室内装饰装修材料测试舱的研制与应用

介绍了测试舱的研制意义、测试舱构造和温度控制部分,以及空气交换、循环控制,空气净化装置和温度、湿度、流速显示装置等.通过实验,对测试舱的温度控制,空气净化系统检验,空气交换、循环的检验,释放甲醛平衡点的快速判断和测试舱的比对等运行技术指标进行了论证、优化.结果表明,简易的室内装饰装修材料测试舱对主要运行参数可以自动运行与控制,运行情况满足国家标准方法的技术指标要求,与同类商品化测试舱相比,误差在2%左右.     

江苏省工业发展与大气污染物排放的时空演变关系

选取2001—2014年的相关数据,采用环境库兹涅茨曲线(EKC曲线)模型和物理学的区域重心模型,分析了江苏省工业发展与大气污染物排放的时空演变关系。结果表明,2001年以来,随着工业总产值的增加,工业废气排放量呈现增加的趋势,虽然增加幅度有所减缓,但是拐点还未出现,而SO_2和烟粉尘排放强度已经跨过EKC曲线高峰进入二者协调发展的新阶段。时空演变关系表明,工业总产值和污染物排放强度重心均有较大的移动,并且二者的移动方向呈现相反的趋势,而SO_2和烟粉尘排放强度重心的移动方向具有相同的趋势,并且移动幅度接近。指出,当污染物减排到一定程度时,新的技术和政策措施必须同步发展,才能使污染物排放得到进一步控制,最终进入第五个阶段。     

深度透析农村水源污染的饮水安全解困之道

正不久前网上关于农夫山泉的"标准门"被炒得沸沸扬扬,媒体报道农夫山泉标准不如自来水,再次触发了公众对饮用水水源的重新思考。不管是商家的竞争,还是水质的问题。水被誉为生命之源,可见其重要性,尤其饮用水的安全,关乎民生大计,绝不容忽视。近些年,我国农村的大多数生活污水直接排放,造成河流、水塘污染,不仅影响农村居民居住环境,而且严重威胁到了农村居民的身体健康。农村普遍存在基础设施建设薄弱、排水系统和污水处理建     

日本城市环境监测技术系统运营管理研究与借鉴

日本城市环境监测技术系统管理经历多年探索和总结,形成了成熟的运营模式,对我国现行技术系统的管理实践极有借鉴价值.目前环保部门在相应的管理、技术和人才等方面准备不足,面对社会专业化公司的参与,在管理和运营中暴露出一些问题,比较和借鉴国外市场化运营理念,将促进我们管理思路的创新.     

关注水环境污染物治理 走良性循环发展道路

正水是世界上分布最广的资源之一,也是人类与生物赖以生存和发展必不可少的物质。但世界上可供人类利用的水资源很少,我国的水资源也很短缺,尽管如此,随着工业、经济、科技的发展,人类的这些活动严重的污染了我们的水资源,造成了水质下降。有毒污染物是指那些直接或者间接生物摄入体内后,导致该生物或者其后代发病、行为反常、遗传异变、生理机能失常、机体变形或者死亡的污染物。随着科学技术的进步,工农业生产的发展,水环境作为     

推进环境监测转型 为探索环保新道路提供技术支撑

环境保护工作是全面落实贯彻科学发展观的重要措施,是科学发展的具体体现.环境监测是环境保护工作的基础,是环境管理的组成部分,对于摸清环境状况,促进环境保护事业的发展,满足广大公众的环境知情权,建设和谐社会具有重要作用.     

编制验收监测方案和报告存在的问题和解决办法

指出编制验收监测方案和报告过程中,在建设项目工程概况介绍,监测内容表达,监测评价标准选定,环境管理检查内容,附件收集及排版规范方面存在的问题.提出了解决问题的办法,这有助于提高验收监测方案和报告的编制水平,更好地为环境管理服务.     

王水消解蒸气发生-原子荧光光谱法测定土壤中的砷、锑和汞

对土壤的前处理进行了研究,通过一系列的实验验证,给出了土壤中砷、锑和汞的监测分析方法,采用王水消解,硫脲还原,蒸气发生连续进样,运用原子荧光光谱法进行测定,得到了令人满意的结果.     

