NUTRIENTS IN STREAMS DURING BASEFLOW IN SELECTED ENVIRONMENTAL SEVFINGS OF THE POTOMAC RiVER BASIN1

ABSTRACT: A regional assessment of water quality in small streams was conducted within four areas of distinct physiography and lithology in the upper Potomac River Basin. The Potomac River is a major tributary to the Chesapeake Bay, and this study provides new insight on the relationships between nutrient concentrations in small streams and watershed characteristics within this river basin. Nutrient concentrations were compared to land-use data including categories for agriculture (cropland and pasture), urban areas, and forests. Among agricultural areas, streams draining areas of intense row cropping typically contained higher nitrate concentrations than did those draining pastures. Streams draining forested areas typically had the lowest nutrient concentrations. Streams in areas underlain by carbonate bedrock were more likely to contain elevated concentrations of inorganic nitrogen and potassium than did streams in areas underlain by fractured siliciclastic or crystalline rocks, and we suggest that this is a physical phenomenon related to high hydraulic conductivities in carbonate ground-water systems. The median nitrate concentrations were highest in the Great Valley portion of the Valley and Ridge physiographic province, particularly in watersheds that have both carbonate bedrock and intensive row cropping. Values of nitrate in these streams ranged up to 8.99 mg/L as nitrogen. The soluble phosphorus concentrations during baseflow were generally low in all sub-units, even in some settings with potential for high phosphorus inputs such as urban areas with municipal point sources or agricultural areas. The mobility of phosphorus in these environments may be hindered by adsorption and geochemical reactions.     

LAND USE AND AQUATIC BIOINTEGRITY IN THE BLACKFOOT RWER WATERSHED,MONTANA1

ABSTRACT: Benthic macroinvertebrate samples representing 151 taxa were collected in August 1995 to examine the linkage between land use, water quality, and aquatic biointegrity in seven tributaries of the Blackfoot River watershed, Montana. The tributaries represent silvicultural (timber harvesting), agricultural (irrigated alfalfa and hay and livestock grazing), and wilderness land uses. A 2.4 km (1.5 mile) reach of a recently restored tributary also was sampled for comparison with the other six sites. A geographic information system (GIS) was used to characterize the seven subwatersheds and estimate soil erosion, using the Modified Universal Soil Loss Equation, and sediment delivery. The wilderness stream had the highest aquatic biointegrity. Two agricultural streams had the largest estimated soil erosion and sediment delivery rates, the greatest habitat impairment from nonpoint source pollution, and the most impoverished macroinvertebrate communities. The silvicultural subwatersheds had greater rates of estimated soil erosion and sediment delivery and lower aquatic biointegrity than the wilderness reference site but evinced better conditions than the agricultural sites. A multiple-use (forestry, grazing, and wildlife management) watershed and the restored site ranked between the silvicultural and agricultural sites. This spectrum of land use and aquatic biointegrity illustrates both the challenges and opportunities that define watershed management.     

MULTISCALE INFLUENCES ON PHYSICAL AND CHEMICAL STREAM CONDITIONS ACROSS BLUE RIDGE LANDSCAPES1

ABSTRACT: Streams integrate biogeochemical processes operating at broad to local spatial scales and long term to short term time scales. Humans have extensively altered those processes in North America, with serious consequences for aquatic ecosystems. We collected data on Upper Tennessee River tributaries in North Carolina to: (1) compare landuse and landscape geomorphology with respect to their ability to explain variation in water quality, sedimentation measures, and large woody debris; (2) determine if landscape change over time contributed significantly to explaining present stream conditions; and (3) assess the importance of spatial scale in examining landuse influences on streams. Stream variables were related to both landuse and landscape geomorphology. Forest cover accounted for the most variation in nearly all models, supporting predictions of nutrient enrichment, thermal pollution, and sedimentation caused by landscape disturbance. Legacy effects from past catchment disturbance were apparent in sedimentation measures. Nitrogen and phosphorus concentrations, as well as stream temperature, were lower where riparian buffers had reforested. Models of stream physicochemistry fit better when predictors were catchment wide rather than more localized (i.e., within 2 km of a site). Cumulative impacts to streams due to changes in landuse must be managed from a watershed perspective with quantitative models that integrate across scales.     

