Sewage sludge as organic ameliorant for revegetation of fine bauxite refining residue

The rise in aluminium demand in the world has significantly increased the generation of bauxite residue which occupies huge areas of land worldwide. Direct revegetation of residue storage areas has been unsuccessful because of the high alkalinity and salinity, and poor nutrient contents of the fine residue (red mud). This paper describes glasshouse and field experiments evaluating the potential use of sewage sludge as an organic ameliorant for gypsum amended red mud. The growth of Agropyron elongatum in red mud receiving gypsum (0 and 38.5 t ha⁻¹) and sewage sludge (0, 38.5 and 77 t ha⁻¹) amendment was assessed in a glasshouse study. Leachate and soil analyses revealed that gypsum was effective in reducing the pH, EC and ESP of red mud, while sewage sludge gave additional reductions in EC, Na and ESP. No evidence of any significant increases in heavy metal contents were observed in the leachates following sewage sludge amendment. However, soil Al contents were more available in red mud receiving only sewage sludge treatment. Sewage sludge amendment significantly increased dry weight yield and provided sufficient nutrients for plant growth except K which was marginal. No heavy metal accumulation was observed in Agropyron. Following that, a field experiment was performed having red mud amended with sewage sludge (38.5, 77 and 154 t ha⁻¹) and gypsum (38.5 and 77 t ha⁻¹) to evaluate their effects on soil physical properties of red mud. Sewage sludge significantly reduced soil bulk density (25%) and particle density (9%) and increased the total porosity of red mud (8%). Hydraulic conductivity also increased from 1.5 to 23 × 10⁻⁵ m s⁻¹. Plant cover percentage and dry weight yield of Agropyron increased with an increase in gypsum and sewage sludge amendment. The results confirm that sewage sludge is effective in improving both soil structure and nutrient status of gypsum amended red mud. The use of sewage sludge for red mud revegetation provides not just an option for sludge disposal, but also a cost effective revegetation strategy for bauxite refining industry.     

Addition of an organic amendment and/or residue mud to bauxite residue sand in order to improve its properties as a growth medium

The effects of addition of carbonated residue mud (RMC) or seawater neutralized residue mud (RMS), at two rates, in the presence or absence of added green waste compost, on the chemical, physical and microbial properties of gypsum-treated bauxite residue sand were studied in a laboratory incubation study. The growth of two species commonly used in revegetation of residue sand (Lolium rigidum and Acacia saligna) in the treatments was then studied in a 18-week greenhouse study. Addition of green waste-based compost increased ammonium acetate-extractable (exchangeable) Mg, K and Na. Addition of residue mud at 5 and 10% w/w reduced exchangeable Ca but increased that of Mg and Na (and K for RMS). Concentrations of K, Na, Mg and level of EC in saturation paste extracts were increased by residue mud additions. Concentrations of cations in water extracts were considerably higher than those in saturation paste extracts but trends with treatment were broadly similar. Addition of both compost and residue mud caused a significant decrease in macroporosity with a concomitant increase in mesoporosity and microporosity, available water holding capacity and the quantity of water held at field capacity. Increasing rates of added residue mud reduced the percentage of sample present as discrete sand particles and increased that in aggregated form (particularly in the 1-2 and >10mm diameter ranges). Organic C content, C/N ratio, soluble organic C, microbial biomass C and basal respiration were increased by compost additions. Where compost was added, residue mud additions caused a substantial increase in microbial biomass and basal respiration. L.?rigidum grew satisfactorily in all treatments although yields tended to be reduced by additions of mud (especially RMC) particularly in the absence of added compost. Growth of A.?saligna was poor in sand alone and mud-amended sand and was greatly promoted by additions of compost. However, in the presence of compost, addition of carbonated mud had a marked depressive effect on both top and root growth. The significant positive effect of compost was attributed to substantial inputs of K and marked reductions in the Na/K ratio in soil solution while the depressive effect of RMC was attributed to its greater alkalinity and consequently higher concentrations of HCO(3)(-) in solution.     

