Winery wastewater treatment using the land filter technique

This study outlines a new approach to the treatment of winery wastewater by application to a land FILTER (Filtration and Irrigated cropping for Land Treatment and Effluent Reuse) system. The land FILTER system was tested at a medium size rural winery crushing ～20,000 tonnes of grapes. The approach consisted of a preliminary treatment through a coarse screening and settling in treatment ponds, followed by application to the land FILTER planted to pasture. The land FILTER system efficiently dealt with variable volumes and nutrient loads in the wastewater. It was operated to minimize pollutant loads in the treated water (subsurface drainage) and provide adequate leaching to manage salt in the soil profile. The land FILTER system was effective in neutralizing the pH of the wastewater and removing nutrient pollutants to meet EPA discharge limits. However, suspended solids (SS) and biological oxygen demand (BOD) levels in the subsurface drainage waters slightly exceeded EPA limits for discharge. The high organic content in the wastewater initially caused some soil blockage and impeded drainage in the land FILTER site. This was addressed by reducing the hydraulic loading rate to allow increased soil drying between wastewater irrigations. The analysis of soil characteristics after the application of wastewater found that there was some potassium accumulation in the profile but sodium and nutrients decreased after wastewater application. Thus, the wastewater application and provision of subsurface drainage ensured adequate leaching, and so was adequate to avoid the risk of soil salinisation.     

A modified risk assessment to establish molybdenum standards for land application of biosolids

The USEPA standards (40 CFR Part 503) for the use or disposal of sewage sludge (biosolids) derived risk-based numerical values for Mo for the biosolids --> land --> plant --> animal pathway (Pathway 6). Following legal challenge, most Mo numerical standards were withdrawn, pending additional field-generated data using modern biosolids (Mo concentrations <75 mg kg(-1) and a reassessment of this pathway. This paper presents a reevaluation of biosolids Mo data, refinement of the risk assessment algorithms, and a reassessment of Mo-induced hypocuprosis from land application of biosolids. Forage Mo uptake coefficients (UC) are derived from field studies, many of which used modern biosolids applied to numerous soil types, with varying soil pH values, and supporting various crops. Typical cattle diet scenarios are used to calculate a diet-weighted UC value that realistically represents forage Mo exposure to cattle. Recent biosolids use data are employed to estimate the fraction of animal forage (FC) likely to be affected by biosolids applications nationally. Field data are used to estimate long-term Mo leaching and a leaching correction factor (LC) is used to adjust cumulative biosolids application limits. The modified UC and new FC and LC factors are used in a new algorithm to calculate biosolids Mo Pathway 6 risk. The resulting numerical standards for Mo are cumulative limit (RPc)=40 kg Mo ha(-1), and alternate pollutant limit (APL) = 40 mg Mo kg(-1) We regard the modifications to algorithms and parameters and calculations as conservative, and believe that the risk of Mo-induced hypocuprosis from biosolids Mo is small. Providing adequate Cu mineral supplements, standard procedure in proper herd management, would augment the conservatism of the new risk assessment.     

Potential risks of copper, zinc, and cadmium pollution due to pig manure application in a soil-rice system under intensive farming: a case study of Nanhu, China

Heavy metal (copper [Cu], zinc [Zn], and cadmium [Cd]) pollution of soils from pig manures in soil-rice ( L.) systems under intensive farming was investigated, taking Nanhu, China, as the case study area. Two hundred pig manures and 154 rice straws, brown rice samples, and corresponding surface soil (0-15 cm) samples were collected in paddy fields from 150 farms in 16 major villages within the study area. The mean Cu and Zn concentrations in pig manures consistently exceeded the related standard. About 44 and 60% of soil samples exceed the Chinese Soil Cu and Cd Environmental Quality Standards, respectively. The concentration of Cu, Zn, and Cd in brown rice did not exceed the Chinese Food Hygiene Standard. There was a significant positive correlation between total Cu and Zn contents in soil and application rate of pig manures. Strong correlation was observed between the extractable Cu, Zn, and Cd in soil and the Cu, Zn, and Cd contents in the brown rice. The spatial distribution maps of Cu and Zn concentrations in brown rice, straw, and extractable soil Cu and Zn concentration also showed similar geographical trends. Further analyses on heavy metals loading flux and accumulation rates from pig manure applied suggested that Cu and Cd contents in soil currently have already exceeded the maximum permissible limit, and Zn, if still at current manure application rates, will reach the ceiling concentration limits in 9 yr. This study assists in understanding the risk of heavy metals accumulating from pig manure applications to agricultural soils.     

