辽宁省第四系地下水库勘察规划

通过分析辽宁省水资源的供需现状、基础地质气候条件以及重点对第四系河谷的野外实地调查,同时根据地方经济的发展趋势、地下水库的功能,论证了辽宁省地下水库开发的必要性和可行性,指出该省的下辽河平原、辽西部分山问河谷、辽西辽南的滨海河谷适宜修建地下水库,并制定了第四系地下水库勘察规划,即把辽宁省规划为5个地下水库勘察区(地下水库已勘察区或建成区、近期地下水库勘察区、中期地下水库勘察区、远期地下水库勘察区、未规划地下水库勘察区).     

基于价值工程的生态旅游资源评价研究——以浙江省丽水市为例

生态旅游资源是发展生态旅游的重要基础,生态旅游资源评价是生态旅游开发的依据,建立指标体系是评价的关键。根据生态旅游的特征,在综合考虑生态旅游资源、生态环境、旅游开发条件和旅游开发潜力的基础上,建立了生态旅游资源评价的指标体系。通过对专家进行问卷征询,运用价值工程评价法对生态旅游资源各评价因素和因子的重要性进行分析,结果表明：生态环境条件和旅游开发条件是重要的影响因素;旅游资源组合条件、知名度和影响力、大气质量、旅游资源对游客的吸引力以及水体质量是居于前5位的重要影响因子。以浙江省丽水市为例,运用价值工程评价法得出丽水生态环境条件优势最明显,11个评价因子中有9个评价因子的价值系数（V）大于1;旅游资源组合条件（V=0.640）、本地投资能力（V=0.655）、区域经济水平（V=0.671）、旅游设施（V=0.672）以及知名度和影响力（V=0.678）等因子相对不足,最后针对评价结果提出了实现丽水生态旅游可持续发展的措施。     

基于二分式问卷的青岛浒苔绿潮灾害对滨海旅游资源非使用价值影响评估

海洋藻华灾害对沿海地区的社会经济产生了相当大的影响。其中对滨海旅游经济及景观资源非使用价值（non-use value）的影响,无法从市场中得到直接评估。在对这部分非使用价值的评估中,条件评价法（contingent valuation method,CVM,也称条件价值法）是目前应用最为广泛的主要方法。该方法通过社会调查,以问卷方式收集被访者的信息,通过社会经济学的计算方法对目标资源的非使用价值受影响程度进行定量评价。本文利用CVM中的二分式实证问卷,以浒苔绿潮灾害对青岛滨海旅游资源非使用价值的影响为目标,调查在浒苔绿潮发生期内游客对改善滨海景观的支付意愿（WTP）信息,通过二值选择模型（Logit回归模型）计算,将浒苔绿潮灾害对青岛滨海旅游资源非使用价值的影响进行货币化评估,得出了该影响的大致范围,以直观的方式评价了浒苔绿潮灾害对青岛滨海旅游资源非使用价值的影响。这一方法可以作为海洋藻华灾害对社会经济影响评估方法的有益补充,为政府及相关组织对海洋藻华灾害的预防、治理以及更合理和有效的应急处置提供灾害经济影响部分的决策依据。     

三亚市风景资源生态敏感性及保护初探

从可持续发展的角度,分析了三亚市海陆自然体系生态完整性和旅游资源单体的生态敏感性,根据区域所具有的承载力和风景资源的生态功能,对典型滨海型旅游景观资源的开发提出了具体保护建议。     

全球变化背景下可持续的滨海旅游资源开发与管理

滨海旅游是最传统的、主要的旅游形式,也是现代旅游增长最快的领域,在国内外均具有举足轻重的地位。全球变化很可能是由人类活动引起,并且影响着旅游业的发展。旅游业通过使用交通运输系统尤其是航空旅行、旅游目的地住宿餐饮等活动排放大量温室气体,对全球变化做出贡献。可持续滨海旅游以可持续的资源开发和管理为基础,在全球变化背景下,要达到这一目标,需要在滨海旅游模式与产品类型转变、旅游资源利用方式转变、利益相关者协作等方面对滨海旅游资源进行优化开发和有效管理:以绿色思维指导低碳旅游模式,发展生态旅游和替代性旅游等新型产品;提倡降碳减排、发展碳补偿和碳经济、制定碳排放标准、鼓励新型节油节能科技应用;鼓励社区参与,平衡利益相关者的收益和兴趣,尤其是探察当地社区居民、旅游者和政府工作人员对全球变化的看法、态度、责任感和共识。这些措施将在规划-管理-监督-评估动态模型中得到优化。     

