Development of a robust chromatographic method for the detection of chlorophenols in cork oak forest soils

A major concern for the cork and wine industry is ‘cork taint’ which is associated with chloroanisoles, the microbial degradation metabolites of chlorophenols. The use of chlorophenolic compounds as pesticides within cork forests was prohibited in 1993 in the European Union (EU) following the introduction of industry guidance. However, cork produced outside the EU is still thought to be affected and simple, robust methods for chlorophenol analysis are required for wider environmental assessment by industry and local environmental regulators. Soil samples were collected from three common-use forests in Tunisia and from one privately owned forest in Sardinia, providing examples of varied management practice and degree of human intervention. These provided challenge samples for the optimisation of a HPLC-UV detection method. It produced recoveries consistently >75 % against a soil CRM (ERM-CC008) for pentachlorophenol. The optimised method, with ultraviolet (diode array) detection is able to separate and quantify 16 different chlorophenols at field concentrations greater than the limits of detection ranging from 6.5 to 191.3 μg/kg (dry weight). Application to a range of field samples demonstrated the absence of widespread contamination in forest soils at sites sampled in Sardinia and Tunisia.     

Tracing the fate of PCBs in forest ecosystems

Forests were shown to play an important role in influencing atmospheric concentrations and transport of persistent organic pollutants (POPs) in the environment. World forests cover more than 4 billion hectares and contain up to 80% of the above ground organic carbon. Given the lipophilic nature of POPs, this suggests that forests can influence the environmental fate of POPs at a global scale. POP accumulation in forest canopies still presents points of concern given the complexity of these ecosystems. In particular, the role of ecological parameters such as LAI (leaf area index) and SLA (specific leaf area) and their dynamics during the growing season was not sufficiently investigated yet. This paper reviews, compares and interprets a unique case study in which air and leaf concentrations and deposition fluxes for selected polychlorinated biphenyls (PCBs) were measured in three different forest types exposed to the same air masses. In order to trace the air-leaf-soil path of these compounds, a dynamic model of POP accumulation into forest canopy was applied. The dynamics of the canopy biomass strongly affected the trend of leaf concentration with time. Growth dilution effect can prevent the more chlorinated compounds from reaching the partitioning equilibrium before litter fall, while the more volatile compounds can approach equilibrium in the range of few weeks. An amount of up to 60 ng of PCBs per square metre of ground surface was predicted to be stored in each of the selected forests at fully developed canopy. Dry gaseous deposition fluxes to forest canopy were estimated to reach a maximum value of about 0.5-1.5 ng m(-2) d(-1) during the spring period.     

A multi-scale metrics approach to forest fragmentation for Strategic Environmental Impact Assessment

Forests are becoming severely fragmented as a result of land development. South Korea has responded to changing community concerns about environmental issues. The nation has developed and is extending a broad range of tools for use in environmental management. Although legally mandated environmental compliance requirements in South Korea have been implemented to predict and evaluate the impacts of land-development projects, these legal instruments are often insufficient to assess the subsequent impact of development on the surrounding forests. It is especially difficult to examine impacts on multiple (e.g., regional and local) scales in detail. Forest configuration and size, including forest fragmentation by land development, are considered on a regional scale. Moreover, forest structure and composition, including biodiversity, are considered on a local scale in the Environmental Impact Assessment process. Recently, the government amended the Environmental Impact Assessment Act, including the SEA, EIA, and small-scale EIA, to require an integrated approach. Therefore, the purpose of this study was to establish an impact assessment system that minimizes the impacts of land development using an approach that is integrated across multiple scales.This study focused on forest fragmentation due to residential development and road construction sites in selected Congestion Restraint Zones (CRZs) in the Greater Seoul Area of South Korea. Based on a review of multiple-scale impacts, this paper integrates models that assess the impacts of land development on forest ecosystems. The applicability of the integrated model for assessing impacts on forest ecosystems through the SEIA process is considered.On a regional scale, it is possible to evaluate the location and size of a land-development project by considering aspects of forest fragmentation, such as the stability of the forest structure and the degree of fragmentation. On a local scale, land-development projects should consider the distances at which impacts occur in the vicinity of the forest ecosystem, and these considerations should include the impacts on forest vegetation and bird species. Impacts can be mitigated by considering the distances at which these influences occur. In particular, this paper presents an integrated environmental impact assessment system to be applied in the SEIA process. The integrated assessment system permits the assessment of the cumulative impacts of land development on multiple scales.     

