河北省地表水重金属污染状况分析

通过对近几年水体中重金属检出率和超标率变化的分析、重金属的环境健康风险评价等对河北省地表水进行研究,研究结果表明:河北省地表水重金属污染虽然总体呈好转趋势,但仍然存在环境健康风险。由此分析了河北省地表水污染原因主要有地表径流少、企业排污等,进一步提出了建立有效的预防机制、加强环境监管能力等对策建议。     

西南某铅锌矿区土壤重金属污染现状与评价研究

为研究西南某铅锌矿区土壤重金属污染的状况,采集采矿区和尾矿区的土壤,对土壤中重金属(Zn、Pb、Cd、Cr、Cu)的水溶态、弱酸提取态和总含量进行了分析,并采用单因子污染指数法和内梅罗综合污染指数法进行了现状评价。研究得出该铅锌矿区土壤存在较为严重的重金属复合污染,重金属生物有效性和迁移能力较强,对当地生态及地下水、地表水存在严重的风险。研究成果可为铅锌矿区土壤重金属污染的监测和治理提供一定的科学依据。     

无锡滨湖河网重金属时空分布特征研究

无锡市滨湖河网不同时空下重金属分布规律不一,探究并掌握此种分布规律对精准治理、防控无锡滨湖河网重金属污染有着重要作用。以无锡市滨湖河网水体重金属污染作为研究基点,通过野外监测、主成分分析及水环境重金属健康风险评价模型分析河网重金属时空分布特征。结果表明:汞含量超标严重,其余重金属浓度均达标。除铬、砷以外其他重金属浓度均表现为枯季大于洪季,铬含量随着与泵站距离的增加呈升高趋势,重金属峰值主要出现在梁韵大桥。河网东南部非调控区河流受重金属污染总体优于其余区域。致癌重金属健康风险远大于非致癌重金属,主要健康风险物质为砷。铜、锌、铅、镉、镍来源于相同的污染源。调水对重金属分布影响较小,调水对铬浓度起改善作用。本研究揭示了河网部分重金属污染现状,为水环境治理提供了理论依据。     

某典型冶炼场地重金属污染风险管控方案及效果评估

文章以湖南某典型工矿冶炼重金属污染场地为例,在明确项目管控目标、管控范围的基础上,构建了集"场地修整+原地阻隔+生态恢复+污水处理+截排水处理+监测系统"为一体的重金属污染场地风险管控体系,采用逐一比对的效果评估方法,对修复后的清洁客土、下游污染区域土壤、场地周边土壤、场地污水处理出水、下游地表水采集样品进行检测分析,以评估项目重金属污染风险管控方案的修复效果,结论显示项目修复管控效果满足相关要求、达到治理修复目标,可为我国典型冶炼场地重金属污染风险管控及效果评估提供参考依据。     

青海省铅锌采选企业重金属污染防控现状及管理对策研究

冶炼、化工等涉重行业进行园区化管理后,铅锌采选企业的重金属污染风险问题凸显了出来。文章通过对青海省铅锌采选企业废水、废气及废渣重金属污染防控水平及存在问题分析,提出相应的环境保护管理对策和建议,为相关企业在重金属污染防控技术选择和环境管理方面提供参考,从而促进区域重金属污染防控工作,确保环境安全。     

河北省地表水环境污染特征及分析

河北省1998年-2005年的水环境质量监测数据分析表明：河北省地表水污染恶化趋势基本得到遏制，但部分地区水污染矛盾仍很突出；水体总体污染减轻，但氨氮污染有加重趋势；主要湖（库）水水质稳定，但普遍呈不同程度的富营养化。在此基础上，分析了地表水污染的原因，并提出了河北省改善地表水环境污染的对策与措施。     