新时代的旅游资源研究：保护利用与创新发展——旅游地理青年学者笔谈

当前,我国已经全面进入大众旅游时代,旅游业持续领跑宏观经济,并成为带动区域发展的支柱产业。旅游资源是传统旅游业的发展基础,我国是旅游资源大国,处理好旅游资源保护与利用的关系、实现创新发展是旅游资源研究的关键。来自旅游地理研究领域的16位青年学者,以笔谈方式探讨了新时期、新阶段下旅游资源保护与利用的基本思路,从旅游发展的新特征、资源价值的新认知、开发与保护的新方式以及针对专项资源的保护开发的新对策等方面重新定义新时代旅游资源研究的重点,核心观点整理如下：（1）随着旅游业的发展,大众旅游方式变化推动旅游产业革新,旅游资源的内涵也相应不断丰富。新时代旅游资源的重构、泛化和组合的变化需要重新对旅游资源进行识别、划分和评价,未来资源仍是旅游产业发展的基础,需要合理认知旅游资源的新特征和新价值。（2）新时代,传统资源开发的条件趋严,坚守生态底线是发展的基础。从供给端看,资源转化为产品的过程中,要尊重市场规律,面向游客新需求,以深入挖掘文化内涵为重点,借助科技新手段,创新资源开发新模式,推出受游客欢迎的旅游产品,从而激发旅游资源的市场价值属性,推动区域旅游产业升级,实现资源、资本、资产的可持续发展。（3）从需求端看,捕捉客群变化特征,构建社会规范和文明旅游新方式,从多方面引导游客主动保护旅游资源的行为,从而形成推动旅游资源保护和开发协调的新思路。（4）旅游资源的类型丰富,决定了旅游资源保护与开发方式的多样化：针对乡村旅游资源,要在资源评估的基础上,重新认识其新价值,在乡村振兴战略的引领下,因地制宜,以产业集聚为突破,重视乡村社区利益,推动乡村旅游资源的创新利用和可持续发展;针对农业文化遗产资源,在可持续发展的基础上,活态利用,构建多方参与的新机制;针对人文旅游资源,需要挖掘人文旅游资源本真性,融入传统文化,促进文化传承与旅游产业的互动发展;针对山地民族旅游资源,在时代价值重新认知的基础上要重视其地域系统的独特性,基于人地关系整体化保护与开发;针对民宿旅游,重视其转化农村闲置资源的重要功能,强化生态保护,构建民宿旅游集聚区。     

南极旅游资源分类及空间分布特征

南极地区以其独特的旅游资源吸引了越来越多人的注意,近年来赴南极旅游的游客人数快速增长。但国内外对南极旅游资源的研究却相对滞后,对其分类和评价研究几乎处于空白状态。本文对南极旅游资源的分类及空间分布特征进行了初步研究,并对我国南极旅游业发展提出建议,以期为南极旅游资源的评价、开发与保护提供参考。结果表明：南极地区已开展实质性旅游活动的主要旅游资源单体共558个,按属性可分为8个主类、18个亚类和30个基本类型,自然资源类型丰富,水域景观占比较大;旅游资源的空间分布不均衡,在南极半岛西北部格雷厄姆地沿海及附近岛屿、罗斯海周边岛屿及大陆形成了两个高密度集聚区;气候环境条件和旅游资源的可达性是影响该地区旅游资源空间分布的重要因素;与我国相关的南极旅游资源较少,中国在南极旅游开发中的参与度和成熟度也相对较低,未来应尽快摸清南极旅游资源状况,加强南极旅游影响研究,推动我国南极旅游发展。     

大陈海岛旅游开发SWOT分析和发展路径研究

大陈海岛为长三角地区著名的滨海休闲度假旅游区,是浙东沿海旅游经济带和浙东南沿海旅游目的地的重要节点。已有相关工作对大陈海岛的资源和旅游开发进行了初步探索,取得了大量研究成果,但尚缺乏系统性的旅游开发策略研究。本文利用SWOT分析方法对台州市大陈海域海岛旅游开发的优势、劣势、机遇和挑战进行了分析,在此基础上,结合大陈海岛的资源现状和全域旅游的战略思想,进一步从可持续发展的理念出发,为大陈海岛旅游开发的发展路径提出可行性的建议,为更好地促进大陈海岛旅游开发、进一步制定科学的开发战略奠定一定的基础。     

