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浙江省饮用水源有机毒物污染特征及健康风险研究 总被引:3,自引:0,他引:3
在对浙江省98个县级以上饮用水源地水体中有机毒物污染进行调查的基础上,运用美国环境保护署(EPA)制定的相关模型对饮用水源地水体中有机毒物污染引起的健康风险进行评价。结果表明,在98个饮用水源地水体中共检出7种有机毒物,分别为微囊藻毒素-LR(MC-LR)、微囊藻毒素-RR(MC-RR)、草甘膦、邻苯二甲酸二异辛酯(DEHP)、邻苯二甲酸二丁酯、多环芳烃、咔唑;各饮用水源地水体中检出的有机毒物引起的健康风险大小依次为多环芳烃DEHP咔唑MC-LR草甘膦邻苯二甲酸二丁酯;存在有机毒物检出的饮用水源地水体的总健康风险约为10-13~10-8a-1,与部分国际机构制定的饮用水源地水质健康风险水平判断标准相比,浙江省饮用水源地水体中有机毒物污染引起的健康风险远低于可接受水平,大部分饮用水源地水体的健康风险甚至达到可忽略水平。 相似文献
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对以再生水为补给水源的通惠河进行水质监测,采用模糊综合评价的方法总体评价了通惠河的水质状况,综合评价结果表明,高碑店污水处理厂处理排放人河道的水质达到Ⅱ类水平,对通惠河的污染起到了一定的缓解作用。引入多元统计分析的方法:(1)空间聚类模型将通惠河水质类型分为两类,并具体分析了两种类型的水质18个参数的差别。分析发现第1类水体的主要污染物为硝态氮、亚硝态氮引起的氮污染、磷污染等工业污染,而第2类水体的污染主要以生活污水带来的有机污染为主。(2)运用因子分析解析通惠河的污染来源——主要来源于点源排放的污水产生的氨氮、硝态氮和有机污染。为保持再生水水质,需要对水质差的污染区设立重点监测点并控制偷排现象。 相似文献
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随着工农业生产的发展,进入环境的人工化合物越来越多,其中氯代芳香族化合物所占的比例也日趋增大。美国环保局(EPA)公布的129种优先控制污染物名单中,含卤有机化合物占一半以上(其中以含氯芳香族有机化合物为主)。我国公布的68种水环境优先控制污染物“黑名单”中,含氯芳香族有机化合物也占了很大的比重。由于它们广泛存在于制药、焦化、石油化工、农药等多种生产废水中,不仅毒性大,污染面也很广。研究氯代芳香族化合物的生物降解性能对其污染的控制具有十分重要的意义。本文拟就此方面的研究进展作一综述。1氯代芳香族化合物… 相似文献
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吴江市地处太湖之滨,同时位于江苏、浙江、上海三省(市)交界之处,水环境质量尤为敏感。在摸清吴江市水系现状的基础上,找出存在的主要环境问题,进而提出近期和远期的水环境污染防治目标,并建立起相应的指标考核体系,最后提出了吴江市进行水系污染防治的方案。 相似文献
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江苏沿江饮用水源水质现状及对策建议 总被引:1,自引:0,他引:1
目前沿江城市均以长江作为饮用水源。沿江大开发战略的实施,必将对长江及其饮用水源的水质产生影响,因此,有必要了解江苏的饮用水源基本状况,分析影响水质的主要因素,并提出合理的对策建议。 相似文献
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长江、嘉陵江(重庆段)源水有机提取物的致突变活性及其季节变化 总被引:3,自引:0,他引:3
为了确定并比较重庆主城区段长江、嘉陵江源水有机提取物的致突变性及其季节变化规律,分别于春、夏、冬季采用GDX-120大孔树脂,对位于城区上游、城区中段、城区下游以长江、嘉陵江源水的5个水厂的进厂水进行了有机物的浓缩提取。提取物的致突变活性采用经典的Ames试验平板掺入法评估,测试菌株为TA98及TA100,同时做加与不加S9的比较。结果显示,嘉陵江及长江源水的有机提取物均有不同程度的致突变活性。嘉陵江源水明显大于长江源水,城区中段源水明显大于上游段及下游段源水。多数断面显示平水期致突变活较为显著并且移码型致突变性大于碱基置换型致密变性。研究结果提示,城市污染源已导致长江、嘉陵江源水具备致突变活性,控制两江沿岸的各种水污染源已成为当务之急。 相似文献
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快速高效丙烯酸系吸油树脂的合成及性能研究 总被引:1,自引:0,他引:1
采用悬浮聚合法合成了低交联度的丙烯酸系高吸油性树脂。研究了单体配比、交联剂用量及种类、分散剂用量和反应温度等反应条件对树脂吸油性能的影响,并且考察了树脂对4种有机毒物(氯苯、吡啶、硝基苯和甲苯) 的吸油效果。结果表明,吸油5 h后,树脂对氯苯、吡啶、硝基苯及甲苯的最大吸油率分别为37.3、34.1、30.5和23.7 g/g;另外,树脂吸油10 min时,其吸油率即可达到最大吸油率的50%。实验证明,该合成树脂对有机毒物有快速高效的吸附效果,可以应用于污染事故应急处理。 相似文献
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Effect of copper in the protistan community of activated sludge 总被引:4,自引:0,他引:4
Protists have proved to be an interesting tool for assessing the occurrence of pollution in wastewater treatment systems along with its role in the control of pollution itself through grazing of dispersed bacteria and maintenance of a healthy trophic web in those artificial ecosystems. Two sets of assays were carried on in a bench scale pilot plant in order to study the response of the activated sludge community of protists to the exposure of copper: the first set was carried on with synthetic sewage and the second one with real sewage. The results emphasize the ability of activated sludge biological communities to survive and to react to toxicants and highlight the role of protistan communities as indicators of toxicants entrance in treatment systems. 相似文献
