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1.
The objective of this study was to assess the radiative forcing due to Finnish anthropogenic greenhouse gas emissions in three scenarios. All the Kyoto Protocol gases, i.e., CO2, CH4, N2O, and fluorinated gases, were included. The calculations showed that forcing due to Finnish emissions will increase in the case of all gases except methane by the year 2100. In 1990, radiative forcing due to Finland's emission history of all Kyoto Protocol gases was 3.2 mW/m2, of which 71% was due to carbon dioxide, 17% to methane, and the rest to nitrous oxide. In 1990 the share of fluorinated gases was negligible. The share of methane in radiative forcing is decreasing, whereas the shares of carbon dioxide and of fluorinated gases are increasing and that of nitrous oxide remains nearly constant. The nonlinear features concerning additional concentrations in the atmosphere and radiative forcing due to emissions caused by a single country or activity are also considered. Radiative forcing due to Finnish emissions was assessed with two different approaches, the marginal forcing approach and the averaged forcing approach. The impact of the so-called background scenario, i.e., the scenario for concentration caused by global emissions, was also estimated. The difference between different forcing models at its highest was 40%, and the averaged forcing approach appeared to be the more recommendable. The effect of background concentrations in the studied cases was up to 11%. Hence, the choice of forcing model and background scenario should be given particular attention.  相似文献   

2.
The aim of this study was to develop and apply an advanced, measurement based method for the estimation of annual CH4 and N2O emissions and thus gain improved understanding on the actual greenhouse gas (GHG) balances of combustion of fossil fuels, peat, biofuels and REF. CH4 and N2O emissions depend strongly on combustion conditions, and therefore the emission factors used in the calculation of annual emissions contain significant uncertainties. Fluidised bed combustion (FBC) has many good properties for combustion of different types of fuels and fuels of varying quality, e.g., biofuels and wastes. Therefore, it is currently increasing its market share. In this study, long term measurements (up to 50 days) were carried out at seven FBC boilers representing different size classes, loadings and fuel mixes. Both decreasing load and increasing share of coal in fuel mix increased N2O emissions. Measurement results from different loading levels were combined with the common loading curves of similar plants in Finland to estimate annual emissions. Based on the results, recommendations for emission factors for the Finnish GHG emission inventory are given. The role of FBC as a potential technology for the utilisation of biofuels and wastes with future GHG reduction requirements is discussed.  相似文献   

3.
Landfills and old waste deposits are some of the major anthropogenic sources of methane (CH4) emissions worldwide. Despite the fact that during the last 15 years the amount of carbon dioxide equivalent (CO2-eq.) emitted from German landfills was reduced by approximately two thirds, estimates show that currently more than 10 Mtonnes are still being emitted annually. As a case study, the in situ aerated former Kuhstedt Landfill (District of Rotenburg (Wümme), Germany) was assessed regarding the possibility of reducing the emitted amounts of greenhouse gases (GHG; here methane). The assessment was based on both a model calculation of the landfill gas emissions that should occur under anaerobic conditions (reference scenario) as well as using monitoring data plus extrapolations to determine the actual emissions from the landfill. It was demonstrated that more than 72% of the total GHG emissions occurring under anaerobic conditions could be avoided by altering the ambient aerobic/oxidizing conditions. By means of subsequent thermal treatment (regenerative thermal oxidation, RTO) of the extracted off-gases during the aeration process, the amount of CO2-eq. savings, as calculated from the amount of emitted methane taking into account secondary emissions for energy production, could be further increased to 96%.  相似文献   

