control structure to determine the effect of sample intake position on nonpoint runoff parameter concentrations and subsequent event loads. Suspended solids (SS), total phosphorus (TP) and organic plus exchangeable nitrogen [(Or+Ex)-N] were consistently higher throughout each runoff event when sampled from the floor of the approach section as opposed to those samples taken at midstage. Dissolved molybdate reactive phosphorus (DMRP) and ammonium (NH₄-N) concentrations did not appear to be significantly affected by the vertical difference in intake position. However, the nitrate plus nitrite nitrogen [(NO₃+NO₂)-N] concentrations were much higher when sampled from the midstage position.Although the concentration differences between the two methods were not appreciable, when evaluated in terms of event loads, discrepancies were evident for all parameters. Midstage sampling produced event loads for SS, TP, (Or + Ex)–N, DMRP, NH₄-N, and (NO₃+NO₂)-N that were 44,39,35,80,71, and 181%, respectively, of floor sampling loads. Differences in loads between the two methods are attributed to the midstage position, sampling less of the bed load. The correct position will depend on the objective; however, such differences should be recognized during the design phase of the monitoring program.This work was supported by the Soil Science Department, College of Agriculture and Life Sciences, University of Wisconsin-Madison, and by the U.S. Environmental Protection Agency, Region V., Chicago, Illinois (Grant No. G005139-01).     

GIS-based spatial regression and prediction of water quality in river networks: A case study in Iowa

Nonpoint source pollution is the leading cause of the U.S.’s water quality problems. One important component of nonpoint source pollution control is an understanding of what and how watershed-scale conditions influence ambient water quality. This paper investigated the use of spatial regression to evaluate the impacts of watershed characteristics on stream NO₃NO₂-N concentration in the Cedar River Watershed, Iowa. An Arc Hydro geodatabase was constructed to organize various datasets on the watershed. Spatial regression models were developed to evaluate the impacts of watershed characteristics on stream NO₃NO₂-N concentration and predict NO₃NO₂-N concentration at unmonitored locations. Unlike the traditional ordinary least square (OLS) method, the spatial regression method incorporates the potential spatial correlation among the observations in its coefficient estimation. Study results show that NO₃NO₂-N observations in the Cedar River Watershed are spatially correlated, and by ignoring the spatial correlation, the OLS method tends to over-estimate the impacts of watershed characteristics on stream NO₃NO₂-N concentration. In conjunction with kriging, the spatial regression method not only makes better stream NO₃NO₂-N concentration predictions than the OLS method, but also gives estimates of the uncertainty of the predictions, which provides useful information for optimizing the design of stream monitoring network. It is a promising tool for better managing and controlling nonpoint source pollution.     

Linking Soil Erosion to Instream Dissolved Phosphorus Cycling and Periphyton Growth

Phosphorus (P) is a limiting nutrient in freshwater systems and when present in runoff from agricultural lands or urban centers may contribute to excessive periphyton growth. In this study, we examined the link between soil erosion and delivery of eroded soil to streams during flow events, and the impact of that freshly deposited soil on dissolved reactive P (DRP) concentrations and periphyton growth under baseflow conditions when the risk of stream eutrophication is greatest. A microcosm experiment was designed to simulate the release of P from soil which had been amended with different amounts of P fertilizer to overlying water during baseflow conditions. Unglazed tiles, inoculated for five days in a second order stream, were incubated for seven days in microcosms containing soil with eight levels of soil Mehlich‐3 plant available phosphorus (M3P) ranging from 20 to 679 mg/kg M3P. Microcosm DRP was monitored. Following incubation tiles were scraped and the periphyton analyzed for chlorophyll a. Microcosm DRP concentrations increased with increasing soil M3P and equilibrium phosphorus concentration (EPC₀). Relationships between M3P, EPC₀, and DRP were nonlinear and increases in soil M3P and/or DRP had a greater impact on biomass accumulation when these parameters were above threshold values of 30 mg/kg M3P and 0.125 mg/L DRP. Significantly, this ecological threshold corresponds to the agronomic thresholds above which increased soil M3P does not increase plant response.     

Rye cover crop and gamagrass strip effects on NO3 concentration and load in tile drainage

