基于MIKE11的江南平原河网动态水环境容量分析

传统水环境容量以90%保证率下的设计枯水流量作为计算条件,存在水文计算条件单一、计算结果固定等局限性,不能很好地表征水流方向不定、产汇流过程复杂、污染负荷分散的江南平原河网的水环境容量。以宜兴市官林镇水系为研究对象,基于MIKE11水质模型计算河网控制单元水环境容量,以探究江南平原河网水环境容量的动态特性。结果表明：MIKE11模型法下官林控制单元COD、氨氮和总磷月均水环境容量为-152.80、0.92和-1.69 t;桐梓控制单元COD、氨氮和总磷月均水环境容量为220.23、4.49和1.45 t;皇新控制单元COD、氨氮和总磷月均水环境容量为15.42、0.90和0.14 t,呈现出明显动态特征。代表河道水环境容量与流量流速等水文要素有密切关系,市镇级等水质达标河道水环境容量与流速呈正相关,村级等未达标河道水环境容量与流速呈负相关。本研究可为平原河网水环境保护与管理提供重要参考和新思路。     

生态环境功能区规划中水环境容量分配方法探讨

水环境容量分配是生态环境功能区规划的重点.针对当前水环境容量分配中存在的问题,以生态环境功能区规划为基础,研究区域污染负荷和各水质控制点的响应关系,统筹考虑区域发展实际需求,采用线性规划法建立了满足科学性、公平性和经济性的生态环境功能区水环境容量优化分配方法.以浙江省龙游县为例,根据其生态环境功能区规划,以建立的优化分配方法对其区域水环境容量进行了分配.结果显示,所分配的水环境容量满足了各区域发展需求,表征分配公平性、科学性和经济性的水环境容量分配合理性指数(TCRI)达到了0.93.     

钱塘江河口段水环境现状与保护对策

系统地分析了2001-2008年钱塘江河口段干流地表水、海水及两岸平原河网地表水的水质变迁与现状.结果表明,钱塘江河口段干流地表水水质总体较好,但大部分河段仍未达到<浙江省水功能Ⅸ水环境功能区划方案>的要求,主要的超标项目为NH4+-N和TP,其次为高锰酸盐指数和BOD5,并且DO浓度总体呈现下降趋势;干流海水水质总体较差,主要超标因子为无机氮与活性磷酸盐;两岸平原河网大部分河段水质为<地面水环境质量标准>(GB 3838-2002)V类或劣于GB 3838-2002 V类.为保障钱塘江河口段水资源的持续利用,提出了相关的水环境保护对策.     

常州市平原环状河网水环境改善方案情景模拟

基于常州市平原河网水力特性,建立相应水环境模型,运用一维圣维南方程组模拟研究区河网水文变化,CSTR水质模型模拟水质指标COD、TN变化,利用2012年7月与2013年4月水文水质同步监测数据对模拟结果的验证表明,模型可以较为准确地反映研究区河网水文水质变化情况。并针对影响河网水质的3个要素(上游引水、污染源和自净能力)设置8个不同改善方案情景,分析河网水质与3个要素的响应关系。结果表明,保证上游引水水质良好的情况下,上游开闸引水更有利于研究区主干河道新澡港河、老澡港河东支河与北塘河水环境的改善,而对于内部河道柴支浜南支河,则需提高上游污水厂出水水质的同时,改善该河段水生态环境,提高其自净能力。研究结果为研究区水系改善措施和规划提供了有力的科学依据和指导。     

东太湖水污染控制途径

根据东太糊形成的历史和演变情况，分析了该湖泊功能的变化。近十年来，该湖生态环境出现了一些令人担忧的情况，主要是水产养殖面积成倍增长，水生生物大幅度减少，水环境质量明显下降，湖泊淤积日趋严重。为了保护东太湖生态环境，恢复湖泊自然生态平衡，作者从生态的保护、水资源的合理利用、污染治理的工程和管理措施等方面探讨了东太湖水污染控制的途径。     

粤西某市小容量河流水污染综合控制研究

对粤西某石化城河段几种主要污染物进行了容量计算，发现即使工业污染源全部达标，其水质状况与目标的差距仍较大，据此提出小容量河流的观点。为保护水环境，结合流域实际情况，本文提出改变以往单纯依靠工业污染源达标控制手段，而采用多手段相结合的综合管理模式来改善水环境的观点，并以中长期水环境规划年内目标值为依据，分析了本方法的有效性、经济性和可操作性，由此对其他具相似条件小容量河流的城市水环境管理起到借鉴性作用。     

