喷雾干燥烟气脱硫工艺的物料平衡计算

通过计算实例，介绍喷雾干燥烟气脱硫工艺物料平衡的计算方法。     

湿法脱硫塔内流场温场的CFD分析

利用Fluent软件对脱硫塔内速度场和温度场进行三维数值模拟，并对模拟结果进行较全面的分析。选择k-ε模型作为计算模型，用SIMPLE算法进行计算。计算结果表明脱硫塔形状及喷淋层高度对流场与温场有很大的影响，实际运行中应当低层喷淋与高层喷淋相结合，从而获得更好的脱硫效果。运用CFD理论，对脱硫塔内运行情况进行数值分析，对于脱硫塔的设计和优化具有一定的指导意义。     

湿法脱硫技术关键问题研究

针对我国烟气脱硫存在的实际问题,研究了湿法脱硫关键技术,如多孔板环面积、层数、安装角度、孔径及开孔率,喷淋塔压力降特性等。解决了湿法烟气脱硫过程中关键问题,实现了除雾器的国产化,优化了物料分配技术,降低了脱硫石膏含水率,形成了一整套具有自主知识产权的湿式高性能脱硫技术,并成功应用于多个燃煤电厂商用脱硫工程,取得了显著的经济效益和社会效益。     

脱硫离心喷嘴雾化特性的研究

根据动量守恒原理，分析了脱硫离心喷嘴的结构参数与喷嘴雾化特性(流量系数、喷雾角等)之间的关系。建立了相应的无粘理论计算模型。将理论计算结果与实验数据进行比较，表明该无粘理论计算模型对脱硫喷嘴雾化特性的研究具有一定的参考价值。     

蒸汽输送半干半湿法烟气脱硫剂/脱硫灰的研究

半干半湿法烟气脱硫工艺采用锅炉蒸汽作为脱硫剂和循环脱硫灰的输送介质,在分析所输送物料的粒度分布、化学成分以及输送过程中物料性质变化的基础上,自行研制了1套蒸汽输送系统。对这种蒸汽输送系统进行了试验研究,结果表明,在蒸汽压力为0.8MPa,温度为200℃时,文丘里喷射器入料口的真空度最高达0.02MPa。该系统可同时输送石灰和粉煤灰两种不同的物料,在蒸汽消耗量只有120 kg/h的条件下,物料总流量达480 kg/h,输送总体积流量为1 040m3/h。     

专利资讯

正专利名称:一种再生橡胶脱硫装置专利申请号:CN201620886920.2公开号:CN205893146U申请日:2016.08.16公开日:2017.01.18申请人:福建省邵武市恒晖橡胶再生有限公司本实用新型提供一种物料搅拌均匀,不易形成盲区,且能有效将粘在脱硫罐体进口端侧壁上的物料刮下来的再生     

乙烯废碱液的ZnO沉淀法脱硫过程优化与动力学研究

采用ZnO沉淀法对乙烯废碱液进行脱硫,通过正交实验确定的最佳工艺条件为:反应温度80～85℃,n(ZnO)∶n(Na2S)=0.9,反应时间150min。在上述最佳工艺条件下,废碱液脱硫率和ZnS质量分数可分别达88%和95%以上。动力学研究结果表明,ZnO沉淀法的脱硫速率可用简化的Na2S浓度的幂函数模型描述,该模型的Na2S转化率计算值与实验值吻合良好。     

湿法脱硫液柱空塔流场数值模拟

利用Fluent软件对一种脱硫塔顺流、逆流及混流喷淋的液柱塔空塔的流场进行三维数值模拟。在计算中选择κ-ε模型作为计算模型。用SIMPLE算法进行计算。计算结果表明，液柱塔形状对流场有很大的影响，此结果对现场运行以及液柱塔的优化设计有一定的指导作用。     