Regulatory context for cumulative impact research

Wetlands protection has become a topic of increased public attention and support, and regulation of wetlands loss under Section 404 of the Clean Water Act has received high priority within the US Environmental Protection Agency (EPA). Despite this, the nation is continuing to experience serious wetlands losses. This situation reflects the contentious nature of wetlands protection; it involves fundamental conflicts between environmental and development interests. Better information is needed to support regulatory decision making, including information on cumulative impacts. Currently, consideration of cumulative impacts, although required by various federal regulations, is limited. One reason is that most regulatory decisions are made on a permit-specific, site-specific basis, whereas cumulative impacts must be assessed on a broader, regional scale. In addition, scientific information and methods necessary to support cumulative impact assessment have been lacking. An anticipatory, planning-oriented framework to complement the existing site-specific permit review program is needed to support more effective consideration of cumulative impacts; such an effort is beginning to emerge. In addition, EPA is supporting research to provide better information on cumulative effects. It is recommended that the EPA program place initial emphasis on synthesis and analysis of existing information, on maximizing its use in decision making, and on information transfer. Recommended approaches include correlation of historic wetlands losses with loss of wetlands function and values, regional case studies, and development of indices of cumulative impact for use in permit review.Formerly Director, Office of Federal Activities, US Environmental Protection Agency     

Laboratory stabilizations/solidification of tank sludges: MVST/BVEST

Oak Ridge tank sludges that have been collected over several decades are being combined for treatment and disposal. Stabilization of the highly radioactive, mixed-waste sludges in the different tank sets has been evaluated prior to the proposed combination and treatment. This paper documents the testing of a Melton Valley Storage Tank (MVST)/Bethel Valley Evaporator Storage Tank set. Subsequent papers will discuss continued work on other tank sets and efforts to maximize the sludge loading. Grout formulations were tested in the laboratory both with a surrogate and with a sample of an actual mixed waste tank sludge from MVST W-25. Wet-sludge loadings of 50-60wt% resulted in strong wasteforms with no free water and gave a volume increase of about 40-50vol%. Resource Conservation and Recovery Act (RCRA) metals included in the surrogate testing were cadmium, chromium, lead, selenium, thallium, and mercury. The actual sludge sample was only characteristically hazardous for mercury by the Toxic Characteristic Leaching Procedure but exceeded the Universal Treatment Standard (UTS) limit for chromium. The grout formulations stabilized these two RCRA metals within UTS limits. In addition, a grout leachability index of about 9.0-10.0 was measured for both (85)Sr and (137)Cs, meeting the recommended requirement of >6.0.     

Response of Nitrogen Loading to the Chesapeake Bay to Source Reduction and Land Use Change Scenarios: A SPARROW‐Informed Analysis

In response to concerns regarding the health of streams and receiving waters, the United States Environmental Protection Agency established a total maximum daily load for nitrogen in the Chesapeake Bay watershed for which practices must be in place by 2025 resulting in an expected 25% reduction in load from 2009 levels. The response of total nitrogen (TN) loads delivered to the Bay to nine source reduction and land use change scenarios was estimated using a Spatially Referenced Regression on Watershed Attributes model. The largest predicted reduction in TN load delivered to the Bay was associated with a scenario in which the mass of TN as fertilizer applied to agricultural lands was decreased. A 25% decrease in the mass of TN applied as fertilizer resulted in a predicted reduction in TN loading to the Bay of 11.3%, which was 2.5–5 times greater than the reductions predicted by other scenarios. Eliminating fertilizer application to all agricultural land in the watershed resulted in a predicted reduction in TN load to the Bay of 45%. It was estimated that an approximate 25% reduction in TN loading to the Bay could be achieved by eliminating fertilizer applied to the 7% of subwatersheds contributing the greatest fertilizer‐sourced TN loads to the Bay. These results indicate that management strategies aimed at decreasing loading from a small number of subwatersheds may be effective for reducing TN loads to the Bay, and similar analyses are possible in other watersheds.     

