Emergy accounting of the Province of Siena: towards a thermodynamic geography for regional studies

This research is part of the SPIn-Eco project for the Province of Siena, Italy, and applies an environmental accounting method to a region with reference to its population, human activities, natural cycles, infrastructures and other settings. This study asserts that the consumption of resources due to the human economy is a source of great concern because of the load it places on the biosphere. Environmental resources locally used, whether directly or indirectly, from both renewable energy fluxes and storage of materials and energies, are investigated. In this paper emergy analysis is presented and applied to the Province of Siena and to each of its municipalities, in order to evaluate the main flows of energy and materials that supply the territorial system, including human subsystems, with reference to their actual environmental cost. Therefore, the behaviour of the whole system and the interactions between natural and human agents were studied; in other words, the attitudes of the territorial systems toward resource use as revealed by their patterns of emergy consumption were observed. Once expressed in units of the same form of energy through the emergy evaluation, categories of resource consumption and systems of varying scales and organization are compared. Furthermore, indexes of environmental performance based on emergy are calculated. Flows of energy and materials are assessed, and their intensities, which vary throughout the area of the Province, are then visualized on maps.     

Emergy analysis of municipal wastewater treatment and generation of electricity by digestion of sewage sludge

This study examines and evaluates, by using emergy analysis, the use of environmental resources for wastewater treatment in a Swedish town. Emergy analysis was applied, while it facilitates the comparison of resource use of substantially different kind. In the emergy analysis, all resources are assessed on the basis of the amount of direct and indirect solar energy required in their generation. The study also includes an evaluation of the amount of emergy associated with the production of wastewater. On the basis of our analysis, we suggest that the large amount of emergy that wastewater contains are in proportion to the amount of resources employed for wastewater treatment and the extensive effects on surrounding ecosystems of discharge of untreated wastewater. The use of local renewable natural resources in Swedish municipal wastewater treatment systems is negligible compared with the use of purchased inputs, processed largely with the support of fossil energy. A drastic shift of this order would demand that extensive land areas surrounding human settlements be (indirectly or directly) devoted to wastewater treatment. These areas are not accessible today. Our analysis also indicates that resource requirements from the economy in the production of electricity by the digestion of sewage sludge is about two times the total resource use for generation of the average mix of electricity used in the town. We, therefore, conclude that if the only reason to digest the sludge were to produce electricity, it would be more resource-efficient to purchase the electricity on the Swedish distribution net. Accordingly, there is no resource economy in producing biomass to digest just to increase the energy production at the wastewater treatment plant.     

Emergy evaluation perspectives of a multipurpose dam proposal in Korea

The 'emergy' concept was used to evaluate the economy of Korea and the contributions of a multipurpose dam proposal to the real wealth of the Korean economy. Emergy is defined as the available energy of one kind previously used up directly and indirectly to make a product or service. The indices for Korea calculated from the emergy evaluation were close to those of developed countries. Even though its monetary balance of payments was negative in 1997, the economy of Korea showed positive balance in trade when exports and imports were expressed in emergy. The emergy evaluation showed that the Korean economy places a large stress on its environment. Water supply and generation of electricity were the most important contributions of the proposed dam in terms of emergy; 46.5 and 45.1% of the total benefit, respectively. Flood control contributed 8.4% of the total benefit. Major costs associated with the proposed dam were from sediments (33.2% of the total cost), construction services (22.8%), and social disruption of the region (21.6%). In terms of emergy, the ratio of benefits to costs of the proposed dam was 2.78 if sediments are not included, and 1.86 if sediments are included, which result in more benefits than costs in both cases. The benefit to cost ratio of the dam was larger than that of the current system (1.42) without the dam whether sediments are included in the total cost or not. The environmental stress of the proposed dam was considerably lower than that of the Korean economy, but the dam might increase stress on local environment.     

