垃圾填埋场渗滤液对地下水污染的修复技术

在查阅国内外相关文献资料的基础上，综述了垃圾填埋场渗滤液的产生以及对地下水的污染，介绍了垃圾渗滤液污染控制措施，包括顶部覆盖层、垃圾分层填埋、地表入渗水导流等；然后主要介绍了地下水的原位修复技术，包括加药法、地下曝气法、生物修复，等。     

土壤修复技术新发展

使用三氯乙烯（TCE）方法进行生物土壤修复；使用压缩空气进行土壤修复；有效封闭隔离被污染土壤；土壤修复与蓄冷，蓄热相结合。[编者按]     

污染场地修复技术的种类

本文旨在归纳总结目前国内外对污染场地的修复的各种技术。认为场地修复通常包括污染土修复和含水层净化等2个方面。污染土常见的处理技术目前大致可归纳为6类，即微生物修复技术、化学处理技术、物理分离技术、固化／安定化技术、高温处理技术、植物修复技术等。而污染地下水的修复方法主要有5项：注气法、原位微生物修复技术、两相蒸气提取法、原位氧化法、原位反应墙技术等。     

专家带您看展会 绿色可持续环境修复将大有可为

正正通过十年的发展,污染土壤和地下水修复产业已快速成长,涉及城市污染场地修复、矿山土壤污染修复及农田土壤污染修复和管控等领域,形成了土壤污染调查、分析检测、修复、管控、工程监理和效果评估等咨询、检测、工程及药剂和装备生产的产业链,出现了一批龙头企业。为打赢"净土保卫战",污染土壤和地下水修复这个新兴环保行业,已成为我国环保产业的重要组成部分。近年来生态环境部正抓紧建立土壤和地下水环境修复的技术标准,2019年1月1日起开始实施的《中华人民共和国土壤污染防治法》,为土壤和地下水环境修复的规范发展提供了法律和技术保障,可以预计土壤和地下水修复产业发展势头良好,是环保产业新的增长点,促进了土地     

原位生物修复硝酸盐污染地下水的模拟实验

对硝态氮污染地下水微生物修复的实验方法进行了介绍。实验采用注入法,从活性污泥中筛选出一株优势反硝化菌,利用室内模拟柱模拟地下含水层,并在进水中添加少量营养碳源。考察了模拟NO3-污染地下水的修复效果及其影响因素,实验结果显示硝酸盐最高去除率可达85.20%。     

释氧材料修复地下水石油烃污染研究进展

石油烃对土壤和地下水的污染不断被重视,释氧材料作为一种强化生物修复技术正日益受到关注。文章介绍了释氧材料的发展史,阐述修复场地条件、地下水化学环境和材料释氧速率控制对修复效果的影响,并对该技术的发展进行了展望。     

基于零价铁(ZVI)的化学还原修复技术

介绍了零价铁的性质特点以及基于零价铁的化学还原技术在污染土壤和地下水修复中的应用,着重介绍了其反应机理、影响因素,并通过中试研究验证了该技术对于氯化脂肪族化合物(CAHs)污染地下水的修复效果。     

EHC原位生物化学修复地下水技术

<正>由北京宜为凯姆环境技术有限公司开发的EHC原位生物化学修复地下水技术,适用于饱和层地下水和土壤的原位修复,可处理的有机污染物包括含氯溶剂、氯苯、有机炸药、大多数农药、卤代烷和硝酸盐等。主要技术内容一、基本原理EHC药剂由缓释碳源、强还原性矿物质和营养物质组成,协同化学还原和厌氧生物修复机理降解地下水中     

石油污染土壤生物修复技术的研究进展

本文综述了30多年来国内外石油污染土壤的生物修复的进展，并介绍了国内外在修复石油污染土壤方面的生物修复工艺：原位生物修复和异位生物修复。原位修复有原位地耕法和土壤气相抽提；异位修复有土壤耕作发、堆放法、堆肥法和反应器法。文章还就今后的研究方向作了阐述，指出生物修复方法作为一种费用低、效果好、对环境影响低、无二次污染的方法，是今后治理石油对土壤污染的最可行的方法。     