融入循环经济体系的滨海湿地资源开发思路探讨

滨海湿地是湿地的重要类型之一,其资源、生态、旅游、文化、教育、科研等多方面的潜在功能对社会、经济发展均有极其重要的作用。而中国滨海湿地遭受破坏的情况较为严重。当前,如何基于科学发展观,将滨海湿地纳入循环经济系统之中,更加合理地进行开发、保护,已成为关系到中国经济可持续发展的重要问题之一。文章基于对山东滨州地区典型滨海湿地资源开发实践的研究,结合中国其他地区湿地开发保护的经验教训,以循环经济理论为指导进而探讨适合中国国情的滨海湿地资源开发思路、模式,并在此基础上提出一些建议,以期能够对中国“十一五”时期的湿地开发、保护工作以及部分地区区域经济发展起到一定借鉴、推进作用。     

漫谈海洋景观与环境保护的关系

在世纪之交,世界旅游业产值达 GDP总量的10%以上,成为第一大产业。我国国土占世界 1/15,人口占世界 1/4,但旅游业产值不足世界的 1%,可见该产业是有着巨大的上升空间。 与我国隔洋相望的美国、加拿大和墨西哥,滨海旅游资源的保护和开发,值得国人借鉴。与我国不同,这些国家历史较短,人文景观较少,自然景观成为绝对主要的旅游资源。太平洋东岸滨海地带有大洋暖流经过,即使是北部地区在冬天也不显寒冷;但是在同一纬度上,从太平洋岸边到200km处终年积雪的喀斯喀特山脉,却可以更换几个季节,植被形成分带。对于旅游而言,气候、地理、交通和地貌…     

Effects of two sludge application on fractionation and phytotoxicity of zinc and copper in the soil

The potential harm of heavy metals is a primary concern in application of sludge to the agricultural land. A pot experiment was conducted to evaluate the effect of two sludges on fractionation of Zn and Cu in soil and their phytotoxicity to pakchoi. The loamy soil was mixed with 0%, 20%, 40%, 60% and 80% (by weight) of digested sewage sludge (SS) and composted sludge (SC). The additions of both sludges caused a significant raise in all fractions, resulting in that exchangeable (EXCH) and organic bound (OM) became predominance of Zn and organic bound Cu occupied the largest portion. There was more available amount of Zn and Cu in SS treatments than SC treatments. During the pot experiment, the concentration of Zn in EXCH, carbonate (CAR) and OM and Cu in EXCH and OM fractions decreased in all treatments, so their bioavailability reduced. Germination rate and plant biomass decreased when the addition rate was high and the best yield appeared in 20% mixtures at the harvest of pakchoi. The two sludges increased tissue contents of Zn and Cu especially in the SS treatments. Zn in pakchoi was not only in relationship to ΔEXCH and ΔCAR forms but also in ΔOM forms in the sludge-soil mixtures. Tissue content of Cu in pakchoi grown on SC-soils could not be predicted by ΔEXCH. These correlation rates between Zn and Cu accumulation in pakchoi and variation of different fractions increased with time, which might indicate that sludges represented stronger impacts on the plant in long-term land application.     

Intraspecific differences in effects of co-contamination of cadmium and

A hydroponic experiment was carried out to study intraspecific differences in the effects of different concentrations of cadmium (Cd)(0-10 mg/L) and arsenate (As(V)) (0-8 mg/L) on the growth parameters and accumulation of Cd and As in six wheat varieties Jing-9428, Duokang-1, Jingdong-11, Jing-411, Jingdong-8 and Zhongmai-8. The endpoints of wheat seedlings, including seed germination,biomass, root length and shoot height, decreased with increasing the Cd and As concentrations. Significant differences in seed germination, biomass, root length, shoot height and the accumulation of Cd and As were observed between the treatments and among the varieties (p ＜ 0.05). The lethal dosage 50% were about 20, 80, 60, 60, 80 and 20 mg As/L for Jing-9428, Duokang-1, Jingdong-11,Jing-411, Jingdong-8 and Zhongmai-8, respectively, and the corresponding values for Cd were about 30, 80, 20, 40, 60 and 10 mg Cd/L, respectively. Among the six varieties, Duokang-1 was found to be the most resistant to Cd and As toxicity, and Zhongmai-8 was the most sensitive to Cd and As co-contamination. The resistance of the six varieties was found dependant on the seedling uptake of Cd and As. Duokang-1 was the most suitable for cultivation in Cd and As co-contaminated soils.     