Integrating emergy evaluation and geographic information systems for monitoring resource use in the Abruzzo region (Italy)

This paper presents an application of an environmental accounting method, namely emergy evaluation, developed for the monitoring and assessment of environmental resource use by local communities in the Abruzzo Region (Italy). Once quantified and classified according to their origin (renewable or non-renewable, local or external), emergy flows were elaborated through a geographic information system (GIS) that allowed us to represent their spatial distribution throughout the region. Outcomes took the form of patterns in which different emergy intensities, namely empower (unit: seJ yr^?1), were represented through a graduated grey-scale and visualized on a cartographic basis. The concentration of emergy flows, depending on the activity of local communities, showed variable levels of environmental load in different areas. In particular, spatial zones with homogeneous values of empower density (unit: seJ yr^?1 km^?2) – high, medium and low – were detected in order to identify areas with a similar “thermodynamic” nature, emergy being a thermodynamics based function. This allowed for the representation, at a glance, of a kind of geography that mirrors the behavior of a population settled in an area as additional information for investigating the effects of the use of urban structures and functions and improving our understanding of regional systems. A combined use of emergy evaluation and GIS could thus provide a complementary view of a territorial system and inform policy makers for planning specific strategies of future development.     

A Multi-Years Analysis of the Energy Balance,Green Gas Emissions,and Production Costs of First and Second Generation Bioethanol

Contemporary reports on the energy and environmental benefits of bioethanol have suggested that the cellulosic ethanol is significantly more efficient. To understand the development potential of energy crops in Taiwan, the present study has assessed the resources and cost inputs for the planning, harvesting, transporting, and storing procedures of the first generation energy crops during 2007–2010 with the perspective of LCA. In addition, a field investigation focusing on rice straw, the largest agricultural waste in Taiwan, has been conducted since 2010 to obtain fundamental data.This study further analyzes the first and second-generation feedstocks from the perspective of LCA based on field investigated data. Taiwan has not yet established an ethanol plant; therefore, this study established production data by simulating the production efficiency of an economical scale using parameters obtained through production trials, and proposed an evaluation model for the energy input, GHG, and production costs of bioethanol in Taiwan. The results of this study were cross-compared with foreign literature to explore the development potential of bioethanol in Taiwan. The results indicate that based on the current cellulosic ethanol technology in Taiwan, regarding the energy balance, GHG, and production costs, is less efficient than that of the first generation bioethanol.     

Energy and resource basis of an Italian coastal resort region integrated using emergy synthesis

Sustainable development of coastal zones must balance economic development that encourages human visitation from a larger population with desires that differ from the local residents with the need to maintain opportunities for the local resident society and conserve ecological capital, which may serve as the basis for residents.We present a case study in which the sustainability level of a coastal zone (Riviera del Beigua), located along the Ligurian coast of north-western Italy, was assessed through the lens of systems ecology using emergy synthesis to integrate across economic, social and environmental sub-systems.Our purposes were (1) to quantify the environmental sustainability level of this coastal zone, (2) to evaluate the role of tourism in affecting the economy, society and environment, and (3) to compare emergy synthesis to Butler's Tourism Area Life Cycle model (TALC). Results showed that 81% of the total emergy consumption in the coastal zone was derived from external sources, indicating that this tourist-heavy community was not sustainable. Tourism, as the dominant economic sub-system, consumed 42% of the total emergy budget, while local residents used the remaining 58%. The progressive stages of the TALC model were found to parallel the dynamic changes in the ratio of external emergy inputs to local emergy inputs, suggesting that emergy synthesis could be a useful tool for detecting a tourist region's TALC stage. Use of such a quantitative tool could expedite sustainability assessment to allow administrative managers to understand the complex relationship between a region's economy, environment and resident society so sound policies can be developed to improve overall sustainability.     