土壤中污染物迁移模型在油田环境影响评价中的应用

在石油的生产、运输、贮存以及炼制等过程中都存在泄油、漏油风险,各生产过程中的废弃物,如油类、重金属等各种化学物质也会危害水土环境,进而危及当地地下水源。文章分析了油田企业污染物对土壤及地下水的主要污染途径,提出了将污染物在土壤中的迁移模型用于预测污染物浓度的方法。建立了污染物由土壤迁至室内空气、地下水、农作物及由地下水转移到地表水的迁移数学模型,该模型可以运用于油田环境影响评价。     

典型企业场地周边土壤重金属污染水平及风险评价

以四川某地8类企业场地周边土壤为研究对象,通过单因子污染指数法、单种重金属潜在生态风险指数及重金属综合污染潜在生态风险指数三种方法对其重金属污染风险进行了分析评价.结果表明:不同类型企业重金属污染程度及污染因子具有差异性;无机盐制造企业与无机材料制造企业场地周边土壤分别存在Cd轻度污染和重度污染;8类企业周边土壤中几种...     

成都绕城高速两侧土壤重金属含量测定及健康风险评价

成都绕城高速公路属于成都市主要交通干线,为成都市带来巨大经济及社会效益,但是,也不可避免给环境带来污染。因此,研究成都绕城高速两侧土壤污染情况具有重要意义。采用"梅花点法"和"四分法"采集得到成都绕城高速公路两侧表层土壤(0~20cm)样品24个,电感耦合等离子体质谱法(ICP-MS)测得土壤样品中铬(Cr)、镍(Ni)、铜(Cu)、锌(Zn)、砷(As)、镉(Cd)和铅(Pb)含量的平均值分别为46.81、192.48、28.24、111.79、4.74、2.79和51.68 mg/kg。讨论重金属分布特点,采用污染指数法对土壤重金属污染进行评价;应用美国环境保护局风险评价方法对成都绕城高速两侧土壤重金属通过直接摄入、皮肤接触和呼吸摄入3种途径进入人体的危害进行了风险计算和初步评价。结果表明:成都绕城高速公路两侧土壤未受到重金属污染(Ni除外),且7种重金属对人体均不存在明显健康风险。     

水体重金属污染治理技术研究进展

随着工业的发展和人口的不断增加,重金属废水排放量增加。有毒重金属对环境的严重威胁正逐渐成为全球性问题,不仅对环境造成危害,还威胁着人类的健康。介绍了水体重金属污染现状及危害,综述了目前国内外治理水体重金属污染主要技术的研究进展,指出了微生物治理重金属污染水体的良好应用前景。     

Five-wheel framework for system-based monitoring of heavy metal pollution in rivers

Sectorial approach for monitoring heavy metal pollution in rivers has failed to report realistic pollution status and associated ecological and human health risks. The increasing spread of heavy metals from different sources and emerging risks to human and environmental health call for reexamining heavy metal pollution monitoring frameworks. Also, the sources, spread, and load of heavy metals in the environment have changed significantly over time, requiring consequent modification in the monitoring frameworks. Therefore, studies on heavy metal monitoring in rivers conducted in the last decade were evaluated for experimental designs, research frameworks, and data presentations. Most studies (∼99%) (i) lacked inclusiveness of all environmental compartments; (ii) focused on “one pollutant – one/two compartment” or sometimes “one pollutant – one compartment – one effect” approach; and (iii) remained “data-rich but information poor.” An ecological approach with integrative system thinking is proposed to develop a holistic approach for monitoring river pollution. It is visualized that heavy metal monitoring, risk analyses, and water management must incorporate tracking pollutants in different environmental compartments of a river (water, sediment, and floodplain/bank soil) and consider correlating it with riverbank land use. The systems-based pollution monitoring and assessment studies will reveal the critical factors that drive heavy metals pollutant movement in ecosystems and associated potential risks to the environment, wildlife, and humans. Also, water quality and pollution indexing tools would help better communicate complex pollution data and associated risks among all stakeholders. Therefore, integrating systems approaches in scientific- and policy-based tools would help sustainably manage the health of rivers, wildlife, and humans.     