4.
Estimation of Nitrous Oxide Emissions from US Grasslands   总被引:2,自引:0,他引:2  
2 O) emissions from temperate grasslands are poorly quantified and may be an important part of the atmospheric N2O budget. In this study N2O emissions were simulated for 1052 grassland sites in the United States using the NGAS model of Parton and others (1996) coupled with an organic matter decomposition model. N2O flux was calculated for each site using soil and land use data obtained from the National Resource Inventory (NRI) database and weather data obtained from NASA. The estimates were regionalized based upon temperature and moisture isotherms. Annual N2O emissions for each region were based on the grassland area of each region and the mean estimated annual N2O flux from NRI grassland sites in the region. The regional fluxes ranged from 0.18 to 1.02 kg N2O N/ha/yr with the mean flux for all regions being 0.28 kg N2O N/ha/yr. Even though fluxes from the western regions were relatively low, these regions made the largest contribution to total emissions due to their large grassland area. Total US grassland N2O emissions were estimated to be about 67 Gg N2O N/yr. Emissions from the Great Plains states, which contain the largest expanse of natural grassland in the United States, were estimated to average 0.24 kg N2O N/ha/yr. Using the annual flux estimate for the temperate Great Plains, we estimate that temperate grasslands worldwide may potentially produce 0.27 Tg N2O N/yr. Even though our estimate for global temperate grassland N2O emissions is less than published estimates for other major temperate and tropical biomes, our results indicate that temperate grasslands are a significant part of both United States and global atmospheric N2O budgets. This study demonstrates the utility of models for regional N2O flux estimation although additional data from carefully designed field studies is needed to further validate model results.  相似文献   

5.
Biomass burning associated with shifting cultivation areas from the northeastern region of India is an important source of trace gas emissions in the Southeast Asian region. In the present study, satellite data pertaining to IRS-P4 OCM data and DMSP-OLS has been used to quantify the intensity, areal extent and amount of biomass burnt in the northeastern region states at district level. Trace gas emissions have been quantified both by using IPCC based emission ratios and ground based emission ratios obtained from field based studies. Areal estimates with respect to shifting cultivation areas from IRS-P4 OCM satellite data of 4th April 2000 suggested nearly 112.99 km2 of the northeastern region of India affected due to shifting cultivation. In the study, DMSP OLS nighttime data has been used to capture the real time fires during the dry season. The results suggested high amount of fires during the March season when compared to April and May. Using the emission ratios obtained from the ground-based studies and IPCC emission ratios, the emissions for the individual non-CO2 trace gases have been computed in a GIS framework using the biomass data, combustion factors and emission ratios. Results suggested emissions of 2.063 Mt CH4, 17.94 Mt CO, 1.419 Mt N2O, and 51.28 Mt NO x and 2.643 Mt release of CH4, 3.7204 Mt CO, 0.145 Mt N2O, and 8.477 Mt NO x , respectively, from biomass burning due to shifting cultivation for the year 2000, from the northeastern region in India. The study highlights the importance of Satellite Remote sensing data and GIS in quantifying the trace gas emissions from biomass burning.  相似文献   

6.
Carbon dioxide emission reduction scenarios for Finland are compared with respect to the radiative forcing they cause (heating power due to the absorption of infrared radiation in the atmosphere). Calculations are made with the REFUGE system model using three carbon cycle models to obtain an uncertainity band for the development of the atmospheric concentration. The future emissions from the use of fossil fuels in Finland are described with three scenarios. In the reference scenario (business-as-usual), the emissions and the radiative forcing they cause would grow continuously. In the scenario of moderate emission reduction, the emissions would decrease annually by 1% from the first half of the next century. The radiative forcing would hardly decrease during the next century, however. In the scenario of strict emission reductions, the emissions are assumed to decrease annually by 3%, but the forcing would not decrease until approximately from the middle of the next century depending on the model used. Still, in the year 2100 the forcing would be considerably higher than the forcing in 1990. Due to the slow removal of CO2 from the atmosphere by the oceans, it is difficult to reach a decreasing radiative forcing only by limiting fossil CO2 emissions. The CO2 emissions from fossil fuels in Finland contribute to the global emissions presently by about 0.2%. The relative contribution of Finnish CO2 emissions from fossil fuels to the global forcing due to CO2 emissions is presently somewhat less than 0.2% due to relatively smaller emissions in the past. The impact of the nonlinearity of both CO2 removal from the atmosphere and of CO2 absorption of infrared radiation on the results is discussed.  相似文献   

7.