Integrating methods for the environmental sustainability: the SPIn-Eco Project in the Province of Siena (Italy)

This paper shows how different methods can be integrated in order to provide an organic evaluation of the environmental sustainability at the territorial level. A territory is a complex, dynamic and open system where a population develops, uses resources, produces goods and services, consumes, depletes and finally obtains economic results. All these elements characterise human behaviour, which can be monitored, measured and compared to the capacity of the environment to sustain it in the long run. The SPIn-Eco Project for the Province of Siena (Italy) is described as an example of an environmental sustainability assessment of an area, and its methods (Ecological Footprint, Greenhouse Gas Inventory, Extended Exergy Analysis, Emergy Evaluation, Life Cycle Assessment (LCA) and Remote Sensing) are briefly introduced. This Project has been proposed and funded by the most important provincial administrative and financial institutions in the territory (the Administration of the Province of Siena and the Monte dei Paschi Foundation, respectively), and was designed and realised in 4 years (2001-2004) by a research team coordinated by the University of Siena.     

From the LCA of food products to the environmental assessment of protected crops districts: a case-study in the south of Italy

In the present study, Life Cycle Assessment (LCA) methodology was applied to evaluate the energy consumption and environmental burdens associated with the production of protected crops in an agricultural district in the Mediterranean region. In this study, LCA was used as a 'support tool', to address local policies for sustainable production and consumption patterns, and to create a 'knowledge base' for environmental assessment of an extended agricultural production area. The proposed approach combines organisation-specific tools, such as Environmental Management Systems and Environmental Product Declarations, with the environmental management of the district. Questionnaires were distributed to producers to determine the life cycle of different protected crops (tomatoes, cherry tomatoes, peppers, melons and zucchinis), and obtain information on greenhouse usage (e.g. tunnel vs. pavilion). Ecoprofiles of products in the district were also estimated, to identify supply chain elements with the highest impact in terms of global energy requirements, greenhouse gas emissions, eutrophication, water consumption and waste production. These results of this study enable selection of the 'best practices' and ecodesign solutions, to reduce the environmental impact of these products. Finally, sensitivity analysis of key LCA issues was performed, to assess the variability associated with different parameters: vegetable production; water usage; fertiliser and pesticide usage; shared greenhouse use; substitution of plastics coverings; and waste recycling.     

An operational method for the evaluation of resource use and environmental impacts of dairy farms by life cycle assessment

This paper describes and applies EDEN-E, an operational method for the environmental evaluation of dairy farms based on the life cycle assessment (LCA) conceptual framework. EDEN-E requires a modest amount of data readily available on-farm, and thus can be used to assess a large number of farms at a reasonable cost. EDEN-E estimates farm resource use and pollutant emissions mostly at the farm scale, based on-farm-gate balances, amongst others. Resource use and emissions are interpreted in terms of potential impacts: eutrophication, acidification, climate change, terrestrial toxicity, non-renewable energy use and land occupation. The method distinguishes for each total impact a direct component (impacts on the farm site) and an indirect component (impacts associated with production and supply of inputs used). A group of 47 dairy farms (41 conventional and six organic) was evaluated. Expressed per 1000 kg of fat-and-protein-corrected milk, total land occupation was significantly larger for organic than for conventional farms, while total impacts for eutrophication, acidification, climate change, terrestrial toxicity, and non-renewable energy use were not significantly different for the two production modes. When expressed per ha of land occupied all total impacts were significantly larger for conventional than organic farms. This study largely confirms previously published findings concerning the effect of production mode on impacts of dairy farms. However, it strikingly reveals that, for the set of farms examined, the contribution of production mode to overall inter-farm variability of impacts was minor relative to inter-farm variability within each of the two production modes examined. The mapping of impact variability through EDEN-E opens promising perspectives to move towards sustainable farming systems by identifying the structural and management characteristics of the farms presenting the lowest impacts.     