Improvement in HSPF's Low‐Flow Predictions by Implementation of a Power Law Groundwater Storage‐Discharge Relationship

We have enhanced the ability of a widely used watershed model, Hydrologic Simulation Program — FORTRAN (HSPF), to predict low flows by reconfiguring the algorithm that simulates groundwater discharge. During dry weather periods, flow in most streams consists primarily of base flow, that is, groundwater discharged from underlying aquifers. In this study, HSPF's groundwater storage‐discharge relationship is changed from a linear to a more general nonlinear relationship which takes the form of a power law. The nonlinear algorithm is capable of simulating streamflow recession curves that have been found in some studies to better match observed dry weather hydrographs. The altered version of HSPF is implemented in the Chesapeake Bay Program's Phase 5 Model, an HSPF‐based model that simulates nutrient and sediment loads to the Chesapeake Bay, and is tested in the upper Potomac River basin, a 29,950 km² drainage area that is part of the Bay watershed. The nonlinear relationship improved median Nash‐Sutcliffe efficiencies for log daily flows at the model's 45 calibration points. Mean absolute percent error on low‐flow days dropped in five major Potomac River tributaries by up to 12 percentage points, and in the Potomac River itself by four percentage points, where low‐flow days were defined as days when observed flows were in the lowest 5th percentile range. Percent bias on low‐flow days improved by eight percentage points in the Potomac River, from ?11 to ?3%.     

Effects of Impervious Cover at Multiple Spatial Scales on Coastal Watershed Streams1

Abstract: The spatial scale and location of land whose development has the strongest influence on aquatic ecosystems must be known to support land use decisions that protect water resources in urbanizing watersheds. We explored impacts of urbanization on streams in the West River watershed, New Haven, Connecticut, to identify the spatial scale of watershed imperviousness that was most strongly related to water chemistry, macroinvertebrates, and physical habitat. A multiparameter water quality index was used to characterize regional urban nonpoint source pollution levels. We identified a critical level of 5% impervious cover, above which stream health declined. Conditions declined with increasing imperviousness and leveled off in a constant state of impairment at 10%. Instream variables were most correlated (0.77 ≤ |r| ≤ 0.92, p < 0.0125) to total impervious area (TIA) in the 100‐m buffer of local contributing areas (～5‐km² drainage area immediately upstream of each study site). Water and habitat quality had a relatively consistent strong relationship with TIA across each of the spatial scales of investigation, whereas macroinvertebrate metrics produced noticeably weaker relationships at the larger scales. Our findings illustrate the need for multiscale watershed management of aquatic ecosystems in small streams flowing through the spatial hierarchies that comprise watersheds with forest‐urban land use gradients.     

Development of an Index of Biotic Integrity for a Southeastern Coastal Plain Watershed,USA1

Abstract: This study evaluated biological integrity expectations of fish assemblages in wadeable streams for the Alabama portion of the Choctawhatchee River watershed using a multimetric approach. Thirty‐four randomly selected stream sites were sampled in late spring 2001 to calibrate an index of biotic integrity (IBI). Validation data were collected during the spring 2001, and summer and fall of 2003 from disturbed and least‐impacted targeted sites (n = 20). Thirty‐five candidate metrics were evaluated for their responsiveness to environmental degradation. Twelve metrics were selected to evaluate wadeable streams and four replacement metrics were selected for headwater streams. Scores that ranged from 58 to 60 were considered to be representative of excellent biotic integrity (none found in this study), scores of 48‐52 as good integrity (31% of the sites in this study), 40‐44 as fair (43%), 28‐34 as poor (21%), and 12‐22 as very poor (5%). Of the four stream condition categories (urban, cattle, row crop, and least impacted), the IBI scores for urban and cattle sites differed significantly from least‐impacted sites. Row crop sites, although not significantly different from least‐impacted, tended to have greater variability than the other categories. Lower IBI scores at both urban and cattle sites suggest that the IBI accurately reflects stream impairment in the Choctawhatchee River drainage.     