A significant portion of the NO3 from agricultural fields that contaminates surface waters in the Midwest Corn Belt is transported to streams or rivers by subsurface drainage systems or "tiles." Previous research has shown that N fertilizer management alone is not sufficient for reducing NO3 concentrations in subsurface drainage to acceptable levels; therefore, additional approaches need to be devised. We compared two cropping system modifications for NO3 concentration and load in subsurface drainage water for a no-till corn (Zea mays L.)-soybean (Glycine max [L.] Merr.) management system. In one treatment, eastern gamagrass (Tripsacum dactyloides L.) was grown in permanent 3.05-m-wide strips above the tiles. For the second treatment, a rye (Secale cereale L.) winter cover crop was seeded over the entire plot area each year near harvest and chemically killed before planting the following spring. Twelve 30.5x42.7-m subsurface-drained field plots were established in 1999 with an automated system for measuring tile flow and collecting flow-weighted samples. Both treatments and a control were initiated in 2000 and replicated four times. Full establishment of both treatments did not occur until fall 2001 because of dry conditions. Treatment comparisons were conducted from 2002 through 2005. The rye cover crop treatment significantly reduced subsurface drainage water flow-weighted NO3 concentrations and NO3 loads in all 4 yr. The rye cover crop treatment did not significantly reduce cumulative annual drainage. Averaged over 4 yr, the rye cover crop reduced flow-weighted NO3 concentrations by 59% and loads by 61%. The gamagrass strips did not significantly reduce cumulative drainage, the average annual flow-weighted NO3 concentrations, or cumulative NO3 loads averaged over the 4 yr. Rye winter cover crops grown after corn and soybean have the potential to reduce the NO3 concentrations and loads delivered to surface waters by subsurface drainage systems.     

Groundwater Nutrient Concentrations and Mass Loading Rates at Iowa Golf Courses

Golf courses are often considered by the public to be significant nitrogen (N) and phosphorus (P) nonpoint sources but only limited information exists on nutrient concentrations and loads in golf course groundwater. In this study, we measured N and P concentrations in groundwater and available surface water at six randomly selected Iowa golf courses to assess the loading risk posed by these facilities to groundwater and local rivers. At each course, three shallow monitoring wells were installed, one each on representative tee, fairway, and rough locations. Wells and available surface water were sampled on eight occasions during 2015 and 2016. NO₃‐N concentrations were not detected above 1 mg/L at three of the six courses monitored in this study and the overall mean NO₃‐N concentration in Iowa golf courses was 2.2 mg/L. The mass of NO₃‐N recharged to groundwater averaged 3.3 kg/ha at the six courses, which represents approximately one‐tenth of the NO₃‐N load exported by the watershed that contains the course and represented approximately 0.1 to 8% of the fertilizer N applied. Groundwater orthophosphorus concentrations averaged 0.13 mg/L and were similar to those measured in a variety of settings across Iowa. Study results should prove useful in evaluating nutrient contributions from golf courses in Midwestern states where nutrient reduction strategies are being pursued.     

Denitrification in alluvial wetlands in an urban landscape

Riparian wetlands have been shown to be effective "sinks" for nitrate N (NO3-), minimizing the downstream export of N to streams and coastal water bodies. However, the vast majority of riparian denitrification research has been in agricultural and forested watersheds, with relatively little work on riparian wetland function in urban watersheds. We investigated the variation and magnitude of denitrification in three constructed and two relict oxbow urban wetlands, and in two forested reference wetlands in the Baltimore metropolitan area. Denitrification rates in wetland sediments were measured with a 15N-enriched NO3- "push-pull" groundwater tracer method during the summer and winter of 2008. Mean denitrification rates did not differ among the wetland types and ranged from 147 +/- 29 microg N kg soil(-1) d(-1) in constructed stormwater wetlands to 100 +/- 11 microg N kg soil(-1) d(-1) in relict oxbows to 106 +/- 32 microg N kg soil(-1) d(-1) in forested reference wetlands. High denitrification rates were observed in both summer and winter, suggesting that these wetlands are sinks for NO3- year round. Comparison of denitrification rates with NO3- standing stocks in the wetland water column and stream NO3- loads indicated that mass removal of NO3- in urban wetland sediments by denitrification could be substantial. Our results suggest that urban wetlands have the potential to reduce NO3- in urban landscapes and should be considered as a means to manage N in urban watersheds.     

DYNAMICS OF ADDED NITRATE AND PHOSPHATE COMPARED IN A NORTHERN CALIFORNIA WOODLAND STREAM1

ABSTRACT: Injections of NO₃ and PO₄ were made during September 1975 into Little Lost Man Creek, a small pristine stream in Redwood National Park, California. Chloride, a conservative constituent, was added in a known ratio to the nutrients. Nutrient loss at a downstream point was calculated using concentration of added Cl as a reference. Nitrate nitrogen (NO₃-N), added for 4 h, reached 920 μg/1 (above 5 μg/1 background) just below the injection point, but increased only to 405 μg/1 at 310 m downstream. The concentration decrease was attributed to dispersion and to uptake by stream biota. Percent of NO₃-N lost decreased with increasing concentration of NO₃-N. Phosphate phosphorus (PO₄-P) was added a week after the NO₃-N for 3 h, causing a concentration increase of 296 μg/1 (above 13 μg/1 background) just below the injection point, of 161 μg/1 at 90 m downstream, and of 98 μg/1 at 310 m. Percent loss of PO₄-P at downstream sites increased with increasing PO₄-P concentration and also for a short period after peak concentration occurred, but then decreased as PO₄-P concentration continued decreasing. Differences in stream response to added NO₃-N and PO₄-P are attributed to differing rates of reaction with biota and differing degrees of interaction with abiotic stream solids.     