ANSI/ASQC E4: A unified management standard for quality assurance of environmental programs

The need for a national consensus standard for quality assurance (QA) for environmental programs emerged from efforts to clean up sites contaminated by hazardous chemical and/or radioactive wastes. The waste management community has been using several different standards or sets of requirements for establishing the QA and quality control (QC) procedures for use during the cleanup of contaminated sites. Some of these requirements have been imposed by federal agencies, including the Department of Energy (DOE), the Department of Defense (DOD), the Nuclear Regulatory Commission (NRC), and the Environmental Protection Agency (EPA). Often, requirements have been chosen to fit a particular mission or regulatory requirements. The remediation and restoration of federally owned or operated hazardous waste sites has created a situation in which multiple organizations (including federal and state regulators, site operators, and remedial contractors) are overseeing or addressing the same technical problem, often at the same site, and using different QA requirements. The occurrence of multiple QA/QC requirements has resulted in costly and time-consuming duplication of effort. In addition, the perception of inconsistent and often conflicting requirements has created confusion and frustration. The need for a single set of QA/QC criteria to bring order and consistency to the application of QA in the environmental waste management area became increasingly clear, and led to the development of ANSI/ASQC E4, which may be approved and issued by this year.     

Laboratory stabilization/solidification of tank sludges: GAAT, OHF, and combined tank sets

Highly radioactive, mixed-waste sludges that have been collected at Oak Ridge over several decades are being combined for treatment and disposal. Stabilization of the sludges in the different tank sets was tested prior to the proposed combination and treatment. This paper, which follows a previous article on the Melton Valley Storage Tank/Bethel Valley Evaporator Storage Tank set, documents the testing of the Gunite and Associated Tank and Old Hydrofracture Facility tank sets, as well as the combined sludges of all the Oak Ridge National Laboratory tank sets; the third paper on this subject will discuss efforts to maximize the sludge loading. The grout formulations were tested in the laboratory with surrogates. A wet-sludge loading of 60wt% resulted in strong wasteforms with no free water and gave a volume increase of about 30-40vol%. The Resource Conservation and Recovery Act metals included in the surrogate testing were silver, cadmium, chromium, lead, selenium, thallium, zinc, and mercury. The grout formulations stabilized these metals within the Universal Treatment Standards limits. In addition, a grout leachability index of about 10.0-12.0 was measured for both (85)Sr and (137)Cs, meeting the recommended requirement of >6.0.     

Characterization of municipal and dairy wastewaters with 30 quality parameters and potential wastewater treatment by biological trickling filters

This study aimed to characterize raw municipal and dairy wastewaters. The quality of the collected wastewaters was determined by measuring 30 quality parameters, such as phenols, oxidation-reduction potential, oil and grease, total organic carbon (TOC), manganese, total viable count of bacteria (TVC), salinity, and biodegradability. Results were compared with wastewater disposal standards. This study also aimed to describe the potential application and performance of biological trickling filters (BTFs) in municipal and dairy wastewater treatment. Detailed reviews of trickling filter models were explained. Results revealed that two wastewater samples exceeded standard limits. The raw municipal and dairy wastewaters need treatment prior to disposal to the natural environment. Additionally, BTFs are efficient municipal and dairy wastewater treatments.     

污泥中重金属的稳定化研究进展与去除方法简述

通过"十一五"污水处理厂的建设,我国污泥产量也随之大幅增长,污泥的处理处置已经成为制约社会经济发展的重要问题。国际上的经验表明土地利用是污泥最终处置的主要发展方向,然而污泥中的重金属成为其土地利用的主要障碍。越来越多的研究者意识到,重金属的环境危害不仅仅取决于其总量,更取决于重金属存在形态。目前,Tessier分步提取法作为主流的污泥重金属划分方法,取得了广泛应用,该法将污泥中的重金属分成5种形态,分别为可交换态、碳酸盐结合态、铁锰氧化物结合态、有机结合态和残渣态。本文以此为基础综述了目前国内外主要的污泥重金属稳定和去除方法的原理及研究进展,比较了不同重金属稳定及去除方法的优点与不足,并提出了新的展望。     

Virtual Intergovernmental Linkage Through the Environmental Information Exchange Network

Over the past decade the U.S. Environmental Protection Agency (EPA) and the states have partnered in developing a web-based information sharing initiative that provides state environmental agencies easy access to federal environmental monitoring data and to the environmental data of other states, and gives the EPA access to data from state sources. The Environmental Information Exchange Network (EIEN) has established basic data exchange nodes in each of the states. Using multiple regression analysis we investigate the factors that account for the number and development stage of the data exchanges in which the states participate as of 2009. Overall, we find that administrative factors, especially the EPA’s grant program, are more important than political or environmental conditions. Participation in the exchanges is important not only as a way to reduce costs for data reporting and communication, but also as a precursor to greater eventual interstate environmental collaboration. Though clear evidence of a transition to collaboration is not yet seen here, there are some indications it may emerge in time.     