光催化氧化技术的应用进展

本文综述了光催化氧化技术在污水治理领域的应用现状，总结了在修复地下水，染料废水，含油废水，杀菌消毒，难降解农药，废水表面活性剂等方面的国内外现状，指出该技术是具有很大发展潜力的高级氧化技术。     

Reductive dechlorination of activated carbon-adsorbed trichloroethylene by zero-valent iron: carbon as electron shuttle

Sequestration of organic contaminants in carbonaceous materials can significantly affect contaminant fate and transport. We investigated the reductive dechlorination of granular-activated carbon (GAC)-adsorbed trichloroethylene (TCE) by nanoscale zero-valent iron (nZVI) to understand the effect of sequestration on abiotic reactivity of organic contaminants. Significant reduction of TCE sequestered in GAC micropores was observed, even though direct contact with nZVI was unlikely. Reduction of sequestered TCE by reactive Fe(II) species or molecular hydrogen was ruled out as the reaction mechanisms. We propose that GAC served as the conductor for the transfer of electrons or atomic hydrogen from nZVI to the micropores, wherein adsorbed TCE molecules were reduced. An important implication for environmental remediation is that carbonaceous adsorbents not only function as a superb sink for organic contaminants but also allow them to be slowly degraded while being trapped.     

Removal of trichloroethylene from soil using the hydration of calcium oxide

Quicklime addition to soil at a remediation site was observed to sufficiently reduce TCE levels, but the cause of the removal could not be confirmed with the field data collected. Potential mechanisms for CaO treatment of trichloroethylene (TCE) in soil include degradation and volatilization. Since earlier studies found TCE degradation to occur during the hydration of CaO under conditions where volatilization was limited, research was conducted on mechanisms of TCE removal from soil by CaO application under conditions where volatilization was allowed to occur. TCE volatilization in soil treated with 0%, 5%, 10%, and 20% CaO doses was measured in experiments where the degree of volatilization could be tracked. The total TCE removal from soil spiked with TCE at CaO doses from 5% to 20% ranged from 97% to 99% of the initial TCE mass. Volatilization accounted for 64.4-92.5% of the TCE removal, with unrecovered TCE and TCE degradation accounting for the remaining fraction. The greater heat encountered with higher CaO doses helped minimize obstacles to TCE volatilization, such as high soil organic and clay content. Treatment with a 20% CaO dose, however, led to the formation of byproducts such as dichloroacetylene. TCE degradation to dichloroacetylene at the 20% CaO dose ranged from 2.7% to 6.4% of the initial TCE. Volatilization was concluded to be the dominant process for TCE removal from soil during CaO treatment.     

Use of mini-sprinklers to strip trichloroethylene and tetrachloroethylene from contaminated ground water

Three low-volume mini-sprinklers were tested for their efficacy to strip trichloroethylene (TCE) and tetrachloroethylene (PCE) from water. Deionized water spiked with TCE and PCE was pumped for approximately 1 h at 0.19 to 0.21 MPa (28 to 30 lb in(-2)) through a mini-sprinkler supported on top of a 1.8-m-tall riser. Water was collected in collection vessels at 0.61 and 1.22 m above the ground on support columns that were spaced at 0.61-m intervals from the riser base, and samples were composited per height and distance from the riser. Overall, air-stripping reduced dissolved concentrations of TCE and PCE by 99.1 to 100 and 96.9 to 100%, respectively, from mean influent dissolved concentrations of 466 to 1675 microg L(-1) TCE and 206 to 940 microg L(-1) PCE. In terms of mass removed, the mini-sprinklers removed TCE and PCE at a rate of approximately 1400 to 1700 and 700 to 900 microg L(-1), respectively, over a 1-h test period. Mini-sprinklers offer the advantages of (i) easy setup in series that can be used on practically any terrain; (ii) operation over a long period of time that does not threaten aquifer depletion; (iii) use in small or confined aquifers in which the capacity is too low to support large irrigation or purging systems; and (iv) use in forests in which the small, low-impact droplets of the mini-sprinklers do not damage bark and in which trees can help manage (via evapotranspiration) excess waste water.     