The life cycle of rice: LCA of alternative agri-food chain management systems in Vercelli (Italy)

The Vercelli rice district in northern Italy plays a key role in the agri-food industry in a country which accounts for more than 50% of the EU rice production and exports roughly 70%. However, although wealth and jobs are created, the sector is said to be responsible for environmental impacts that are increasingly being perceived as topical. As a complex and comprehensive environmental evaluation is necessary to understand and manage the environmental impact of the agri-food chain, the Life Cycle Assessment (LCA) methodology has been applied to the rice production system: from the paddy field to the supermarket. The LCA has pointed out the magnitude of impact per kg of delivered white milled rice: a CO_2eq emission of 2.9 kg, a primary energy consumption of 17.8 MJ and the use of 4.9 m³ of water for irrigation purposes. Improvement scenarios have been analysed considering alternative rice farming and food processing methods, such as organic and upland farming, as well as parboiling. The research has shown that organic and upland farming have the potential to decrease the impact per unit of cultivated area. However, due to the lower grain yields, the environmental benefits per kg of the final products are greatly reduced in the case of upland rice production and almost cancelled for organic rice. LCA has proved to be an effective tool for understanding the eco-profile of Italian rice and should be used for transparent and credible communication between suppliers and their customers.     

An inventory of trace element inputs to agricultural soils in China

It is important to understand the status and extent of soil contamination with trace elements to make sustainable management strategies for agricultural soils. The inputs of trace elements to agricultural soils via atmospheric deposition, livestock manures, fertilizers and agrochemicals, sewage irrigation and sewage sludge in China were analyzed and an annual inventory of trace element inputs was developed. The results showed that atmospheric deposition was responsible for 43–85% of the total As, Cr, Hg, Ni and Pb inputs, while livestock manures accounted for approximately 55%, 69% and 51% of the total Cd, Cu and Zn inputs, respectively. Among the elements concerned, Cd was a top priority in agricultural soils in China, with an average input rate of 0.004 mg/kg/yr in the plough layer (0–20 cm). Due to the spatial and temporal heterogeneity of the sources, the inventory as well as the environmental risks of trace elements in soils varies on a regional scale. For example, sewage sludge and fertilizers (mainly organic and phosphate-based inorganic fertilizers) can also be the predominant sources of trace elements where these materials were excessively applied. This work provides baseline information to develop policies to control and reduce toxic element inputs to and accumulation in agricultural soils.     

An analysis of the use of life cycle assessment for waste co-incineration in cement kilns

Life cycle assessment, LCA, has become a key methodology to evaluate the environmental performance of products, services and processes and it is considered a powerful tool for decision makers. Waste treatment options are frequently evaluated using LCA methodologies in order to determine the option with the lowest environmental impact. Due to the approximate nature of LCA, where results are highly influenced by the assumptions made in the definition of the system, this methodology has certain non-negligible limitations. Because of that, the use of LCA to assess waste co-incineration in cement kilns is reviewed in this paper, with a special attention to those key inventory results highly dependent on the initial assumptions made. Therefore, the main focus of this paper is the life cycle inventory, LCI, of carbon emissions, primary energy and air emissions. When the focus is made on cement production, a tonne of cement is usually the functional unit. In this case, waste co-incineration has a non-significant role on CO₂ emissions from the cement kiln and an important energy efficiency loss can be deduced from the industry performance data, which is rarely taken into account by LCA practitioners. If cement kilns are considered as another waste treatment option, the functional unit is usually 1 t of waste to be treated. In this case, it has been observed that contradictory results may arise depending on the initial assumptions, generating high uncertainty in the results. Air emissions, as heavy metals, are quite relevant when assessing waste co-incineration, as the amount of pollutants in the input are increased. Constant transfer factors are mainly used for heavy metals, but it may not be the correct approach for mercury emissions.     

Ecological and economic dynamics of the Shunde agricultural system under China's small city development strategy

