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1.
In the context of the Water Framework Directive (EP and CEU, 2000), management plans have to be set up to monitor and to maintain water quality in groundwater bodies in the EU. In heavily industrialized and urbanized areas, the cumulative effect of multiple contaminant sources is likely and has to be evaluated. In order to propose adequate measures, the calculated risk should be based on criteria reflecting the risk of groundwater quality deterioration, in a cumulative manner and at the scale of the entire groundwater body. An integrated GIS- and flux-based risk assessment approach for groundwater bodies is described, with a regional scale indicator for evaluating the quality status of the groundwater body. It is based on the SEQ-ESO currently used in the Walloon Region of Belgium which defines, for different water uses and for a detailed list of groundwater contaminants, a set of threshold values reflecting the levels of water quality and degradation with respect to each contaminant. The methodology is illustrated with first results at a regional scale on a groundwater body-scale application to a contaminated alluvial aquifer which has been classified to be at risk of not reaching a good quality status by 2015. These first results show that contaminants resulting from old industrial activities in that area are likely to contribute significantly to the degradation of groundwater quality. However, further investigations are required on the evaluation of the actual polluting pressures before any definitive conclusion be established.  相似文献   

2.
The Bitterfeld/Wolfen region is a megasite with multiple contaminant sources from more than a century of industrial activity, which have a considerable impact on the environment. At present, the contaminated groundwater covers an area of about 25km(2) and poses a threat for the surrounding aquifers and the Mulde River. This study focuses on the Schachtgraben, a man-made channel in the Mulde Floodplain that collects the effluents of the industrial area. It aims to characterise the relationship between surface water (channels, rivers) and the groundwater in the shallow Quaternary aquifer. Waters are Ca-SO(4) type with TDS reaching 3.8gL(-1) in the industrial area. Stable isotopes (delta(18)O, delta(2)H) show that two of the rivers are recharged mainly by groundwater that can be divided into two groups. Strontium isotopes ((87)Sr/(86)Sr) designate different geochemical end-members and enable the identification of mixing between natural and anthropogenic surface and groundwater.  相似文献   

3.
A computational model is applied to the optimization of pulsed pumping systems for efficient in situ remediation of groundwater contaminants. In the pulsed pumping mode of operation, periodic rather than continuous pumping is used. During the pump-off or trapping phase, natural gradient flow transports contaminated groundwater into a treatment zone surrounding a line of injection and extraction wells that transect the contaminant plume. Prior to breakthrough of the contaminated water from the treatment zone, the wells are activated and the pump-on or treatment phase ensues, wherein extracted water is augmented to stimulate pollutant degradation and recirculated for a sufficient period of time to achieve mandated levels of contaminant removal. An important design consideration in pulsed pumping groundwater remediation systems is the pumping schedule adopted to best minimize operational costs for the well grid while still satisfying treatment requirements. Using an analytic two-dimensional potential flow model, optimal pumping frequencies and pumping event durations have been investigated for a set of model aquifer-well systems with different well spacings and well-line lengths, and varying aquifer physical properties. The results for homogeneous systems with greater than five wells and moderate to high pumping rates are reduced to a single, dimensionless correlation. Results for heterogeneous systems are presented graphically in terms of dimensionless parameters to serve as an efficient tool for initial design and selection of the pumping regimen best suited for pulsed pumping operation for a particular well configuration and extraction rate. In the absence of significant retardation or degradation during the pump-off phase, average pumping rates for pulsed operation were found to be greater than the continuous pumping rate required to prevent contaminant breakthrough.  相似文献   