On the Assessment of Sulphur Deposition on Forests Growing Over the Areas of Industrial Impact

A method of calculation of sulphur deposition values on forests subjectto long-term industrial influence is presented. Investigations wereconducted in the vicinities of nickel smelters of Kola peninsula. Sulphurdioxide (SO₂) is the major phytotoxicant emitted by theseenterprises. Depositions of sulphur were calculated on the basis of ground air layer pollution. To determine it a mathematical model was applied.Field surveys of forest ecosystems response to air contamination werecarried out and areas of different forest damage degree were identified.More than 4300 km² of the territory of Kola peninsula isunder the impact of nickel enterprises. Average SO₂concentration over the area of slight damage to forests is about 20µg/m³. It corresponds to the critical level proposed for forest ecosystems (UN ECE, 1993). Sulphur deposition over thearea of slight damage varies from 0.6 to 1.0 g/m²yr^-1 for coniferous forests. For deciduous forests it isabout 1.0 g/m² yr^-1. These values are close totarget loads for highly sensitive ecosystems (Nilsson et al., 1991), but they exceed critical loads for the northern regions of Europe (Downing etal., 1993).     

Monitoring and analysis of natural vegetation in a Special Protected Area of Mountain Antichasia—Meteora, central Greece

Natural ecosystems are renewable resources with special environmental, social, and economical attributes and characteristics. The increasing need of human beings for a better environment results in the use of new technologies that offer many advantages in detecting changes in the ecosystems. Remote sensing tools, technology, and the spatial analysis of the Geographic Information System were used in determining any changes in this study which attempts to classify land cover over a 10-year period. The study area is in Thessaly, central Greece, and has been classified as a Special Protection Area, because of its important wild fauna. The results have shown that current technologies can be used for modeling environmental parameters which improve our knowledge of the attributes, characteristics, situation, trends, and changes of natural ecosystems. The changes over time that have been observed result from the development of the vegetation or to anthropogenic and socioeconomic reasons. Rational range management will be a very comprehensive tool for farmers. This action will have a positive impact on flora in the rangelands. The core strategy is to combine forest, pasture, and livestock so that each component produces usable products.     

Spatial dynamics of carbon storage: a case study from Turkey

Forest ecosystems have an important role in carbon cycle at both regional and global scales as an important carbon sink. Forest degradation and land cover changes, caused by deforestation and conversion to non-forest area, have a strong impact on carbon storage. The carbon storage of forest biomass and its changes over time in the Hartlap planning unit of the southeastern part of Turkey have been estimated using the biomass expansion factor method based on field measurements of forests plots with forest inventory data between 1991 and 2002. The amount of carbon storage associated with land use and land cover changes were also analyzed. The results showed that the total forested area of the Hartlap planning unit slightly increased by 2.1 %, from 27,978.7 ha to 28,282.6 ha during the 11-year period, and carbon storage increased by 9.6 %, from 390,367.6 to 427,826.9 tons. Carbon storage of conifer and mixed forests accounted for about 70.6 % of carbon storage in 1991, and 67.8 % in 2002 which increased by 14,274.6 tons. Land use change and increasing forest area have a strong influence on increasing biomass and carbon storage.     

Spatial Distribution and Temporal Change of Carbon Storage in Timber Biomass of Two Different Forest Management Units

Forests make up large ecosystems and can play an important role in mitigating the emissions of CO₂, the most important greenhouse gas. However, they are sources of atmospheric carbon when they are disturbed by human or natural causes. Storage of carbon through expansion and adaptive management of forest ecosystems can assist in reducing carbon concentrations in atmosphere. This study proposes a methodology to produce spatially explicit estimates of the carbon storages (aboveground plus belowground) depending on land use/cover changes in two different forest ecosystems during various periods. Carbon storages for each forest ecosystem were projected according to inventory data, and carbon storages were mapped in a geographic information system (GIS). Results showed that total carbon stored in above and belowground of both forest ecosystems increased from one period to other because of especially increase of productive forest areas and decline of degraded forest areas as well as protection of spruce forests subject to insect attacks.     