洞庭湖流域土壤中有机氯杀虫剂的残留规律研究

2004年5月采集了洞庭湖流域45个土壤样品,用AES萃取技术,使用GC/MS方法测定了样品中的六氯笨、滴滴涕(DDTs)、氯丹、艾氏剂、狄氏剂、异狄氏剂、七氟和灭蚁灵.结果表明,六氯苯、滴滴涕的检出率为100%,氯丹和灭蚁灵的检出率很低,艾氏剂、狄氏剂、异狄氏剂和七氯未检出.总有机氯杀虫剂残留量平均值216.24μg/k,其中滴滴涕214.7μg/kg,占总OCPs的99.3%,且有些土壤样品中w(DDT)/w(DDE DDD)值较大,说明DDTs曾作为湘江流域的主要杀虫剂在洞庭湖流域土壤中广泛施用过,并且近期内仍然有输入.六氯苯的残留量虽然较低,但其施用范围广泛.总OCPs在棉田中的残留量很高,在茶场土壤中最低,表明棉田土壤曾因为各种原因施用过大量的有机氯杀虫剂,茶场土壤中有机氯农药的残存量处于安全范围.     

建设项目环评报告书中存在的水环境监测问题及解决方法

项目建设前的环境质量(包括水环境质量)是环境影响评价的基础,预测项目建设后的环境质量是环境可行性评价结论的依据,环境质量的表征数据是通过环境监测工作取得,环境监测的规范性要求,开展监测要得到的数据必须具备"五性",才能表征某一监测地区的环境质量。由于环境评价的中介服务性,以及时间与经费的关系,对环境监测点位、频次进行压缩与省略,使得监测数据无法保障其代表性,影响建设项目环境影响报告书得出可信的结论。如何保障监测数据的质量,以最少的监测点、最恰当的监测时期、最少的监测频次,取得最有代表性的数据表征建设项目周围的环境质量,从而确保评价依靠的环境质量基础可靠,评价结论可信,是一个值得探讨的问题。     

Polycyclic aromatic hydrocarbons with molecular weight 302 in PM 2.5 at two industrial sites in South China

Daytime and nighttime PM(2.5) samples were collected between August 5 and 16, 2009 and between January 24 and February 4, 2010 in an industrial complex site (site A) and an electronic waste recycling site (site B) to determine the seasonal and diurnal variations of 19 individual polycyclic aromatic hydrocarbons (PAHs) with molecular weight 302 (MW302) including four highly carcinogenic dibenzopyrene (DBP) isomers dibenzo[a,l]pyrene (DBalP), dibenzo[a,e]pyrene (DBaeP), dibenzo[a,i]pyrene (DBaiP), and dibenzo[a,h]pyrene (DBahP). This is the first report on DBP isomers in air particles from South China. The total concentration of PAH MW302 isomers ranged from 1.65 to 3.60 ng m(-3) in summer and 3.82 to 9.81 ng m(-3) in winter. The strongest peaks in the chromatograms of the MW302 isomers were naphtha[2,1-a]pyrene (N21aP), dibenzo[j,l]fluoranthene (DBjlF), naphtha[1,2-b]fluoranthene (N12bF), naphtha[1,2-k]fluoranthene (N12kF) and dibenzo[a,e]fluoranthene (DBaeF), constituting 52.0 to 55.4% of the total MW302 isomers. All the MW302 isomers showed notable seasonal variations. Most of the MW302 isomers in site B showed distinctive diurnal variations with higher concentrations occurring in the night. Taking into account both concentration and potency equivalence factors (PEFs), the strongest carcinogen in the analyzed samples was DBaiP, and the ratios of sum carcinogenic potency of four highly carcinogenic DBP isomers to benzo[a]pyrene (BaP) was about 0.94 in winter to 1.89 in summer, indicating the importance of DBP isomers for the risk assessment. Health risk assessment indicated that on average, 1 in 100 000 residents in the two industrial sites may have an increased risk of cancer due to PAH exposure.     

Levels and temporal trends of HCH isomers in ringed seals from West and East Greenland

Levels and temporal trends of the hexachlorocyclohexane isomers alpha-, beta- and gamma-HCH were analysed in blubber of juvenile ringed seals from West Greenland (1994 to 2006) and juvenile and adult ringed seals from East Greenland (1986 to 2006). No significant differences in the concentration levels in the juvenile seals were found between East and West Greenland for any of the three isomers. alpha-HCH concentrations were not significantly different between juvenile and adult ringed seals from East Greenland, whereas beta- and gamma-HCH concentrations were significantly higher in adult ringed seals. alpha- and beta-HCH in Greenland ringed seals were approximately a factor two lower than in the Canadian Arctic, and alpha-HCH was a factor 2-3 higher than in ringed seals from an area east of Svalbard, Norway. Annual decreases in ringed seals from Greenland during the study periods were detected to be 9.1-11.7%, 1.4-3.9% and 6.0-6.4% for alpha-, beta- and gamma-HCH, respectively, being quite similar in both East and West Greenland. Similar levels and trends in East and West Greenland support the general understanding of the pathways of HCH isomers to and in the Arctic.     