Seawater neutralization of alkaline bauxite residue and implications for revegetation

Reaction of bauxite residue with seawater results in neutralization of alkalinity through precipitation of Mg-, Ca-, and Al-hydroxide and carbonate minerals. In batch studies, the initial pH neutralization reaction was rapid (<5 min), with further reaction continuing to reduce pH for several weeks. Reaction with seawater produced a residue pH of 8 to 8.5. Laboratory leaching column studies were undertaken to provide information on seawater neutralization of the coarse-textured fraction of the waste, residue sand (RS), under conditions comparable with those that might be applied in the field. An 0.80-m-deep column of RS was neutralized by the application of the equivalent of 2-m depth of seawater. In addition to lowering the pH and Na content of the residue, seawater neutralization resulted in the addition of substantial amounts of the plant nutrients Ca, Mg, and K to the profile. Similar results were also obtained from a field-scale assessment of neutralization. However, the accumulation of precipitate, consisting of hydrotalcite, aragonite, and pyroaurite, in the drainage system may preclude the use of in situ seawater neutralization as a routine rehabilitation practice. Following seawater neutralization, RS remains too saline to support plant growth and would require fresh water leaching before revegetation.     

Removal of radium from groundwater using a modified bauxite refinery residue

Radium (Ra) removal by an unconventional sorbent, a modified bauxite refinery residue (MBRR), is investigated for a groundwater extracted in Missouri, USA. The MBRR treatment causes substantial reductions of both gross α and combined Ra activities from 0.955 ± 0.005 and 0.66 ± 0.005 Bq L to below detection limits (0.037 Bq L or 1 pCi L). Column breakthrough occurs at 0.555 Bq L for gross α and 0.185 Bq L for combined Ra (15 and 5 pCi L; USEPA's maximum contaminant levels) after 54 and 40 d run time, respectively. At 84 d the MBRR media continues to remove 24.3% of raw water gross α and 39.7% of the combined Ra. The treatment effluent has an initial pH of 10.9, outside the USEPA guides (6.5-8.5); this may be readily mitigated by posttreatment acid injection, or by raw water blending. The MBRR simultaneously removes other potentially hazardous trace elements (e.g., Cu, Zn, and Fe) to extremely low concentrations. In addition, toxicity characteristic leaching procedure testing of spent MBRR suggests that metals are bound tightly, such that it is nonhazardous, permitting cost-effective disposal to landfill without special confinement or storage. Consequently, MBRR may be utilized as an alternative adsorbent for treating Ra-contaminated groundwater.     

BAUXITE LAND-USE POLICY AND RESETTLEMENT PROGRAMMES IN JAMAICA

The Government of Jamaica has just completed agreements with four of the five bauxite and alumina companies operating in Jamaica, Kaiser, Reynolds, Alcoa, and Alcan. The agreements went into effect on 1 February 1980. One of the results of these new agreements is the acquisition of all company-owned bauxite lands by the government, and the rationalization of bauxite reserves. This article examines the bauxite resource management approach being taken by the government of Jamaica, considers the provisions of the new agreements, describes some of the problems associated with resettlement and relocation of people and structures to make the bauxite available for mining and details the formulae being pursued to deal with them. Le Gouvernement de la Jamaïque vient de conclure des accords avec quatre des cinq compagnies de bauxite ed d'alumine qui travaillent à a Jamaïque: Kaiser, Reynolds, Alcoa et Alcan. Ces accords sont entrés en vigueur le 1er février 1980. L'un des résultats de ces nouveaux accords est l'acquisition par le gouvernement de tous les terrains de bauxite possédés par les compagnies et l'utilisation rationnelle des réserves de bauxite. Cet article montre la politique suivie par le gouvernement en matière de ressources de bauxite, étudie les clauses des nouveaux accords, décrit quelques-uns des problèmes posés par la réinstallation des gens et la remise en ordre des structures pour permettre l'exploitation de la bauxite et indique les mesures qui ont été prises en liaison avec ces problèmes. El Gobierno de Jamaica acaba de concluir acuerdos con cuatro de las cinco compañías de bauxita y aluminio que operan en Jamaica: Kaiser, Reynolds, Alcoa y Alcan. Los acuerdos entraron en vigor el primero de febrero de 1980. Algunos de los resultados de estos acuerdos son la adquisición por el gobierno de todos los territorios de bauxita poseídos por las compañías y la nacionalizacíon de las reserves de bauxita. Este artículo examina el enfoque seguido por el Gobierno en la gestión del recurso de bauxita, analiza las provisiones de los nuevos acuerdos, describe algunos de los problemas asociados con la relocación de habitantes y detalla las fórmulas que se están siguiendo para resolverlas.     

