2015-2018年衡阳市城区环境空气污染特征分析

本文利用2015~2018年衡阳市城区空气质量监测数据,分析环境空气污染特征及变化趋势。研究结果表明:2015~2018年衡阳市城区环境空气以PM2.5、PM10、O3污染为主,其中PM2.5和PM10年均值浓度呈下降趋势,O3年均值浓度呈不规则波动变化;年内时空变化上,O3呈现夏、秋季浓度高和冬、春季浓度低的特点,PM2.5和PM10呈现出夏季浓度低、冬季浓度高的特点。针对衡阳市空气污染物特征,提出了衡阳市城区空气质量改善的对策建议。     

Characteristics of major secondary ions in typical polluted atmospheric aerosols during autumn in central Taiwan

In autumn of 2008, the chemical characteristics of major secondary ionic aerosols at a suburban site in central Taiwan were measured during an annually occurring season of high pollution. The semicontinuous measurement system measured major soluble inorganic species, including NH(4)(+), NO(3)(-), and SO(4)(2-), in PM(10) with a 15 min resolution time. The atmospheric conditions, except for the influences of typhoons, were dominated by the local sea-land breeze with clear diurnal variations of meteorological parameters and air pollutant concentrations. To evaluate secondary aerosol formation at different ozone levels, daily ozone maximum concentration (O(3,daily max)) was used as an index of photochemical activity for dividing between the heavily polluted period (O(3,daily max) ≧80 ppb) and the lightly polluted period (O(3,daily max)<80 ppb). The concentrations of PM(10), NO(3)(-), SO(4)(2-), NH(4)(+) and total major ions during the heavily polluted period were 1.6, 1.9, 2.4, 2.7 and 2.3 times the concentrations during the lightly polluted period, respectively. Results showed that the daily maximum concentrations of PM(10) occurred around midnight and the daily maximum ozone concentration occurred during daytime. The average concentration of SO(2) was higher during daytime, which could be explained by the transportation of coastal industry emissions to the sampling site. In contrast, the high concentration of NO(2) at night was due to the land breeze flow that transport inland urban air masses toward this site. The simulations of breeze circulations and transitions were reflected in transports and distributions of these pollutants. During heavily polluted periods, NO(3)(-) and NH(4)(+) showed a clear diurnal variations with lower concentrations after midday, possibly due to the thermal volatilization of NH(4)NO(3) during daytime and transport of inland urban plume at night. The diurnal variation of PM(10) showed the similar pattern to that of NO(3)(-) and NH(4)(+) aerosols. This indicated that the formatted secondary aerosols in the inland urban area could be transported to the coastal area by the weak land breeze and deteriorated the air quality in the coastal area at night.     

Indoor air quality investigation according to age of the school buildings in Korea

Since the majority of schools are housed in buildings dating from the 1960s and 1970s, a comprehensive construction and renovation program of school buildings has been carried out to improve the educational conditions in Korea. However, classrooms and computer rooms, with pressed wood desks, chairs and furnishings, as well as construction materials, might have negative effects on the indoor air quality. Furthermore, most schools have naturally ventilated classrooms. The purpose of this study was to characterize the concentrations of different indoor air pollutants within Korean schools and to compare their indoor levels within schools according to the age of school buildings. Indoor and outdoor air samples of carbon monoxide (CO), carbon dioxide (CO(2)), particulate matter (PM(10)), total microbial count (TBC), total volatile organic compounds (TVOCs) and formaldehyde (HCHO) were obtained during summer, autumn and winter from three sites; a classroom, a laboratory and a computer classroom at 55 different schools. The selection of the schools was based on the number of years since the schools had been constructed. The problems causing indoor air pollution at the schools were chemicals emitted by building materials or furnishings, and insufficient ventilation rates. The I/O ratio for HCHO was 6.32 during the autumn, and the indoor HCHO concentrations (mean = 0.16 ppm) in schools constructed within 1 year were significantly higher than the Korean Indoor Air Standard, indicating that schools have indoor sources of HCHO. Therefore, increasing the ventilation rate by means of a mechanical system and the use of low-emission furnishings can play key roles in improving the indoor air quality within schools.     

An Application and Evaluation of the CAL3QHC Model for Predicting Carbon Monoxide Concentrations from Motor Vehicles Near a Roadway Intersection in Muscat,Oman

The CAL3QHC model was used to predict carbon monoxide (CO) concentrations from motor vehicles at an existing urban intersection (Star Cinema in Muscat area, Oman). The CO concentrations predicted from the model were compared with those measured in the field. Predicted average CO concentrations were found to compare favorably with measured values obtained at all eight receptors considered within the modeled intersection. In general, the comparison indicates good agreement with some underprediction for CO. For receptor 6, the model overpredicts the average CO concentration. This overprediction is associated with the presence of trees and green area in the location of receptor 6. In general, the measurements and the model results indicated that the highest CO concentrations were found to occur close to the intersection and, hence, a decrease in the concentration levels was seen as the distance from the road increased. The results indicated that the levels of CO were well below the ambient air quality standard and that probably no health risk was present in areas adjacent to the star cinema intersection. However, the predicted worst-case 1-h CO concentrations assuming inversion atmospheric stability conditions (class F) and wind speed of 1 m/s indicated that the levels of CO were close to or higher than the Omans National Ambient Air Quality Standards (NAAQS) value of 35 ppm at all receptors considered. The results of this study are useful in transport development and traffic management planning.Published online.     