As part of the studies related to the obligations of the UN Framework Convention on Climate Change, the Republic of Kazakhstan started activities to inventory greenhouse gas (GHG) emissions and assess of GHG mitigation options. The objective of this paper is to present an estimate of the possibility of mitigating GHG emissions and determine the mitigation priorities. It presents a compilation of the possible options and their assessment in terms of major criteria and implementation feasibility. Taking into account the structure of GHG emissions in Kazakhstan in 1990, preliminary estimates of the potential for mitigation are presented for eight options for the energy sector and agriculture and forestry sector. The reference scenario prepared by expert assessments assumes a reduction of CO2 emissions in 1996–1998 by about 26% from the 1990 level due to general economic decline, but then emissions increase. It is estimated that the total potential for the mitigation of CO2 emissions for the year 2000 is 3% of the CO2 emissions in the reference scenario. The annual reduction in methane emissions due to the estimated options can amount to 5%–6% of the 1990 level.

  相似文献   

8.
Nonpoint source pollution from agriculture and urbanization is increasing globally at the same time climate extremes have increased in frequency and intensity. We review >200 studies of hydrologic and gaseous fluxes and show how the interaction between land use and climate variability alters magnitude and frequency of carbon, nutrient, and greenhouse gas pulses in watersheds. Agricultural and urban watersheds respond similarly to climate variability due to headwater alteration and loss of ecosystem services to buffer runoff and temperature changes. Organic carbon concentrations/exports increase and organic carbon quality changes with runoff. Nitrogen and phosphorus exports increase during floods (sometimes by an order of magnitude) and decrease during droughts. Relationships between annual runoff and nitrogen and phosphorus exports differ across land use. CH4 and N2O pulses in riparian zones/floodplains predominantly increase with: flooding, warming, low oxygen, nutrient enrichment, and organic carbon. CH4, N2O, and CO2 pulses in streams/rivers increase due to similar factors but effects of floods are less known compared to base flow/droughts. Emerging questions include: (1) What factors influence lag times of contaminant pulses in response to extreme events? (2) What drives resistance/resilience to hydrologic and gaseous pulses? We conclude with eight recommendations for managing watershed pulses in response to interactive effects of land use and climate change.  相似文献   

9.
Methane fluxes from artificial wetlands: A global appraisal   总被引:1,自引:0,他引:1  
Methane emissions make an important contribution to the enhanced greenhouse effect, emissions from rice growing being one of its major anthropogenic sources. The estimation of global fluxes of methane from rice and from coarse fiber production depends on extrapolating observed data across countries and agroclimatic zones: the estimates are therefore imprecise. We present a revised estimate of global emissions of 96 Tg CH4/yr, given 1991 rice areas, and 1991 production data for those tropical coarse fibers that also produce methane under anaerobic conditions. This is higher than many previous studies, which systematically underestimated the fluxes from tropical countries. As the world's population increases, the demand for rice will rise. This demand can only be satisfied through greater rice production, either by bringing new areas into rice growing or by using the present area more intensively. Strategies based on improved water management and fertilizer use will allow increased rice production and yields and reduce the methane flux per unit or rice production.  相似文献   

10.
Abstract: Arctic lakes are significant emitters of methane (CH4), a potent greenhouse gas, to the atmosphere; yet no rigorous quantification of the magnitude and variability of pan‐Arctic lake emissions exists. In this study, we demonstrate the potential for a new method using synthetic aperture radar (SAR) imagery to detect methane bubbles in lake ice to scale up whole‐lake measurements of CH4 ebullition (bubbling) to regional scales. We estimated ebullition from lakes, which is often the dominant mode of lake emissions, by mapping the distribution of bubble clusters frozen in early winter ice across surfaces of seven tundra lakes and one boreal forest lake in Alaska. Applying previously measured ebullition rates associated with four distinct classes of bubble clusters found in lake ice, we estimated whole‐lake emissions from individual lakes. The percent surface area of lake ice covered with bubbles (R2 = 0.68) and CH4 ebullition rates from lakes (R2 = 0.59) and were correlated with radar return values from RADARSAT‐1 Standard Beam mode 3 for the tundra lakes, suggesting that with appropriate scaling and consideration for variability in lake‐ice conditions, this technique has the potential to be used for estimating broader‐scale regional and pan‐Arctic lake methane emissions.  相似文献   