Potential for enhanced phytoremediation of landfills using biosolids – a review

Despite the use of recyclable materials increasing worldwide, waste disposal to landfill remains the most common method of waste management because it is simple and relatively inexpensive. Although landfill disposal is an effective waste management system, if not managed correctly, a number of potential detrimental environmental impacts have been identified including soil and ground water contamination, leachate generation, and gas emissions. In particular, improper post-closure treatment of landfills or deterioration of the conventional clay landfill capping were shown to result in land degradation which required remediation to secure contaminants within the landfill site.Phytoremediation is an attractive technology for landfill remediation, as it can stabilize soil and simultaneously remediate landfill leachate. In addition, landfill phytoremediation systems can potentially be combined with landfill covers (Phytocapping) for hydrological control of infiltrated rainfall. However, for the successful application of any phytoremediation system, the effective establishment of appropriate, desired vegetation is critical. This is because the typically harsh and sterile nature of landfill capping soil limits the sustainable establishment of vegetation. Therefore, the physicochemical properties of landfill capping soils often need to be improved by incorporating soil amendments. Biosolids are a common soil amendment and will often meet these demanding conditions because they contain a variety of plant nutrients such as nitrogen, phosphate, potassium, as well as a large proportion of organic matter. Such amendment will also ameliorate the physical properties of the capping soils by increasing porosity, moisture content, and soil aggregation. Contaminants which potentially originate from biosolids will also be remediated by activities congruent with the establishment of plants and bacteria.     

Seasonal influences on inorganic anion monitoring of the New Calabar River,Nigeria

The inorganic anion pollution of the New Calabar River surface water was investigated. Results showed seasonal variations in the inorganic anion levels. Water parameters such as sulfite, nitrate, phosphate, and alkalinity showed significantly higher values in the rainy season than in the dry season. Dissolved oxygen, pH, sulfide, sulfate, ammonia, and nitrite showed no significant differences between their rainy and dry season levels. Upstream-downstream changes were shown by conductivity, total dissolved solids, chloride, salinity, and temperature. Exceptions occurred in the nitrite levels, where the effect was minimal. Although the concentrations of some anions analyzed fell within internationally acceptable limits, the New Calabar River water is, in the main, polluted with inorganic anions and may be unacceptable for potable and industrial uses without treatment.     

Laboratory-scale measurement of trace gas fluxes from landfarm soils

Trace gas emissions from refinery and bioremediation landfarms were investigated in a mesocosm-scale simulator facility. Five simulators were constructed and integrated with a data acquisition system and trace gas analyzers, allowing automated real-time sampling and calculation of total hydrocarbon (THC), CO2, and water vapor fluxes. Experiments evaluating the influence of simulated cultivation and rainfall on trace gas fluxes from the soil surfaces were conducted. Results were compared with published field results. Results showed that cultivating dry or moderately wet soil resulted in brief enhancements of THC fluxes, up to a factor of 10, followed by a sharp decline. Cultivating dry soil did not enhance respiration. Cultivating wet soil did result in sustained elevated levels of respiration. Total hydrocarbon emissions were also briefly enhanced in wet soils, but to a lesser magnitude than in dry soil. Hydrocarbon fluxes from refinery landfarm soil were very low for the duration of the experiments. This lead to the conclusion that elevated THC fluxes would only be expected during waste application. An evaluation of the influence of simultaneous water vapor fluxes on other trace gas fluxes highlighted the importance in lab-scale experiments of correcting trace gas fluxes from soils. The results from this research can be used to guide management practices at landfarms and to provide data to aid in assessing the effect of landfarms.     