Assessment of a turfgrass sod best management practice on water quality in a suburban watershed

The disposal of manure on agricultural land has caused water quality concerns in many rural watersheds, sometimes requiring state environmental agencies to conduct total maximum daily load (TMDL) assessments of stream nutrients, such as nitrogen (N) and phosphorus (P). A best management practice (BMP) has been developed in response to a TMDL that mandates a 50% reduction of annual P load to the North Bosque River (NBR) in central Texas. This BMP exports composted dairy manure P through turfgrass sod from the NBR watershed to urban watersheds. The manure-grown sod releases P slowly and would not require additional P fertilizer for up to 20 years in the receiving watershed. This would eliminate P application to the sod and improve the water quality of urban streams. The soil and water assessment tool (SWAT) was used to model a typical suburban watershed that would receive the sod grown with composted dairy manure to assess water quality changes due to this BMP. The SWAT model was calibrated to simulate historical flow and estimated sediment and nutrient loading to Mary's Creek near Fort Worth, Texas. The total P stream loading to Mary's Creek was lower when manure-grown sod was transplanted instead of sod grown with inorganic fertilizers. Flow, sediment and total N yield were the same for both cases at the watershed outlet. The SWAT simulations indicated that the turfgrass BMP can be used effectively to import manure P into an urban watershed and reduce in-stream P levels when compared to sod grown with inorganic fertilizers.     

Use of watershed characteristics to select control streams for estimating effects of metal mining wastes on extensively disturbed streams

Impacts of sediments and heavy metals on the biota of streams in the copper-mining district of southwestern Montana were examined by comparing aquatic communities of impacted streams with those of control streams. Control streams were chosen through the use of a technique that identifies similar streams based on similarities in their watershed characteristics. Significant differences between impacted and control sites existed for surface substrate, riparian vegetation, and the number of macroinvertebrate taxa. These results revealed that: (a) chemical and physical habitats at the impacted sites were disrupted, (b) the presence of trout was an inadequate measure of ecological integrity for these sites, and (c) watershed classification based on a combination of mapped terrestrial characteristics provided a reasonable method to select control sites where potential control sites upstream and downstream were unsuitable.     

Evaluating the Eco‐Geomorphological Condition of Restored Streams Using Visual Assessment and Macroinvertebrate Metrics

The Stream Performance Assessment (SPA), a new rapid assessment method, was applied to 93 restored, 21 impaired, 29 reference, and 13 reference streams with some incision throughout North Carolina. Principal component analysis (PCA) indicated restored streams align more closely with reference streams rather than impaired streams. Further, PCA‐based factor analysis revealed restored streams were similar to reference streams in terms of morphologic condition, but exhibited a greater range of scores relative to aquatic habitat and bedform. Macroinvertebrate sampling and GIS watershed analyses were conducted on 84 restored streams. SPA and watershed data were compared to Ephemeroptera, Plecoptera, and Trichoptera (EPT) taxa to determine which factors indicate stream health. SPA and watershed factors were used in least squares, ridge, and principal component regression (PCR) to develop a prediction model for EPT taxa. All three methods produced reasonable predictions for EPT taxa. Cross‐validation indicated ridge regression resulted in the lowest prediction error. The ridge model was then used to predict EPT taxa numbers for 21 impaired and 25 reference streams in addition to the 84 restored streams. Statistical comparisons of the predicted scores indicated urban streams (>10% impervious watershed cover) have lower expected numbers of EPT taxa. Rural restored streams have macroinvertebrate metric scores similar to those predicted for rural reference streams.     

Phosphorus concentrations, loads, and sources within the Illinois River drainage area, northwest Arkansas, 1997-2008