11.
This paper analyses the relationship between nitrous oxide (N2O) emissions, economic growth, agricultural land used and exports in Germany. We use time‐series data between 1970 and 2012 and the Autoregressive Distributed Lag (ARDL) methodology to test for cointegration in the long run. Results show that there is a quadratic long run relationship between N2O emissions and economic growth, confirming the existence of an Environmental Kuznets Curve (EKC) for Germany. Agricultural land area affects N2O emissions positively, whereas exports affect emissions negatively. The turning point is $27,880, which is within the sample and implies that Germany is in the decreasing part of the curve of environmental degradation. The paper shows that, contrary to testing the EKC in less developed countries, mitigation of N2O emissions does not negatively affect growth in Germany. As such, it is feasible to undertake any conservative policy in order to reduce emissions without major consequences on economic sectors.  相似文献   

12.
Little is known about the impact of agricultural legacy on subsurface biogeochemical processes in the years following restoration of riparian wetlands (WLs). More knowledge is also needed on the relative importance of seasons, precipitation events, and inputs of water and nutrients driving nitrogen (N), phosphorus (P), sulfur (S), and greenhouse gas (GHG) (N2O, CO2, CH4) dynamics in these systems. This investigation of a riparian zone comprising a restored WL area and a nonrestored well‐drained alluvium (AL) area in the United States Midwest revealed that despite successful hydrological restoration a decade earlier, biogeochemical conditions in the WL area remained less anoxic than in natural WLs, and not significantly different from those in the AL area. No significant differences in N, P, S, and C compound concentrations or fluxes were observed between the AL and WL areas. Over the duration of the study, nitrate (NO3?) and soluble reactive phosphorus appeared to be primarily driven by hillslope contributions. Ammonium (NH4+), sulfate (SO42?), and CO2 responded strongly to seasonal changes in biogeochemical conditions in the riparian zone, while N2O and CH4 fluxes were most influenced by large rewetting events. Overall, our results challenge overly simplistic assumptions derived from direct interpretation of redox thermodynamics, and show complex patterns of solutes and GHGs at the riparian zone scale.  相似文献   

13.

Waste management has at least five types of impacts on climate change, attributable to: (1) landfill methane emissions; (2) reduction in industrial energy use and emissions due to recycling and waste reduction; (3) energy recovery from waste; (4) carbon sequestration in forests due to decreased demand for virgin paper; and (5) energy used in long-distance transport of waste: A recent USEPA study provides estimates of overall per-tonne greenhouse gas reductions due to recycling. Plausible calculations using these estimates suggest that countries such as the US or Australia could realise substantial greenhouse gas reductions through increased recycling, particularly of paper.  相似文献   

14.
One of the techniques used to dispose of 4,000 tons per day (TPD) of non‐recyclable waste from Tehran is to burn it as an alternative fuel in cement kilns. This practice reduces emissions from landfills, prevents the loss of waste energy, and conserves fossil fuel resources. The aim of our study was to conduct a life cycle assessment (LCA) of clinker production in cement kilns using a combination of natural gas, mazut, a form of heavy, low‐quality fuel oil, and refuse‐derived fuel (RDF) from Tehran. We used SimaPro 7.1 software to perform an LCA of 1 kilogram (kg) of clinker produced using the following fuel combinations: the first scenario involved natural gas consumption alone, the second scenario involved a combination of natural gas and mazut, with the mazut providing 5% to 30% of the heating value needed to produce cement clinker in the kiln, and the third scenario involved a combination of natural gas and RDF (providing 5% to 30% of the heating needed in the kiln). The impact categories in the LCA of global warming, eutrophication, and acidification were assessed by the Center of Environmental Science of Leiden University (Centrum voor Milieukunde Leiden—CML) CML 2000 method. The results indicated that the third scenario, involving natural gas and RDF, reduced acidification by 2.14–11.5% and global warming by 0–1.3% relative to the first scenario involving the use of only natural gas. In addition, we observed a 0.65–3.81% reduction in acidification and a 0.9–3.8% reduction in global warming under the third scenario compared with the second scenario (co‐firing of natural gas and mazut). The amount of nitrogen oxides (NOX) emitted from the combustion of the Tehran RDF was greater than that was emitted when burning mazut. Therefore, reduction of nitrogen from the RDF composition is necessary. This study indicates that the use of Tehran RDF (with reduced nitrogen) in Tehran cement kilns does not increase cement kiln NOX, sulfur dioxide (SO2), and carbon dioxide (CO2) emissions; however, we need to conduct additional investigation into the chemical composition of the Tehran waste before using solid waste in place of fossil fuels.  相似文献   

