沈阳市八达能源技术研究所 沈阳八达能源环保科技发展有限公司

沈阳市八达能源技术研究所是专业从事节能、环保和清洁生产等系统集成研究的科技研发型企业,主要致力于耗能系统的综合规律性探求和问题解决、节能环保系统设计、产品开发、故障诊断、生产设备工艺难题咨询、性能参数测试、技术服务。沈阳八达能源环保科技发展有限公司是集节能环保产品生产、技术实施、销售服务为一体的科技生产型企业。     

沈阳市八达能源技术研究所 沈阳八达能源环保科技发展有限公司

沈阳市八达能源技术研究所是专业从事节能、环保和清洁生产等系统集成研究的科技研发型企业,主要致力于耗能系统的综合规律性探求和问题解决、节能环保系统设计、产品开发、故障诊断、生产设备工艺难题咨询、性能参数测试、技术服务。沈阳八达能源环保科技发展有限公司是集节能环保产品生产、技术实施、销售服务为一体的科技生产型企业。     

冀中能源峰峰集团清洁生产工作的实践与创新

开展清洁生产环保对标工作是峰峰集团实现建设绿色矿区、和谐矿区、富强矿区的重要途径,为了实现企业经济结构转变、提高企业污染防治水平、提高企业资源综合利用,峰峰集团从2008年至今,紧紧围绕国家清洁生产环保先进水平的标准,全面推行实施清洁生产审核,开展了在资源综合高效利用、降低污染物排放等方面的环保对标和实践工作,＂废物＂资源利用指标也达到了国内同行业清洁生产先进水平,通过清洁生产环保对标工作的实施,不仅改善了环境,实现了绿色开采,同时又促进了企业的和谐发展、科学发展。     

中国清洁生产科学研究技术开发与推广的问题与对策

一、清洁生产概念提到环境保护,使人马上想到污染治理,即处理处置废水、废气、固体废弃物、嗓声等污染,这种对污染物的常规治理被形象地称为“尾部”控制,如今,许多国家正在设法改变这种消极被动的办法,改为“源头”控制,即采用即有利于环境,又有利于经济的积极主动的“清洁技术”.清洁生产——采用清洁技术的生产活动,从严格意义上讲,是指在工艺和技术上使生产过程不产生废物,这在实际上是不可能的.因此,清洁生产的合理含义是采用能够降低能源、资源消耗,并有效地阻止污染物和其它废物产生的工艺和技术的生产过程.实现清洁生产,不仅可使产品在生产中尽量产生的工艺和技术的生产过程.实现清洁生产,不仅可使产品在生产中尽量减少能源和资源的消耗,减少有害于环境的副产品的产生,而且可使产品在使用期终结时,容易被处理处置,使其对环境的影响减少到最小.     

环境影响评价中清洁生产分析要点及方法

通过实施清洁生产,不仅可以减少甚至消除污染物的排放,而且能够节约大量能源和原材料、降低废物处理和处置费用,从而在经济上有助于提高生产效率和产品质量,降低生产成本,使产品在市场上具有竞争力。清洁生产的污染预防思想是一种“源头控制”的环境战略,将清洁生产的内容纳入环境影响评价中,将提高环境影响评价的作用,有利于项目采用资源利用率高和产生少量污染物的技术、工艺和设备。因此,清洁生产理论可促进环境影响评价进一步拓展和深化,避免环境影响评价失去真实性、有效性。同时,清洁生产分析可以强化人们的环保措施,提高人们的环保意识。     

甲基叔丁基醚生产的清洁生产分析评价

清洁生产是我国实施可持续发展的主要举措,清洁生产分析评价也是环境影响评价中的重要组成部分。以某甲基叔丁基醚生产企业为例,主要从生产工艺与装备、资源与能源利用、产品、污染物产生、废物回收利用等方面,对企业的清洁生产水平进行评价,以期为同类项目环境影响评价中清洁生产的编写提供一些思路。     