4.
This article reports on a field modelling study to investigate the processes controlling the plume evolution of para-toluenesulfonamide (p-TSA) in anoxic groundwater in Berlin, Germany. The organic contaminant p-TSA originates from the industrial production process of plasticisers, pesticides, antiseptics and drugs and is of general environmental concern for urban water management. Previous laboratory studies revealed that p-TSA is degradable under oxic conditions, whereas it appears to behave conservatively in the absence of oxygen (O2). p-TSA is ubiquitous in the aquatic environment of Berlin and present in high concentrations (up to 38 μg L?1) in an anoxic aquifer downgradient of a former sewage farm, where groundwater is partly used for drinking water production. To obtain refined knowledge of p-TSA transport and degradation in an aquifer at field scale, measurements of p-TSA were carried out at 11 locations (at different depths) between 2005 and 2010. Comparison of chloride (Cl?) and p-TSA field data showed that p-TSA has been retarded in the same manner as Cl?. To verify the transport behaviour under field conditions, a two-dimensional transport model was setup, applying the dual-domain mass transfer approach in the model sector corresponding to an area of high aquifer heterogeneity. The distribution of Cl? and p-TSA concentrations from the site was reproduced well, confirming that both compounds behave conservatively and are subjected to retardation due to back diffusion from water stagnant zones. Predictive simulations showed that without any remediation measures, the groundwater quality near the drinking water well galleries will be affected by high p-TSA loads for about a hundred years.  相似文献   

5.

Antu County in the Changbai Mountains is an important source of mineral water, but there is a lack of research on the source of groundwater characteristic components, affecting the protection of water resources. This study obtained hydrochemical and isotopic data (28 groups in total, April and September in 2019) by summarizing research and sampling data in order to identify the formation process of characteristics. The formation mechanism of the characteristic components was revealed using geostatistical, isotopic, and hydrogeochemical inversion simulations. The results show that the metasilicic acid is a common component of groundwater water chemistry in the study area. The water body primarily receives stable recharge from low-mineralized precipitation with ages ranging from 27.7 to 38.4 years and recharge elevations ranging from 1160 to 2393 m, providing ample time for water–rock interaction. The dissolution of olivine, pyroxene, albite, and other siliceous minerals is the source of characteristic components, and deep faults and deep basalt heat flow are the key conditions for the formation of metasilicic acid. When low-mineralized precipitation recharges the underground aquifer, it dissolves the silica-aluminate and silicon-containing minerals in the surrounding rocks through the water–rock action under the effect of CO2, causing a large amount of metasilic acid to dissolve into the groundwater and forming metasilic acid-type mineral water.

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6.
Three sulfonamides -para-toluenesulfonamide (p-TSA), ortho-toluenesulfonamide (o-TSA) and benzenesulfonamide (BSA) - have recently been detected in groundwater within a catchment area of one drinking water treatment plant (DWTP), which is located downstream of a former sewage farm. The degradation pathways of p-TSA, o-TSA and BSA were investigated during drinking water treatment with incubation experiments and an experimental filter. Incubation experiments showed that p-TSA is removed during the treatment by microbiological processes. Removal of p-TSA is performed by adapted microorganisms only present in polluted groundwater. The elimination in an experimental filter of 1.6m length applying filtration velocities from 2 to 6 m h(-1) was approximately 93% of p-TSA. The microbial degradation rates in the incubation experiment were approximately 0.029 microg l(-1) h(-1) (zero order reaction). In the experimental filter, the reaction rate constants were around 0.0063 s(-1) for all filtration velocities (1st order reaction). Drinking water treatment does not reduce the concentration of o-TSA and BSA under conditions encountered in Berlin. p-TSA, o-TSA and BSA were only measured in the low microg l(-1) concentrations range in the purified water.  相似文献   

7.
Indian statutes identify twelve different types of biomedical wastes and give the treatment and disposal options for each. Since it is not possible for every generator of biomedical waste to go for their own treatment and disposal facility, the small-scale generators take the service of centralized treatment and disposal facilities available to them on payment. In the state of Kerala in India, where the basic health indicators match those of many developed countries, the centralized biomedical waste treatment facility is run by Indian Medical Association (IMA), Kerala, under the banner IMAGE (IMA Goes Eco-Friendly) at a place called “Kanjikode” in the Palakkad District. The facility receives biomedical waste from around 4500 hospitals across the State and an equal number of medical laboratories. The plant incinerates the incinerable waste and the other kind of waste are disinfected and decontaminated. The residual ash and dried sludge are then moved to the landfill area. Recently, the facility was in the middle of a controversy due to the alleged health hazards it posed to the surrounding population. An environmental forensic investigation was carried out at the site to establish the merits of the allegation. The reported study is a part of the investigation where groundwater was analysed for the presence of heavy metals. As the biomedical waste contain heavy metals like Zn, Pb, Cd, Cr, and Hg, the presence of these were analysed to establish contamination of groundwater by the facility. The study area is bounded by Malampuzha dam and Korayar river. Groundwater contaminant transport modelling was done for a 3430 m × 3960 m area surrounding the waste treatment facility using Visual MODFLOW and MODPATH. Ground water flow direction and particle pathlines were computed to track the movement of contaminants. Groundwater samples were collected from the area shown to be polluted by the model, if metals were discharged by the facility, and also from outside this area. Water samples were collected conforming to the guidelines in the “Pollution Crime Forensic Investigation Manual” published by INTERPOL. The collected water samples were tested for heavy metal concentration using atomic absorption spectroscopy (AAS). The water sample analysis showed that the groundwater is not contaminated by heavy metal discharge from the biomedical treatment facility.  相似文献   