15.
Use of amines is one of the leading technologies for post-combustion carbon dioxide capture from gas and coal-fired power plants. This study assesses the potential environmental impact of emissions to air that result from use of monoethanol amine (MEA) as an absorption solvent for the capture of carbon dioxide (CO2). Depending on operation conditions and installed reduction technology, emissions of MEA to the air due to solvent volatility losses are expected to be in the range of 0.01–0.8 kg/tonne CO2 captured. Literature data for human and environmental toxicity, together with atmospheric dispersion model calculations, were used to derive maximum tolerable emissions of amines from CO2 capture. To reflect operating conditions with typical and with elevated emissions, we defined a scenario MEA-LOW, with emissions of 40 t/year MEA and 5 t/year diethyl amine (DEYA), and a scenario MEA-HIGH, with emissions of 80 t/year MEA and 15 t/year DEYA. Maximum MEA deposition fluxes would exceed toxicity limits for aquatic organisms by about a factor of 3–7 depending on the scenario. Due to the formation of nitrosamines and nitramines, the estimated emissions of DEYA are close to or exceed safety limits for drinking water and aquatic ecosystems. The “worst case” scenario approach to determine maximum tolerable emissions of MEA and other amines is in particular useful when both expected environmental loads and the toxic effects are associated with high uncertainties.  相似文献   

16.
In this study the methodology of life cycle assessment has been used to assess the environmental impacts of three pulverized coal fired electricity supply chains with and without carbon capture and storage (CCS) on a cradle to grave basis. The chain with CCS comprises post-combustion CO2 capture with monoethanolamine, compression, transport by pipeline and storage in a geological reservoir. The two reference chains represent sub-critical and state-of-the-art ultra supercritical pulverized coal fired electricity generation. For the three chains we have constructed a detailed greenhouse gas (GHG) balance, and disclosed environmental trade-offs and co-benefits due to CO2 capture, transport and storage. Results show that, due to CCS, the GHG emissions per kWh are reduced substantially to 243 g/kWh. This is a reduction of 78 and 71% compared to the sub-critical and state-of-the-art power plant, respectively. The removal of CO2 is partially offset by increased GHG emissions in up- and downstream processes, to a small extent (0.7 g/kWh) caused by the CCS infrastructure. An environmental co-benefit is expected following from the deeper reduction of hydrogen fluoride and hydrogen chloride emissions. Most notable environmental trade-offs are the increase in human toxicity, ozone layer depletion and fresh water ecotoxicity potential for which the CCS chain is outperformed by both other chains. The state-of-the-art power plant without CCS also shows a better score for the eutrophication, acidification and photochemical oxidation potential despite the deeper reduction of SOx and NOx in the CCS power plant. These reductions are offset by increased emissions in the life cycle due to the energy penalty and a factor five increase in NH3 emissions.  相似文献   

17.
In 1988 the Toronto World Conference on the Changing Atmosphere called for a reduction of CO2 emissions of the industrialized countries by approximately 20% by the year 2005 as compared with 1988. A stabilization of CO2 concentrations would require an eventual emissions reduction of more than 50% of present levels. Model runs were performed with the Dutch Integrated Model for the Assessment of the Greenhouse Effect (IMAGE) to put these figures into perspective. It was found that the suggested emissions reduction levels could indeed be adequate to prevent global temperature change from moving beyond past climate experience. However, this would only be the case when these reduced levels of emissions were achieved at a global scale and maximum emission control for the other greenhouse gases was implemented. A delayed response analysis shows that the policies of the coming decades are crucial for the eventual control of the greenhouse effect.  相似文献   