Levels and distribution of persistent organochlorine pesticide residues in water and sediments of Gomti River (India)—a tributary of the Ganges River

This study reports the concentration levels and distribution pattern of the persistent organochlorine pesticide (OCPs) residues in the water and bed-sediments of the Gomti River collected seasonally over a period of 2 years. The water and bed-sediment samples were collected from eight different sites and analyzed for aldrin, dieldrin, endrin, HCB, HCH isomers, DDT isomers/metabolites, endosulfan isomers (alpha and beta), endosulfan sulfate, heptachlor and its metabolites, alpha-chlordane, gamma-chlordane and methoxychlor. In the river water and sediments SigmaOCPs residues ranged between 2.16 and 567.49 ng l(-1) and 0.92 and 813.59 ng g(-1), respectively. The results, further, suggested that source of DDT contamination is from the aged and weathered agricultural soils with signature of recently used DDT in the river catchments. To assess any adverse effect of OCPs contamination on river's biological component, the threshold effect level (TEL) was used. The results revealed that bed-sediments of the Gomti River are contaminated with lindane, endrin, heptachlor epoxides and DDT, particularly at site-4 and may contribute to sediment toxicity in the freshwater ecosystem of the river.     

Persistent Organochlorine Pesticide Residues in Soil and Surface Water of Northern Indo-Gangetic Alluvial Plains

This study reports the concentration levels and distribution pattern of the organochlorine pesticide (OCPs) residues in the soil and surface water samples collected from the northern Indo-Gangetic alluvial plains. A total of 31 soil and 23 surface water samples were collected from the study region in Unnao district covering an area of 2150 km² and analyzed for aldrin, dieldrin, endrin, HCB, HCH isomers, DDT isomers/metabolites, endosulfan isomers (α and β), endosulfan sulfate, heptachlor and its metabolites, α-chlordane, γ-chlordane and methoxychlor. In both the soil and surface water samples β- and δ-isomers of HCH were detected most frequently, whereas, methoxychlor was the least detected pesticide. The results showed contamination of soil and surface water of the region with several persistent organic pesticides. The total OCPs level ranged from 0.36–104.50 ng g^–1 and 2.63–3.72 μg L^–1 in soil and surface water samples, respectively.     

Occurrence and behaviour of 4-nonylphenol in river water of Germany

An analytical method composed of solid-phase-extraction (SPE) followed by gas chromatography-mass spectrometry (GC-MS) has been developed to investigate the occurrence and the behaviour of the endocrine disruptor 4-nonylphenol (4-NP) in river water of Germany. 16 Para-isomers of the complex mixture of 4-NP isomers have been resolved in the SPE-extracts of river water samples. The mass spectra indicate the presence of four distinct groups of isomers. The different groups are characterised by different base peaks of the mass spectra dependent on the substitution of the alpha-carbon on the alkyl chain. The different isomers show (i) alpha-methyl, alpha-ethyl (base peak 149), (ii) alpha-dimethyl (base peak 135), (iii) alpha-methyl, alpha-propyl, alpha-butyl (base peak 121) and (iv) alpha-methyl, alpha-propyl, alpha-butyl (base peak 107) configuration of the alkyl chain. The recovery of the unbranched compound 4-n-NP was > or = 90%. Detection limit and determination limit of the whole analytical procedure were 6 ng L(-1) and 25 ng L(-1), respectively with a relative standard deviation of 11.7%. The concentration of the sum of the 4-NP isomers in all samples of river water ranged from 28 ng L(-1) (Elbe River) to 1220 ng L(-1)(Oder River). In a period of a higher river water level, a higher amount of 4-NP was detected in the Oder River than in a period of a lower water level. Therefore dilution was not the determinant factor of the 4-NP concentration in river water. The diurnal dynamics of the sewage treatment works (STWs) have to be considered as an influencing factor for the presence of 4-NP in river water.     