Seasonal dynamics of denitrification along topohydrosequences in three different riparian wetlands

We investigated the seasonal patterns of denitrification rates and potentials in soil profiles along the topohydrosequence formed at the upland-wetland interface in three riparian wetlands with different vegetation cover (i.e., forest, understory vegetation, and grass). Denitrification was measured using the acetylene inhibition method on soil cores and slurries, which provided a means of comparing the relative activity of this process in different locations. We evaluated, on a seasonal basis, the respective importance of the vegetative cover and the hydromorphic gradient as factors limiting denitrification. Regardless of the season, vegetation type, or lateral position along each topohydrosequence in the riparian wetlands, strong significant gradients of both in situ and potential denitrification rates were measured within a soil profile. Results confirm that the upper organic soil horizon is the most active, when in contact with the ground water. In deeper soil horizons, denitrification activity was low (from 0.004 to 0.5 mg N kg(-1) dry soil d(-1)), but contributed significantly to the reduction of ground water NO3- load along the riparian ground water flowpath (from 9.32 to 0.98 mg NO3-N L(-1)). Along the soil topohydrosequence, the denitrifying community of the upper soil horizons did not vary significantly on a seasonal basis despite the large seasonal ground water fluctuations. Along each topohydrosequence, the denitrification-limiting factor gradually shifted from anaerobiosis to NO3- supply. In situ denitrification rates in the forested, understory vegetation and grass sites were not significantly different. This result emphasizes the importance of the topography of the valley rather than the vegetation cover in controlling denitrification activity in riparian wetlands.     

NITROGEN AND ORGANIC MATTER LOSSES IN NO‐TILL CORN CROPPING SYSTEMS1

ABSTRACT: Intensive cropping systems based on mechanical movement of soil have induced land degradation in most agricultural areas due to soil erosion and soil fertility losses. Thus, farmers have been increasing fertilization rates to maintain an economically competitive crop yield. This practice has resulted in water quality degradation and lake eutrophication in many agricultural watersheds. Research was conducted in the Patzcuaro watershed in central Mexico to develop appropriate technology that prevents nonpoint source pollution from fertilizers. Organic matter (OM) and nitrogen (N) losses in runoff and nitrate (NO₃‐N) percolation in Andisols with corn under conventional till (CT) and no‐till (NT) treatments using variable percentages of crop residue as soil cover were investigated for steep‐slope agriculture. USLE type runoff plots were used to collect water runoff, while suction tubes with porous caps at 30, 60, and 90 cm depth were used to sample soil water solutes for NO₃‐N analyses. Results indicated a significant reduction of N and OM losses in runoff as residue cover increased in the NT treatments. Inorganic N in runoff was 25 kg/ha for NT without residue cover (NT‐0) and 6 kg/ha for the NT with 100 percent residue cover (NT‐100). Organic matter losses in runoff were 157 and 24 kg/ha for the NT‐0 and NT‐100 treatments, respectively. Nitrate‐N percolation was evident in CT and NT with 100 percent residue cover (NT‐100). However, NT‐100 had higher NO₃‐N concentration at the root zone, suggesting the possibility of reducing fertilization rates with the use of NT treatments.     

制药行业药渣污泥干化工艺研究

通过对南阳市危废处置中心药渣污泥干化系统的研究,设计了一套有效的干化系统,使药渣污泥的含水率从75%～80%干化至含水率20%,为药渣污泥进一步减量化、无害化和资源化处理提供更多的可能。系统配套有效的尾气处理系统,使该项目废气排放指标达到《工业炉窑大气污染物排放标准》(GB9078-96)以及《恶臭污染物排放标准》(GB14554-93)中的相关要求。     

高浓度废水处理技术在柴油碱渣处理中的应用

炼厂柴油碱渣废水中含有成分复杂的酚及硫化物,因而其浓度较高。大港石化公司运用高浓度废水处理技术进行生物前期处理,其装置试运及柴油碱渣标定应用表明该技术先进。在生物处理过程中,工艺系统运行安全可靠,各项技术指标都达到或超过设计目标。其中,CODCr由处理前的34744mg/L降低到370mg/L,氨氮控制在50mg/L以下。高浓度废水处理技术流程简单,对周边环境无污染。     

Spatial prioritization of revegetation sites for dryland salinity management: an analytical framework using GIS

To address the limited application of analytical and modelling techniques in prioritizing revegetation sites for dryland salinity (saline land) management, a case study of the Hodgson Creek catchment in Queensland, Australia, was conducted. An analytical framework was developed, incorporating the use of spatial datasets (Landsat 7 image, DEM, soil map, and salinity map), which were processed using digital image processing techniques and a geographic information system (GIS). Revegetation sites were mapped and their priority determined based on recharge area, land use/cover and sub‐catchment salinity. The analytical framework presented here enhances the systematic use of land information, widens the scope for scenario testing, and improves the testing of alternative revegetation options. The spatial patterns of revegetation sites could provide an additional set of information relevant in the design of revegetation strategies.     