基于问卷调查的淮河水环境状况评估

通过问卷对淮河流域干流、沙颍河的水环境状况进行了调查,调查的对象包括沿河居住的农民、渔民和城市居民.结果显示,评估期内(2005-2010年)淮河水质没有明显改善,不同河段水质现状差异较大.沙河和淮河干流中游下段蚌埠闸、五河等断面和洪泽湖水质较好,满足游泳或水产养殖功能,颍河和淮河干流中游上段王家坝、润河集、鲁台子等断面水质较差,仅能满足灌溉功能；颍河上游、淮河干流中游下段水质好转,颍河下游、淮河干流中游上段水质恶化；淮河生态仍在恶化中,水生动植物持续减少,河畔林减少;部分居民因水质恶劣发生取水困难;渔业生产也遭受严重损失,淮河下游著名渔场——洪泽湖渔场仍面临水污染的威胁.     

沭阳县水环境安全管理与污染防治对策探讨

在简要介绍沭阳县水环境概况后,着重分析了该县的水污染现状和主要的水环境问题,并针对性地提出了一些水环境安全管理和污染防治的建议,建立淮河流域水环境安全协调机制和沭阳水环境保护机制,完善水质监测,加强工业、农业和生活污染的防治,建立清污分流系统,并加强宣传教育等项工作.     

常熟河网区水污染物总量控制研究

基于常熟河网原型调水实验和水功能区划，建立了感潮地区河网水量水质模型，对常熟河道水质降解系数及水环境容量进行了计算，并按照点源和面源对区域内污染源进行统计，在此基础上进行了常熟河网水污染物总量控制值和现状削减量的计算，为该地区的水污染防控提供了科学依据。     

盐河淮阴区段水质污染现状评价及防治对策

水污染是困扰淮阴区工农业发展的问题之一。因此对盐河淮阴区段近几年来的水质状况进行了评价，分析了水体污染形成的原因及发展趋势，阐述了污染特征和程度，并提出了改善水环境的对策。     

Perfluorinated compounds in the Pearl River and Yangtze River of China

A total of 14 perfluorinated compounds (PFCs) were quantified in river water samples collected from tributaries of the Pearl River (Guangzhou Province, south China) and the Yangtze River (central China). Among the PFCs analyzed, perfluorooctane sulfonate (PFOS) and perfluorooctanoic acid (PFOA) were the two compounds with the highest concentrations. PFOS concentrations ranged from 0.90 to 99 ng/l and <0.01–14 ng/l in samples from the Pearl River and Yangtze River, respectively; whereas those for PFOA ranged from 0.85 to 13 ng/l and 2.0–260 ng/l. Lower concentrations were measured for perfluorobutane sulfonate (PFBS), perfluorohexane sulfonate (PFHxS), perfluorooctanesulfoamide (PFOSA), perfluorohexanoic acid (PFHxA), perfluoroheptanoic acid (PFHpA), perfluorononaoic acid (PFNA), perfluorodecanoic acid (PFDA), and perfluoroundecanoic acid (PFUnDA). Concentrations of several perfluorocarboxylic acids, including perfluorododecanoic acid (PFDoDA), perfluorotetradecanoic acid (PFTeDA), perfluorohexadecanoic acid (PFHxDA) and perfluorooctadecanoic acid (PFOcDA) were lower than the limits of quantification in all the samples analyzed. The highest concentrations of most PFCs were observed in water samples from the Yangtze River near Shanghai, the major industrial and financial centre in China. In addition, sampling locations in the lower reaches of the Yangtze River with a reduced flow rate might serve as a final sink for contaminants from the upstream river runoffs. Generally, PFOS was the dominant PFC found in samples from the Pearl River, while PFOA was the predominant PFC in water from the Yangtze River. Specifically, a considerable amount of PFBS (22.9–26.1% of total PFC analyzed) was measured in water collected near Nanjing, which indicates the presence of potential sources of PFBS in this part of China. Completely different PFC composition profiles were observed for samples from the Pearl River and the Yangtze River. This indicates the presence of dissimilar sources in these two regions.     