烟气脱硫吸收塔总体结构计算方法

研究了火电厂烟气脱硫吸收塔总体结构，分析了吸收塔各种荷载对结构计算的影响，运用国内有关标准规范计算吸收塔壳体厚度，为脱硫行业吸收塔的总体结构计算提供参考。     

喷雾液滴在容器气流中的运动分析与计算

对喷雾干燥脱硫中液滴在具有气流的竖立容器内的运动情况进行了分析，提出了有关计算式，为喷雾干燥脱硫容器和其他类似容器的设计提供了较为科学的计算依据。     

上海市生活垃圾处置计划量指标测算模型初探

对生活垃圾处置计划管理政策的意义、生活垃圾处置计划指标测算模型建立的意义和作用进行分析,对建立模型的因素、计算公式、计算流程等进行详细说明,并对3个典型区县的实际情况进行了计算和分析,总结了模型存在的问题和完善方向。     

湿法脱硫改造条件下烟囱防腐的若干技术问题

叙述了扬州二电厂一期脱硫改造过程中烟囱配套的防腐方案,防腐材料选用过程,以及施工过程中的工艺要求,对电站现役机组进行湿法脱硫改造条件下烟囱的防腐技术方案选用和施工有一定的借鉴意义.     

Commercialization of Dredged-Material Decontamination Technologies

This article describe a unique federal project aimed at the commercialization of different technologies for the decontamination of dredged material. The project is organized so that commercialization is achieved in a seamless way, starting with validation at the bench- and pilot-scale levels, and ending with the actual construction of operational facilities. This is the first integrated sediment decontamination program in which a step-wise bench-scale validation process of innovative/emerging technologies will scale-up to a production-scale facility capable of processing up to 375,000 m³ of dredged material per year. The need to develop public-private partnerships for the facility construction is emphasized as a way of obtaining adequate finding for capital and operating costs during the startup time of the commercialization process. It is expected that the end result of the project work will be the creation of economically-viable, self-sustaining decontamination technology companies.     

Trends in waste plastics and recycling

Zero emission is an ambitious project aimed at the conversion of the conventional top-down or one-directional flow type production systems of modern society to those of a recycling type. The basic idea underlying this project is to understand in detail the material flow mechanism in a particular segment of society and to evaluate the transformability of the hitherto one-directional types of process into recycling types. The authors, members of the Zero-Emission Research Group of Japan, are investigating the material flow of plastics in Japan. The present work describes the features of this project, as well as the results obtained so far. Received: May 28, 1998 / Accepted: October 16, 1998     

大型磷铵工程磷石膏制硫酸联产水泥装置的三废治理及利用

介绍了大型磷铵工程磷石膏制硫酸联产水泥装置排出的废水，废气和废渣的利用及治理情况，并对生产过程的磷、硫和氟的转化及损失量进行了衡算。     

A new approach to estimation of methane emission rates from landfills

Methane emission monitoring has become increasingly essential for diffusive area sources, especially for landfills, which contribute to a significant fraction of the total anthropogenic methane emission globally. Statutorily, methane emission rate from landfills in Germany shall be examined on a semiannual basis; however, an appropriate approach has yet to be developed and adopted for general use. In this study, a new method is proposed based on experimental results, which utilizes a TDLAS (Tunable Diode Laser Absorption Spectroscopy) instrument – GasFinder2.0® system and a dispersion model LASAT (Lagrangian Simulation of Aerosol Transport) as the measurement device and calculation model, respectively. Between April 2010 and December 2011, a research project was conducted at a pilot scale landfill in the south of Germany. Drawing on the extensive research into this pilot project, an effective strategy of measurement setup was determined. Methane concentration was measured with GasFinder2.0® system in the upstream and downstream sections of the project site, while wind and turbulence data were measured simultaneously by an ultrasonic anemometer. The average methane emission rate from the source can be calculated by using the results as input data in the dispersion model. With this method, site-specific measurement approaches can be designed for not only landfills, but also different diffusive area sources with less workload and lower cost compared to conventional FID (Flame Ionization Detector) method.     

Exploration of urban deposits: long-term prospects for resource and waste management.

