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1.
ABSTRACT: The South Prong watershed is a major tributary system of the Sebastian River and adjacent Indian River Lagoon. Continued urbanization of the Sebastian River drainage basin and other watersheds of the Indian River Lagoon is expected to increase runoff and nonpoint source pollutant loads. The St. Johns River Water Management District developed watershed simulation models to estimate potential impacts on the ecological systems of receiving waters and to assist planners in devising strategies to prevent further degradation of water resources. In the South Prong system, a storm water sampling program was carried out to calibrate the water quality components of the watershed model for total suspended solids (TSS), total phosphorous (TP), and total nitrogen (TN). During the period of May to November 1999, water quality and flow data were collected at three locations within the watershed. Two of the sampling stations were located at the downstream end of major watercourses. The third station was located at the watershed outlet. Five storm events were sampled and measured at each station. Sampling was conducted at appropriate intervals to represent the rising limb, peak, and recession limb of each storm event. The simulations were handled by HSPF (Hydrologic Simulation Program‐Fortran). Results include calibration of the hydrology and calibration of the individual storm loads. The hydrologic calibration was continuous over the period 1994 through 1999. Simulated storm runoff, storm loads, and event mean concentrations were compared with their corresponding observed values. The hydrologic calibration showed good results. The outcome of the individual storm calibrations was mixed. Overall, however, the simulated storm loads agreed reasonably well with measured loads for a majority of the storms.  相似文献   

2.
Abstract: A study was conducted to determine the effects of three land covers (sunn hemp –Crotalaria juncea, sudex, a sorghum‐sudangrass hybrid –Sorghum bicolor x S. bicolor var. sudanese, and common oats –Avena sativa) planted as vegetative filter strips on the reduction of sediment and nutrient loading of surface runoff within the Kaika‐Waialua watershed on the island of Oahu, Hawaii. Runoff samples were collected and analyzed for total suspended solids (TSS), total dissolved solids (TDS), phosphorous, and three forms of nitrogen (nitrate, ammonium, total nitrogen). Study results show that during seven out of 10 runoff events, the three cover crop treatments significantly reduced TSS as compared to the fallow treatment. Average removal efficiencies were 85, 77, and 73% for oats, sunn hemp, and sudex, respectively, as compared to the fallow treatment. Nutrient concentrations were low with phosphorous concentrations, lower than 1 (μg/ml) for all treatments, and total nitrogen (TN) concentrations below 7 (μg/ml) except in the sunn hemp treatment, where TN concentrations were less than 10 (μg/ml). Results of analysis of TDS showed that the cover crop treatments did not decrease dissolved solids concentrations in comparison with the fallow treatment. Analysis of nutrient concentrations in runoff samples did not detect any significant decreases in phosphorous, nitrogen, ammonium, or TN concentrations in comparison to the fallow treatment. However, a significant increase in TN concentrations in the sunn hemp treatment was detected and showed the nitrogen fixing capacity of sunn hemp. No treatment effects on runoff volume were detected, and runoff volumes were directly correlated with rainfall amounts showing no crops significantly impacted soil infiltration rates. These results were attributed to extremely low soil hydraulic conductivities (0.0001‐7 cm/day at the soil surface, 15 and 30 cm below the soil surface). This study showed that cover crops planted as vegetative filters can effectively reduce sediment loads coming from idle and fallow fields on moderately steep volcanically derived highly weathered soils.  相似文献   

3.
ABSTRACT: The St. Johns River Water Management District (SJR-WMD) is using a Geographic Information System (GIS) screening model to estimate annual nonpoint source pollution loads to surface waters and determine nonpoint source pollution problem areas within the SJRWMD. The model is a significant improvement over current practice because it is contained entirely within the district's GIS software, resulting in greater flexibility and efficiency, and useful visualization capabilities. Model inputs consist of five spatial data layers, runoff coefficients, mean runoff concentrations, and stormwater treatment efficiencies. The spatial data layers are: existing land use, future land use, soils, rainfall, and hydrologic boundaries. These data layers are processed using the analytical capabilities of a cell-based GIS. Model output consists of seven spatial data layers: runoff, total nitrogen, total phosphorous, suspended solids, biochemical oxygen demand, lead, and zinc. Model output can be examined visually or summarized numerically by drainage basin. Results are reported for only one of the SJRWMD's ten major drainage basins, the lower St. Johns River basin. The model was created to serve a major planning effort at the SJRWMD; results are being actively used to address nonpoint source pollution problems.  相似文献   

