流域水质监测站对江河重大污染事故的应急监测措施的研究

流域水质监测站对发生在江河中的重大水质污染事故中承担着前哨的重要作用.因此,建立起江河重大污染事故的应急监测体系已迫在眉睫.本文结合多年来松花江水质监测的实际工作,对环境水质监测部门开展重大污染事故应惠监测措施研究的必要性、应急监测工作必需的配置、预警监测断面在应急监测中的功能与作用等进行了较全面的论述.指出,应加大江河水环境监测的投入,切实加强水环境应急监测工作,尽快建成主要江河应急防控体系,提高江河重大污染事件的预警预测、监测、处置、后期评估等方面能力与水平.     

化工企业突发性环境污染事故的应急监测

化工企业突发性环境污染事故,具有污染毒性大,危害性强,后果严重等特性,及时有效地开展应急监测,可为应急处置和救援提供有力的保障。该文从前期准备、现场监测、数据上报等方面,探讨了如何做好应急监测工作。     

流域水质监测站对江河重大污染事故的应急监测措施的研究

流域水质监测站对发生在江河中的重大水质污染事故中承担着前哨的重要作用。因此，建立起江河重大污染事故的应急监测体系已迫在眉睫。本文结合多年来松花江水质监测的实际工作，对环境水质监测部门开展重大污染事故应急监测措施研究的必要性、应急监测工作必需的配置、预警监测断面在应急监测中的功能与作用等进行了较全面的论述。指出，应加大江河水环境监测的投入，切实加强水环境应急监测工作，尽快建成主要江河应急防控体系，提高江河重大污染事件的预警预测、监测、处置、后期评估等方面能力与水平。     

突发性环境污染事故应急监测方案探讨

通过对有关应急监测方案的探讨和总结,提出了应急监测方案的内容应包括:应急监测程序、应急监测组织机构、应急监测技术和设备、应急监测信息系统、后勤系统。总结了目前常用的应急监测技术和方法。提出在突发性污染事故发生时应如何开展应急监测。     

试论化学污染事故中的环境应急检测

化学污染事故对环境监测管理实施影响恶劣,当前我国环境建设工作开展,对化学污染工作处置提出了新要求,要求严格按照监测工作实施要求,进行事故应急处理。本文针对试论化学污染事故中的环境应急检测进行了研究,旨在能够为化学污染事故处理中的环境应急检测工作实施提供参考。     

突发性环境污染事故应急监测信息支持系统

丹东市突发性环境污染事故应急监测信息支持系统，是由危险源、危险物和地理信息等子系统组成。系统包含了危险源的数量、分布，危险物的种类、危险特性、监测方法、处置技术等信息，应用实践证明。该系统在污染事故的监测和处置过程中，具有很强的实用性。     

应急监测分析方法存在的问题及建议

环境污染事故应急监测工作是处置突发性环境污染事故的前提和保证,而应急监测分析方法则是开展环境污染事故应急监测工作的基础和手段.通过对中国环境应急监测分析方法的现状、使用情况的阐述,同时结合三个实际案例,指出了存在的主要问题;并针对性的提出了建立和完善环境监测分析方法体系、对现有环境监测分析方法进行技术分级、重视应急监测期间的质量保证/质量控制(QA/QC)工作、加强监测人员应急监测技术培训等四点建议.     

浅谈突发性环境污染事故应急监测要求

阐述了应急监测在污染事故中的关键作用,建立先进的环境应急监测预警体系,完善事故应急预案,做好应急监测的准备,提高应急处置能力是及时有效处理突发性环境污染事故的首要环节,通过说明应急监测的不足与发展,提出了在应急监测和现场处理中的建议和要求。     

河流环境污染事件的应急监测与处置

结合一起具体河流污染事件,研究了河流污染的应急监测处置方法。河流污染环境应急中,对事故点位水质进行现场定性定量分析,了解污染物种类与浓度。在河流上下游布设监测点位,明确污染程度和污染范围。边监测边进行应急处置,减轻污染物扩散。     

如何做好突发环境事件应急监测的快速响应

应急监测是突发性环境污染事故处置中的首要环节,是对污染事故及时、正确地进行应急处理、减轻事故危害和制定恢复措施的根本依据。文章从制定应急监测预案、加强应急监测能力建设、摸清污染源状况、加强应急培训和应急演练等方面对做好突发环境事件应急监测的快速响应作了简要的阐述,供大家探讨。     

Distribution and ecological effect of mercury in Laogang landfill, Shanghai, China

