长江三角洲地区土壤无机碳库研究

土壤碳库变化对于全球温室效应、全球碳循环有重大的影响。研究基于最新完成的1〖DK〗∶250 000多目标地球化学调查及相关研究成果，运用地理信息系统软件ARCGIS 92、统计分析软件SPSS130，对长江三角洲地区0~20、0~100、0~180 cm深度土壤无机碳密度及储量做出实测统计。长江三角洲地区0~20、0~100、0~180 cm深度土壤无机碳库储量分别为5099、35647、67726Tg，无机碳密度分别为070、490、930 kg/m2。研究区主要分布土壤为水稻土、潮土，水稻土0~20、0~100、0~180 cm深度土壤无机碳密度分别为057、385、886 kg/m2；潮土无机碳密度分别为117、854 、1537 kg/m2。研究提供最新的土壤无机碳库实测统计信息，弥补中国区域土壤无机碳库清单的空白，完善了中国区域土壤碳库清单，为研究中国区域土壤碳固定潜力、深入全面理解区域碳循环提供了基准数据.     

论水稻土肥力进化与土壤质量——以太湖地区为例

太湖地区是我国古老农业区之一。在六七千年之前先民已开始种植水稻 ,随着耕作培肥措施不断加强 ,与土壤肥力进化同步伴随着耕作轮作制的不断演进 ,由轮荒———沤田———水旱轮作———三熟制的变化 ,土壤基础肥力稳步提高 ,稻麦单位面积产量逐年上升。该区水稻土历经数千年的耕肥与平田整地等人为活动 ,在起源土壤背景上发育成五类水稻土 ,这五类水稻土经过培肥改良均达到水旱轮作高产稳产阶段 ,尽管地力上还存在不同程度的差异 ,这不能不说是人为定向培育的成果。在一般情况下 ,土壤质量是由土壤肥力决定的 ,基础肥力高低是农业生产优质高产低耗的关键 ,在评价土壤质量时必需首先予以关注。当然 ,随着工业的发展 ,土壤污染所波及的农产品超标问题 ,也应在评价土壤质量时予以关注 ,并作为评价因素在综合评价体系中占有应有的份量     

Observations and modelling of thoron and its progeny in the soil-atmosphere-plant system

Samples of pasture vegetation, mainly Trifolium pratensis, were collected at the Botanic Garden of the University of Bologna during the period 1998-2000 and measured by gamma-spectrometry for determining thoron progeny. Concentrations of ²¹²Pb were between 1.5 and 20 Bq m⁻², with individual peaks up to 70 Bq m⁻². Soil samples were collected at the same location and physically characterised. Their chemical composition (particularly Th and U) was determined by X-ray fluorescence spectroscopy. Lead-212 on plants mainly originates from dry and wet deposition of this isotope generated in the lower atmosphere by the decay of its short-lived precursor ²²⁰Rn, which is produced in the upper soil layers as a member of the natural thorium decay chain and exhales into the atmosphere. Concentrations of ²²⁰Rn in the atmosphere depend on (1) the amount of Th present in soil, (2) the radon fraction which escapes from the soil minerals into the soil pore space, (3) its transport into the atmosphere, and (4) its redistribution within the atmosphere. The mobility of radon in soil pore space can vary by orders of magnitude depending on the soil water content, thus being the main factor for varying concentrations of ²²⁰Rn and ²¹²Pb in the atmosphere. We present a simple model to predict concentrations of thoron in air and its progeny deposited from the atmosphere, which takes into account varying soil moisture contents calculated by the OPUS code. Results of this model show close agreement with our observations.     

Total fluoride in Guangdong soil profiles, China: spatial distribution and vertical variation

A total of 260 soil profiles were reported to investigate the fluoride distribution and vertical variation in Guangdong province. The soil fluoride contents followed an approximately lognormal distribution. Although the soil fluoride geometric mean concentration of 407 mg/kg is lower than that of China, its content varied from 87 to 2860 mg/kg. An upper baseline concentration of 688 mg/kg was estimated for surface soils. In A-, B-, and C-horizon soil fluoride spatial distribution presented similar patterns that high fluoride concentration mainly located in limestone, purple shale, and sandshale areas, indicated that soil fluoride spatial distribution was primarily dependent on the regional bedrock properties rather than anthropogenic inputs. From A- to C- horizon soil fluoride geometric mean concentration had an increasing tendency of 407, 448, and 465 mg/kg. This vertical variation was the result of the intensive eluviation under the subtropical hydrothermal condition, and had closely related with soil properties, such as lower organic matters and clay content variations. Moreover, the soil degradation and erosion was also an important pathway of soil fluoride movement, as a result the soil fluoride exported into surface and groundwaters would reach about 4.1x10(4) t year-1 in the study area.     