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Distinguishing between effects of natural and anthropogenic environmental factors on ecosystems is a fundamental problem in environmental science. In river systems the longitudinal gradient of environmental factors is one of the most relevant sources of dissimilarity between communities that could be confounded with anthropogenic disturbances. To test the hypothesis that in macroinvertebrate communities the distribution of species' sensitivity to organic toxicants is independent of natural longitudinal factors, but depends on contamination with organic toxicants, we analysed the relationship between community sensitivity SPEARorganic (average community sensitivity to organic toxicants) and natural and anthropogenic environmental factors in a large-scale river system, from alpine streams to a lowland river. The results show that SPEARorganic is largely independent of natural longitudinal factors, but strongly dependent on contamination with organic toxicants (petrochemicals and synthetic surfactants). Usage of SPEARorganic as a stressor-specific longitude-independent measure will facilitate detection of community disturbance by organic toxicants. 相似文献
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The interactions of environmental toxicants with organic substances affect the speciation and dynamics, and subsequent toxicity, mobility, and fate of toxicants in the environment. For the purpose of understanding the complexation of As(V) with humic substances, arsenate-containing solutions with As concentrations from 1 to 8 mg l−1 were prepared to react with the water extract of compost (WEC). All the reaction systems including the control were incubated for 48 h at 25 °C. The complexation of As(V) with humic substance was examined by dialysis and ion exchange techniques. From 30% to 51% of added As(V) reacted with organic substance in WEC to form an As–metal–organic complex. This was verified as a hydrophobic organic fraction after separation of As–metal–organic complex fraction from the hydrophilic fraction by XAD-8 resin. The complex substance was also identified as a humic substance by the method of proton binding formation function determination. This suggests that cations, such as Ca and Mg, and especially Fe, Al, and Mn act in cation bridging in the complexation of As(V) with humic substance. The role of metals in the complexation of As(V) with humic substance in terrestrial and especially aquatic environments thus merits close attention. 相似文献
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Chau KW 《Chemosphere》2006,64(9):1545-1549
As a byproduct of rapid urbanization and industrial development in the Pearl River estuary of South China, excessive release of various types of persistent toxic substances were conveyed from agricultural, industrial and municipal discharges at upstream section down into the estuary largely via various river outlets. In this paper, a persistent organic pollution (POP) characterization of sediments in the estuary is undertaken. More than one bioavailable toxicants are detected to play active roles in causing toxicity of marine sediments in the estuary. POPs may be transported for long distances to the downstream end of the Pearl River delta region. The data suggests that DDT might still be applied illegally within the region recently and that the prevalent levels of DDTs and HCHs in sediments are likely to pose detrimental biological effects on benthic organisms. The findings have significant implications in order to understand the environmental changes, to determine reasonable ways for future development, and to maintain a sustainable environment in the Pearl River estuary region. 相似文献
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Species-specific responses to metals in organically enriched river water, with emphasis on effects of humic acids 总被引:2,自引:0,他引:2
Stuijfzand SC Jonker MJ van Ammelrooy E Admiraal W 《Environmental pollution (Barking, Essex : 1987)》1999,106(1):115-121