Trichloroethylene (TCE) removal in a single pulse suspension bioreactor

This work describes TCE biotic removal in a single-pulse bioreactor under aerobic conditions. Activated sludge from a wastewater-treatment plant was used for inoculation of the cultivator. The experiment focused on a more detailed verification of microbial composition of mixed heterotrophic culture during pulsed phenol dosage. Attention was given to suppressing eucaryotic organisms, particularly yeasts and fungi, by the addition of cycloheximide. The TCE-removal capacity of the heterotrophic culture, described by kinetic tests, was dependent on pulsed phenol injection and on cyclic addition of phenol and TCE. Maximum TCE degradation was determined in a batch test. It was found that the addition of cycloheximide (an antibiotic against propagation and growth of fungi and yeast) increased the TCE degradation activity of the mixed microbial suspension. A certain residual amount of TCE remained in some of the experiments.     

Dynamic modeling of chemical fate and transport in multimedia environments at watershed scale-II: trichloroethylene test case

A multimedia environmental fate model was developed to study the temporal dynamics and spatial distribution of a chemical pollutant at watershed scale. The theoretical considerations and implementation of the model were described in the accompanying paper (Part I). This paper presents the result of a test simulation on the transport of trichloroethylene (TCE) in the Connecticut River Basin. The simulation results were reported as time series of concentrations and inter-media transport fluxes in the compartments of atmosphere, plant, soil, surface water, and sediment. Predicted concentrations from the test simulation were compared with published field data or predictions by validated models. The temporal trends in TCE predictions were evaluated by comparing the simulation results with monthly TCE concentrations in various environmental compartments and monthly fluxes of inter-media transport processes. Results indicated that the simulation results were in reasonable agreement with reported data in the literature. The results also revealed that the mass transport of TCE from the atmosphere compartment to soil and surface water was a major route of TCE dispersion in the environment.     

Remediation of contaminated land and groundwater: experience in England and Wales

Remediation of contaminated land and groundwater is of common international concern. The context and approach taken to the problem are, however, country-specific. A survey of remedial activity occurring within England and Wales over the period 1996-1999 was commissioned by the Environment Agency (for England and Wales) to establish a baseline against which future trends in remedial activity could be judged. This paper: explains the context of contaminated land and groundwater remediation in England and Wales (Britain); provides an overview of the 1996-1999 survey of remedial activity, discussing its findings within its legislative and institutional context; and, discusses the survey results of significance to the management of contaminated land and groundwater internationally. The survey obtained specific data from 367 remediated sites supplemented by general data from a further 1189 contaminated (not necessarily remediated) sites. The survey aimed to be, and was indicative of remediation practice, and did not seek to identify every remediation scheme operating. Previous anecdotal evidences were generally confirmed. Civil engineering-based techniques dominated and were used at 94% of sites with in situ techniques (predominantly vapour extraction-based) on 16% and ex situ on just 5%. Although disposal to landfill was dominant and occurred at over 80% of sites, integrated use of multiple techniques was common. Remediation was predominantly of soil (rather than water), development-based, designed to protect human health and reflected national development-led and 'suitable for use' policies. Lessons of international relevance from the survey and general British experience are drawn concerning remediation technique selection, regulatory and financial support of innovative remediation techniques and demonstration sites, competent use of risk-based approaches to allow pragmatic remediation and effective use of quality guidelines, need for effective guidance to highlight water quality issues, the necessity of post remediation monitoring to prove remediation effectiveness and the keeping of remediation databases.     

A Proactive Approach Can Make Site Remediation Less Expensive

Without any incentive to clean up a contaminated site, remediation is often delayed until the site owner is compelled to act by regulatory agencies. In such a context, the selected technology is typically the one that will reach the remediation goals as quickly as possible. Unfortunately, this criterion is often met by overly expensive technologies, resulting in high and sometimes unaffordable total remediation costs, leading to a remediation with a negative net benefit. This study examines the effects of time constraint and benefit value on the optimal remediation strategy for a diesel-contaminated site. This strategy is developed using the technico-economic model METEORS, which takes into account the technology’s effectiveness, the uncertainty of the level of contamination, and the possibility of reducing this uncertainty through either an additional characterization (before selecting and applying a technology) or the monitoring of the remediation technology (during its use). Results of simulations with both economic and temporal constraints support a proactive approach to site remediation.     