An alternative approach for delineating eco-sensitive zones around a wildlife sanctuary applying geospatial techniques

The dynamics, degradation, and conservation of forest ecosystems are matters of prime concerns worldwide at the present. Proper planning and management of a forest area are essentially needed to protect it from the grasp of burgeoning pressure of urban-industrial sprawl. Establishment of eco-sensitive zones (ESZs), which act as buffer areas around the core forests, is one of the key approaches towards achieving this goal. This paper deals with the applicability of geospatial techniques to identify the ESZ around an Indian wildlife sanctuary following the different rules and acts prescribed by the Government of India. Gumti Wildlife Sanctuary, located in the northeastern state of Tripura in India, has been selected here as a case study. Collected pieces of information on the distribution of biodiversity and human population in the area were also used to make the approach more holistic. As inferred from this study, remote sensing and geographical information systems were found to be easily implementable and time as well as cost-effective tools for this purpose with a distinct advantage of spatial as well as temporal accuracy in identifying the existing land use and land cover patterns in pilot assessments. However, the results indicated that only appropriate hybridization of field-based information on the biodiversity and ecological aspects of the forest as well as patterns of human interferences with the remote sensing and GIS-based data could make this approach more relevant in actual implementations.     

Accounting for Active Management and Risk Attitude in Forest Sector Models

Given the importance of anthropogenic determinants in forest ecosystems within Europe, the objective of this paper is to link the evidence arising from biological models to socio-economic determinants, where the expected returns of forest investments represent the main driver. A micro-economic area allocation module is therefore coupled with an inventory-based forest dynamics module and a partial-equilibrium market module in a national-level forest sector model for France (FFSM++). Running long-term scenarios (until 2100), we show the implication of an active management policy on forest composition: when the most profitable option drives forest investments, coniferous forests are generally preferred over broadleaved ones. This result is, however, reappraised when the risk aversion of forest owners is explicitly considered in the model, given the higher risk associated with the former. We further show the strong stability of forest ecosystems that, due to the very long cycles, undergoes very small variations in volume stocks, even in scenarios where the initial forest regeneration is strongly influenced.     

Analyzing riparian forest cover changes along the Firniz River in the Mediterranean City of Kahramanmaras in Turkey

Riparian forests adjacent to surface water are important transitional zones which maintain and enrich biodiversity and ensure the sustainability in a forest ecosystem. Also, riparian forests maintain water quality, reduce sediment delivery, enhance habitat areas for aquatic life and wildlife, and provide ecological corridors between the upland and the downstream. However, the riparian ecosystems have been degraded mainly due to human development, forest operations, and agricultural activities. In order to evaluate the impacts of these factors on riparian forests, it is necessary to estimate trends in forest cover changes. This study aims to analyze riparian forest cover changes along the Firniz River located in Mediterranean city of Kahramanmaras in Turkey. Changes in riparian forest cover from 1989 to 2010 have been determined by implementing supervised classification method on a series of Landsat TM imagery of the study area. The results indicated that the classification process applied on 1989 and 2010 images provided overall accuracy of 80.08 and 75 %, respectively. It was found that the most common land use class within the riparian zone was productive forest, followed by degraded forest, agricultural areas, and other land use classes. The results also indicated that the areas of degraded forest and forest openings increased, while productive forest and agricultural areas decreased between the years of 1989 and 2010. The amount of agricultural areas decreased due to the reduction in the population of rural people. According to these results, it can be concluded that special forest management and operation techniques should be implemented to restore the forest ecosystem in riparian areas.     

Identification of new photoreduction products of pentachlorophenol

Pentachlorophenol (PCP), a fungicide and insecticide, leaves behind considerable residue in the environment in the form of unreacted molecule, metabolites and photoreduction products. Most of the previously reported photoproducts have resulted from dechlorination of the parent molecule. We have shown that photoreduction of PCP also proceeds by photoreduction of the parent molecule at carbons 2 and 4. These products were identified and characterized as 2-dehydro-2,3,4,5,6-pentachlorocyclohexanone (II) and 2,3,4,5,6-pentachlorocyclohexanone (IV). Both of them display keto-enol tautomerism. Identification and characterization of new photoproducts of PCP is significant for determining its overall environmental impact in the ecosystem.     