Variations of the ambient dose equivalent rate in the ground level air

The ambient dose equivalent rate is caused by ionizing radiation of radionuclides in the atmosphere and on the ground surface as well as by cosmic radiation. Seasonal and diurnal variations of the ambient dose equivalent rate (ADER) in the ground level air are influenced by the concentration of 222Rn daughters. The 222Rn concentration in the ground level atmosphere, in turn, depends on the rate of the 222Rn exhalation from soil and turbulent air mixing. Its diurnal and seasonal variations depend on meteorological conditions. The aim of this study is to estimate the influence of variations of the rate of the 222Rn exhalation from soil and its concentrations in the ground level air on variations of ADER in the ground level air, as well as the dependence of these parameters on meteorological conditions. The 222Rn diffusion coefficient and its exhalation rate in undisturbed loamy soil have been determined. The 222Rn concentration in the soil air and its concentration in the ground level air correlate inversely (correlation coefficient is r = -0.62). The main factors determining the 222Rn exhalation from soil are: the soil temperature (r = 0.64), the difference in temperature of soil and air (r = 0.57), and the precipitation amount (r = 0.50). The intensity of gamma radiation in the ground level air is mostly related to the 222Rn concentration in the air (r = 0.62), while the effect of the exhalation rate from soil is relatively low (r = 0.36). It has been shown that ADER due to 222Rn progeny causes only 7-16% of the total ADER and influences its variation. The comparison of variations of ADER due to 222Rn progeny and the total ADER during several years shows that these parameters correlate positively.     

Evolution of Sr distribution coefficient as a function of time, incubation conditions and measurement technique

A thorough understanding of the dynamics of radiostrontium in soil is required to allow accurate long-term predictions of its mobility. We have followed the soil solution distribution of 85Sr as a function of time under controlled conditions over 4 months and studied the effect of soil moisture content and organic matter amendments. Data have been compared to redox conditions and soil pH. To fuel the ongoing debate on the validity of distribution coefficient (K(d)) values measured in dilute suspension, we have compared values obtained from the activity concentration in soil solution obtained by centrifugation to data obtained in suspension with or without air-drying of the soil samples after incubation. The 85Sr adsorption properties of soil, incubated without prior contamination were also measured. There is some time-dependent adsorption of Sr. This is partly due to changing soil composition due to the decomposition of added organic matter and anaerobic conditions induced by flooding. There is also a kinetic effect, but adsorption remains largely reversible. Most of the observed effects are lost when soil is suspended in electrolyte solution.     

平原湖区潜育化水稻土改良与利用的研究

对平原湖区农业持续发展急需研究解决的一个重要问题——潜育化水稻土改良与利用,进行全面系统研究总结。阐明了在特定环境条件下,潜育化水稻土分布、成因、类型、特性及障碍因素,并着重对采用耐潜(渍)高产优质水稻品种(组合)、开沟治渍、水稻垄作、优化施肥、水旱轮作等改良利用技术及其组装配套的综合改良利用技术体系的试验研究作了深入系统的阐述。对改良利用的经济、生态和社会效益进行了综合评价。     

