生物滴滤池法处理有机废气甲苯工艺填料的选择

生物滴滤池法处理挥发性有机污染物的研究是世界工业废气净化的前沿热点之一，本研究比较了阶梯环，聚乙烯小球，煤炭渣和某种活性炭附着纤维作为滴滤池中生物附着载体性能的优劣，结果表明，活性炭附着纤维填料系统具有较好的有机污染物去除能力。     

复合绝缘子覆冰闪络特性及其影响因素的研究

本文主要研究复合绝缘子在轻覆冰条件下的覆冰闪络特性,通过具有憎水性表面的平板模型,分析覆冰过程中间隙长度、间隙位置、间隙分布、融冰时间及染污程度对覆冰闪络过程的影响。研究发现,间隙是产生起始电弧的主要因素,间隙长度与冰闪电压之间呈先降后升的变化趋势,且间隙愈接近电极愈容易发生闪络。冰闪电压与融冰时间呈U型趋势,染污程度与冰闪电压正相关,且高染污条件下闪络会沿着冰层与污层交界面发生。最后,通过复合绝缘子全尺寸人工覆冰试验发现,轻覆冰条件下,起始电弧出现在覆冰量较少的杆径及下表面处,且覆冰闪络电压随染污程度的上升呈下降趋势。     

成都市2002年1月2日至4日浓雾天气雾的化学组成

为了查明雾天雾的化学学组成，2002年1月2日至1月4日，利用人为结露的方法采集了雾天的雾，并洲定了阴离子组成。与室内采集的凝结露水的研究进行比较，大雾天的雾中含有极高的硝酸粮，这是因为雾的形成过程中亚硝酸根进一步氧化为硝酸根的原因。     

低温有冰条件下吸油绳收油效率试验研究＊

总结国外试验经验的基础上,用亲油性绳式收油机中的吸油绳对-35#柴油和原油模拟在有冰的水域进行测试,试验表明了吸油绳不同长度与油和冰相对位置对收油效率的影响。该试验结果对寻求如何在冰区回收溢油有积极作用,也是溢油应急清理时选择技术方法的科学指导。     

飞机除冰废水处理研究进展

介绍了飞机除冰废水对机场周围环境的危害,分析了国内外除冰废水收集、储运、处理的现状,指出机场除冰废水治理难点。提出引入绿色航空管理理念,积极开展飞机除冰废水治理政策和方案研究,为促进机场除冰、防冰行业的可持续发展提出了建议。     

1997～2002年成都市区酸雨监测

本文对1997年～2002年成都市区的酸雨污染状况，酸雨分布，以及市区降水中阴离子成分随时间和空间的变化进行了探讨，为成都市区确定酸雨来源、酸雨类型、酸雨分布提供基础数据，并对控制和降低酸雨污染提出了建议。     

有冰条件下撇油器回收溢油速率试验研究＊

为评价一种进口多功能撇油器应对渤海冬季溢油的能力,试验分别对刷式、盘式、鼓式三种撇油头在无冰和有冰(冰密集度约5成)条件下进行收油速率测试。试验以100 L油品为基数,测出在各种组合条件下回收油品所需要的时间,并把鼓式撇油头在有冰条件下的泵速提高,再进行试验。结果发现三种撇油方式的回收速率不仅与撇油头类型有关,同时也取决于是否有冰;在有冰条件下,三种撇油头收油效果都受到影响,其中盘式撇油器受影响最大,无法回收溢油;在有冰条件下加大鼓式撇油头泵速会提高总回收速率,但含水率同时提高;对凝固原油,撇油器无能为力。试验结果对正确评估三种类型的撇油头在两种情况下的收油效果和相关单位应具备的清除溢油能力,以及今后引进设备提高应急能力将起到借鉴作用。     