Artificial intelligence assisted intelligent planning framework for environmental restoration of terrestrial ecosystems

The environmental restoration of terrestrial ecosystems helps to protect the natural world and enhances sustainable land resource development. Modern and efficient approaches for the conservation of ecological functions must be established for more severe land degradation. In this paper, artificial intelligence assisted intelligent planning framework has been proposed to manage the environmental restoration of the terrestrial ecosystem. Facilitating balance of ecosystem service provision, demand, and using machine learning to dynamically build Biological Retreat Configuration (BRCs) that helps better to apprehend the influence of urban growth on environment-related procedures. Such factors can be used as a theoretical reference in the combination of commercial development and eco-friendly conservation. The BRC of the metro area of Changsha Zhuzhou Xiangtan (CZX) has been developed in this study to classify ecological sources using the Bayesian network model efficiently. Using the Least Collective Resistance (LCR) model and circuit theory, the environmental passage and environmental strategy points were established. The BRC was developed by integrating seven environmental factors with 35 ecological policy points. The results showed that the supply and demand of organic unit services (EUS) were spatially decoupled with the deterioration in locations with a significant EUS trend. The urban agglomeration's environmental sources and ecological corridors have been primarily located in forests and waters. The terrestrial environmental pathway has been scattered around the outer edge of the region, while the aquatic green corridor has been extended over the whole town. The environmentally sensitive areas were located primarily around the borders of the growing region and the intersections between land development and forest area. Finally, environmental components have been mainly identified in existing zones of biological defense, which support the effectiveness of Machine Learning (ML) in green sources forecasting and offer novel insight into the development of urban BRCs. The proposed approach has proven to be effective for the planning of assessing environmental restoration in terrestrial ecosystems.     

The use of aerospace methods for forest state assessment

Siberian forests occupy a significant part of the Asian continent. Their role as an essential component of the Earth's surface, biomass and oxygen producer is increasing annually. Expanded reproduction of taiga forests necessitated by the intensive development of Siberian productive forces, results in an evergrowing need of forest productivity constancy and increase. Proper forest exploitation is a crucial part of the solution of such important problems as the rational use of land and water resources, stable crop yields, and the creation of favourable conditions for human life.To solve these important economic problems, the Siberian branch of the USSR Academy of Sciences has devised a long-term programme of ecological monitoring of Siberian forest resources using aerospace techniques. The programme provides for the establishment and improvement of ecogeographical and physicotechnological principles of the remote sensing of forests and the development of fundamental forest-biological research based on new methodologies, the results of which are used to solve urgent forestry and nature protection problems. The research is carried out in the following major directions: studying spectral characteristics of forest vegetation for forest-state indication; thematic mapping of taiga territories; assessing biological productivity of natural complexes; environmental state monitoring; fire protection of forests; pest and disease control; developin instruments and methods for automatized aerospace data processing for real-time use.We consider forest-state monitoring to be one of the crucial tools in providing the optimum use of forest ecosystems for resource and ecological functions.     

A comparative assessment of land cover dynamics of three protected forest areas in tropical eastern Africa

Processes of deforestation, known to threaten tropical forest biodiversity, have not yet been studied sufficiently in East Africa. To shed light on the patterns and causes of human influences on protected forest ecosystems, comparisons of different study areas regarding land cover dynamics and potential drivers are needed. We analyze the development of land cover since the early 1970s for three protected East African rainforests and their surrounding farmlands and assess the relationship between the observed changes in the context of the protection status of the forests. Processing of Landsat satellite imagery of eight or seven time steps in regular intervals results in 12 land cover classes for the Kakamega–Nandi forests (Kenya) and Budongo Forest (Uganda) whereas ten are distinguished for Mabira Forest (Uganda). The overall classification accuracy assessed for the year 2001 or 2003 is similarly high for all three study areas (81% to 85%). The time series reveal that, despite their protection status, Kakamega–Nandi forests and Mabira Forest experienced major forest decrease, the first a continuous forest loss of 31% between 1972/1973 and 2001, the latter an abrupt loss of 24% in the late 1970s/early 1980s. For both forests, the temporally dense time series show short-term fluctuations in forest classes (e.g., areas of forest regrowth since the 1980s or exotic secondary bushland species from the 1990s onwards). Although selectively logged, Budongo Forest shows a much more stable forest cover extent. A visual overlay with population distribution for all three regions clearly indicates a relationship between forest loss and areas of high population density, suggesting population pressure as a main driver of deforestation. The revealed forest losses due to local and commercial exploitation further demonstrate that weak management impedes effective forest protection in East Africa.     