18.
The International Energy Agency Energy Technologies Perspectives (ETP) model is used to assess the prospects for carbon abatement options, including carbon capture and storage, up to 2050. Three main scenarios are considered: a Baseline scenario with current energy policies, an accelerated technology scenario that seeks to return energy-related CO2 emissions in 2050 to their level in 2005, and a scenario for which CO2 emissions are reduced at 50% of current levels by 2050. To reach these emissions reduction targets, annual global CO2 emissions in the year 2050 must be reduced by 35 GtCO2 to 48 GtCO2 compared to the Baseline scenario. The analysis presented here shows that a broad portfolio of emissions reducing technologies will need to be deployed across all economic sectors of the global economy to reach these targets. Carbon dioxide capture and storage (CCS) is one of the suite of technologies employed across the globe to reach these targets. CCS adoption occurs in many aspects of the global economy and accounts for 14–19% of all emissions reductions. The total amount of CO2 captured and stored in deep geologic reservoirs up to 2050 ranges between 5.1 GtCO2 and 10.4 GtCO2 in these two climate policy scenarios. Up to 2030, more than half of total CCS deployment takes place in OECD countries. After 2035, emerging economies account for more than half of total CCS use. This paper also demonstrates that as the climate policy becomes more stringent it will be necessary for CCS to deploy more extensively in many different industries outside of the electric power sector which often receives the most attention in discussions of CCS's role in addressing climate change.  相似文献   

19.
Here we report N2O emission results for freshwater marshes isolated from human activities at the Sanjiang Experimental Station of Marsh Wetland Ecology in northeastern China. These results are important for us to understand N2O emission in natural processes in undisturbed freshwater marsh. Two adjacent plots of Deyeuxia angustifolia freshwater marsh with different water regimes, i.e., seasonally waterlogged (SW) and not- waterlogged (NW), were chosen for gas sampling, and soil and biomass studies. Emissions of N2O from NW plots were obviously higher than from the SW plots. Daily maximum N2O flux was observed at 13 o′clock and the seasonal maximum occurred in end July to early August. The annual average N2O emissions from the NW marsh were 4.45 μg m−2 h−1 in 2002 and 6.85 μg m−2 h−1 in 2003 during growing season. The SW marsh was overall a sink for N2O with corresponding annual emissions of −1.00 μg m−2 h−1 for 2002 and −0.76 μg m−2 h−1 for 2003. There were significant correlations between N2O fluxes and temperatures of both air and 5-cm-depth soil. The range of soil redox potential 200–400 mV appeared to be optimum for N2O flux. Besides temperature and plant biomass, the freeze–thaw process is also an important factor for N2O emission burst. Our results show that the freshwater marsh isolated from human activity in northeastern China is not a major source of N2O.  相似文献   

20.
Under the framework of the European project named COPOWER, the possibility to partially substitute coal used in a 243 MWth Power Plant by biomass and non-hazardous wastes for the production of electricity and steam was assessed. Three combustion scenarios were studied, based on the combustion tests performed in a Power Plant located in Duisburg (Germany): Scenario 0 (Sc0) - combustion of coal; Scenario 1 (Sc1) - combustion of coal + sewage sludge (SS) + meat and bone meal (MBM); Scenario 2 (Sc2) - coal + SS + wood pellets (WP). An environmental and socio-economic assessment of these three scenarios was performed. In the environmental point of view, Sc0 was the worst scenario, mainly due to the emission of greenhouse gases (GHG). Sc1 was the best scenario, mainly due to the reduction of GHG emission, eutrophication chemical species and ozone depletion gases. In the socio-economic point of view, Sc0 was the worst scenario, mainly due to the absence of GHG abatement, and Sc1 was the best scenario due to the best cost of electricity production and negative cost of avoided emissions.  相似文献   

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