Many materials currently in use are potentially available to become raw materials for future production if the materials are recycled instead of discarded as solid waste. However, the structure and life-expectancy of these secondary resources have not been sufficiently examined, and comprehensive methods for forecasting the availability of such materials are still lacking. This study presents a method for identifying anthropogenic material stocks in combination with the method of material flow analysis (MFA). The method was applied to copper in Switzerland as an example, with the focus on use in buildings. The exploration concept was a three-step process. First, a MFA identified the relevant stocks within the inventory of the region. Second, these stocks were inventoried through a building stock model and determination of key parameters that were defined by surveying selected buildings and from the literature. Third, the study team developed a dynamic MFA model to describe the copper stocks and flows during the period 1900-2000. The results of the copper stock calculation (in kg capita(-1)) were: buildings 79 +/- 11, infrastructure 107 +/- 25, movables 34 +/- 9, landfills 50 +/- 12. The calibrated model enabled the study team to develop resource and waste management scenarios forecasting waste flows. It is shown that the conversion of buildings into other uses may affect the waste flows significantly.     

高分子除氯剂对水中氯离子的吸附机理

采用高分子除氯剂吸附水中的氯离子,考察了除氯剂投加量、反应时间、反应温度、竞争离子等对氯离子去除率的影响。实验结果表明:随着除氯剂投加量增加,氯离子去除率不断提高;吸附动力学符合拟二级动力学模型,表明化学吸附可能是氯离子吸附过程的速率控制步骤;Elovich模型表明除氯剂表面吸附的氯离子存在非均相扩散的吸附-脱附过程;Freundlich等温吸附模型能更好地描述吸附过程,结合热力学计算表明该过程是一个自发进行的吸热熵增的化学吸附过程,温度越高自发程度越大。     

A multi-component two-phase flow algorithm for use in landfill processes modelling

This paper describes the finite difference algorithm that has been developed for the flow sub-model of the University of Southampton landfill degradation and transport model LDAT. The liquid and gas phase flow components are first decoupled from the solid phase of the full multi-phase, multi-component landfill process constitutive equations and are then rearranged into a format that can be applied as a calculation procedure within the framework of a three dimensional array of finite difference rectangular elements.The algorithm contains a source term which accommodates the non-flow landfill processes of degradation, gas solubility, and leachate chemical equilibrium, sub-models that have been described in White and Beaven (2013).The paper includes an illustration of the application of the flow sub-model in the context of the leachate recirculation tests carried out at the Beddington landfill project. This illustration demonstrates the ability of the sub-model to track movement in the gas phase as well as the liquid phase, and to simulate multi-directional flow patterns that are different in each of the phases.     

Characterization and modelling of the heat transfers in a pilot-scale reactor during composting under forced aeration

The paper focused on the modelling of the heat transfers during composting in a pilot-scale reactor under forced aeration. The model took into account the heat production and the transfers by evaporation, convection between material and gas crossing the material, conduction and surface convection between gas and material in bottom and upper parts of the reactor. The model was adjusted thanks to the measurements practised during fifteen composting experiments in which five organic wastes were, each, composted under three constant aeration rates. Heat production was considered proportional to oxygen consumption rate and the enthalpy per mole oxygen consumed was assumed constant. The convective heat transfer coefficients were determined on basis of the continuous measurements of the temperatures of both the lid and the bottom part of the reactor. The model allowed a satisfying prediction of the temperature of the composting material. In most cases, the mean absolute discard between the experimental and the simulated temperatures was inferior to 2.5°C and the peaks of temperature occurred with less than 8h delay. For the half of the experiments the temperature discard between the simulated peak and the experimental one was inferior to 5°C. On basis of the calculation of a stoichiometric production of water through oxidation of the biodegradable organic matter, the simulation of water going out from material as vapour also allowed a rather satisfying prediction of the mass of water in final mixture. The influence of the aeration rate on every type of heat loss was characterized. Finally, the model was used to evaluate the impacts on material temperature caused by the change of the insulation thickness, the ambient temperature, take the lid away, the increase or the decrease of the mass of waste to compost.