4.
Effective water quality management of streams in urbanized basins requires identification of the elements of urbanization that contribute most to pollutant concentrations and loads. Drainage connection (the proportion of impervious area directly connected to streams by pipes or lined drains) is proposed as a variable explaining variance in the generally weak relationships between pollutant concentrations and imperviousness. Fifteen small streams draining independent subbasins east of Melbourne, Australia, were sampled for a suite of water quality variables. Geometric mean concentrations of all variables were calculated separately for baseflow and storm events, and these, together with estimates of runoff derived from a rainfall-runoff model, were used to estimate mean annual loads. Patterns of concentrations among the streams were assessed against patterns of imperviousness, drainage connection, unsealed (unpaved) road density, elevation, longitude (all of which were intercorrelated), septic tank density, and basin area. Baseflow and storm event concentrations of dissolved organic carbon (DOC), filterable reactive phosphorus (FRP), total phosphorus (TP) and ammonium, along with electrical conductivity (EC), all increased with imperviousness and its correlates. Hierarchical partitioning showed that DOC, EC, FRP, and storm event TP were independently correlated with drainage connection more strongly than could be explained by chance. Neither pH nor total suspended solids concentrations were strongly correlated with any basin variable. Oxidized and total nitrogen concentrations were most strongly explained by septic tank density. Loads of all variables were strongly correlated with imperviousness and connection. Priority should be given to low-impact urban design, which primarily involves reducing drainage connection, to minimize urbanization-related pollutant impacts on streams.  相似文献   

5.
ABSTRACT: The influence of sediment resuspension on the water quality of shallow lakes is well documented. However, a search of the literature reveals no deterministic mass-balance eutrophication models that explicitly include resuspension. We modified the Lake Okeechobee water quality model - which uses the Water Analysis Simulation Package (WASP) to simulate algal dynamics and phosphorus, nitrogen, and oxygen cycles - to include inorganic suspend. ed solids and algorithms that: (1) define changes in depth with changes in volume; (2) compute sediment resuspension based on bottom shear stress; (3) compute partition coefficients for ammonia and ortho-phosphorus to solids; and (4) relate light attenuation to solids concentrations. The model calibration and validation were successful with the exception of dissolved inorganic nitrogen species which did not correspond well to observed data in the validation phase. This could be attributed to an inaccurate formulation of algal nitrogen preference and/or the absence of nitrogen fixation in the model. The model correctly predicted that the lake is light-limited from resuspended solids, and algae are primarily nitrogen limited. The model simulation suggested that biological fluxes greatly exceed external loads of dissolved nutrients; and sediment-water interactions of organic nitrogen and phosphorus far exceed external loads. A sensitivity analysis demonstrated that parameters affecting resuspension, settling, sediment nutrient and solids concentrations, mineralization, algal productivity, and algal stoichiometry are factors requiring further study to improve our understanding of the Lake Okeechobee ecosystem.  相似文献   

6.
ABSTRACT: A computerized technique was developed to identify storm runoff episodes and calculate storm discharges, storm loads, and storm average concentrations for each event in datasets with up to 10,000 records. This technique was applied to four watersheds within the Lake Erie drainage basin and identified between 160 and 250 runoff events in each. Storm event loads and storm event mean concentrations were calculated for each runoff event for suspended solids, total phosphorus, soluble reactive phosphorus, nitrate, and total Kjeldahl nitrogen. The basic characteristics of the resulting data are described, as are systematic differences as a function of watershed size, seasonal differences, and trends over time. Many of the results of this study reflect the importance of nonpoint processes and improvements in agricultural best management practices in these watersheds.  相似文献   