In the Ozark Highlands and across the United States, effluent phosphorus (P) sources often have a profound impact on water column concentrations and riverine transport. This study evaluated (i) annual P loads at the Illinois River at Arkansas Highway 59 from calendar year 1997 through 2008, (ii) the relative contribution of effluent P sources to annual riverine P transport, (iii) longitudinal gradients in water column P concentrations downstream from several wastewater treatment plant effluent discharges, and (iv) changes in monthly P loads over the last decade. This study showed that annual P loads have ranged from 64,000 kg to over 426,000 kg and that P transport was positively correlated to hydrology (i.e., the amount of water delivered downstream). The relative contribution of P inputs from municipal facilities has decreased from 40% of the annual P load at the Illinois River at Arkansas Highway 59 to < 15% in recent years. Elevated P concentrations during base flow conditions were traced 45 river km upstream to one municipal effluent discharge, but all effluent discharges influenced P concentrations in the receiving streams. Most important, flow-adjusted monthly P loads showed two distinct trends over time. Flow-adjusted loads significantly increased from 1997 through 2002 and significantly decreased from 2002 through 2008. The concentrations and transport of P within the Illinois River drainage area are significantly decreasing from all the watershed management changes that have occurred, and monitoring should continue to determine if this decrease continues at the same rate over the next several years.     

ORIGIN AND TRANSPORT OF DISSOLVED CHEMICALS IN A KARST WATERSHED,SOUTHWESTERN ILLINOIS1

ABSTRACT: An extensive base of water quality information emphasizing the effects of land use and hydrology was obtained in the karstified Fountain Creek watershed of southwestern Illinois to help resolve local water quality issues. Agrichemicals dominate the loads of most water quality constituents in the streams and shallow karstic ground water. Only calcium (Ca), magnesium (Mg), Aluminum (A1), and sulfate (SO₄) ions are predominantly derived from bedrock or soils, while agrichemicals contribute most of the sodium (Na), potassium (K), chlorine (Cl), nitrate (NO₃), fluorine (F), phosphorus (P), and atrazine. Concentrations of individual ions correlate with discharge variations in karst springs and surface streams; highly soluble ions supplied by diffuse ground water are diluted by high flows, while less soluble ions increase with flow as they are mobilized from fields to karst conduits under storm conditions. Treated wastewater containing detergent residues dominates the boron load of streams and provides important subordinate loads of several other constituents, including atrazine derived from the Mississippi River via the public water supply. Average surface water concentrations at the watershed outlet closely approximate a 92:8 mixture of karst ground water and treated wastewater, demonstrating the dominance of ground water contributions to streams. Therefore the karst aquifer and watershed streams form a single water quality system that is also affected by wastewater effluent.     

ASSESSING RELATIVE RISKS TO AQUATIC ECOSYSTEMS: A MID-APPALACHIAN CASE STUDY1

ABSTRACT: Aquatic monitoring aims to assess the condition of aquatic habitats and biota. To make statements about condition, the range of human activities and the risks they pose to aquatic ecosystems must be identified. Assessing relative risk and placing sample sites on a human disturbance gradient is necessary for interpreting biological response and distinguishing human disturbance from natural controls in aquatic systems. We describe a process that uses readily available sources, such as topographic maps, aerial photographs, and field information, to identify and prioritize stream reach and watershed stressors for 102 streams in the mid-Appalachian region of the United States. All perceptible human alterations to riparian and upland areas along with their number, type, intensity, and extent of impact were recorded and ranked; a relative risk index was developed to assign scores to the watersheds. The resulting risk index scores were consistent with measures of stream condition based on water chemistry and benthic macroinvertebrates. The risk index gives a cost-effective, regional picture of the relative risk of impairment to aquatic ecosystems in the mid-Appalachian region of the USA and could be modified for other regions or ecosystem types.     

LARGE AREA HYDROLOGIC MODELING AND ASSESSMENT PART II: MODEL APPLICATION1

ABSTRACT: This paper describes the application of a river basin scale hydrologic model (described in Part I) to Richland and Chambers Creeks watershed (RC watershed) in upper Trinity River basin in Texas. The inputs to the model were accumulated from hydro-graphic and geographic databases and maps using a raster-based GIS. Available weather data from 12 weather stations in and around the watershed and stream flow data from two USGS stream gauge station for the period 1965 to 1984 were used in the flow calibration and validation. Sediment calibration was carried out for the period 1988 through 1994 using the 1994 sediment survey data from the Richland-Chambers lake. Sediment validation was conducted on a subwatershed (Mill Creek watershed) situated on Chambers Creek of the RC watershed. The model was evaluated by well established statistical and visual methods and was found to explain at least 84 percent and 65 percent of the variability in the observed stream flow data for the calibration and validation periods, respectively. In addition, the model predicted the accumulated sediment load within 2 percent and 9 percent from the observed data for the RC watershed and Mill Creek watershed, respectively.     