Development of a decision support system for Prioritization of multimedia dischargers

In 1990 the Environmental Protection Agency (EPA) began sponsoring several pilot projects in its regional offices to examine the potential benefits of adopting a multimedia approach to facility management. This approach differs from traditional practices at EPA in that facilities (dischargers regulated under permits issued by the agency) are managed based upon their cumulative impacts to all media: air, water, and land. Currently, facilities are managed by separate programs at EPA that evaluate environmental impacts from a single-media perspective. One aspect of discharger management is the necessity to allocate limited financial resources in a way that will minimize risk to human health and the environment. A careful, risk-based prioritization of facilities is one means of providing insight to the most effective strategy of allocating monitoring, inspection, and enforcement resources. Prioritization from a multimedia perspective is particularly difficult, however, since it requires translation and integration of medium-specific facility performances, management objectives, and perceptions of risk into a cumulative rating. A computerized decision support system (DSS) designed to guide management through the prioritization process from a multimedia perspective was identified as a potentially valuable tool for use in the pilot projects. This article describes the development of such a prototype, outlines the features of the completed system, and discusses its potential for use at EPA.     

Land application of phosphorus-laden sludge: a feasibility analysis

An investigation was conducted to examine aerobic digestion of the phosphorus-laden sludge produced at the Regina Wastewater Treatment Plant and feasibility of land use of this sludge combined with the dewatered anaerobically digested primary sludge from this plant. Experimental studies showed that aerobic digestion can be employed for the stabilization of the chemical sludge. Results of the feasibility analysis showed that mixing the two digested sludges met the heavy metal criteria set by various guidelines for agricultural use, presented the advantage of an increased concentration of nutrients and a decreased concentration of heavy metals, and a longer useful life of the agricultural site compared to using dewatered anaerobically digested primary sludge alone. Land application of the mixed digested sludges would be a more appropriate method of sludge disposal compared to the present practice of landfilling the dewatered sludge and lagooning the chemical sludge.     

Development and use of site-specific chemical and biological criteria for assessing New Bedford Harbor pilot dredging project

Numerical site-specific chemical and biological criteria were established to assess the impact of a pilot dredging project on water quality at the New Bedford Harbor, Massachusetts, USA, Superfund site. Because most existing chemical concentrations in the water column and indigenous biota exceeded federal and state water quality limits, the derivation of site-specific criteria was required. Prior to any operational phases of the project (i.e., dike construction, dredging), criteria values were developed from background concentrations of PCBs and metals in water and biota, as well as for the toxic effects of water quality on the biota. During each operational phase of the project, water samples were collected, analyzed within 16 h, and the data supplied to a management committee in order to assess the environmental impact of the previous days' operation. The ambient unfiltered water concentration of PCBs and metals were the only chemical or biological criteria exceeded. Modification of the next days' operations resulted in a return of these concentrations to background levels. The combined use of site-specific criteria and a real-time decision making management process allowed for successful completion of this project with a minimal effect on water quality.     

Establishment of permit limits for mill effluent

Various governmental regulatory agencies are responsible for establishing regulations on the discharge of chlorinated organic compounds from pulp and paper mills. The procedures for setting permit limits are the basic topic of this article. Different methods of determining permit limits are set forth and discussed in a number of references, including documents of the Environmental Protection Agency. This paper discusses in detail the application of one particular methodology—the lognormal model approach. In this paper we utilize a real data set and include the necessary calculations required to set up permit limits. The basic tenets of the permit process are such that if limits are set too low, operators who are in full regulatory compliance will still be frequently cited, and if limits are set too high, operators who are not in compliance will seldom if ever be cited. Thus there is a great need for these effluent limits to be determined with great care, both to protect the environment receiving the wastewater and the industry producing the wastewater.     