7.
ABSTRACT: A dynamic, compartmental, simulation model (WETLAND) was developed for the design and evaluation of constructed wetlands to optimize nonpoint source (NPS) pollution control. The model simulates the hydrologic, nitrogen, carbon, dissolved oxygen (DO), bacteria, vegetative, phosphorous, and sediment cycles of a wetland system. Written in Fortran 77, the WETLAND models both free‐water surface (FWS) and subsurface flow (SSF) wetlands, and is designed in a modular manner that gives the user the flexibility to decide which cycles and processes to model. WETLAND differs from many existing wetland models in that the interactions between the different nutrient cycles are modeled, minimizing the number of assumptions concerning wetland processes. It also directly links microbial growth and death to the consumption and transformations of nutrients in the wetland system. The WETLAND model is intended to be utilized with an existing NPS hydro‐logic simulation model, such as ANSWERS or BASINS, but also may be used in situations where measured input data to the wetland are available. The model was calibrated and validated using limited data from a FWS wetland located at Benton, Kentucky. The WETLAND predictions were not statistically different from measured values for of five‐day biochemical oxygen demand (BOD5), suspended sediment, nitrogen, and phosphorous. Effluent DO predictions were not always consistent with measured concentrations. A sensitivity analysis indicated the most significant input parameters to the model were those that directly affected bacterial growth and DO uptake and movement. The model was used to design a hypothetical constructed wetland in a subwatershed of the Nomini Creek watershed, located in Virginia. Two‐year simulations were completed for five separate wetland designs. Predicted percent reductions in BOD5 (4 to 45 percent), total suspended solids (85 to 100 percent), total nitrogen (42 to 56 percent), and total phosphorous (38 to 57 percent) were similar to levels reported by previous research.  相似文献   

8.
ABSTRACT: Loading functions are proposed as a general model for estimating monthly nitrogen and phosphorus fluxes in stream flow. The functions have a simple mathematical structure, describe a wide range of rural and urban nonpoint sources, and couple surface runoff and ground water discharge. Rural runoff loads are computed from daily runoff and erosion and monthly sediment yield calculations. Urban runoff loads are based on daily nutrient accumulation rates and exponential wash off functions. Ground water discharge is determined by lumped parameter unsaturated and saturated zone soil moisture balances. Default values for model chemical parameters were estimated from literature values. Validation studies over a three-year period for an 850 km2 watershed showed that the loading functions explained at least 90 percent of the observed monthly variation in dissolved and total nitrogen and phosphorus fluxes in stream flow. Errors in model predictions of mean monthly fluxes were: dissolved phosphorus - 4 percent; total phosphorus - 2 percent; dissolved nitrogen - 18 percent; and total nitrogen - 28 percent. These results were obtained without model calibration.  相似文献   

9.
Nutrient concentration targets are an important component of managing river eutrophication. Relationships between periphyton biomass and site characteristics for 78 gravel‐bed rivers in New Zealand were represented by regression models. The regression models had large uncertainties but identified broad‐scale drivers of periphyton biomass. The models were used to derive concentration targets for the nutrients, total nitrogen (TN) and dissolved reactive phosphorous (DRP), for 21 river classes to achieve periphyton biomass thresholds of 50, 120, and 200 mg chlorophyll a m?2. The targets incorporated a temporal exceedance criterion requiring the specified biomass threshold not be exceeded by more than 8% of samples. The targets also incorporated a spatial exceedance criterion requiring the biomass thresholds will not be exceeded at more than a fixed proportion (10%, 20%, or 50%) of locations. The spatial exceedance criterion implies, rather than requiring specific conditions at individual sites, the objective is to restrict biomass to acceptable levels at a majority of locations within a domain of interest. A Monte Carlo analysis was used to derive the uncertainty of the derived nutrient concentration targets for TN and DRP. The uncertainties reduce with increasing size of the spatial domain. Tests indicated the nutrient concentration targets were reasonably consistent with independent periphyton biomass data despite differences in the protocols used to measure biomass at the training and test sites.  相似文献   