8.
The aim of this study is to evaluate the groundwater geochemistry in Burg Elarab area as an example of a calcareous eolianite aquifer that is covered with saline soil in a semiarid climatic condition. To conduct this study, 37 groundwater samples were taped from the production wells in addition to two surface water samples from Mallahet Mariut Lake and Bahig Canal. To elucidate the origin of dissolved ions and the geochemical processes influencing this groundwater, combinations of geomorphological, pedological, hydrogeological, hydrochemical, and statistical approaches were considered. Results suggest that the groundwater flows from both sides of the plain to the central area. Soil type and salinity and the intruded brackish lake water are the main factors controlling the groundwater chemistry. Chemically, the groundwater samples were classified into three groups. Group 1 samples have higher salinity range and characterize the area close to Mallahet Mariut and are influenced by cation exchange processes. Group 2 samples have an intermediate salinity range, occupy most of the plain area, and receive water from direct infiltrations and mixing between different recharge sources. Group 3 samples have low salinity range and limited areal extent and characterize the groundwater flowing from the Mariut Tableland. Reverse ion exchange is the predominant process in the latter group. Calcite precipitation is a general phenomenon characterizing all the groundwater types in the study area.  相似文献   

9.
Increasing application of nitrogen fertilizers in the irrigated lands of the studied area is likely to create a blanket non-point source of nitrate. Groundwater contamination from fertilizers, in this context, has been reported as derived from N03, K+ and 180 composition of groundwater. The data suggest both point and non-point sources of groundwater pollution. Thirty-three percent of the groundwater samples showed nitrate contents exceeding the general acceptable limit of 20 p.p.m. and 15% of the samples crossed the maximum permissible limit of 45 p.p.m. High nitrate levels are associated with high δ18O values, clearly indicating that significant quantities of evaporated (isotopically enriched) irrigation water infiltrate along with fertilizer nitrate to the groundwater system. Different δ18O---N03 trends suggest isotopically distinct, non-point source origins which vary spatially and temporally, due to different degrees of evaporation/recharge and amounts of fertilizer applied. A scatter diagram of N03 vs K+ suggests a common source of these ions when the concentration is less than 40 p.p.m. The investigation indicates that a combination of isotope (180) and hydrochemical data can clearly characterize the impact of fertilizer on groundwater. Application of high nitrate, high potassium groundwater irrigation can minimize the requirement for inorganic fertilizers and bring down the cost of cultivation considerably, through appropriate management of fertilizer and water and modifications in agronomic practices and strategies on crops grown. Such practices will help protect groundwater from further degradation.  相似文献   