Iron and arsenic release from aquifer solids in response to biostimulation

Biostimulation has been used at various contaminated sites to promote the reductive dechlorination of trichloroethylene (TCE), but the addition of carbon and energy donor also stimulates bacteria that use Fe(III) as the terminal electron acceptor (TEA) in potential competition with dechlorination processes. Microcosm studies were conducted to determine the influence of various carbon donors on the extent of reductive dissolution of aquifer solids containing Fe(III) and arsenic. Glucose, a fermentable and respirable carbon donor, led to the production of 1500 mg Fe(II) kg(-1), or 24% of the total Fe in the aquifer sediment being reduced to Fe(II), whereas the same concentration of carbon as acetate resulted in only 300 mg Fe(II) kg(-1) being produced. The biogenic Fe(II) produced with acetate was exclusively associated with the solid phase whereas with fermentable carbon donors as whey and glucose, 22 and 54% of the Fe(II) was in solution. With fermentation, some of the metabolites appear to be electron shuttling chemicals and chelating agents that facilitate the reductive dissolution of even crystalline Fe(III) oxides. Without the presence of electron shuttling chemicals, only surficial Fe in direct contact with the bacteria was bioavailable, as illustrated when acetate was used. Regardless of carbon donor type and concentration, As concentrations in the water exceeded drinking water standards. The As dissolution appears to have been the result of the direct use of As as an electron acceptor by dissimilatory arsenic reducing bacteria. Our findings indicate that selection of the carbon and energy donor for biostimulation for remediation of chlorinated solvent impacted aquifers may greatly influence the extent of the reductive dissolution of iron minerals in direct competition with dechlorination processes. Biostimulation may also result in a significant release of As to the solution phase, contributing to further contamination of the aquifer.     

中国土壤修复与治理的投融资政策最新进展与展望

中国目前的土壤污染修复资金主要来源于政府财政性投资,融资渠道较为单一。《土壤污染防治行动计划》实施后,如何满足实现土壤污染修复与治理目标的投资需求是一个迫切需要解决的问题,充分创新发挥市场力量,建立长效的融资政策机制是核心内容。本文评估了中国土壤污染修复与治理投融资政策现状,识别了投融资面临的关键问题和挑战,提出了"十三五"时期中国土壤修复与治理的投融资机制建设的政策建议,为"十三五"时期中国土壤修复投融资模式创新提供管理技术支撑。     

Eco-efficiency in contaminated land management in Finland – Barriers and development needs

In Finland the number of potentially contaminated sites totals ca. 20?000. The annual costs of remediation are 60–70 million euros. Excavation combined with disposal or off-site treatment is the most common soil remediation method. To define which factors make contaminated land management (CLM) eco-efficient and to study whether eco-efficiency has been considered in CLM decisions we carried out a literature survey, two stakeholder seminars, thematic interviews and a questionnaire study on economic instruments. Generally speaking, eco-efficiency means gaining environmental benefits with fewer resources. To assess its realization in CLM, it is necessary to have a more specific definition. In our study, we arrived at a list of several qualifications for eco-efficiency. It was also shown that eco-efficiency has hardly been a real issue in the selection of remediation techniques or generally, in the decision-making concerning contaminated sites. The existing policy instruments seem to be insufficient to promote eco-efficiency in CLM. Several concrete barriers to eco-efficiency also came up, urgency and lack of money being the most important. The scarcity of the use of in situ remediation methods and the difficulties involved in recycling slightly contaminated or treated soil were considered to be major problems. Insufficient site studies, inadequate or unsuitable methods for risk assessment and cost evaluation, and deficient and mistimed risk communication can also hinder the realization of eco-efficiency. Hence, there is a need to promote the use of more eco-efficient remediation techniques and to develop CLM policy instruments, guidelines, and participatory processes and methods to assess the eco-efficiency of CLM options.