EDTA-enhanced phytoremediation of lead contaminated soil by Bidens maximowicziana

Phytoremediation is a potential cleanup technology for the removal of heavy metals from contaminated soils.Bidens maximowicziana is a new Pb hyperaccumulator,which not only has remarkable tolerance to Pb but also extraordinary accumulation capacity for Pb.The maximum Pb concentration was 1509.3 mg/kg in roots and 2164.7 mg/kg in overground tissues.The Pb distribution order in the B. maximowicziana was:leaf>stem>root.The effect of amendments on phytoremediation was also studied.The mobility of soil Pb and the Pb concentrations in plants were both increased by EDTA application.Compared with CK(control check),EDTA application promoted translocation of Pb to overground parts of the plant.The Pb concentrations in overground parts of plants was increased from 24.23-680.56 mg/kg to 29.07-1905.57 mg/kg.This research demonstrated that B.maximowicziana appeared to be suitable for phytoremediation of Pb contaminated soil,especially,combination with EDTA.     

Distribution and ecological effect of mercury in Laogang landfill, Shanghai, China

Laogang landfill near Shanghai is the largest landfill in China, and receives about 10000 t of daily garbage per day, Samples of topsoil and plants were analyzed to evaluate mercury pollution from the landfill. For topsoil samples, there were significant correlations among total mercury （HgT）, combinative mercury （Hgc） and gaseous mercury （HgG）, and content of total organic carbon （TOC）, but, no significantly relationship was found between Hg content and filling time. Hg content changes in vertical profiles with time showed that the average Hgv of profiles 1992, 1996, and 2000 was similar, but their average HgG was quite different. HgT was significantly correlated with Hgc in profile 1992 and 2000, and Hgv was significantly correlated with Hg6 in profile 1996. HgG/Hgv ratio in profile samples decreased in the order of （HgG,/HgT）1992〉（HgG/HgT）1996〉〉（HgG/HgT）2000. A simple outline of Hg release in landfill could be drawn： with increasing of filling time, degradation undergoes different biodegradation, accordingly, gaseous mercury goes through small, more, and small proportion to total mercury. Distribution of Hg in plants was inhomogeneous, following the order of leaf〉root〉stem. The highest value of leaf may be associated with higher atmospheric Hg from landfill. Ligneous plants （e.g. Phyllostachys glanca, Prunus salicina and Ligustrum lucidum） are capable of enriching more Hg than herbaceous plants.     

Toxic effects of acetochlor, methamidophos and their combination on nifH gene in soil

Toxic effects of two agrochemicals on nifH gene in agricultural black soil were investigated using denaturing gradient gel electrophoresis （DGGE） and sequencing approaches in a microcosm experiment. Changes of soil nifH gene diversity and composition were examined following the application of acetochlor, methamidophos and their combination. Acetochlor reduced the nifH gene diversity （both in gene richness and diversity index values） and caused changes in the nifH gene composition. The effects of acetochlor on nifH gene were strengthened as the concentration of acetochlor increased. Cluster analysis of DGGE banding patterns showed that nifH gene composition which had been affected by low concentration of acetochlor （50 mg/kg） recovered firstly. Methamidophos reduced nifH gene richness that except at 4 weeks. The medium concentration of methamidophos （150 mg/kg） caused the most apparent changes in nifH gene diversity at the first week while the high concentration of methamidophos （250 mg/kg） produced prominent effects on nifH gene diversity in the following weeks. Cluster analysis showed that minimal changes of nifH gene composition were found at 1 week and maximal changes at 4 weeks. Toxic effects of acetochlor and methamidophos combination on nifH gene were also apparent. Different nifH genes （bands） responded differently to the impact of agrochemicals： four individual bands were eliminated by the application of the agrochemicals, five bands became predominant by the stimulation of the agrochemicals, and four bands showed strong resistance to the influence of the agrochemicals. Fifteen prominent bands were partially sequenced, yielding 15 different nifH sequences, which were used for phylogenetic reconstructions. All sequences were affiliated with the alpha- and beta-proteobacteria, showing higher similarity to eight different diazotrophic genera.     

Enzymatic oxidation of aqueous pentachlorophenol

The influence of the nonionic surfactant Tween 80 on pentachlorophenol （PCP） oxidation catalyzed by horseradish peroxidase was studied. The surfactant was tested at concentrations below and above its critical micelle concentration （CMC）. Enhancement of PCP removal was observed at sub-CMCs. The presence of Tween 80 in the reaction mixture reduced enzyme inactivation which occurred through a combination of free radical attack and sorption by precipitated products. A simple first-order model was able to simulate time profiles for enzyme inactivation in the presence or absence of Tween 80. At supra-CMCs, the surfactant caused noticeable reductions in PCP removal, presumably through micelle partitioning of PCP which precluded the hydrophobic PCP molecule from interacting with the enzyme.     