Partition of iodine (¹²⁹I and ¹²⁷I) isotopes in soils and marine sediments

Natural organic matter, such as humic and fulvic acids and humin, plays a key role in determining the fate and mobility of radioiodine in soil and sediments. The radioisotope ¹²⁹I is continuously produced and released from nuclear fuel reprocessing plants, and as a biophilic element, its environmental mobility is strongly linked to organic matter.Due to its long half-life (15.7 million years), ¹²⁹I builds up in the environment and can be traced since the beginning of the nuclear era in reservoirs such as soils and marine sediments. Nevertheless, partition of the isotope between the different types of organic matter in soil and sediment is rarely explored. Here we present a sequential extraction of ¹²⁹I and ¹²⁷I chemical forms encountered in a Danish soil, a soil reference material (IAEA-375), an anoxic marine sediment from Southern Norway and an oxic sediment from the Barents Sea. The different forms of iodine are related to water soluble, exchangeable, carbonates, oxides as well as iodine bound to humic acid, fulvic acid and to humin and minerals. This is the first study to identify ¹²⁹I in humic and fulvic acid and humin. The results show that 30-56% of the total ¹²⁷I and 42-60% of the total ¹²⁹I are associated with organic matter in soil and sediment samples. At a soil/sediment pH below 5.0-5.5, ¹²⁷I and ¹²⁹I in the organic fraction associate primarily with the humic acid while at soil/sediment pH > 6 ¹²⁹I was mostly found to be bound to fulvic acid. Anoxic conditions seem to increase the mobility and availability of iodine compared to oxic, while subaerial conditions (soils) reduces the availability of water soluble fraction compared to subaqueous (marine) conditions.     

Radon-222 exhalation from open ground on and around a uranium mine in the wet-dry tropics

Radon-222 exhalation from the ground surface depends upon a number of variables such as the 226Ra activity concentration and its distribution in soil grains; soil grain size; soil porosity, temperature and moisture; atmospheric pressure, rainfall and temperature. In this study, 222Rn exhalation flux density measurements within and around the Ranger uranium mine in northern Australia were performed to investigate the effect of these variables within a tropical region. Measurements were taken at the waste rock dumps, ore stockpiles, mine pits, and at sites where effluent water with elevated 226Ra concentration has been spray irrigated over land, as well as at sites outside the mine. The sites selected represented a variety of geomorphic regions ranging from uranium-bearing rocks to ambient soils. Generally, wet season rains reduced 222Rn exhalation but at a few sites the onset of rains caused a step rise in exhalation flux densities. The results show that parameters such as 226Ra activity concentration, soil grain size and soil porosity have a marked effect on 222Rn flux densities. For similar geomorphic sites, 226Ra activity concentration is a dominant factor, but soil grain size and porosity also influence 222Rn exhalation. Surfaces with vegetation showed higher exhalation flux densities than their barren counterparts, perhaps because the associated root structure increases soil porosity and moisture retention. Repeated measurements over one year at eight sites enabled an analysis of precipitation and soil moisture effects on 222Rn exhalation. Soil moisture depth profiles varied both between seasons and at different times during the wet season, indicating that factors such as duration, intensity and time between precipitation events can influence 222Rn flux densities considerably.     

上海土壤有机碳储量及其空间分布特征

区域土壤碳库的估算不仅是陆地土壤碳循环研究的重要内容，同时也可为国家尺度的土壤碳库的估算提供更多的数据支持。利用上海第二次土壤普查资料，结合GIS技术对上海土壤有机碳储量、碳密度及其空间分布格局展开研究，结果表明，上海地区0～100 cm深度的土壤有机碳总储量为576×107 t，占全国的0.062 6%，0～100 cm的平均土壤有机碳密度为1055 kg/m2，高于全国平均值，反映出上海土壤具有较高的碳蓄积能力。各类土壤中，水稻土的土壤碳储量最大，其次是灰潮土和滨海盐土，而黄棕壤由于面积狭小，所以土壤碳储量最小。各类土壤0～100 cm土壤有机碳密度的大小顺序依次为水稻土>灰潮土>黄棕壤>滨海盐土。从空间分布格局来看，上海土壤碳密度呈现为西高东低，在局部范围内还表现出高低相间，错综复杂的局面，这种分布规律在一定程度上体现了地形、微地貌、母质、土地利用方式等因素的影响。而快速的城市化引起的土地利用变化造成了土壤碳库的净碳损失量为39244万t，相当于2000年化石燃料产生的碳排放的9.86%，这表明在经济和城市快速发展地区，土地利用变化已经成为影响土壤碳库的重要驱动力。     

Aqueous, solid and gaseous partitioning of selenium in an oxic sandy soil under different microbiological states

The aim of this study was to investigate the role of microorganisms on the behaviour of selenium in natural soil maintained under strictly aerobic conditions. Six-day batch experiments were performed with soils constrained to different microbiological states, either by sterilisation or by adding organic substrates. Selenium was added to the soil as selenite. The distribution of selenium in the gaseous, liquid and solid phases of the batch was measured. Selenium partitioning between the various solid phases was investigated by chemical sequential extractions. Active microorganisms played major effects on the distribution of selenium within the soil. On the one hand, microorganisms could promote selenium volatilisation (in relatively small amounts), leading to the spreading of selenium compounds outside the soil. On the other hand, microbial activities increased both amount of selenium retained by the soil and the strength of its retention (less exchangeable selenium), making selenium less susceptible to remobilisation.     