“第一类污染物”防治需求的紧迫性及其对策措施

"第一类污染物"是指会对人体健康产生长远不良影响的污染物,包括8种重金属和类金属。已经证实,工业源重金属超量排放严重,使水土及生态环境遭受到"第一类污染物"的严重污染,面临的"第一类污染物"防治形势更加紧迫。本文在重金属污染现状与治理需求分析的基础上,通过长期调研,针对重点行业提出了6项综合防治措施,建议从源头严格控制排放总量,对重点企业进行监管与治理,总结与创新重金属修复新技术等,旨在推动第一类污染物的污染防治。     

某区域内矿区土壤重金属污染与生态风险评价

探究区域内矿区土壤重金属变化并对其进行污染评价,旨在为该区域环境保护及污染治理提供一定的理论依据,以期实现矿山地质环境保护与矿产资源开发并行的矿业绿色发展。以铅、锌、镉、砷含量为评价指标,结合《土壤环境质量标准》(GB 15618—2018),采用重金属单因子污染指数法与内梅罗综合污染指数法进行重金属污染评价,并对该区域矿区潜在生态风险作出评定。结果表明,A矿区土壤各重金属含量的变异系数为149.05%~211.42%,B矿区土壤各重金属含量变异系数为60.88%~118.58%;A矿区土壤重金属均出现超标现象,其中铅、锌和镉含量超标较为严重,超标率在72%以上,而砷含量超标现象则相对较轻,超标率为36.36%;B矿区土壤铅和锌含量均未出现超标,超标率为0,而砷和镉含量则出现不同程度的超标,其中砷含量超标率为92.31%,镉含量超标率为65.38%;两个矿区土壤各重金属含量均超背景值的现象,超背景值比例为42.31%~100.00%。A矿区土壤以铅、锌和镉污染为主,而B矿区土壤中砷和镉的污染较为严重。两个矿区土壤重金属综合污染指数均属重度污染,A矿区生态风险综合指数为很强生态风险危害,而B矿区为中等生态风险危害。     

从水污染防治角度出发的全国分省域水环境安全研究

针对我国日益严峻的水环境安全问题,本文从水污染防治角度出发,依据影响我国水环境安全的关键污染问题,即水环境质量、水污染物排放、水环境风险,构建了水环境安全指标体系。利用相关分析法、主成分分析法,简化、优化评价指标体系。利用层次分析法与专家打分法,估算各指标权重,采集各指标数据对全国31个省(自治区、直辖市)2011—2013年的水环境安全状况进行评估。结果表明:该指标体系在一定条件和范围内是合理的,我国水环境安全大体呈西高中东低的空间分布,京津冀区域水环境安全评价值较低。"十三五"时期,京津冀地区应着重于降低主要污染物浓度,削减劣V类断面比例,提高水环境质量,海南、福建、广东等地区着力于减少农业等水污染物排放强度,湖南等地区则需要重点关注涉重企业的污染物排放。     

Formulation of criteria for pollution control on cement products produced from solid wastes in China

The process of producing cement products from solid waste can increase the level of pollutants in the cement products. Therefore, it is very important to establish a pollution control standard for cement products to protect the environment and human health. This paper presents acceptance limits for the availability of heavy metals in cement products which have been produced from solid wastes and explains how the limits have been calculated. The approach and method used to formulate these criteria were based on EN 12920. The typical exposure scenarios used in this paper involve concrete being used for drinking water supply pipelines and concrete pavements and are based on an analysis of typical applications of cement in China, and the potential for contact with water. The parameters of a tank test which was based on NEN 7375 were set in accordance with the environmental conditions of typical scenarios in China. Mechanisms controlling the release of heavy metals in concrete and a model for that release were obtained using the leaching test. Finally, based on acceptance criteria for drinking water and groundwater quality in China, limit values for the availability of heavy metals in concrete were calculated.     