Invertebrate communities in polluted rivers are often exposed to a wide variety of compounds. Due to complex interactions, 'pollution tolerant' species are not necessarily the most tolerant species to toxicants tested under standard laboratory conditions. It was hypothesized that the distribution of species in polluted rivers is not only dependent on the tolerance of species to toxicants, but also on species-specific capacities to modify or compensate for negative effects of toxicants. To test this hypothesis, species-specific responses to metals in organically enriched river water were studied under controlled conditions. The zebra mussel Dreissena polymorpha and the midge Chironomus riparius were exposed to metal-polluted water from the River Dommel. Additionally, the (interactive) effects of metals and humic acids (HA) on both species were evaluated. In spite of a lower tolerance of Chironomus riparius to metals in laboratory studies, the midge was the most tolerant of the two test species to metal-polluted site water. The results indicated that the sensitivities of the two test species determined in laboratory tests were inversely related to their sensitivities to polluted river water. In accordance with these results, midge larvae were protected from copper (Cu) toxicity by HA, while metal toxicity was not reduced (Cu) or even amplified (cadmium) by HA for the zebra mussel. Thus, the presence of (naturally occurring) HA in site water may partly account for discrepancies between responses of species to bioassays and toxicity tests. It is suggested that these differences in responses to metals in site water are strongly influenced by species-specific preferences for organic compounds (like HA). It is concluded that the response to organic compounds present in site water largely determines whether a species is classified as 'pollution tolerant' or 'pollution sensitive'. 相似文献
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Toxic substances in rivers and streams 总被引:1,自引:0,他引:1
Hellawell JM 《Environmental pollution (Barking, Essex : 1987)》1988,50(1-2):61-85
Many of the toxic substances entering freshwaters today are those which were present several decades ago, but others have become significant recently. The effects of toxicants in flowing waters are modified by unidirectional transport and dispersion which afford the potential for a degree of 'self-purification'. The chemical quality of the receiving water also affects toxicity. Biological factors also contribute to the ultimate effect of pollutants. The potential for accumulation of toxic substances within tissues increases the significance of certain pollutants which may be present in water even though ambient concentrations are very low. The biota of flowing waters may be restored, following catastrophic entry of pollutants, by drift from unaffected regions upstream. The range of potential toxic substances is very extensive and includes inorganic poisons, organic poisons, heavy metals, pesticides and PCBs. Metals, pesticides and PCBs have the greatest potential for bioaccumulation. Few generalisations can be made regarding the effects of toxic substances on the biota. Each species tends to respond to different toxicants in different ways and even at different stages in its life-history. Toxicity tests conducted under controlled laboratory conditions sometimes produce conflicting results: it is not then to be unexpected that field observations should sometimes vary widely. Determinations of toxicity in laboratory tests must be applied with caution to field conditions and it is not wise to extrapolate findings to other species or environments. 相似文献