10.
Kenney, Terry A. and Susan G. Buto, 2012. Evaluation of the Temporal Transferability of a Model Describing Dissolved Solids in Streams of the Upper Colorado River Basin. Journal of the American Water Resources Association (JAWRA) 48(5): 1041‐1053. DOI: 10.1111/j.1752‐1688.2012.00667.x Abstract: The application of a nonlinear least‐squares regression model describing the sources and transport of dissolved solids in streams of the Upper Colorado River Basin, and that was calibrated using data from water year 1991, was evaluated for use in predicting annual dissolved‐solids loads for the years 1974 through 1998. Simulations for each water year were run using annual climate data. To evaluate how well the model captures the observed annual variability across the basin, differences in predicted annual dissolved‐solids loads for each simulated year and 1991 were compared with differences in monitored annual loads. The temporal trend of the differences between predicted annual loads for the simulated years and the load for 1991 generally followed the trend of the monitored loads. The model appears to underpredict the largest annual loads and overpredict some of the smaller annual loads. An underprediction bias for wetter years was evident in the residuals as was an overprediction bias, to a lesser degree, for drier years. A regression analysis on the residuals suggests that the underprediction bias is associated with precipitation differences from 1991 and with previously defined downward trends in dissolved‐solids concentrations in the basin. In general, given the representative climatic conditions, the model adequately performs throughout the period examined. However, the model is most transferable to years with climatic conditions similar to 1991.  相似文献   

11.
A combination of above-normal precipitation during the winter and spring of 2007-2008 and extensive rainfall during June 2008 led to severe flooding in many parts of the midwestern United States. This resulted in transport of substantial amounts of nutrients and sediment from Iowa basins into the Mississippi River. Water samples were collected from 31 sites on six large Iowa tributaries to the Mississippi River to characterize water quality and to quantify nutrient and sediment loads during this extreme discharge event. Each sample was analyzed for total nitrogen, dissolved nitrate plus nitrite nitrogen, dissolved ammonia as nitrogen, total phosphorus, orthophosphate, and suspended sediment. Concentrations measured near peak flow in June 2008 were compared with the corresponding mean concentrations from June 1979 to 2007 using a paired t test. While there was no consistent pattern in concentrations between historical samples and those from the 2008 flood, increased flow during the flood resulted in near-peak June 2008 flood daily loads that were statistically greater (p < 0.05) than the median June 1979 to 2007 daily loads for all constituents. Estimates of loads for the 16-d period during the flood were calculated for four major tributaries and totaled 4.95 x 10(7) kg of nitrogen (N) and 2.9 x 10(6) kg of phosphorus (P) leaving Iowa, which accounted for about 22 and 46% of the total average annual nutrient yield, respectively. This study demonstrates the importance of large flood events to the total annual nutrient load in both small streams and large rivers.  相似文献   

12.
In this paper, the viability of modeling the instantaneous thermal efficiency (ηith) of a solar still was determined using meteorological and operational data with an artificial neural network (ANN), multivariate regression (MVR), and stepwise regression (SWR). This study used meteorological and operational variables to hypothesize the effect of solar still performance. In the ANN model, nine variables were used as input parameters: Julian day, ambient temperature, relative humidity, wind speed, solar radiation, feed water temperature, brine water temperature, total dissolved solids of feed water, and total dissolved solids of brine water. The ηith was represented by one node in the output layer. The same parameters were used in the MVR and SWR models. The advantages and disadvantages were discussed to provide different points of view for the models. The performance evaluation criteria indicated that the ANN model was better than the MVR and SWR models. The mean coefficient of determination for the ANN model was about 13% and14% more accurate than those of the MVR and SWR models, respectively. In addition, the mean root mean square error values of 6.534% and 6.589% for the MVR and SWR models, respectively, were almost double that of the mean values for the ANN model. Although both MVR and SWR models provided similar results, those for the MVR were comparatively better. The relative errors of predicted ηith values for the ANN model were mostly in the vicinity of ±10%. Consequently, the use of the ANN model is preferred, due to its high precision in predicting ηith compared to the MVR and SWR models. This study should be extremely beneficial to those coping with the design of solar stills.  相似文献   

13.
ABSTRACT: Specific conductivity, pH, dissolved oxygen, carbon, phosphorous, and nitrogen species were measured at 36 stations in the Richibucto River drainage basin, including the estuary, in New Brunswick, Canada, over the six‐year period 1996 through 2001. Each station was sampled between 1 and 26 times (mean = 7.5, standard deviation = 6.0) during the ice free seasons without regard to tide. There was significant variance among stations in most parameters. Principal component analysis (PCA) was used to identify the processes explaining the observed variance in water quality. Because of the high variability in specific conductance, stations were first grouped in a freshwater subset and an estuarine (brackish water) subset. For freshwater stations, most of the variance in water quality was explained by pH and total organic carbon, as well as high nutrient concentrations. These high nutrient concentrations, along with water salinity, which varies with flow and tides, are also important in determining water quality variability in brackish water. It is recommended that water quality parameters that were found to explain most of the variance by PCA be monitored more closely, as they are key elements in understanding the variability in water quality in the Richibucto drainage basin. Cluster analyses showed that high phosphorous and nitrate concentrations were mostly found in areas of peat runoff, tributaries receiving treated municipal effluent, and lentic zones upstream of culverts. Peat runoff was also shown to be acidic, whether it is runoff from a harvested area or a natural bog.  相似文献   