EFFECTS OF URBANIZATION ON CHANNEL INSTABILITY1

ABSTRACT: Channel instability and aquatic ecosystem degradation have been linked to watershed imperviousness in humid regions of the U.S. In an effort to provide a more process‐based linkage between observed thresholds of aquatic ecosystem degradation and urbanization, standard single event approaches (U.S. Geological Survey Flood Regression Equations and rational) and continuous hydrologic models (HSPF and CASC2D) were used to examine potential changes in flow regime associated with varying levels of watershed imperviousness. The predicted changes in flow parameters were then interpreted in concert with risk‐based models of channel form and instability. Although low levels of imperviousness (10 to 20 percent) clearly have the potential to destabilize streams, changes in discharge, and thus stream power, associated with increased impervious area are highly variable and dependent upon watershed‐specific conditions. In addition to the storage characteristics of the pre‐development watershed, the magnitude of change is sensitive to the connectivity and conveyance of impervious areas as well as the specific characteristics of the receiving channels. Different stream types are likely to exhibit varying degrees and types of instability, depending on entrenchment, relative erodibility of bed and banks, riparian condition, mode of sediment transport (bedload versus suspended load), and proximity to geomorphic thresholds. Nonetheless, simple risk‐based analyses of the potential impacts of land use change on aquatic ecosystems have the potential to redirect and improve the effectiveness of watershed management strategies by facilitating the identification of channels that may be most sensitive to changes in stream power.     

DETERMINING NUTRIENT EXPORT COEFFICIENTS AND SOURCE LOADING UNCERTAINTY USING IN‐STREAM MONITORING DATA1

ABSTRACT: Over a three‐year period, flow and nutrients were monitored at 13 sites in the upper North Bosque River watershed in Texas. Drainage areas above sampling sites differed in percent of dairy waste application fields, forage fields, wood/range, and urban land area. A multiple regression approach was used to develop total phosphorus (TP) and total nitrogen (TN) export coefficients for the major land uses in these heterogeneous drainage areas. The largest export coefficients were associated with dairy waste application fields followed by urban, forage fields, and wood/range. An empirical model was then established to assess nutrient contribution by major sources using developed export coefficients and point source loadings from municipal wastewater treatment. This model was verified by comparison of estimated loadings to measured in‐stream data. Monte Carlo simulation techniques were applied to provide an uncertainty analysis for nutrient loads by source, based on the variance associated with each export coefficient. The largest sources of nutrients contributing to the upper North Bosque River were associated with dairy waste application fields and forage fields, while the greatest relative uncertainty in source contribution was associated with loadings from urban and wood/range land uses.     

Model evaluation of potential impacts of on-site wastewater systems on phosphorus in Turkey creek watershed

Nutrient loading to surface water systems has traditionally been associated with agricultural sources. Sources such as on-site wastewater systems (OWS) may be of concern especially in rural, nonagricultural watersheds. The impact of various point and nonpoint sources including OWS in Turkey Creek Watershed was evaluated using the Watershed Analysis Risk Management Framework, which was calibrated using 10 yr of observed stream flow and total P concentrations. Doubling the population in the watershed or OWS septic tank effluent P concentration increased mean stream total P concentration by a factor of 1.05. Converting all the OWS to a conventional sewer system with a removal efficiency of 93% at the wastewater treatment plant increased the mean total P concentration at the watershed outlet by a factor of 1.26. Reducing the soil adsorption capacity by 50% increased the mean stream total P concentration by a factor of 3.2. Doubling the initial P concentration increased the mean stream total P concentration by a factor of 1.96. Stream flow and sediment transport also substantially affected stream P concentration. The results suggest that OWS contribution to stream P in this watershed is minimal compared with other factors within the simulated time frame of 10 yr.     