甘蔗制糖业清洁生产技术指标体系

实施清洁生产是保证甘蔗制糖业可持续发展的根本途径。本文在分析国内外甘蔗制糖生产技术水平的基础上,结合我国甘蔗制糖业的工艺特点、污染特征,按照清洁生产的要求,提出甘蔗制糖企业的清洁生产技术指标体系,该体系包括资源能源利用、产品、污染物产生、生产工艺与装备、废物回收利用和环境管理共6个方面的评价指标。     

甘蔗制糖业清洁生产技术指标体系

实施清洁生产是保证甘蔗制糖业可持续发展的根本途径。本文在分析国内外甘蔗制糖生产技术水平的基础上，结合我国甘蔗制糖业的工艺特点、污染特征，按照清洁生产的要求，提出甘蔗制糖企业的清洁生产技术指标体系，该体系包括资源能源利用、产品、污染物产生、生产工艺与装备、废物回收利用和环境管理共6个方面的评价指标。     

清洁生产审核在果汁企业的应用研究

中国是全球最大的浓缩苹果汁生产和出口国,年产量和出口量均占全球总量的60%左右,均位居世界第一。中国浓缩果汁行业高速发展的同时,严峻的行业环境问题严重限制了中国浓缩果汁行业的进一步发展[1]。企业实施清洁生产审核是企业实现清洁生产最有效的手段.实践表明,通过实施清洁生产审核活动,企业提高了资源能源利用效率,降低了环境污染,取得了经济和环境的同步发展,为浓缩果汁企业今后的清洁生产审核积累了经验。     

燃煤电厂清洁生产审核应用探讨

作为国家明确要求开展清洁生产审核行业之一,某燃煤电厂依据清洁生产审核思路,从原辅料和能源、技术工艺、过程控制、设备、管理、员工、产品、废物生产过程的八个方面,按照审核准备、预审核、审核、方案产生和筛选、方案确定、方案实施、持续清洁生产七个实施阶段在企业内部开展清洁生产审核工作,实现了本轮清洁生产目标,并取得了显著的环境效益和经济效益。     

Distribution and ecological effect of mercury in Laogang landfill, Shanghai, China

Laogang landfill near Shanghai is the largest landfill in China, and receives about 10000 t of daily garbage per day, Samples of topsoil and plants were analyzed to evaluate mercury pollution from the landfill. For topsoil samples, there were significant correlations among total mercury （HgT）, combinative mercury （Hgc） and gaseous mercury （HgG）, and content of total organic carbon （TOC）, but, no significantly relationship was found between Hg content and filling time. Hg content changes in vertical profiles with time showed that the average Hgv of profiles 1992, 1996, and 2000 was similar, but their average HgG was quite different. HgT was significantly correlated with Hgc in profile 1992 and 2000, and Hgv was significantly correlated with Hg6 in profile 1996. HgG/Hgv ratio in profile samples decreased in the order of （HgG,/HgT）1992〉（HgG/HgT）1996〉〉（HgG/HgT）2000. A simple outline of Hg release in landfill could be drawn： with increasing of filling time, degradation undergoes different biodegradation, accordingly, gaseous mercury goes through small, more, and small proportion to total mercury. Distribution of Hg in plants was inhomogeneous, following the order of leaf〉root〉stem. The highest value of leaf may be associated with higher atmospheric Hg from landfill. Ligneous plants （e.g. Phyllostachys glanca, Prunus salicina and Ligustrum lucidum） are capable of enriching more Hg than herbaceous plants.     

EDTA-enhanced phytoremediation of lead contaminated soil by Bidens maximowicziana

Phytoremediation is a potential cleanup technology for the removal of heavy metals from contaminated soils.Bidens maximowicziana is a new Pb hyperaccumulator,which not only has remarkable tolerance to Pb but also extraordinary accumulation capacity for Pb.The maximum Pb concentration was 1509.3 mg/kg in roots and 2164.7 mg/kg in overground tissues.The Pb distribution order in the B. maximowicziana was:leaf>stem>root.The effect of amendments on phytoremediation was also studied.The mobility of soil Pb and the Pb concentrations in plants were both increased by EDTA application.Compared with CK(control check),EDTA application promoted translocation of Pb to overground parts of the plant.The Pb concentrations in overground parts of plants was increased from 24.23-680.56 mg/kg to 29.07-1905.57 mg/kg.This research demonstrated that B.maximowicziana appeared to be suitable for phytoremediation of Pb contaminated soil,especially,combination with EDTA.     