Monitoring Sustainable Forest Management in Different Jurisdictions

The concept of sustainable forest management (SFM) requires forest resource managers to monitor and collect information pertaining to their environmental, economic and social impact. There are increasing expectations from a variety of publics (government, customers, and other stakeholders) that forests be demonstrably well-managed, creating incentives for forest managers to design credible systems for assessing their management performance. It is against this background that local, national and international approaches to regulating forest practices have been evolving. This article reviews the different dimensions of governance as they relate to monitoring and information reporting in the forest sector. Specifically, it discusses the changing role of sovereignty, the effects of globalization and the emergence of civil society stakeholders in forestry-related decision-making. Concepts such as sovereignty and globalization have important implications for monitoring forest practices and for defining SFM. Whether SFM standard creation and enforcement involves a sovereign, shared-sovereignty or civil society approach will affect the level and nature of SFM monitoring. As a result, we need to better consider the concept of monitoring appropriate to the scale and intensity of operations, how monitoring and information reporting standards differ between jurisdictions, and what this means for independently verifying SFM at an inter-jurisdictional level.     

Soil microarthropod communities from Mediterranean forest ecosystems in Central Italy under different disturbances

The aim of this study is to assess soil quality in Mediterranean forests of Central Italy, from evergreen to deciduous, with different types of management (coppice vs. high forest vs. secondary old growth) and compaction impacts (machinery vs. recreational). Soil quality was evaluated studying soil microarthropod communities and applying a biological index (QBS-ar) based on the concept that the higher is the soil quality, the higher will be the number of microarthropod groups well adapted to the soil habitat. Our results confirm that hardwood soils are characterised by the highest biodiversity level among terrestrial communities and by a well-structured and mature microarthropod community, which is typical of stable ecosystems (QBS value, >200). While silvicultural practices and forest composition do not seem to influence QBS-ar values or microarthropod community structure, the index is very efficient in detecting soil impacts (soil compaction due to logging activities). Several taxa (Protura, Diplura, Coleoptera adults, Pauropoda, Diplopoda, Symphyla, Chilopoda, Diptera larvae and Opiliones) react negatively to soil compaction and degradation (QBS value, <150). In particular, Protura, Diplura, Symphyla and Pauropoda, are taxonomic groups linked to undisturbed soil. This index could also be a useful tool in monitoring soil biodiversity in protected areas and in urban forestry to prevent the negative effects of trampling. QBS-ar is a candidate index for biomonitoring of soil microarthropod biodiversity across the landscape to provide guidance for the sustainable management of renewable resource and nature conservation.     

Fluroxypyr biodegradation in soils by multiple factors

Fluroxypyr (4-amino-3,5-dichloro-6-fluoro-2-pyridinyl-1-methylheptyl ester) is a widely used herbicide for controlling weeds, fungi, and insects. However, extensive use of the herbicide has led to its high accumulation in ecosystems and contamination to soils and crops. Environmental behaviors and fate of herbicides are dependent on many physiochemical and biological factors. Whether fluroxypyr is significantly affected and how it is degraded under the environmental conditions is largely unknown. The present study investigated the effects of soil microbe, soil type, dissolved organic matter (DOM), temperature, soil moisture, and surfactant on fluroxypyr degradation in soils. Application of DOM derived from sludge and straw to fluroxypyr-contaminated soils increased degradation of fluroxypyr. Environmental factors such as temperature, moisture, soil microbe and soil type could affect the rate of fluroxypyr dissipation. Also, the microorganism affected the degradation of fluroxypyr. Analysis by gas chromatography-mass revealed that the reaction in soils might include the removal of 1-methylheptyl ester to generate fluroxypyr acid (4-amino-3,5-dichloro-6-fluoro-2-pyridiny). Our results provided initial data that a set of biological and physiochemical factors coordinately regulates the decay of fluroxypyr in soils.     