Decomposition of alachlor by ozonation and its mechanism

Decomposition and corresponding mechanism of alachlor, an endocrine disruptor in water by ozonation were investigated. Results showed that alachlor could not be completely mineralized by ozone alone. Many intermediates and final products were formed during the process, including aromatic compounds, aliphatic carboxylic acids, and inorganic ions. In evoluting these products, some of them with weak polarity were qualitatively identified by GC-MS. The information of inorganic ions suggested that the dechlorination was the first and the fastest step in the ozonation of alachlor.     

Arsenic uptake by arbuscular mycorrhizal maize （Zea mays L.） grown in an arsenic-contaminated soil with added phosphorus

The effects of arbuscular mycorrhizal (AM) fungus (Glomus mosseae) and phosphorus (P) addition (100 mg/kg soil) on arsenic (As) uptake by maize plants (Zea mays L.) from an As-contaminated soil were examined in a glasshouse experiment.Non-mycorrhizal and zero-P addition controls were included.Plant biomass and concentrations and uptake of As,P,and other nutrients,AM colonization,root lengths,and hyphal length densities were determined.The results indicated that addition of P significantly inhibited root colonization and development of extraradical mycelium.Root length and dry weight both increased markedly with mycorrhizal colonization under the zero-P treatments,but shoot and root biomass of AM plants was depressed by P application.AM fungal inoculation decreased shoot As concentrations when no P was added,and shoot and root As concentrations of AM plants increased 2.6 and 1.4 times with P addition,respectively.Shoot and root uptake of P,Mn,Cu,and Zn increased,but shoot Fe uptake decreased by 44.6%,with inoculation, when P was added.P addition reduced shoot P,Fe,Mn,Cu,and Zn uptake of AM plants,but increased root Fe and Mn uptake of the nonmycorrhizal ones.AM colonization therefore appeared to enhance plant tolerance to As in low P soil,and have some potential for the phytostabilization of As-contaminated soil,however,P application may introduce additional environmental risk by increasing soil As mobility.     

Degradation of metabolites accumulated of benzo[a]pyrene by coupling Penicillium Chrysogenum with KMnO4

Several main metabolites of benzo[a]pyrene （BaP） formed by Penicillium chrysogenum, Benzo[a]pyrene-1,6-quinone （BP 1,6- quinone）, trans-7,8-dihydroxy-7,8-dihydrobenzo[a]pyrene （BP 7,8-diol）, 3-hydroxybenzo[a]pyrene （3-OHBP）, were identified by high-performance liquid chromatography （HPLC）. The three metabolites were liable to be accumulated and were hardly further metabolized because of their toxicity to microorganisms. However, their further degradation was essential for the complete degradation of BaP. To enhance their degradation, two methods, degradation by coupling Penicillium chrysogenum with KMnO4 and degradation only by Penicillium chrysogenum, were compared; Meanwhile, the parameters of degradation in the superior method were optimized. The results showed that （1） the method of coupling Penicillium chrysogenum with KMnO4 was better and was the first method to be used in the degradation of BaP and its metabolites; （2） the metabolite, BP 1,6-quinone was the most liable to be accumulated in pure cultures; （3） the effect of degradation was the best when the concentration of KMnO4 in the cultures was 0.01% （w/v）, concentration of the three compounds was 5 mg/L and pH was 6.2. Based on the experimental results, a novel concept with regard to the bioremediation of BaP-contaminated environment was discussed, considering the influence on environmental toxicity of the accumulated metabolites.     

Impact of atrazine and nitrogen fertilizers on the sorption of chlorotoluron in soil and model sorbents

Sorption of chlorotoluron in ammonium sulfate, urea and atrazine multi-solutes system was investigated by batch experiments. The results showed application of nitrogen fertilizers to the soil could affect the behavior of chlorotoluron. At the same concentration of N, sorption of chlorotoluron decreased as the concentration of atrazine increased on the day 0 and 6 in soil, respectively. The sorption of chlorotoluron increased from 0 to 6 d when soils were preincubated with deionized water, ammonium sulfate and urea solution for 6 d. That indicated incubation time was one of the most important factors for the sorption of chlorotoluron in nitrogen fertilizers treatments. The individual sorption isotherms of chlorotoluron in rubbery polymer and silica were strictly linear in single solute system, but there were competition sorption between pesticides or between pesticides and nitrogen fertilizers. That indicated the sorption taken place by concurrent solid-phase dissolution mechanism and sorption on the interface of water-organic matter or water-mineral matter.