Persistent organochlorine pesticide residues in animal feed

Animal products like milk and meat are often found to be contaminated with residues of persistent pesticides and other toxic substances. The major source of entry of these compounds to animal body is the contaminated feed and fodder. So, unless the residues are managed at this stage, it is very difficult to prevent contamination in milk and meat. Therefore, the status of residue level of most persistent organochlorinated pesticides (OCP) in feed and fodder should be monitored regularly. The frequency of occurrence and contamination levels of OCP residues in different kinds of animal concentrate feed and straw samples collected from Bundelkhand region of India were determined. Out of 533 total samples, 301 i.e. 56.47% samples were positive containing residues of different OCPs like hexachlorocyclohexane (HCH) isomers, dichlorodiphenyltrichloroethane (DDT) complex, endosulfan and dicofol. Among different HCH isomers, the mean concentration of ??-HCH was highest, and total HCH varied from 0.01 to 0.306 mg kg^???1. In case of DDT complex, i.e. DDD, DDE and DDT, the concentration ranged between 0.016 and 0.118 mg kg^???1 and the pp^| isomers were more frequently encountered than their op^| counterparts. Endosulfan was also found in some samples in concentration ranging from 0.009 to 0.237 mg/kg, but dicofol could be recorded in very few samples. Although feed samples were found to contain OC residues, after comparing their levels in positive samples with the limiting values of respective pesticides, only very few were found to exceed the threshold level. Otherwise, they were mostly within safe limits.     

Residues of organochlorine compounds in starlings (Sturnus vulgaris), 1979

Starlings were collected for the National Pesticides Monitoring Program from 112 sites throughout the contiguous United States and analyzed for organochlorine compounds. Starling samples from 14 sites had greater than 1.0 ppm DDE residues with the highest DDE level being 15.8 ppm in a sample taken near Roswell, New Mexico. The occurrence of PCBs and chlordane isomers increased since the 1976 collection, but DDT, DDE, and dieldrin occurrence decreased. DDE and dieldrin levels decreased since the 1976 collection, but the level of PCBs has increased.     

西夫(Schiff)碱侧链聚硅氧烷毛细管柱气相色谱固定相的制备与色谱性能

将合成的西夫 (Schiff)碱侧链聚硅氧烷高分子液晶化合物用作毛细管柱气相色谱固定相 ,具有较高的柱效 ,热稳定性较好 ,最高柱温可达 2 80℃ ,对苯的各种取代物、酚类及多环芳烃有良好的选择性 ,尤其对位置异构体有独特的分离效果。     

Linear alkylbenzenesulfonates (LAS) of an urban stream in Korea

Profiles of alkyl homologues and isomers of LAS were monitored for an urban stream polluted with municipal wastewaters in Korea. Alkylchains of the stream LAS were shorter than commercial standards and higher I/E ratios were associated with lower LAS concentrations. These suggested a partial biodegradation of LAS in the stream. Higher LAS concentrations were observed in the upper stream. LAS levels were at their lowest during summer probably due to high precipitation and faster biodegradation rates. LAS contributed to about 29% of MBAS and could be used to roughly estimate BOD concentration of the stream.     

Protein adducts as biomarkers of exposure to aromatic diisocyanates in workers manufacturing polyurethane (PUR) foam

This work was undertaken to investigate the usefulness of diisocyanate-related protein adducts in blood samples as biomarkers of occupational exposure to toluene diisocyanate (TDI; 2,4- and 2,6-isomers) and 4,4'-methylenediphenyl diisocyanate (MDI). Quantification of adducts as toluene diamines (TDAs) and methylenedianiline (MDA) was performed on perfluoroacylated derivatives by gas chromatography-mass spectrometry (GC-MS/MS) in negative chemical ionisation mode. TDI-derived adducts were found in 77% of plasma and in 59% of globin samples from exposed workers manufacturing flexible polyurethane foam. The plasma levels ranged from 0.003 to 0.58 nmol mL(-1) and those in globin from 0.012 to 0.33 nmol g(-1). The 2,6-isomer amounted to about two-thirds of the sum concentration of TDA isomers. MDI-derived adducts were detected in 3.5% of plasma and in 7% of globin samples from exposed workers manufacturing rigid polyurethane foam. A good correlation was found between the sum of TDA isomers in urine and that in plasma. The relationship between globin adducts and urinary metabolites was ambiguous. Monitoring TDI-derived TDA in plasma thus appears to be an appropriate method for assessing occupational exposure. Contrary to TDI exposure, adducts in plasma or globin were not useful in assessing workers' exposure to MDI. An important outcome of the study was that no amine-related adducts were detected in globin samples from TDI- or MDI-exposed workers, alleviating concerns that TDI or MDI might pose a carcinogenic hazard. Further studies are nevertheless required to judge whether diisocyanates per se could be such a hazard.