Landscape approach for quantifying land use land cover change (1972–2006) and habitat diversity in a mining area in Central India (Bokaro, Jharkhand)

The rate and intensity of land use land cover (LULC) change has increased considerably during the past couple of decades. Mining brings significant alterations in LULC specifically due to its impact on forests. Parts of Central India are well endowed with both forests and minerals. Here, the conflict between human interests and nature has intensified over time. Monitoring and assessment of such conflicts are important for land management and policy making. Remote sensing and Geographical Information System have the potential to serve as accurate tools for environmental monitoring. Understanding the importance of landscape metrics in land use planning is challenging but important. These metrics calculated at landscape, class, and patch level provide an insight into changing spatiotemporal distribution of LULC and ecological connectedness. In the present study, geospatial tools in conjunction with landscape metrics have been used to assess the impact of coal mining on habitat diversity. LULC maps, change detection analysis, and landscape metrics have been computed for the four time periods (1972, 1992, 2001, and 2006). There has been a significant decline in forest cover especially of the Sal-mixed forests, both in area as well as quality, due to flouted mining regulations. Reclamation of mined lands has also been observed in some of the areas since 2001.     

Evaluation of soil contamination in intensive agricultural areas by pesticides and organic pollutants: south-eastern Spain as a case study

A comprehensive survey of the occurrence and fate of pesticides and organic contaminants in soils from an intensive agricultural area devoted to horticultural production in plastic-based greenhouses has been performed to determine if the operation under integrated pest management practices has contributed to reduce the levels of these compounds. Almería province (south-eastern Spain) was selected for the case study. 38 agricultural soil samples (each sample corresponds to an independent private greenhouse) of areas working under integrated pest management (IPM) programs have been analyzed in order to evaluate their contamination fate. Sampling was designed to cover an area of about 400 km(2). Pesticides, polycyclic aromatic hydrocarbons (PAHs), polychlorinated biphenyls (PCBs), phenolic compounds and di-(2-ethylhexyl)phthalate (DEHP) were monitored. The obtained results were compared to other studies reported in Spain and Europe. Among relevant persistent pesticides, DDTs and endosulfans were mainly found and the results indicated historical application, although recent application of endosulfan was rarely detected. PAHs were also found but to a lesser extent and derived from pyrogenic sources. DEHP levels were considerably higher in comparison to the other monitored analytes. The evaluation revealed that despite the use of IPM programs, pesticide and organic contaminants are still being detected in this type of agricultural soil, although at relatively low concentration levels. In general, the contamination rate was similar or lower in comparison to other agricultural areas from nearby regions or countries. However, further monitoring studies should be carried out to establish the possible reduction in contamination by the selected compounds.     

An argument for ecosystem level monitoring

One objective of environmental monitoring programs is documentation of qualitative and quantitative environmental changes in response to external stresses, including chemical contamination. Chemical contaminant, biological, and ecological measurements have been used as environmental monitors. Contaminant monitoring allows estimation of exposures; biological and ecological monitoring allow estimation of uptake and effects.Measurements of ecosystem homeostasis such as nutrient cycling processes have been shown to be good ecosystem level monitors. The rate of dissolved nutrient loss from ecosystems has been conclusively shown to increase as a function of chemical contamination until a new equilibrium is reached, the pollutant input has become negligible, or until nutrient pools have been depleted. Consequently, nutrient pools in environmental strata and in biota are altered and eventually depleted by chemical stress.The use of nutrient cycling to determine sensitive responses to and long-term changes for chemical contamination is an essential monitoring strategy for environmental management and compliance purposes. Measurements of export (rapid response) and pools (long-term consequences) are within current technology, are cost-effective, and allow rapid implementation of remedial measures or environmental controls.Paper presented at a Symposium held on 20–21 April 1982, in Edmonton, Alberta, Canada.