成都市郊区雾水中阴离子变化的研究

本文用冷凝法采集雾水样品,用离子色谱法测定雾水样品中阴离子(氟离子、氯离子、亚硝酸根离子、硝酸根离子、硫酸根离子)的浓度,研究表明雾水中阴离子浓度与雾的浓密有关,雾水中硫酸根离子含量最高;雾水中阴离子浓度随大雾的消失而降低;雾水中阴离子浓度大于雨水。所得结果对在大雾天气情况下保护人体健康有一定参考意义。     

水体中阴离子表面活性剂（LAS）测定方法的改进

通过亚甲蓝分光光度法测定水体中阴离子表面活性剂所用三氯甲烷体积的选择以及萃取方法、萃取时间的比较，从标准曲线、线性相关系数计算以及方法所测样品的准确度、精密度等方面进行了分析，为建立简便、快捷的测定方法提供了依据。     

城沐一线500kV线路取消架空地线力学性能分析

架空地线的主要作用是防止雷电直击导线,但在冬季,由于架空地线线径较细,强度较低,多次因地线覆冰引发断线、跳闸事故,因此提出了取消重冰区500 k V线路架空地线的做法。使用有限元仿真工具ANSYS Workbench,以城沐一线500 k V线路三基杆塔为对象进行建模,对取消地线前后城沐一线的力学性能做了仿真计算。计算结果表明,在不同的覆冰强度下,取消地线后杆塔塔头及塔身主材所受拉力及应力都有所下降,提高了整个塔线体系在冬季运行的可靠性。结果可为冰区超高压电网的运行维护工作提供指导。     

HYDROMETEOROLOGICAL SIGNIFICANCE OF RIME ICE DEPOSITS IN THE COLORADO ROCKIES1

ABSTRACT Observations and measurements were made during storm periods at mountain top sites in the Colorado Rockies during the winter of 1981-1982. On average, liquid clouds occurred with and without snowfall for, respectively, 75 percent and 15 percent of the observations. On average, the rime ice deposition rates were measured to be seven times the precipitation rates. The rime deposits were estimated to contribute 10 percent to the water content of the snowpack. Combining this figure with the estimated rime deposits on falling snow crystals (up to 50 percent by mass), up to 60 percent of the water content of the annual snowpack in the mountains near Steamboat Springs, Colorado, could be due to rime ice deposits.     

Factors controlling sorption of prosulfuron by variable-charge soils and model sorbents

Prosulfuron [1-(4-methoxy-6-methyltriazin-2-yl)-3-[2-(3,3,3-trifluoropropyl) phenylsulfonyl]-urea), a relatively new sulfonylurea herbicide, is a weak acid (pK(a) 3.76), and therefore, will undergo pH-dependent speciation and sorption. Understanding prosulfuron sorption in soils is important for predicting its environmental fate. Soil and solution factors controlling sorption were investigated by measuring prosulfuron sorption on five model sorbents (amorphous silica, alpha-alumina, CaSWy1 montmorillonite, commercial humic acid, and anion exchange resin) and 10 variable-charge soils from CaCl(2) and Ca(H(2)PO(4))(2) solutions as a function of pH and ionic strength. Anion exchange of prosulfuron accounted for up to 82% of overall sorption in the pH range from 3 to 7. The relative importance of anion exchange to prosulfuron sorption was positively correlated to the ratio of anion and cation exchange capacities. Comparison between organic carbon (OC)-normalized sorption (K(oc)) versus pH for humic acid and variable-charge soils show similar trends with sorption decreasing with increasing pH. However, K(oc) values estimated from variable-charge soils in the lower pH range where anion exchange has the greatest contribution to sorption was almost one log unit greater than that estimated from humic acid clearly exemplifying the impact of anion exchange. Similarity in K(oc)-pH curves for humic acid and variable-charge soils may result from the fact that (i) cation exchange capacity increases with increasing OC content, thus effective anion exchange capacity is reduced; and (ii) the relative contribution of hydrophobic and hydrophilic sorption mechanisms was fairly constant. Given that both hydrophilic and hydrophobic sorption of prosulfuron decrease with increasing pH, addition of fertilizer and lime amendments may enhance the potential for off-site leaching of recently applied acidic pesticides.     