污泥农用对土壤环境的影响

土地利用是解决城市污泥处理处置的有效途径之一,本文从土壤理化性质、重金属污染风险以及有机污染风险3方面综述城市污泥农用对土壤环境的影响。城市污泥利用为植物提供营养元素,改良土壤结构,提高土壤肥力。污泥施用年限的长短与土壤中重金属的含量高低关系不明显,导致土壤重金属含量增加的主要因素是污泥施用量和污泥中重金属含量。在正常...     

ISO 14001 in state regulatory offices: A survey of activities

Is ISO 14001 just for the private sector? The answer is definitely “No.” The survey in this article was conducted to better understand how ISO 14001/Environmental Management Systems (EMSs) was being addressed by state agencies around the country. The survey goals were to determine where the focus on ISO 14001/EMSs is within state government, what the level of interest is, and how far states have progressed toward some form of use or recognition of ISO 14001. During the months that this survey was conducted, the progress at the state and federal levels was remarkable. Many states are aggressively moving forward and encouraging the investigation of ISO 14001 implementation. There is a well coordinated effort between several states (the Multi-State Working Group) to gather data on ISO 14001 effectiveness in a consistent manner. The cooperation between EPA and the states is beginning to solidify, with federal dollars going to state-managed pilot programs, and EPA has stepped forward with a more organized effort led by the Office of Reinvention.     

美国环境与健康管理体制借鉴

美国为应对环境污染带来的公共健康灾难,建立了环保局与卫生部既分工又协作的体制,两个部门都关注环境污染对人类健康的危害。在职能上,环保局侧重于管制和"污染者",卫生部侧重于服务和"潜在受害者"。联邦层面,环保局与卫生部在管制方面和研究(信息共享)方面紧密合作。地方层面,环保局的主要职能是监督各州执行联邦标准,卫生部的主要职能是提供健康和医疗服务,并在具体工作中密切配合。借鉴美国的经验教训,明确建立"公众健康优先"的环境管理价值取向,针对环境与健康风险管理的特点推进生态环境统一监管机构改革,以法治思维和法治方法推进环境与健康治理体系建设;加强科学研究,加快建设环境与健康风险控制信息系统。     

Traditional agricultural practices enable sustainable remediation of highly polluted soils in Southern Spain for cultivation of food crops

This study relates elemental content of a range of edible crops grown in soils severely polluted by metals and metalloids as affected by traditional smallholder management practices. Five agricultural plots close to a sulfidic waste dump were monitored. Soil analysis demonstrated elevated concentrations of As, Cu, Pb and Zn that were greatly in excess of maximum statutory limits for agricultural soils in the studied region. The main vegetables (lettuce, chard, onion, potatoes) and lemon, together with their associated soils, were measured for elemental content. Extractable soil element concentrations were very low. There were differences in elemental accumulation between crops, but none exceeded statutory concentrations in edible parts. Soil-plant transfer factors were uniformly low for all elements and crops. It is concluded that traditional soil management practices (annual liming and application of animal manures) have created conditions for sustainable long-term safety use, with potential for multiple end-use, of these highly polluted soils.     

The possibility of in situ heavy metal decontamination of polluted soils using crops of metal-accumulating plants

The decontamination of soils and wastes polluted with heavy metals presents one of the most intractable problems for soil clean-up. Present technology relies upon metal extraction or immobilization processes, both of which are expensive and which remove all biological activity in the soil during decontamination. They may only be appropriate for small areas of valuable redevelopment land. In this paper the use of metal-accumulating plants is explored for the removal of metals from superficially-contaminated soils such as those resulting from the long-term application to land of metal-contaminated sewage sludges. Green remediation employs plants native to metalliferous soils with a capacity to bioaccumulate metals such as zinc and nickel to concentrations greater than 2% in the aerial plant dry matter (hyperaccumulators). Growing such plants under intensive crop conditions and harvesting the dry matter is proposed as a possible method of metal removal and for ‘polishing’ contaminated agricultural soils down to metal concentrations below statutory limits. Not only are the biological activity and physical structure of soils maintained but the technique is potentially cheap, visually unobtrusive and offers the possibility of biorecovery of metals. The limitations of the process are reviewed and the future requirements for the development of efficient phytoremediators are outlined.