海河干流、大沽排污河沉积物中有机氯农药的残留状况

调查了海河干流和大沽排污河沉积物中持久性有机氯杀虫剂(OCPs)的残留状况.在所选取的16个断面沉积物样品中均有大量HCHs、DDTs检出,表明海河和大沽排污河的DDT和HCH污染相当严重.海河沉积物中HCHs和DDTs总质量浓度分别为3.30～75.96、1.57～221.57 ng/g.大沽排污河沉积物中HCHs和DDTs的残留量分别为2.30～124.61、11.28～237.30ng/g.与国内外部分河流表层沉积物中HCHs、DDTs的含量相比,海河和大沽排污河沉积物中有机氯农药含量较高.最后根据两条河流沉积物中的OCPs的残留量,分析了其可能的污染源.     

River water quality assessment using environmentric techniques: case study of Jakara River Basin

Jakara River Basin has been extensively studied to assess the overall water quality and to identify the major variables responsible for water quality variations in the basin. A total of 27 sampling points were selected in the riverine network of the Upper Jakara River Basin. Water samples were collected in triplicate and analyzed for physicochemical variables. Pearson product-moment correlation analysis was conducted to evaluate the relationship of water quality parameters and revealed a significant relationship between salinity, conductivity with dissolved solids (DS) and 5-day biochemical oxygen demand (BOD₅), chemical oxygen demand (COD), and nitrogen in form of ammonia (NH₄). Partial correlation analysis (r _p) results showed that there is a strong relationship between salinity and turbidity (r _p?=?0.930, p?=?0.001) and BOD₅ and COD (r _p?=?0.839, p?=?0.001) controlling for the linear effects of conductivity and NH₄, respectively. Principal component analysis and or factor analysis was used to investigate the origin of each water quality parameter in the Jakara Basin and identified three major factors explaining 68.11 % of the total variance in water quality. The major variations are related to anthropogenic activities (irrigation agricultural, construction activities, clearing of land, and domestic waste disposal) and natural processes (erosion of river bank and runoff). Discriminant analysis (DA) was applied on the dataset to maximize the similarities between group relative to within-group variance of the parameters. DA provided better results with great discriminatory ability using eight variables (DO, BOD₅, COD, SS, NH₄, conductivity, salinity, and DS) as the most statistically significantly responsible for surface water quality variation in the area. The present study, however, makes several noteworthy contributions to the existing knowledge on the spatial variations of surface water quality and is believed to serve as a baseline data for further studies. Future research should therefore concentrate on the investigation of temporal variations of water quality in the basin.     

Metals in edible fish from Vistula River and Dead Vistula River channel, Baltic Sea

Metals including Al, Ba, Ca, Cd, Co, Cr, Cu, Fe, Hg, K, Mg, Mn, Na, Ni, Pb, Sr and Zn were determined in muscle tissue of 12 fish species by inductively coupled plasma-atomic emission spectroscopy (ICP-AES) and cold vapour-atomic absorption spectroscopy (CV-AAS). Fish were collected from Vistula River at lower course and Dead Vistula River channel in south of Baltic Sea in Poland. The fish species examined include Round Goby (Neogobius melanostomus), Crucian Carp (Carassius carassius), Bull-rout (Myoxocephalus scorpius), Tench (Tinca tinca), Bream (Abramis brama), Burbot (Lota lot), Perch (Perca perca), Roach (Rutilus rutilus), Silver Carp (Hypophthalmichthys molitrix), Pikeperch (Stizostediun lucioperca), Brown salmon (Salmo trutta m. Trutta) and Eel (Anguilla anguilla). The median values of metal concentrations in fresh muscle tissue of 11 fish species varied as follows: Al < 0.5-60; Ba < 0.05-0.31; Ca 120-1800; Cd < 0.05-0.096; Co < 0.10; Cr < 0.10-0.50; Cu < 0.15-0.77; Fe 1.5-21; Hg 0.0058-0.65; K 1800-4200; Mg 130-560; Mn 0.12-0.59; Na 350-840; Ni < 0.2-0.31; Pb < 0.75; Sr 0.079-2.9; Zn 3.3-23 μg/g fresh weight. The Target Hazard Quotient (THQ) values calculated in this study for Cd and Hg from muscles of fish species collected from Vistula River were low in the range of 0.4 for Hg and 0.8 for Cd.     

Plateau River research: ecological risk assessment of surface sediments in the Yarlung Tsangpo River

Environmental Science and Pollution Research - To fully understand the environmental quality of sediments in the Yarlung Tsangpo River Basin, surface sediments of the mainstream of the Yarlung...     