Bacterial community changes during plant establishment at the San Pedro River mine tailings site

Mine tailings are moderately to severely impacted sites that lack normal plant cover, soil structure and development, and the associated microbial community. In arid and semiarid environments, tailings and their associated contaminants are prone to eolian dispersion and water erosion, thus becoming sources of metal contamination. One approach to minimize or eliminate these processes is to establish a permanent vegetation cover on tailings piles. Here we report a revegetation trial conducted at a moderately impacted mine tailings site in southern Arizona. A salt and drought-tolerant plant, four-wing saltbush [Atriplex canescens (Pursh) Nutt.], was chosen for the trial. A series of 3 by 3 m plots were established in quadruplicate on the test site to evaluate growth of four-wing saltbush transplants alone or with compost addition. Results show that >80% of the transplanted saltbush survived after 1.5 yr in both treatments. Enumeration of heterotrophs and community structure analysis were conducted to monitor bacterial community changes during plant establishment as an indicator of plant and soil health. The bacterial community was evaluated using denaturing gradient gel electrophoresis (DGGE) analysis of 16S rDNA PCR gene products from tailings samples taken beneath transplant canopies. Significant differences in heterotrophic counts and community composition were observed between the two treatments and unplanted controls throughout the trial, but treatment effects were not observed. The results suggest that compost is not necessary for plant establishment at this site and that plants, rather than added compost, is the primary factor enhancing bacterial heterotrophic counts and affecting community composition.     

污水深度处理及回收利用的可行性分析

大庆炼化公司从单一化工污水深度处理及回收利用发展为炼油、化工、生活污水统一处理和回用于循环水,既充分利用了现有污水处理场的处理余量,同时由于生活污水中含有比例适当的微生物需要的营养物质,对炼油和化工污水起到补充和稀释作用。这种处理方法既降低了工业污水对污水处理场的冲击,又起到了稳定水质的作用。     

Hydrologic behavior of two engineered barriers following extreme wetting

Many engineered barriers are expected to function for hundreds of years or longer. Over the course of time, it is likely that some barriers will experience infiltration to the point of breakthrough. This study compares the recovery from breakthrough of two storage-evapotranspiration type engineered barriers. Replicates of test plots comprising thick soil and capillary-biobarrier covers were wetted to breakthrough in 1997. Test plots were kept cleared of vegetation to maximize hydrologic stress during recovery. Following cessation of drainage resulting from the wetting irrigations, water storage levels in all plots were at elevated levels compared with pre-irrigation levels. As a result, infiltration of melting snow during the subsequent spring overloaded the storage capacity and produced drainage in all plots. Relatively rapid melting of accumulated snowfall produced the most significant infiltration events each year during the study. Capillary barriers yielded less total drainage than thick soil barriers. By limiting drainage, capillary barriers increased water storage in the upper portions of the test plots, which led to increased evaporation from the capillary barrier plots compared with thick soil plots. Increased evaporation in the capillary barrier plots allowed more water to infiltrate in the second season following the wetting tests without triggering drainage. All thick soil plots again yielded drainage in the second season. Within two years of intentionally induced breakthrough, evaporation alone (without transpiration) restored the capability of the capillary barrier covers to function as intended, although water storage in these covers remained at elevated levels.     