The agricultural and industrial development of small cities is the primary environmental management strategy employed to make full use of extra labor in the rural areas of China. The ecological and economic consequences of this development strategy will affect over 100 million people and change the organization of the Chinese landscape. In this study, we examined the agricultural development of Shunde, a small city in Guangdong Province, over the period 1978 until 2000. Our analysis of the ecological and economic dynamics of the agricultural system revealed the dominant role of labor in the intensification of agricultural production, even though the use of fuels, fertilizers and machines also increased during this time. The Shunde agricultural system was examined from both biophysical or donor-based and human utility or receiver-based perspectives, using emergy and economic methods, respectively. After 22 years of urbanization, the Shunde agricultural system was still able to fill 96% of the local demand for agricultural products using only 6% of its total yield compared to using 14% of the total yield in 1978. Aquaculture developed quickly during the study period as grain production decreased. In 2000, the production of fish, pork, and vegetables accounted for 92% of the total emergy output of the system; however, the emergy buying power of the money received in exchange was lower than the emergy contained in the products exported. The excess emergy exported is the basis for a high quality diet delivered to city dwellers at a relatively low price. In the 1980s, the productivity of both land and labor increased; but after 1992 the productivity of labor decreased, causing the efficiency of the whole agricultural system to decrease. We recommend that processing plants be established for the main agricultural products of Shunde to decrease the emergy loss in trading and to increase employment. The effect of including monetized ecosystem services in the balance between the emergy delivered to the markets in agricultural products and the emergy buying power of the money received was to decrease the emergy gained by the Shunde agricultural system.     

Simplified LCA and matrix methods in identifying the environmental aspects of a product system

In order to effectively integrate environmental attributes into the product design and development processes, it is crucial to identify the significant environmental aspects related to a product system within a relatively short period of time. In this study, the usefulness of life cycle assessment (LCA) and a matrix method as tools for identifying the key environmental issues of a product system were examined. For this, a simplified LCA (SLCA) method that can be applied to Electrical and Electronic Equipment (EEE) was developed to efficiently identify their significant environmental aspects for eco-design, since a full scale LCA study is usually very detailed, expensive and time-consuming. The environmentally responsible product assessment (ERPA) method, which is one of the matrix methods, was also analyzed. Then, the usefulness of each method in eco-design processes was evaluated and compared using the case studies of the cellular phone and vacuum cleaner systems. It was found that the SLCA and the ERPA methods provided different information but they complemented each other to some extent. The SLCA method generated more information on the inherent environmental characteristics of a product system so that it might be useful for new design/eco-innovation when developing a completely new product or method where environmental considerations play a major role from the beginning. On the other hand, the ERPA method gave more information on the potential for improving a product so that it could be effectively used in eco-redesign which intends to alleviate environmental impacts of an existing product or process.     

Environmental life cycle assessment of different types of the municipal wastewater pipeline network

With the onset of social life, humans have considered waste disposal as essential, and they have been able to repel it through brick and clay channels. Checking sewage pipes for energy consumption and a longer lifetime than other sewage system components is important. Climate change and exploitation of industrial resources have made environmental impacts, which are important factors in decision making. The purpose of this study was to introduce the most suitable type of sewage pipe considering environmental protection. Therefore, we applied the environmental life cycle assessment (LCA) method, using Sima Pro 8.2.3 software for the one-kilometer length of concrete pipes (300 mm in diameter), Polyvinyl chloride (PVC), and polyethylene (PE) (315 mm in diameter). Also, the BEES method and sensitivity analysis were used to validate the results. The comparison between three types of municipal wastewater pipes indicated that PE pipes are a more environmentally friendly option than PVC, and concrete pipes in pipe recycling, reducing extraction from untapped resources, and inefficient extraction of resources. Electricity, diesel fuel, and sulfate resistance cement consumption for concrete production are the most pollution elements in the LCA of concrete pipes. Usage of PVC granular, sanitary landfill of PVC pipes, and using hydraulic drill in LCA of PVC pipes are the most elements of generating pollution. The usage of PE granules, PE pipes landfilling, hydraulic excavator, and electricity consumption in the LCA of the PE pipes are the greatest polluting parameters.     