A comparison of the soil migration and plant uptake of radioactive chlorine and iodine from contaminated groundwater

A 6-month soil column experiment was conducted to compare the upward migration and plant uptake of radiochlorine and radioiodine from shallow, near-surface contaminated water tables. Both fixed and fluctuating water tables were studied. After 6 months, (36)Cl activity concentrations were relatively uniform throughout the soil profile apart from an accumulation at the soil surface, which was especially marked under a fluctuating water table scenario. In contrast, (125)I (a surrogate for (129)I) tended to accumulate at the boundary between the anoxic conditions at the base of the column and the oxic conditions above, due to its redox-dependent sorption behaviour. The uptake of (36)Cl by perennial ryegrass was much greater than that of (125)I due to its greater migration into the rooting zone and its ready availability in soil solution. In the context of radioactive waste disposal, where these radionuclides may potentially be released into groundwater, (36)Cl would be expected to present a greater potential for contamination of the biosphere than (129)I.     

Rural settlement expansion and paddy soil loss across an ex-urbanizing watershed in eastern coastal China during market transition

Historically, paddy soils are the most valuable natural resources that produce about 90% of staple food in eastern coastal China. Dispersed patterns of rapid rural settlement expansion, or “exurban”, are recognized as key threats to the region’s food security through paddy soil loss. Analyzing the process of ex-urbanization and its impact has profound implications for the sustainable development of rural China. Based on official statistics and data derived from satellite images, dynamics of rural settlement expansion and paddy soil loss were outlined for Tiaoxi watershed during China’s market transition period (1994–2003). Particularly, rural settlements became more aggregated and total area expanded by 183% at an average rate of 12.3% per year for the whole watershed. Existing cores, open areas away from urban centers and areas near major transportation lines and river channels, observed the highest specialization in rural residential growth. Being closely associated with rural settlement in spatial distribution, open large paddy soil patches acted as another kind of center for rural settlement expansion within the landscape. Variations in rural settlement expansion were detected among different-tier counties, such as speed of rural settlement expansion, speed of build-ups growth per capita. These variations were closely related to social-economic development. The rapid rural settlement expansion led to a considerable loss of paddy soil, about 11% of the total amount for the whole watershed. Linear regression identified a significant relationship between paddy soil loss and rural settlement expansion. Given the social and ecological problems associated with paddy soil loss, we argue that innovative and effective planning policies as well as management programs that target at paddy soil protection should be developed and implemented in rural China. In particular, we suggest using watershed as an appropriate spatial unit for sustainable paddy soil management in this investigation.     

川中丘陵紫色土区农田土壤有机碳储量及空间分布特征

土壤有机碳在陆地生态系统碳循环中起着举足轻重的作用。针对农田区域内典型县域尺度有机碳储量及其空间格局特征的研究,可以为区域农田土壤固碳提供参考,为研究我国土壤有机碳储量提供基础数据支持。基于2012年农田土壤有机碳分析调查数据,结合GIS和GPS技术对川中丘陵区盐亭县土壤有机碳密度和储量及空间格局进行了估算和分析。结果表明:其主要土壤类型的0~20 cm耕层土壤有机碳密度为111~426 kg/m2,平均值为266 kg/m2,水田和旱地耕层土壤有机碳密度分别为345和234 kg/m2,均低于全国平均值;全县20 cm深度土壤有机碳总储量250×109 kg C,紫色土类土壤有机碳储量最大,为153×109kg C,水稻土次之,有机碳储量0.93×109kg C,两者占据了农田土壤有机碳储量约98%,冲积土和黄壤土类由于面积小,有机碳储量也最低。各土壤类型有机碳储量丰度指数(RI)值都较低,碳存储能力处于中下水平。在县域农田尺度,有机碳空间格局与气候差异、植被类型关系不大,土壤类型空间差异和地形差异是有机碳空间格局形成的主要原因。     