Laogang landfill near Shanghai is the largest landfill in China, and receives about 10000 t of daily garbage per day, Samples of topsoil and plants were analyzed to evaluate mercury pollution from the landfill. For topsoil samples, there were significant correlations among total mercury （HgT）, combinative mercury （Hgc） and gaseous mercury （HgG）, and content of total organic carbon （TOC）, but, no significantly relationship was found between Hg content and filling time. Hg content changes in vertical profiles with time showed that the average Hgv of profiles 1992, 1996, and 2000 was similar, but their average HgG was quite different. HgT was significantly correlated with Hgc in profile 1992 and 2000, and Hgv was significantly correlated with Hg6 in profile 1996. HgG/Hgv ratio in profile samples decreased in the order of （HgG,/HgT）1992〉（HgG/HgT）1996〉〉（HgG/HgT）2000. A simple outline of Hg release in landfill could be drawn： with increasing of filling time, degradation undergoes different biodegradation, accordingly, gaseous mercury goes through small, more, and small proportion to total mercury. Distribution of Hg in plants was inhomogeneous, following the order of leaf〉root〉stem. The highest value of leaf may be associated with higher atmospheric Hg from landfill. Ligneous plants （e.g. Phyllostachys glanca, Prunus salicina and Ligustrum lucidum） are capable of enriching more Hg than herbaceous plants.     

EDTA-enhanced phytoremediation of lead contaminated soil by Bidens maximowicziana

Phytoremediation is a potential cleanup technology for the removal of heavy metals from contaminated soils.Bidens maximowicziana is a new Pb hyperaccumulator,which not only has remarkable tolerance to Pb but also extraordinary accumulation capacity for Pb.The maximum Pb concentration was 1509.3 mg/kg in roots and 2164.7 mg/kg in overground tissues.The Pb distribution order in the B. maximowicziana was:leaf>stem>root.The effect of amendments on phytoremediation was also studied.The mobility of soil Pb and the Pb concentrations in plants were both increased by EDTA application.Compared with CK(control check),EDTA application promoted translocation of Pb to overground parts of the plant.The Pb concentrations in overground parts of plants was increased from 24.23-680.56 mg/kg to 29.07-1905.57 mg/kg.This research demonstrated that B.maximowicziana appeared to be suitable for phytoremediation of Pb contaminated soil,especially,combination with EDTA.     

Decomposition of alachlor by ozonation and its mechanism

Decomposition and corresponding mechanism of alachlor, an endocrine disruptor in water by ozonation were investigated. Results showed that alachlor could not be completely mineralized by ozone alone. Many intermediates and final products were formed during the process, including aromatic compounds, aliphatic carboxylic acids, and inorganic ions. In evoluting these products, some of them with weak polarity were qualitatively identified by GC-MS. The information of inorganic ions suggested that the dechlorination was the first and the fastest step in the ozonation of alachlor.     

Enzymatic oxidation of aqueous pentachlorophenol

The influence of the nonionic surfactant Tween 80 on pentachlorophenol （PCP） oxidation catalyzed by horseradish peroxidase was studied. The surfactant was tested at concentrations below and above its critical micelle concentration （CMC）. Enhancement of PCP removal was observed at sub-CMCs. The presence of Tween 80 in the reaction mixture reduced enzyme inactivation which occurred through a combination of free radical attack and sorption by precipitated products. A simple first-order model was able to simulate time profiles for enzyme inactivation in the presence or absence of Tween 80. At supra-CMCs, the surfactant caused noticeable reductions in PCP removal, presumably through micelle partitioning of PCP which precluded the hydrophobic PCP molecule from interacting with the enzyme.     

基于综合水质标识指数和对应分析法的校园河道水质评价

以三峡大学的校园河道求索溪为研究对象,利用综合水质标识指数法确定求索溪水质类别,分析其水质时空变化规律,并利用对应分析法得出求索溪中不同监测点的主要污染因子.研究结果表明:求索溪整体的综合水质标识指数为7.423,整体水质为劣V类(地表水环境质量标准GB 3838-2002)且黑臭.从时间变化来看,求索溪4月份的水质最差,5月份次之,4、5月份所有监测点的水质都劣于V类且黑臭;8月份水质最好,水质为Ⅳ类;从空间分布来看,8个监测点综合水质标识指数均超过6.0,水质为劣V类,其中6号监测点的水质相对最好,监测点3号的水质相对最差;对应分析法得出求索溪的整体水体污染程度受总氮因子的影响最大,其次为总磷.该研究拟为求索溪及类似校园河道的水环境治理研究提供基础依据和参考.     