Decomposition of alachlor by ozonation and its mechanism

Decomposition and corresponding mechanism of alachlor, an endocrine disruptor in water by ozonation were investigated. Results showed that alachlor could not be completely mineralized by ozone alone. Many intermediates and final products were formed during the process, including aromatic compounds, aliphatic carboxylic acids, and inorganic ions. In evoluting these products, some of them with weak polarity were qualitatively identified by GC-MS. The information of inorganic ions suggested that the dechlorination was the first and the fastest step in the ozonation of alachlor.     

Enzymatic oxidation of aqueous pentachlorophenol

The influence of the nonionic surfactant Tween 80 on pentachlorophenol （PCP） oxidation catalyzed by horseradish peroxidase was studied. The surfactant was tested at concentrations below and above its critical micelle concentration （CMC）. Enhancement of PCP removal was observed at sub-CMCs. The presence of Tween 80 in the reaction mixture reduced enzyme inactivation which occurred through a combination of free radical attack and sorption by precipitated products. A simple first-order model was able to simulate time profiles for enzyme inactivation in the presence or absence of Tween 80. At supra-CMCs, the surfactant caused noticeable reductions in PCP removal, presumably through micelle partitioning of PCP which precluded the hydrophobic PCP molecule from interacting with the enzyme.     

基于综合水质标识指数和对应分析法的校园河道水质评价

以三峡大学的校园河道求索溪为研究对象,利用综合水质标识指数法确定求索溪水质类别,分析其水质时空变化规律,并利用对应分析法得出求索溪中不同监测点的主要污染因子.研究结果表明:求索溪整体的综合水质标识指数为7.423,整体水质为劣V类(地表水环境质量标准GB 3838-2002)且黑臭.从时间变化来看,求索溪4月份的水质最差,5月份次之,4、5月份所有监测点的水质都劣于V类且黑臭;8月份水质最好,水质为Ⅳ类;从空间分布来看,8个监测点综合水质标识指数均超过6.0,水质为劣V类,其中6号监测点的水质相对最好,监测点3号的水质相对最差;对应分析法得出求索溪的整体水体污染程度受总氮因子的影响最大,其次为总磷.该研究拟为求索溪及类似校园河道的水环境治理研究提供基础依据和参考.     

Effects of chitosan on growth of an aquatic plant (Hydrilla verticillata) in polluted waters with different chemical oxygen demands

Effects of chitosan on a submersed plant, Hydrilla verticillata, were investigated. Results indicated that H. venicillata could prevent ultrastructure phytotoxicities and oxidativereaction from polluted water with high chemical oxygen demand (COD). Superoxide dismutase (SOD) activity and malondialdehyde (MDA) contents in H. verticillata treated with 0.1% chitosan in wastewater increased with high COD (980 mg/L) and decreased with low COD (63 mg/L), respectively. Ultrastructural analysis showed that the stroma and grana of chloroplast basically remained normal. However, plant cells from the control experiment (untreated with chitosan) were vacuolated and the cell interval increased. The relict of protoplast moved to the center, with cells tending to disjoint. Our findings indicate that wastewater with high COD concentration can cause a substantial damage to submersed plant, nevertheless, chitosan probably could alleviate the membrane lipid peroxidization and ultrastructure phytotoxicities, and protect plant cells from stress of high COD concentration polluted water.     