Significance of anion exchange in pentachlorophenol sorption by variable-charge soils

Sorption data and subsequent predictive models for evaluating acidic pesticide behavior on variable-charge soils are needed to improve pesticide management and environmental stewardship. Previous work demonstrated that sorption of pentachlorophenol (PCP), a model organic acid, was adequately modeled by accounting for pH-and pKa-dependent chemical speciation and using two organic carbon-normalized sorption coefficients; one each for the neutral and anionic species. Such models do not account for organic anion interaction to positively charged surface sites, which can be significant for variable-charge minerals present in weathered soils typical of tropical and subtropical regions. The role of anion exchange in sorption of ionizable chemicals by variable-charge soils was assessed by measuring sorption of PCP by several variable-charge soils from aqueous solutions of CaCl2, CaSO4, Ca(H2PO4)2 as a function of pH. Differences in sorption from phosphate and chloride electrolyte solutions were attributed to pentachlorophenolate interactions with anion exchange sites. Suppression of PCP sorption by phosphate ranged from negligible in a soil with essentially no positively charge sites, as measured by negligible anion exchange capacity, to as much as 69% for variable-charge soils. Pentachlorophenolate exchange correlated well with the ratio of pH-dependent anion exchange capacity to net surface charge. Sorption reversibility of PCP by both CaCl2 and Ca(H2PO4)2 solutions was also demonstrated. Results for PCP clearly demonstrate that sorption to anion exchange sites in variable-charge soils should be considered in assessing pesticide mobility and that phosphate fertilizer application may increase the mobility of acidic pesticides.     

Oxytetracycline sorption to organic matter by metal-bridging

The sorption of oxytetracycline to metal-loaded ion exchange resin and to natural organic matter by the formation of ternary complexes between polyvalent metal cations and sorbent- and sorbate ligand groups was investigated. Oxytetracycline (OTC) sorption to Ca- and Cu-loaded Chelex-100 resin increased with increasing metal/sorbate ratio at pH 7.6 (OTC speciation: 55% zwitterion, 45% anion). Greater sorption to Cu- than Ca-loaded resin was observed, consistent with the greater stability constants of Cu with both the resin sites and with OTC. Oxytetracycline sorption to organic matter was measured at pH 5.5 (OTC speciation: 1% cation, 98% zwitterion, 1% anion). No detectable sorption was measured for cellulose or lignin sorbents that contain few metal-complexing ligand groups. Sorption to Aldrich humic acid increased from "clean" < "dirty" (no cation exchange pretreatment) < Al-amended < Fe(III)-amended clean humic acid with K(d) values of 5500, 32000, 48000, and 250000 L kg(-1) C, respectively. Calcium amendments of clean humic acid suggested that a portion of the sorbed OTC was interacting by cation exchange. Oxytetracycline sorption coefficients for all humic acid sorbents were well-correlated with the total sorbed Al-plus-Fe(III) concentrations (r(2) = 0.87, log-log plot), suggesting that sorption by ternary complex formation with humic acid is important. Results of this research indicate that organic matter may be an important sorbent phase in soils and sediments for pharmaceutical compounds that can complex metals by the formation of ternary complexes between organic matter ligand groups and pharmaceutical ligand groups.     

CHANNEL CHANGES DOWNSTREAM FROM A DAM1

ABSTRACT: A flood-control dam was completed during 1979 on Bear Creek, a small tributary stream to the South Platte River in the Denver, Colorado, area. Before and after dam closure, repetitive surveys between 1977 and 1992 at five cross sections downstream of the dam documented changes in channel morphology. During this 15-year period, channel width increased slightly, but channel depth increased by more than 40 percent. Within the study reach, stream gradient decreased and median bed material sizes coarsened from sand in the pools and fine gravel on the rime to a median coarse gravel throughout the reach. The most striking visual change was from a sparse growth of streamside grasses to a dense growth of riparian woody vegetation.     