Evaluating agricultural best management practices in tile-drained subwatersheds of the Mackinaw River, Illinois

Best management practices (BMPs) are widely promoted in agricultural watersheds as a means of improving water quality and ameliorating altered hydrology. We used a paired watershed approach to evaluate whether focused outreach could increase BMP implementation rates and whether BMPs could induce watershed-scale (4000 ha) changes in nutrients, suspended sediment concentrations, or hydrology in an agricultural watershed in central Illinois. Land use was >90% row crop agriculture with extensive subsurface tile drainage. Outreach successfully increased BMP implementation rates for grassed waterways, stream buffers, and strip-tillage within the treatment watershed, which are designed to reduce surface runoff and soil erosion. No significant changes in nitrate-nitrogen (NO-N), total phosphorus (TP), dissolved reactive phosphorus, total suspended sediment (TSS), or hydrology were observed after implementation of these BMPs over 7 yr of monitoring. Annual NO-N export (39-299 Mg) in the two watersheds was equally exported during baseflow and stormflow. Mean annual TP export was similar between the watersheds (3.8 Mg) and was greater for TSS in the treatment (1626 ± 497 Mg) than in the reference (940 ± 327 Mg) watershed. Export of TP and TSS was primarily due to stormflow (>85%). Results suggest that the BMPs established during this study were not adequate to override nutrient export from subsurface drainage tiles. Conservation planning in tile-drained agricultural watersheds will require a combination of surface-water BMPs and conservation practices that intercept and retain subsurface agricultural runoff. Our study emphasizes the need to measure conservation outcomes and not just implementation rates of conservation practices.     

Particulate phosphorus transport within stream flow of an agricultural catchment

There is interest in quantifying phosphorus (P) loss from intensively grazed dairy landscapes to identify key pathways and target remediation methods. The Bog Burn drains a dairying catchment in Southland, New Zealand, and has been monitored at fortnightly intervals over a 12-mo period at four sites for suspended sediment (SS), dissolved reactive phosphorus (DRP), and total phosphorus (TP). Time-integrated samplers, deployed at 0.6 median water depth at each site (calculated from previous year's flow data), collected sediment samples, which were analyzed for SS, bioavailable phosphorus (BAP), and TP. Mean concentrations of DRP and TP in stream flow and BAP and TP in sediment were generally highest in summer or autumn (0.043 mg DRP L(-1), 0.160 mg TP L(-1), 173 mg BAP kg(-1), 2228 mg TP kg(-1)) and lowest in winter or spring (0.012 mg DRP L(-1), 0.034 mg TP L(-1), 6 mg BAP kg(-1), 711 mg TP kg(-1)), while loads were highest in winter. Analysis of (137)Cs concentrations in trapped sediment, topsoil, subsoil, and stream bed and bank sediment indicated that trapped sediment was derived from topsoil and entered the stream either through tile drainage or, to a lesser extent, overland flow. Because concentrations of DRP and TP in stream flow are in excess of recommended limits for good water quality (>0.01 mg DRP L(-1), 0.033 mg TP L(-1)), management should focus on the topsoil and specifically on decreasing P loss via tile drainage. This is best achieved by decreasing soil Olsen P concentrations, especially because, on average, Olsen P concentrations in the catchment were above the agronomic optimum.     

Groundwater Nitrate Concentration Reductions in a Riparian Buffer Enrolled in the NC Conservation Reserve Enhancement Program

Riparian buffers have been used for many years as a best management practice to decrease the effects of nonpoint pollution from watersheds. The NC Conservation Reserve Enhancement Program (NC CREP) has established buffers to treat groundwater nitrate‐nitrogen (NO₃^?‐N) from agricultural sources in multiple river basins. A maturing 46 m wide riparian buffer enrolled in NC CREP was studied to determine its effectiveness in reducing groundwater NO₃^?‐N concentrations from a cattle pasture fertilized with poultry litter. Three monitoring blocks that included groundwater quality wells, water table wells, and soil redox probes, were established in the buffer. NO₃^?‐N concentrations decreased significantly across the buffer in all of the monitoring blocks with mean reductions of 76‐92%. Many biological processes, including denitrification and plant uptake, may have been responsible for the observed NO₃^?‐N reductions but could not be differentiated in this study. However, mean reductions in Cl^? concentrations ranged from 48‐65% through the blocks, which indicated that dilution was an important factor in observed NO₃^?‐N reductions. These findings should be carefully considered for future buffer enrollments when assigning nitrogen removal credits.