10.
Influence of pH on persulfate oxidation of TCE at ambient temperatures   总被引:10,自引:0,他引:10  
Liang C  Wang ZS  Bruell CJ 《Chemosphere》2007,66(1):106-113
In situ chemical oxidation (ISCO) is a technology used for groundwater remediation. This laboratory study investigated the use of the oxidant sodium persulfate for the chemical oxidation of trichloroethylene (TCE) at near ambient temperatures (10, 20 and 30 degrees C) to determine the influence of pH (pH=4, 7 and 9) on the reaction rate (i.e., pseudo-first-order rate constants) over the range of temperatures utilized. TCE solutions (60 mg l(-1); 0.46 mM) were prepared in phosphate buffered RO water and a fixed persulfate/TCE molar ratio of 50/1 was employed in all tests. Half-lives of TCE degradation at 10, 20 and 30 degrees C (pH 7) were 115.5, 35.0 and 5.5h, respectively. Maximum TCE degradation occurred at pH 7. Lowering system pH resulted in a greater decrease in TCE degradation rates than increasing system pH. Radical scavenging tests used to identify predominant radical species suggested that the sulfate radical (SO(4)(.-)) predominates under acidic conditions and the hydroxyl radical (.OH) predominates under basic conditions. In a side by side comparison of TCE degradation in a groundwater vs. unbuffered RO water it was demonstrated that when the system pH is buffered to near neutral pH conditions due to the presence of natural occurring groundwater constituents that the TCE degradation rate is higher than in unbuffered RO water where the system pH dropped from 5.9 to 2.8. The results of this study suggest that in a field application of ISCO, pH should be monitored and adjusted to near neutral if necessary.  相似文献   

11.
Environmental impact of diuron transformation: a review   总被引:3,自引:0,他引:3  
Giacomazzi S  Cochet N 《Chemosphere》2004,56(11):1021-1032
Diuron is a biologically active pollutant present in soil, water and sediments. A synthesis of literature data on its physicochemical properties, partitioning behaviour, abiotic and biotic transformations, toxicological and ecotoxicological impacts has been here performed. Data have shown that diuron is generally persistent in soil, water and groundwater. It is also slightly toxic to mammals and birds as well as moderately toxic to aquatic invertebrates. However, its principal product of biodegradation, 3,4-dichloroaniline exhibits a higher toxicity and is also persistent in soil, water and groundwater. Thus, diuron indirectly possesses a significant amount of toxicity and could be a potential poisoning pesticide contaminant of groundwater. Unfortunately, groundwater contamination will still persist despite the progressive suppression of diuron (Directive 200/60/CE). Therefore, determining the main factors influencing its degradation and its ecotoxicological effects on the environment and health could provide a basis for further development of bioremediation processes.  相似文献   

12.

The urban groundwater of the Quaternary aquifer of the Lake Chad basin in N’Djamena has been subject to many hydrochemical studies. However, the results are often not presented in a way that enables water quality managers to make an appropriate decisions, which restrict development and poverty reduction efforts. The objective of the present study was to contribute the improved management of the local groundwater resources. A total of 85 groundwater samples were interpreted using hydrochemical techniques associated with integrated numerical indices and multivariate statistical analysis. The hydrochemical results coupled with the relative residence time of water have shown that the chemical composition of these waters is linked to geogenic and anthropogenic factors and to their proximity to the Chari-Logone rivers. These investigations showed that the groundwater quality in N’Djamena is characterized by a high spatial variability. This study also assessed the suitability of groundwater for user needs and identified areas which are more/less favorable for a specific use. The evaluation of water quality and its suitability for human consumption is also a problem of optimizing data acquisition strategy, and this study used the correlation between water quality index (WQI) and electrical conductivity (EC) to orientate future data acquisition strategies. This parametrization can assist the decision makers and water management professionals in evaluating groundwater availability and setting up a robust water quality management plan in areas with similar hydrogeological and climatic conditions.

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13.
以硝基苯、苯胺为主要污染物的污染地下水为研究对象,加入激活剂(乳糖、Na2HPO4、乳糖+Na2HPO4、乙醇、牛肉膏、蛋白胨)激活土著微生物,并考察其对土著微生物生长及硝基苯、苯胺降解效果的影响。加入激活剂3d后测各个水样的脱氢酶活性,对培养9d后的水样进行气相色谱/质谱(GC/MS)分析。结果表明,加入乳糖的水样中,其微生物相对增长率达157.2%,硝基苯、苯胺的相对去除率分别为14.90%和0.79%;加入Na2HPO4和乙醇的水样中,其微生物增长和硝基苯、苯胺降解情况均没有明显变化;加入乳糖+Na2HPO4的水样中,微生物相对增长率达180.3%,硝基苯、苯胺的相对去除率分别为24.20%和1.21%;加入牛肉膏的水样中,微生物的相对增长率为830.7%,硝基苯、苯胺的相对去除率分别为99.99%和99.67%;加入蛋白胨的水样中,其微生物相对增长率为686.0%,硝基苯、苯胺的相对去除率分别为99.33%和58.94%。GC/MS分析结果表明,加入激活剂后对氯苯胺、1-甲基-4-硝基苯等其他有机物的降解率均有提高。由此可见,通过激活土著微生物修复有机物污染地下水是可行的。  相似文献   