生命周期评价在我国固体废物环境管理中的应用

生命周期评价是评价产品、工艺或活动（服务）整个生命周期阶段有关环境负荷,进而辨识和评价减少环境影响机会的一种非常有用的工具。将生命周期评价应用于固体废物环境管理,无疑对于我国建立科学化的固体废物环境管理模式具有十分重要的作用。本文对生命周期评价的定义、主要阶段、应用工具、特点进行了阐述,并对生命周期评价如何应用于我国固体废物环境管理进行了探讨。     

Implementing by-product management into the Life Cycle Assessment of the mussel sector

In Galicia (NW Spain), the mussel sector is an economic and social cornerstone, with great relevance at both regional and international scales. The environmental impact of this sector has been recently discussed from a Life Cycle Assessment (LCA) perspective. In previous studies, it was concluded that the management of mussel shells and mussel organic by-products needed to be implemented into future life cycle assessments. In this article, LCA methodology was used in order to assess the environmental performance of two valorization alternatives for mussel by-products: mussel shell valorization to produce calcium carbonate, and mussel organic remains valorization to produce pâté.From the environmental characterization for mussel shell valorization, propane and electricity production, sludge and ash management, haulage and atmospheric releases were identified as the hot-spots on which improvement potentials should be focused. Furthermore, the environmental profile for mussel shell valorization was compared to those for incineration and landfilling as alternative management options.The environmental characterization of pâté production from mussel organic by-product led to the recommendation of acting on the formulation of mussel pâté, the thermal energy demand and the product transport. Additionally, this valorization alternative was compared to another common scenario which considered the use of mussel organic by-product to manufacture fish meal.Finally, the valorization of mussel shells and organic by-products was implemented into the assessment of the Galician mussel sector. Thus, mussel by-product management was found to contribute to the potential environmental impacts to a lesser extent than mussel culture, purification and canning transformation.     

Life cycle modelling of fossil fuel power generation with post-combustion CO2 capture

Due to its compatibility with the current energy infrastructures and the potential to reduce CO₂ emissions significantly, CO₂ capture and geological storage is recognised as one of the main options in the portfolio of greenhouse gas mitigation technologies being developed worldwide. The CO₂ capture technologies offer a number of alternatives, which involve different energy consumption rates and subsequent environmental impacts. While the main objective of this technology is to minimise the atmospheric greenhouse gas emissions, it is also important to ensure that CO₂ capture and storage does not aggravate other environmental concerns. This requires a holistic and system-wide environmental assessment rather than focusing on the greenhouse gases only. Life Cycle Assessment meets this criteria as it not only tracks energy and non-energy-related greenhouse gas releases but also tracks various other environmental releases, such as solid wastes, toxic substances and common air pollutants, as well as the consumption of other resources, such as water, minerals and land use. This paper presents the principles of the CO₂ capture and storage LCA model developed at Imperial College and uses the pulverised coal post-combustion capture example to demonstrate the methodology in detail. At first, the LCA models developed for the coal combustion system and the chemical absorption CO₂ capture system are presented together with examples of relevant model applications. Next, the two models are applied to a plant with post-combustion CO₂ capture, in order to compare the life cycle environmental performance of systems with and without CO₂ capture. The LCA results for the alternative post-combustion CO₂ capture methods (including MEA, K⁺/PZ, and KS-1) have shown that, compared to plants without capture, the alternative CO₂ capture methods can achieve approximately 80% reduction in global warming potential without a significant increase in other life cycle impact categories. The results have also shown that, of all the solvent options modelled, KS-1 performed the best in most impact categories.     

Dynamic emergy evaluation of a fish farm rearing process

The environmental sustainability of a fish farm rearing process was examined by means of emergy analysis. Many emergy analyses integrate data for a whole year smoothing short term variations and sometimes losing meaningful information (aliasing). For this reason we developed a model for an instantaneous emergy evaluation in an aquacultural system so that transformities, efficiency and effort spent at each moment during the fish rearing activity could be calculated. By means of the model and dynamic emergy calculations it is possible to recognize step by step the importance of the various emergy contributions and verify where and when to modify the system to move toward optimum production of a sustainable product. By the application of the model we confirmed that the emergy trends in a fish farm installation follow wide oscillations during a year due to variations in both internal and external emergy contributions. Among the fluxes considered, those due to the introduction of fingerlings represented the highest contributions to the total emergy budget. Thus, to improve the sustainability of the analyzed system the amount, frequency and timing of these fluxes must be carefully considered. For this purpose, a comparison between two different fry introduction schedules was performed to evaluate differences in the efficiency of the rearing process.