A spatial-statistical approach for modeling the effect of non-point source pollution on different water quality parameters in the Velhas river watershed--Brazil

In this article, a methodology for evaluating the effect of land use/land cover on the quality of nearby stream water in a semiarid environment is described and tested on a large watershed in Southeastern Brazil. The approach aims at identifying the width of the riparian area having the strongest effect on different water quality parameters. The land use/land cover data were generated from remotely sensed data while water quality point data were supplied by a government agency. Testing was conducted for both the rainy and dry seasons in an effort to understand the direct effect of surface runoff. The approach combines cartographic modelling using a geographical information system (GIS) and statistics to establish the strength of the relationship between water quality, land use and the distance from the stream. Results suggest a strong relationship between land use/land cover and turbidity, nitrogen and fecal coliforms. They also suggest that each of these parameters has a unique behavior when distance from the stream is considered. Finally, although it was expected that the models would apply better during the wet season, some parameters had the opposite behavior and displayed a better fit during the dry season.     

Use of Landsat Thematic Mapper Data to Assess Seasonal Rangeland Changes in the Southeast Kalahari, Botswana

/ Management problems arise in semiarid rangeland that are characterized by marked wet and dry seasons because of forage deficiencies in the dry season. These natural vegetation rangelands can sustain livestock all year long when forage and senesced grass are available into the dry season. Seasonal range condition data are required to provide a basis for pasture management to help locate dry season cover and thereby minimize overstocking and degradation. The generation of seasonal data using Thematic Mapper (TM) imagery was undertaken to assess changes in natural vegetation cover in the southern Botswana Kalahari. Visual analysis of spectral reflectance curves, the development of spectral separability indexes, and conventional classification analysis techniques were used to identify and differentiate rangeland features. Results from reflectance curves indicated that most rangeland cover types could be preferentially distinguished using mainly wet season data, especially on the longer TM wavebands, and that range feature differentiation was more problematic on darker soils than on lighter soils. Spectral separability indexes (SSIs) confirmed that range feature separation varied considerably as a function of waveband and was more effective in the wet than the dry season. The SSIs also showed that range feature differentiation in both seasons was most effective using a combination of the chlorophyll absorpance band (TM3) and two mid-infrared bands (TM5 and TM7). Wet season data were more effectively classified in terms of range features than dry season data although some class similarity was inferred across the two classified data sets. The work shows that overall trends may be generated by comparing seasonal data sets, thereby providing an overall basis for dry season decision making. However, particular problems arise within the dry season data sets probably because of spectral similarities between shadow and darkened vegetation cover, thereby implying that further work is needed. KEY WORDS: Semiarid rangelands; Botswana; Kalahari; Spectral differentiation; Seasonal change; Darkened vegetation cover     

CLASSIFYING STORM RUNOFF POTENTIAL WITH PASSIVE MICROWAVE MEASUREMENTS1

ABSTRACT: The average microwave temperature of the watershed surface as detected by an airborne Passive Microwave Imaging Scanner (PMIS) was compared with the measured Soil Conservation Service (SCS) watershed storm runoff coefficient (CN). Previous laboratory work suggested that microwave response to the watershed surface is influenced by some of the same surface characteristics that affect runoff, i.e., soil moisture, surface roughness, vegetative cover, and soil texture. In order to field test and develop relations between runoff potentfal and microwave response, several highly instrumented watersheds of approximately 1.5 to 17 km2 were scanned under wet- and dry-soil conditions in April and June 1973. The polarized (horizontal and vertical) scans at 2.8 cm wavelength provided the data base from which other values were calculated. The best relationship between runoff coefficients (CN) and PMIS temperatures was observed when horizontally polarized temperatures from the near-dormant, early-growing season flight were used. Lower SCS runoff coefficients seem to be correlated with the cross-polarized response under dry watershed conditions late in the growing season and the difference in horizontal polarized response between wet conditions early in the growing season and dry conditions late in the growing season. To apply the results, the relationships need to be verified further.     

罗布泊极旱荒漠区的土壤

新疆罗布泊野骆驼国家级自然保护区位于哈密、巴州、吐鲁番三地州.罗布泊是塔里木盆地最低的断陷洼地,也是第四纪以来盆地地表水的集水中心和积盐中心.1970年干涸后4000 km2的湖盆成为平坦的岩盐地,其外围分布着各种类型的盐壳、棕漠土、风沙土等极旱荒漠土壤,局部地段分布有草甸土、盐土等,山地分布有棕钙土、高寒荒漠土,各种土壤有其不同的特征.