14.
A study was conducted to evaluate long-term trends in nitrate concentrations and to try to identify the origin of nitrate using stable isotopes (15N(NO3-) and 18O(NO3-)) in the aquifers of the western Central Valley, Costa Rica, where more than 1 million people depend on groundwater to satisfy their daily needs. Data from 20 sites periodically sampled for 4 to 17 years indicate an increasing trend in nitrate concentrations at five sites, which in a period ranging from 10 to 40 years, will exceed recommended maximum concentrations. Results of isotopic analysis indicate a correspondence between land use patterns and the isotopic signature of nitrate in groundwater and suggest that urbanization processes without adequate waste disposal systems, followed by coffee fertilization practices, are threatening water quality in the region. We conclude that groundwater management in this area is not sustainable, and that land use substitution processes from agricultural activity to residential occupation that do not have proper sewage disposal systems may cause a significant increment in the nitrate contaminant load.  相似文献   

15.
The assessment of aquifer vulnerability is a very important task, especially in agricultural areas because the quality and availability of groundwater affects both the sustainability of agriculture and the quality of life. In this study, an integrated approach is considered, with the use of the generic and agricultural DRASTIC models as well as a geographic information system (GIS), to assess groundwater vulnerability in the agricultural area of Barrax, in the province of Albacete, in Spain. Seven parameters—depth to water, net recharge, aquifer media, soil media, topography, impact of vadose zone media, and hydraulic conductivity of the aquifer (DRASTIC)—have been considered as weighted layers to enable an accurate groundwater risk mapping. The results of the generic DRASTIC model indicated very low vulnerability to contamination for Barrax groundwater due to limited urban and industrial development in the wider area. However, agricultural activities impose pressure to groundwater resources and the results of the agricultural DRASTIC model show that 6.86% of the study area is characterized by very high, 2.29% by high, 47.28% by medium, 38.28% by low, and the remaining 5.29% by no vulnerability to groundwater contamination. The distribution of nitrate concentration in groundwater in the area under study is quite well correlated with the agricultural DRASTIC vulnerability index. Sensitivity analysis was also performed to acknowledge statistical uncertainty in the estimation of each parameter used, to assess its impact, and thus to identify the most critical parameters that require further investigation. Depth to water and impact of vadose zone are the parameters that had the most noticeable impact on the generic DRASTIC vulnerability index followed by the soil media and topography. In contrast, the agricultural DRASTIC method is more sensitive to the removal of the depth to water parameter followed by the topography and the soil media parameters.  相似文献   

16.
A field investigation of a TCE plume in a surficial sand aquifer shows that groundwater-surface water interactions strongly influence apparent plume attenuation. At the site, a former industrial facility in Connecticut, depth-discrete monitoring along three cross-sections (transects) perpendicular to groundwater flow shows a persistent VOC plume extending 700 m from the DNAPL source zone to a mid-size river. Maximum TCE concentrations along a transect 280 m from the source were in the 1000s of microg/L with minimal degradation products. Beyond this, the land surface drops abruptly to a lower terrace where a shallow pond and small streams occur. Two transects along the lower terrace, one midway between the facility and river just downgradient of the pond and one along the edge of the river, give the appearance that the plume has strongly attenuated. At the river, maximum TCE concentrations in the 10s of microg/L and similar levels of its degradation product cis-DCE show direct plume discharge from groundwater to the river is negligible. Although degradation plays a role in the strong plume attenuation, the major attenuation factor is partial groundwater plume discharge to surface water (i.e. the pond and small streams), where some mass loss occurs via water-air exchange. Groundwater and stream mass discharge estimates show that more than half of the plume mass discharge crossing the first transect, before surface water interactions occur, reaches the river directly via streamflow, although river concentrations were below detection due to dilution. This study shows that groundwater and surface water concentration measurements together provide greater confidence in identifying and quantifying natural attenuation processes at this site, rather than groundwater measurements alone.  相似文献   