Metals in edible fish from Vistula River and Dead Vistula River channel,Baltic Sea

Metals including Al, Ba, Ca, Cd, Co, Cr, Cu, Fe, Hg, K, Mg, Mn, Na, Ni, Pb, Sr and Zn were determined in muscle tissue of 12 fish species by inductively coupled plasma-atomic emission spectroscopy (ICP-AES) and cold vapour-atomic absorption spectroscopy (CV-AAS). Fish were collected from Vistula River at lower course and Dead Vistula River channel in south of Baltic Sea in Poland. The fish species examined include Round Goby (Neogobius melanostomus), Crucian Carp (Carassius carassius), Bull-rout (Myoxocephalus scorpius), Tench (Tinca tinca), Bream (Abramis brama), Burbot (Lota lot), Perch (Perca perca), Roach (Rutilus rutilus), Silver Carp (Hypophthalmichthys molitrix), Pikeperch (Stizostediun lucioperca), Brown salmon (Salmo trutta m. Trutta) and Eel (Anguilla anguilla). The median values of metal concentrations in fresh muscle tissue of 11 fish species varied as follows: Al < 0.5–60; Ba < 0.05–0.31; Ca 120–1800; Cd < 0.05–0.096; Co < 0.10; Cr < 0.10–0.50; Cu < 0.15–0.77; Fe 1.5–21; Hg 0.0058–0.65; K 1800–4200; Mg 130–560; Mn 0.12–0.59; Na 350–840; Ni < 0.2–0.31; Pb < 0.75; Sr 0.079–2.9; Zn 3.3–23 μg/g fresh weight. The Target Hazard Quotient (THQ) values calculated in this study for Cd and Hg from muscles of fish species collected from Vistula River were low in the range of 0.4 for Hg and 0.8 for Cd. Supplemental materials are available for this article. Go to the publisher's online edition of Journal of Environmental Science and Health, Part B to view the free supplemental file.     

Trends in the occurrence of human and veterinary antibiotics in the sediments of the Yellow River, Hai River and Liao River in northern China

The occurrence of four classes of 17 commonly used antibiotics (including fluoroquinolones, tetracycline, sulfonamides, and macrolides) was investigated in the sediments of the Yellow River, Hai River and Liao River in northern China by using rapid resolution liquid chromatography-tandem mass spectrometry. Higher concentrations were detected for most antibiotics in the sediments of the Hai River than in the sediments of the other rivers. Norfloxacin, ofloxacin, ciprofloxacin and oxytetracycline in the three rivers were most frequently detected with concentrations up to 5770, 1290, 653 and 652 ng/g, respectively. High frequencies and concentrations of the detected antibiotics were often found in the downstream of large cities and areas influenced by feedlot and fish ponds. Good fitted linear regression equations between antibiotic concentration and sediment physicochemical properties (TOC, texture and pH) were also found, indicating that sediment properties are important factors influencing the distribution of antibiotics in the sediment of rivers.     

Polychlorinated organic compounds in Yangtse River sediments

Polychlorinated organic compounds (PCOCs) were analyzed in Yangtse River sediments. The results show that the concentrations of PCOCs in Yangtse River sediments followed the order of DDTs > HCB > HCHs > PCBs. High PCOCs concentrations were detected in sediments from station Y02a and Y02b, which are located in the main input of the Yangtse River (Nanjing section). Results also show that the PCOCs values were highly correlated with organic carbon content and heavy metal contamination.     

南苕溪支流锦溪水质时空变化特征分析

综合运用灰色聚类法、综合污染指数法、等级聚类法就南苕溪支流锦溪近年水质时空变化特征进行分析。结果表明,锦溪入青山水库断面水质2005—2009年逐年改善,2007年后达到灰色聚类等级Ⅲ类水质要求;2009年秋季至2010年夏季期间秋、冬两季的污染程度高于春、夏季节;枯水期综合污染指数最高,但TN、TP污染分指数在丰水期最高,表明污染源中面源污染已占相当比例。空间变化方面从玲珑桥到江桥锦溪水质的综合污染指数不断提升,到江桥时达到极值13.25,锦溪末端三眼桥断面水质较江桥断面有所改善;SPSS空间聚类分析可分为轻污染区(从玲珑桥到冬韵桥)、重污染区(从群利桥到江桥)和中度污染区(从江桥到三眼桥)。锦溪上游农业区对河水中的COD、TN和TP的贡献率分别为66%、54%和49%,农业面源污染已成为制约锦溪水质改善的主要因素。