14.
Welker, Andrea L., James D. Barbis, and Patrick A. Jeffers, 2012. A Side‐by‐Side Comparison of Pervious Concrete and Porous Asphalt. Journal of the American Water Resources Association (JAWRA) 48(4): 809‐819. DOI: 10.1111/j.1752‐1688.2012.00654.x Abstract: This article compares the performance of two permeable pavements, pervious concrete and porous asphalt, that were installed side‐by‐side in fall 2007. Because the pavements are located directly adjacent to one another, they experience the same vehicle loads, precipitation, and pollution loads. These permeable pavements are part of an infiltration stormwater control measure (SCM). This article focuses on the comparison of water quality parameters, maintenance and durability, and user perception. Eleven different water quality parameters were analyzed at this site for 19 different storm events over a one year period: pH, conductivity, total suspended solids, chlorides, total nitrogen, total phosphorus, total dissolved copper, total dissolved lead, total dissolved cadmium, total dissolved chromium, and total dissolved zinc. Results from the two pavement types were compared using the Mann–Whitney U‐test. The only parameter that was found to be statistically different between the two pavements was pH. Periodic inspection of the two pavement types indicated that after two years of use both pavements were wearing well. However, there was some evidence of clogging of both pavements and some evidence of surface wear. A survey of users of the lot indicated that the perception of these permeable pavements was favorable.  相似文献   

15.
ABSTRACT: A 1990 nitrogen and phosphorus mass balance calculated for eight National Stream Quality Accounting Network (NASQAN) basins in the Albemarle-Pamlico Drainage Basin indicated the importance of agricultural nonpoint sources of nitrogen and phosphorus and watershed nitrogen retention and processing capabilities. Basin total nitrogen and phosphorus input estimates were calculated for atmospheric deposition (which averaged 27 percent of total nitrogen inputs and 22 percent of total phosphorus inputs); crop fertilizer (27 and 25 percent); animal-waste (22 and 50 percent, respectively); point sources (3 percent each of total nitrogen and total phosphorus inputs); and biological nitrogen fixation (21 percent of total nitrogen inputs). Highest in-stream nitrogen and phosphorus loads were measured in predominantly agricultural drainage areas. Intermediate loads were observed in mixed agricultural/urban drainage areas; the lowest loads were measured in mixed agricultural/forested drainage areas. The difference between the sum of the nutrient input categories and the sum of the in-stream nutrient loads and crop-harvest nutrient removal was assigned to a residual category for the basin. The residual category averaged 51 percent of total nitrogen inputs and 54 percent of total phosphorus inputs.  相似文献   

16.
Lake Holiday, a human-made recreational lake in northern Illinois, was threatened with closure due to high bacterial levels. A factorially designed experiment with multivatiate responses was developed to study and identify the main sources of pollution. Data on total coliform, fecal coliform, fecal streptococci, dissolved oxygen, pH, ammonia-N, total phosphorus, nitrate/nitrite-N were analyzed using regression models describing dam spillway loads as a function of source loads and time. The results suggest that the relationships among source, time, and load are complex, even though only two sources account for most of the lake's loading Stevens Brook, which receives the discharge from the Somonauk Sewage Treatment Plant, and Somonauk Creek, which is the major drainage, contribute high loads of bacteria and nutrients to the lake. The influent loads contributed to the lake are discharged at the dam over about 4 weeks  相似文献   