17.
The purpose of the paper is to assess the groundwater quality near the landfill sites using landfill water pollution index (LWPI). In order to investigate the scale of groundwater contamination, three landfills (E, H and S) in different stages of their operation were taken into analysis. Samples of groundwater in the vicinity of studied landfills were collected four times each year in the period from 2004 to 2014. A total of over 300 groundwater samples were analysed for pH, EC, PAH, TOC, Cr, Hg, Zn, Pb, Cd, Cu, as required by the UE legal acts for landfill monitoring system. The calculated values of the LWPI allowed the quantification of the overall water quality near the landfill sites. The obtained results indicated that the most negative impact on groundwater quality is observed near the old Landfill H. Improper location of piezometer at the Landfill S favoured infiltration of run-off from road pavement into the soil-water environment. Deep deposition of the groundwater level at Landfill S area reduced the landfill impact on the water quality. Conducted analyses revealed that the LWPI can be used for evaluation of water pollution near a landfill, for assessment of the variability of water pollution with time and for comparison of water quality from different piezometers, landfills or time periods. The applied WQI (Water Quality Index) can also be an important information tool for landfill policy makers and the public about the groundwater pollution threat from landfill.  相似文献   

18.
The operating life of an Fe(0)-based permeable reactive barrier (PRB) is limited due to chemical reactions of Fe(0) in groundwater. The relative contributions from mineral precipitation, gas production, and microbial activity to the degradation of PRB performance have been uncertain. In this controlled field study, nitrate-rich, site groundwater was treated by Fe(0) in large-volume, flow-through columns to monitor the changes in chemical and hydraulic parameters over time. Tracer tests showed a close relationship between hydraulic residence time and pH measurements. The ionic profiles suggest that mineral precipitation and accumulation is the primary mechanism for pore clogging around the inlet of the column. Accumulated N(2) gas generated by biotic processes also affected the hydraulics although the effects were secondary to that of mineral precipitation. Quantitative estimates indicate a porosity reduction of up to 45.3% near the column inlet over 72 days of operation under accelerated flow conditions. According to this study, preferential flow through a PRB at a site with similar groundwater chemistry should be detected over approximately 1 year of operation. During the early operation of a PRB, pH is a key indicator for monitoring the change in hydraulic residence time resulting from heterogeneity development. If the surrounding native material is more conductive than the clogged Fe-media, groundwater bypass may render the PRB ineffective for treating contaminated groundwater.  相似文献   

19.
The raw water quality and associations between the factors considered as threats to water safety were studied in 20 groundwater supplies in central Finland in 2002-2004. Faecal contaminations indicated by the appearance of Escherichia coli or intestinal enterococci were present in five small community water supplies, all these managed by local water cooperatives. Elevated concentrations of nutrients in raw water were linked with the presence of faecal bacteria. The presence of on-site technical hazards to water safety, such as inadequate well construction and maintenance enabling surface water to enter into the well and the insufficient depth of protective soil layers above the groundwater table, showed the vulnerability of the quality of groundwater used for drinking purposes. To minimize the risk of waterborne illnesses, the vulnerable water supplies need to be identified and appropriate prevention measures such as disinfection should be applied.  相似文献   

20.

Background

A three-dimensional groundwater flow model was used to evaluate the groundwater potential and assess the effects of groundwater withdrawal on the regional water level and flow direction in the central Beijing area. A program of groundwater modeling aimed at estimating current contaminant fluxes to the central area and site streams via groundwater was developed.

Results and discussion

The conceptual model developed for the site attempted to incorporate a complex stratigraphic profile in which groundwater flow and contaminant transport is strongly controlled by a shallow aquifer. Here, a conceptual model for groundwater flow and contaminant transport in central Beijing is presented.

Conclusion

Model simulations indicated that a sharp drop in the hydraulic head occurs at the center of the model area, which generates a cone of depression and a continuous decline of head with respect to time as a result of heavy groundwater abstraction.  相似文献   

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