Removal of cadmium using MnO2 loaded D301 resin

MnO2 loaded weak basic anion exchange resin D301 （Anion exchange resin, macroreticular weak basic styrene） as adsorbent has been prepared and applied to the removal of cadmium. The adsorption characteristics have been investigated with respect to effect of pH, equilibrium isotherms, removal kinetic data, and interference of the coexisting ions. The results indicated that the Cd^2＋ could be efficiently removed using MnO2 loaded D301 resin in the pH range of 3-8 from aqueous solutions with the co-existence of high concentration of alkali and alkaline-earth metals ions. The saturate adsorption capacity of the Cd^2＋ was 77.88 mg/g. The adsorption process followed the pseudo first-order kinetics. The equilibrium data obtained in this study accorded excellently with the Langmuir adsorption isotherm.     

Effect of coagulation pretreatment on the fouling of ultrafiltration membrane

The purpose of this study is to understand the effect and mechanism of preventing membrane fouling, by coagulation pretreatment, in terms of fractional component and molecular weight of natural organic matter （NOM）. A relatively higher molecular weight （MW） of hydrophobic compounds was responsible for a rapid decline in the ultrafiltration flux. Coagulation could effectively remove the hydrophobic organics, resulting in the increase of flux. It was found that a lower MW of neutral hydrophilic compounds, which could remove inadequately by coagulation, was responsible for the slow declining flux. The fluxes in the filtration of coagulated water and supernatant water were compared and the results showed that a lower MW of neutral hydrophilic compounds remained in the supernatant water after coagulation could be rejected by a membrane, resulting in fouling. It was also found that the coagulated flocs could absorb neutral hydrophilic compounds effectively. Therefore, with the coagulated flocs formed on the membrane surface, the flux decline could be improved.     

Penetration analysis of elements and bioleaching treatment of spent refractory for recycling

Acidithiobacillus ferrooxidans ATCC23270 and Acidithiobacillus thiooxidans TM-32 were used for bioleaching of spent refractories of aluminium and copper melting furnaces for their recycling.Firstly,penetration of elements into aluminium melting furnace refractory was investigated and it was found that up to 7 cm from surface was contaminated.Comparison on leaching efficiency by the strains ATCC23270 and TM-32 found that the strain ATCC23270 could treat larger amount of the refractories than the strain TM-32 could do.In the experiment of bioleaching of spent refractory aluminium melting furnace by the strain ATCC23270,high leaching efficiency were obtained on Al,Si,and Ca,and extremely low leaching performance was,however,shown on the rest of elements i.e.,Na,Mn,and Zn.Under the strain TM-32 use,relatively high leaching performance was recognized on Al,Si,Ca,Na,Mn,and Zn.In the experiment of bioleaching for spent refractory copper melting furnace,almost the same leaching trends were shown on Cu,Zn,Al,and Si under the strains ACTT23270 and TM-32 uses.     

Simultaneous removal of ammonium and phosphate by zeolite synthesized from coal fly ash as influenced by acid treatment

Zeolite synthesized from fly ash （ZFA） without modification is not efficient for the purification of NH4＋ and phosphate at low concentrations that occur in real effluents, despite the high potential removal capacity. To develop an effective technique to enhance the removal efficiency of ammonium and phosphate at low concentrations, ZFA was modified with acid treatment and the simultaneous removal of ammonium and phosphate in a wide range of concentration was investigated. It was seen that when compared with untreated ZFA, only the treatment by 0.01 mol/L of H2SO4 significantly improved the removal efficiency of ammonium at low initial concentrations. The behavior was well explained by the pH effect. Treatment by more concentrated H2SO4 led to the deterioration of the ZFA structure and a decrease in the cation exchange capacity. Treatment by 0.01 mol/L H2SO4 improved the removal efficiency of phosphate by ZFA at all initial P concentrations, while the treatment by concentrated H2SO4 （≥0.9 mol/L） resulted in a limited maximum phosphate immobilization capacity （PIC）. It was concluded that through a previous mild acid treatment （e.g. 0.01 mol/L of H2SO4）, ZFA can be used in the simultaneous removal of NH4＋ and P at low concentrations simulating real effluent.