17.
The application of inorganic nitrogen fertilizers on agricultural landscapes has the potential to generate concerns of environmental degradation at fine to coarse scales across the catchment and landscape. Inorganic nitrogen species (NO3*, NO2*, and NH3) are typically associated with subsurface flow processes; however, surface runoff from rainfall events in no-till agriculture with inorganic surface fertilizers might contribute to downstream eutrophication. Inorganic nitrogen reduction capacity of agricultural drainage ditches under no-till cotton was determined under natural, variable rainfall conditions in northern Mississippi. Monthly grab baseflow samples and storm-generated flow samples were variably sampled temporally within two experimental farm ditches over 2 yr. Inorganic nitrogen concentrations, in conjunction with Manning's equation and Natural Resources Conservation Service dimensionless hydrographs, provided individual water volumes per storm event and thus maximum effluent and outflow nitrogen loads. Base and stormflow regression results indicate drainage ditches reducing NO3* and NH3 over the length of the ditch for growing and dormant seasons. Overall, maximum storm loads of dissolved inorganic nitrogen (DIN) from the farm over the 2-yr sampling period accounted for 2.2% of the initial fertilizer application, of which 1.1% left the ditch (0.84 kg ha(-1) yr(-1)) (a 57% ditch reduction of DIN load over 2 yr). Long-term sampling incorporating data on application and loss of fertilizers and farm management will provide critical information for farmers and scientists on the potential of economic gains and downstream ecosystem eutrophication, respectively.  相似文献   

18.
ABSTRACT: The impact of various urban land uses on water flow and quality in streams is being studied by monitoring small streams in the Milwaukee urban area. This paper compares the responses of an urban watershed and an agricultural watershed to an autumn rainfall of 2.2 cm. Flow from the urban basin showed a substantially greater response to the rain than that from the rural. Dilution, resulting from the greater quantities of surface runoff in the urban watershed, caused lower concentrations of sodium, chloride, calcium, magnesium, bicarbonate and total dissolved solids in the urban stream. The total quantity of these materials removed per unit drainage area of the urban basin was much greater, however. Road salt was still among the dominant dissolved materials in the urban water chemistry seven months after the last road salting. Sodium was apparently being released from adsorption by clays in the urban basin. Suspended sediment concentrations and total loads were higher in the urban stream.  相似文献   

19.
ABSTRACT: The salinity of the lower South Platte River in Colorado is characterized by plotting the average annual flow, total dissolved solids, and salt mass flow against distance along the stream. The plots show that salts are being leached from the irrigated lands above Greeley and are being deposited on the irrigated lands below Greeley. The salt deposition on the lower lands will result in their salination. The plots show also that fall and winter stream flows carry most of the salt loads. These fall and winter flows are stored in off stream reservoirs for use during the irrigation season. Therefore these salts are transferred to the lower irrigated lands where they accumulate. The salt balance for these lands can be improved by permitting the fall and winter flows to leave the basin, or by providing adequate land drainage coupled with supplemental irrigation water.  相似文献   

20.
The effect of mechanically aerating grassland before liquid manure application in the fall on surface runoff and transport of nutrients and solids was studied in a high rainfall area. The two treatments were control and aeration, the latter receiving one pass with an aerator perpendicular to the slope before fall application of liquid manure (dairy in Years 1-3 and swine in Year 4). Treatments were randomly assigned on 3 to 5% sloping land with a silt loam surface soil (Aquic Dystroxerept) planted in orchardgrass (Dactylis glomerata L.). Runoff from natural rainfall events was sampled for nutrient and solids analysis. Aeration significantly reduced runoff and loads of suspended solids, total Kjeldahl N (TKN), and dissolved reactive P in all years. Annual runoff amounts were reduced by 47 to 81%, suspended and volatile solid loads by 48 to 69% and 42 to 83%, respectively, TKN loads by 56 to 81%, and total P (TP) loads by 25 to 75%. Loads of the soluble nutrient NH4-N, dissolved reactive P, and K were reduced by 41 to 83%. The first three runoff events after manure application accounted for approximately one-third of the annual total runoff and solid and nutrient loads when averaged across treatments, with loads of TKN, K, and NH4-N totaling 4.4, 3.3, and 1.9 kg ha-1, respectively. Aeration slightly increased downward movement of NO3-N, but not other nutrients in the soil. Thus mechanical aeration can be an effective tool for reducing runoff and loads of solids and nutrients after surface application of liquid manure on sloping grassland.  相似文献   

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