土壤污染风险评价研究进展

随着工业化和城镇化快速发展,土壤污染带来的人体健康和生态风险日益凸显.本文针对我国土壤污染环境风险评价体系在风险管控中的缺失问题,系统总结了国内外土壤污染的风险研究发展成果,按照土壤污染的人体健康风险和生态风险,分别进行评价方法、评价标准和管理实践的总结与评述.文章着重指出:土壤污染风险评价在生态系统水平及区域流域尺度上缺失,评价方法未能与污染物存在形态完全匹配,评价指标还不能覆盖大部分重金属和有机物,健康风险与生态风险还没有实现综合评价.     

Nonpoint source pollution, environmental quality, and ecosystem health in China: introduction to the special section

The rapid economic and industrial growth of China, exemplified by a 10-fold increase in its gross domestic product in the past 15 years, has lifted millions of its citizens out of poverty but has simultaneously led to severe environmental problems. The World Health Organization estimates that approximately 2.4 million deaths in China per year could be attributed to degraded environmental quality. Much of China's soil, air, and water are polluted by xenobiotic contaminants, such as heavy metals and organic compounds. In addition, soil quality is degraded by erosion, desertification, and nutrient runoff. Air quality is further compromised by particulates, especially in heavily populated areas. Research shows that 80% of urban rivers in China are significantly polluted, and poor water quality is a key contributor to poverty in rural China. Economic and industrial growth has also greatly expanded the demand for water sources of appropriate quality; however, pollution has markedly diminished usable water resource quantity. Desertification and diminishing water resources threaten future food security. In recent years, China's government has increased efforts to reverse these trends and to improve ecosystem health. The Web of Science database showed that the percentage of articles on China devoting to environmental sciences increased dramatically in recent years. In addition, the top 25 institutes publishing the papers in environmental sciences were all in China. This special issue includes seven articles focusing on nonpoint source pollution, environmental quality, and ecosystem health in China. The major issues, and results of these studies, are discussed in this introduction.     

成渝经济区主要河流沉积物重金属赋存形态及生态风险评估

以成渝经济区主要水系水体沉积物为研究对象,利用Eri（单一金属潜在生态风险因子）和RI（多金属潜在风险指数）等定量诊断工具分析沉积物中的重金属的潜在生态风险,为成渝经济区战略环评提供数据支撑。根据风险指标评价结果和重金属空间分布规律,将区域水系分为3种生态风险功能区。结合沉积物中重金属赋存形态,得出区域Cd的生态风险较...     

西湖和东苕溪沉积物重金属化学形态分析

不同赋存形态重金属的环境行为和生态效应不同,水体沉积物中重金属的迁移转化及其潜在环境危害更大程度上取决于其赋存形态。本研究在西湖和东苕溪设置12个采样点采集沉积物样品,采用改进BCR分步提取法,提取了重金属污染物的4种化学形态,分别为弱酸提取态、可还原态、可氧化态及残渣态。结果表明:沉积物中Cd以弱酸提取态为主,对外界环境的变化极其敏感,并易于发生迁移转化,生态风险较高。Cu离子对有机质表现出极强的亲和力导致Cu的可氧化态含量较高也有一定的生态风险。Pb会被Fe-Mn氧化物所吸附导致Pb的可还原态含量较高,存在较高的潜在生态危害。Mn的弱酸提取态、可还原态和残渣态含量都较高,在迁移的过程中变化地较快,能够逐渐降低Mn对自然环境的危害。其他各重金属(As、Cr、Zn)则都以残渣态为主,潜在危害较低。     

重庆市大足县生态环境质量建设成效

大足生态农业县经过13年的建设，生态环境质量改善明显，通过对大足县大气、水质、农田土壤和农作物（水稻，小麦）的监测分析可知，污染程度都有比较明显的改善，特别是重金属在土壤和农作物中的含量有着显著的降低。