Cellulose-based anion exchanger with tertiary amine functionality for the extraction of arsenic(V) from aqueous media

A novel cellulose-based anion exchanger (Cell-AE) with tertiary amine functionality was synthesized by graft polymerization reaction of cellulose and glycidyl methacrylate using N,N′-methylene-bis-acrylamide as a crosslinker and benzoyl peroxide as an initiator, followed by dimethylamine (amination) and acid (HCl) treatment. The chemical modification was confirmed by infrared spectroscopy and CHN analysis. The anion exchanger was used in batch processes to study AS(V) adsorption in solutions. The operating variables studied were pH, contact time, initial As(V) concentration, sorbent mass, and ionic strength. The process was affected by solution pH with an optimum adsorption occurring at pH 6.0. Adsorption equilibrium was achieved within 1 h. Increasing ionic strength of solution negatively affected the arsenic uptake. The adsorption process performed more than 99.0% of As(V) removal from an initial concentration of 25.0 mg/L. The process of adsorption followed pseudo-second-order kinetics. The adsorption equilibrium isotherm data were analyzed using the Langmuir, Freundlich, Redlich–Peterson and Langmuir–Freundlich equations. The Langmuir–Freundlich isotherm described the adsorption data over the concentration range 25–400 mg/L. The adsorption mechanism appears to be a ligand-exchange process. A simulated groundwater sample was treated with Cell-AE to demonstrate its efficiency in removing As(V). The adsorbed As(V) ions were desorbed effectively by a 0.1 M NaOH solution.     

Quaternized agricultural by-products as anion exchange resins

The objectives of this study were the chemical modification of readily available, low-cost agricultural by-products to anion exchange resins and the selection of the best modified by-product for further use in anion removal. Resins were prepared through the quaternization of a series of 12 agricultural by-products with N-(3-chloro-2-hydroxypropyl) trimethylammonium chloride (CHMAC). Phosphate ion adsorption assays were conducted at pH 7 in order to compare adsorption properties among the by-products. Quaternized corn stover showed the highest phosphorus adsorption at 0.66 mmole/g. Since corn stover exhibited the best uptake of phosphate ion, it was compared to a commercially available, cellulose-based anion exchange resin. Additionally, adsorption capacities of quaternized corn stover for arsenate, chromate, and selenate were evaluated and adsorption efficiencies were determined in simulated wastewater samples. Our results indicate that modified corn stover demonstrates good adsorption uptake for arsenate and selenate and especially for chromate.     

蜈蚣草总黄酮体外抗氧化作用的研究

通过回流法提取蜈蚣草黄酮类化合物,利用分光光度法测定总黄酮的含量,并分析了它对羟基自由基、超氧阴离子自由基的清除作用和总抗氧化能力。结果表明,蜈蚣草总黄酮含量为6.15%,且具有较好的抗氧化能力。     

Seasonal influences on inorganic anion monitoring of the New Calabar River,Nigeria

The inorganic anion pollution of the New Calabar River surface water was investigated. Results showed seasonal variations in the inorganic anion levels. Water parameters such as sulfite, nitrate, phosphate, and alkalinity showed significantly higher values in the rainy season than in the dry season. Dissolved oxygen, pH, sulfide, sulfate, ammonia, and nitrite showed no significant differences between their rainy and dry season levels. Upstream-downstream changes were shown by conductivity, total dissolved solids, chloride, salinity, and temperature. Exceptions occurred in the nitrite levels, where the effect was minimal. Although the concentrations of some anions analyzed fell within internationally acceptable limits, the New Calabar River water is, in the main, polluted with inorganic anions and may be unacceptable for potable and industrial uses without treatment.