鄂西北山区耕层土壤pH值空间变异特征及其影响因素研究

土壤pH值是耕地质量表征的重要指标之一,精确估算土壤pH值具有重要意义。以鄂西北山区十堰市为研究区,采集了701个耕作层土样,测定分析土壤pH值,运用地统计学方法和GIS技术探讨了鄂西北耕层土壤pH值的空间变异特征,利用方差分析和回归分析对其主要影响因素进行量化分析。结果表明:研究区土壤pH值为6.46±0.84,变异系数为13.00%,属中等变异强度。全市土壤pH值空间分布总体特征表现为低值区主要分布在研究区中部和西南部,高值区主要分布在北部和东南部;整体上呈现从东北向西南逐渐降低的空间分布格局,通过回归分析得出成土母质是研究区土壤pH值空间变异的主控因素,能够独立解释空间变异的13.6%,其次是海拔高度,独立解释能力为6.30%,较弱的是土地利用方式,独立解释能力仅为1.4%,坡度几乎没有独立解释能力。说明目前影响研究区耕层土壤pH值空间变异的主要影响因素是结构因素,土地利用方式和生产方式将是研究区土壤pH值进一步变化的重要驱动因素。     

南水北调中线水源地不同植被类型坡地土壤水分特征研究——以秦岭南坡宁陕县寨沟小流域为例

为了解不同植被类型土壤水资源的变化规律,选择南水北调中线水源区宁陕县寨沟区域典型植被针阔混交林、针叶林、板栗林、灌木林、荒坡草地和坡耕地为研究对象,通过样地调查与实验分析的方法对其土壤水分物理特征及有机质含量进行测定研究.结果表明,各种有林地的土壤容重、孔隙度和有机质等理化特征均优于荒坡和坡耕地;针阔混交林土壤含水量最高,蓄水能力明显好于其它植被类型;在垂直剖面上,各种植被类型坡地土壤含水量和饱和蓄水量随土壤深度的增加基本呈递减趋势,但有林地下降幅度较大,表层含水量明显高于荒坡与坡耕地表层.由此可见,在涵养水源方面,针阔混交林最好,针叶林、板栗林与灌木林次之,荒坡与坡耕地较差.     

The use of molecular techniques to characterize the microbial communities in contaminated soil and water

Traditionally, the identification and characterization of microbial communities in contaminated soil and water has previously been limited to those microorganisms that are culturable. The application of molecular techniques to study microbial populations at contaminated sites without the need for culturing has led to the discovery of unique and previously unrecognized microorganisms as well as complex microbial diversity in contaminated soil and water which shows an exciting opportunity for bioremediation strategies. Nucleic acid extraction from contaminated sites and their subsequent amplification by polymerase chain reaction (PCR) has proved extremely useful in assessing the changes in microbial community structure by several microbial community profiling techniques. This review examines the current application of molecular techniques for the characterization of microbial communities in contaminated soil and water. Techniques that identify and quantify microbial population and catabolic genes involved in biodegradation are examined. In addition, methods that directly link microbial phylogeny to its ecological function at contaminated sites as well as high throughput methods for complex microbial community studies are discussed.     

On the influence of soil properties on the transfer of 137Cs from two soils (Chromic Luvisol and Eutric Fluvisol) to wheat and cabbage

Two types of soils (Eutric Fluvisol and Chromic Luvisol) and two crops (wheat and cabbage) were investigated for determination of the transfer of 137Cs from soil to plant. Measurements were performed using gamma-spectrometry. Results for the soil characteristics, transfer factors of the radionuclides (TF), and conversion factors (CF) (cabbage/wheat) were obtained. The transfer of 137Cs was higher for Chromic Luvisol for both the plants. Statistically significant dependence of TF of 137Cs on its concentration in soil was established for cabbage. Dependence between K content in the soil and the transfer factor of 137Cs was not found due to the high concentrations of available K. Use of bioconcentration factor (BCF) (ratio between the activity concentration of a radionuclide in a reference plant to its concentration in another plant) is demonstrated and proposed for risk assessment studies.