Summer Temperature Patterns in Headwater Streams of the Oregon Coast Range1

Abstract: Cool summertime stream temperature is an important component of high quality aquatic habitat in Oregon coastal streams. Within the Oregon Coast Range, small headwater streams make up a majority of the stream network; yet, little information is available on temperature patterns and the longitudinal variability for these streams. In this paper we describe preharvest spatial and temporal patterns in summer stream temperature for small streams of the Oregon Coast Range in forests managed for timber production. We also explore relationships between stream and riparian attributes and observed stream temperature conditions and patterns. Summer stream temperature, channel, and riparian data were collected on 36 headwater streams in 2002, 2003, and 2004. Mean stream temperatures were consistent among summers and generally warmed in a downstream direction. However, longitudinal trends in maximum temperatures were more variable. At the reach scale of 0.5‐1.7 km, maximum temperatures increased in 17 streams, decreased in seven streams and did not change in three reaches. At the subreach scale (0.1‐1.5 km), maximum temperatures increased in 28 subreaches, decreased in 14, and did not change in 12 subreaches. Models of increasing temperature in a downstream direction may oversimplify fine‐scale patterns in small streams. Stream and riparian attributes that correlated with observed temperature patterns included cover, channel substrate, channel gradient, instream wood jam volume, riparian stand density, and geology type. Longitudinal patterns of stream temperature are an important consideration for background characterization of water quality. Studies attempting to evaluate stream temperature response to timber harvest or other modifications should quantify variability in longitudinal patterns of stream temperature prior to logging.     

USING STREAM BIOASSESSMENT PROTOCOLS TO MONITOR IMPACTS OF A CONFINED SWINE OPERATION1

ABSTRACT: The processing of waste from confined animal feeding operations (CAFOs) presents a major environmental challenge. Treatment of waste and subsequent land application is a common best management practice (BMP) for these operations in Kentucky, USA, but there are few data assessing the effect of runoff from such operations on aquatic communities. The authors sampled a stream bordering a CAFO with a land application program to determine if runoff from the fertilized fields was adversely affecting stream communities. Water chemistry, periphyton, and macroinvertebrate samples from riffle habitats downstream of the CAFO were compared to samples collected from an upstream site and a control stream in 1999 and 2000. Riffle communities downstream of the fertilized fields had higher chlorophyll a levels than other sites, but there were no significant differences in macroinvertebrate numbers or in biometrics such as taxa richness among the sites. The BMP in place at this site may be effective in reducing this CAFO's impact on the stream; however, similar assessments at other CAFO sites should be done to assess their impacts. Functional measures such as nutrient retention and litter decomposition of streams impacted by CAFOs should also be investigated to ensure that these operations are not adversely affecting stream communities.     

Impact of flood control reservoirs and pollution influx on the Sandy Creek Watershed,Mercer County,Pennsylvania, USA

A study of the impact of two flood control reservoirs and pollution influx was conducted on two streams within the Sandy Creek Watershed, Mercer County, Pennsylvania, USA. Fecal coliforms were significantly reduced in the outflows without affecting water chemistry, thereby improving the overall water quality. The size and composition of the aquatic communities as well as stream metabolism varied seasonably among the different sampling stations. Pollution influx primarily from communities and agricultural drainage had a greater impact on the stream ecosystem than did impounding of the streams. Natural wetlands and riparian vegetation were important factors in reducing the pollution load in these streams. The reestablishment and maintenance of riparian vegetation should therefore be an integral part of the land-use plan for watersheds in order to improve water quality and wildlife habitats. In the future, the maintenance of riparian vegetation should be given prime consideration in the development of watershed projects.     

URBANIZATION AND STREAM QUALITY IMPAIRMENT1

ABSTRACT: A study was conducted in the Piedmont province of Maryland to determine if a relationship exists between stream quality and the extent of watershed urbanization. During the first phase of the study 27 small watersheds, having similar characteristics but varied according to land use, were investigated. Using these controlled conditions, eliminating as many interferences as possible, this first phase was intended to determine if a definite relationship did exist between the two factors. Finding that the first phase was successful the second was initiated which consisted of a comparison of biological sampling data, from other studies, with degree of watershed urbanization. The purpose of this second phase was to ascertain if the relationship between degrees of urbanization and decline in stream quality was linear as watershed area increased and in streams spread throughout the Maryland Piedmont. The principal finding of this study was that stream quality impairment is first evidenced when watershed imperviousness reaches 12%, but does not become severe until imperviousness reaches 30%.