Effects of chitosan on growth of an aquatic plant (Hydrilla verticillata) in polluted waters with different chemical oxygen demands

Effects of chitosan on a submersed plant, Hydrilla verticillata, were investigated. Results indicated that H. venicillata could prevent ultrastructure phytotoxicities and oxidativereaction from polluted water with high chemical oxygen demand (COD). Superoxide dismutase (SOD) activity and malondialdehyde (MDA) contents in H. verticillata treated with 0.1% chitosan in wastewater increased with high COD (980 mg/L) and decreased with low COD (63 mg/L), respectively. Ultrastructural analysis showed that the stroma and grana of chloroplast basically remained normal. However, plant cells from the control experiment (untreated with chitosan) were vacuolated and the cell interval increased. The relict of protoplast moved to the center, with cells tending to disjoint. Our findings indicate that wastewater with high COD concentration can cause a substantial damage to submersed plant, nevertheless, chitosan probably could alleviate the membrane lipid peroxidization and ultrastructure phytotoxicities, and protect plant cells from stress of high COD concentration polluted water.     

Removal of cadmium using MnO2 loaded D301 resin

MnO2 loaded weak basic anion exchange resin D301 （Anion exchange resin, macroreticular weak basic styrene） as adsorbent has been prepared and applied to the removal of cadmium. The adsorption characteristics have been investigated with respect to effect of pH, equilibrium isotherms, removal kinetic data, and interference of the coexisting ions. The results indicated that the Cd^2＋ could be efficiently removed using MnO2 loaded D301 resin in the pH range of 3-8 from aqueous solutions with the co-existence of high concentration of alkali and alkaline-earth metals ions. The saturate adsorption capacity of the Cd^2＋ was 77.88 mg/g. The adsorption process followed the pseudo first-order kinetics. The equilibrium data obtained in this study accorded excellently with the Langmuir adsorption isotherm.     

Effect of coagulation pretreatment on the fouling of ultrafiltration membrane

The purpose of this study is to understand the effect and mechanism of preventing membrane fouling, by coagulation pretreatment, in terms of fractional component and molecular weight of natural organic matter （NOM）. A relatively higher molecular weight （MW） of hydrophobic compounds was responsible for a rapid decline in the ultrafiltration flux. Coagulation could effectively remove the hydrophobic organics, resulting in the increase of flux. It was found that a lower MW of neutral hydrophilic compounds, which could remove inadequately by coagulation, was responsible for the slow declining flux. The fluxes in the filtration of coagulated water and supernatant water were compared and the results showed that a lower MW of neutral hydrophilic compounds remained in the supernatant water after coagulation could be rejected by a membrane, resulting in fouling. It was also found that the coagulated flocs could absorb neutral hydrophilic compounds effectively. Therefore, with the coagulated flocs formed on the membrane surface, the flux decline could be improved.     

Penetration analysis of elements and bioleaching treatment of spent refractory for recycling

Acidithiobacillus ferrooxidans ATCC23270 and Acidithiobacillus thiooxidans TM-32 were used for bioleaching of spent refractories of aluminium and copper melting furnaces for their recycling.Firstly,penetration of elements into aluminium melting furnace refractory was investigated and it was found that up to 7 cm from surface was contaminated.Comparison on leaching efficiency by the strains ATCC23270 and TM-32 found that the strain ATCC23270 could treat larger amount of the refractories than the strain TM-32 could do.In the experiment of bioleaching of spent refractory aluminium melting furnace by the strain ATCC23270,high leaching efficiency were obtained on Al,Si,and Ca,and extremely low leaching performance was,however,shown on the rest of elements i.e.,Na,Mn,and Zn.Under the strain TM-32 use,relatively high leaching performance was recognized on Al,Si,Ca,Na,Mn,and Zn.In the experiment of bioleaching for spent refractory copper melting furnace,almost the same leaching trends were shown on Cu,Zn,Al,and Si under the strains ACTT23270 and TM-32 uses.     

Simultaneous removal of ammonium and phosphate by zeolite synthesized from coal fly ash as influenced by acid treatment

Zeolite synthesized from fly ash （ZFA） without modification is not efficient for the purification of NH4＋ and phosphate at low concentrations that occur in real effluents, despite the high potential removal capacity. To develop an effective technique to enhance the removal efficiency of ammonium and phosphate at low concentrations, ZFA was modified with acid treatment and the simultaneous removal of ammonium and phosphate in a wide range of concentration was investigated. It was seen that when compared with untreated ZFA, only the treatment by 0.01 mol/L of H2SO4 significantly improved the removal efficiency of ammonium at low initial concentrations. The behavior was well explained by the pH effect. Treatment by more concentrated H2SO4 led to the deterioration of the ZFA structure and a decrease in the cation exchange capacity. Treatment by 0.01 mol/L H2SO4 improved the removal efficiency of phosphate by ZFA at all initial P concentrations, while the treatment by concentrated H2SO4 （≥0.9 mol/L） resulted in a limited maximum phosphate immobilization capacity （PIC）. It was concluded that through a previous mild acid treatment （e.g. 0.01 mol/L of H2SO4）, ZFA can be used in the simultaneous removal of NH4＋ and P at low concentrations simulating real effluent.