Growth and yield responses of potato to mixtures of carbon dioxide and ozone

Elevated carbon dioxide (CO2) concentrations in the atmosphere can stimulate plant growth and yield, whereas ground-level ozone (O3) concentrations cause the opposite effect in many areas of the world. Recent experiments show that elevated CO2 can protect some plants from O3 stress, but this has not been tested for most crop species. Our objective was to determine if elevated CO2 protects Irish potato (Solanum tuberosum L.) from foliar injury and suppression of growth and yield caused by O3. An O3-resistant cultivar (Superior) and an O3-sensitive cultivar (Dark Red Norland) were exposed from within 10 d after emergence to maturity to mixtures of three CO2 and three O3 treatments in open-top field chambers. The three CO2 treatments were ambient (370 microL L(-1)) and two treatments with CO2 added to ambient CO2 for 24 h d(-1) (540 and 715 microL L(-1)). The O3 treatments were charcoal-filtered air (15 nL L(-1)), nonfiltered air (45 nL L(-1)), and nonfiltered air with O3 added for 12 h d(-1) (80 nL L(-1)). Elevated O3 and CO2 caused extensive foliar injury of Dark Red Norland, but caused only slight injury of Superior. Elevated CO2 increased growth and tuber yield of both cultivars, whereas elevated O3 generally suppressed growth and yield, mainly of Dark Red Norland. Elevated CO2 appeared to protect Dark Red Norland from O3-induced suppression of shoot, root, and tuber weight as measured at midseason but did not protect either cultivar from O3 stress at the final harvest. The results further illustrate the difficulty in predicting effects of O3 + CO2 mixtures based on the effects of the individual gases.     

成都市城区环境大气中典型特征VOCs示踪物种分析

VOCs排放来源较多且成分复杂,通过某些特征物种的浓度比值可以获得相应的VOCs来源信息,2018年12月至2019年11月使用TH-300B大气挥发性有机物快速在线监测系统在成都市内进行监测,并用比值法对VOCs的示踪物种进行分析,研究表明,在监测时间范围内,乙烷、丙烷、正戊烷、异戊烷、异戊二烯、乙炔、苯、甲苯、乙苯、间(对)二甲苯的平均浓度分别为5.49ppb、3.60ppb、0.54ppb、1.14ppb、0.1ppb、3.87ppb、0.53ppb、0.87ppb、0.25ppb和0.87ppb;甲苯/苯和异戊烷/正戊烷的比值分别为1.17和1.67,表明市区VOCs的排放受机动车尾气影响较为显著,需继续加强机动车的管控;对二甲苯/乙苯和苯/甲苯的比值分别为3.7和0.85,市区气团有一定老化,春季和冬季气团老化程度较大,光化学年龄较长。     

Growth and yield responses of snap bean to mixtures of carbon dioxide and ozone

Elevated CO2 concentrations expected in the 21st century can stimulate plant growth and yield, whereas tropospheric O3 suppresses plant growth and yield in many areas of the world. Recent experiments showed that elevated CO2 often protects plants from O3 stress, but this has not been tested for many important crop species including snap bean (Phaseolus vulgaris L.). The objective of this study was to determine if elevated CO2 protects snap bean from O3 stress. An O3-tolerant cultivar (Tenderette) and an O3-sensitive selection (S156) were exposed from shortly after emergence to maturity to mixtures of CO2 and O3 in open-top field chambers. The two CO2 treatments were ambient and ambient with CO2 added for 24 h d(-1) resulting in seasonal 12 h d(-1) (0800-2000 h EST) mean concentrations of 366 and 697 microL L(-1), respectively. The two O3 treatments were charcoal-filtered air and nonfiltered air with O3 added for 12 h d(-1) to achieve seasonal 12 h d(-1) (0800-2000 h EST) mean concentrations of 23 and 72 nL L(-1), respectively. Elevated CO2 significantly stimulated growth and pod weight of Tenderette and S156, whereas elevated O3 significantly suppressed growth and pod weight of S156 but not of Tenderette. The suppressive effect of elevated O3 on pod dry weight of S156 was approximately 75% at ambient CO2 and approximately 60% at elevated CO2 (harvests combined). This amount of protection from O3 stress afforded by elevated CO2 was much less than reported for other crop species. Extreme sensitivity to O3 may be the reason elevated CO2 failed to significantly protect S156 from O3 stress.     

Emission of CO2, CH4 and N2O from freshwater marsh in northeast of China

The wetlands play an important role in carbon storage, especially at high latitudes, at which they store nearly one-third of global soil carbons. However, few studies have investigated the emissions of CO(2), CH(4) and N(2)O in the long-term, especially effects of freeze-thaw cycles on these gases emissions in freshwater marsh ecosystems. In this paper, we collected greenhouse gas emission data from a freshwater marsh area in China for 4 years, evaluated their release variables and speculated on their potential atmospheric impact. For this paper, we report on the CO(2), CH(4) and N(2)O emission rates recorded from June 2002 to November 2005 in the Sanjiang Plain of northeast China. We measured their interannual variations and fluctuations, as well as factors affecting their emissions, and estimated their regulation and freeze-thaw cycle impacts. Our results revealed obvious CO(2) and CH(4) emission fluctuations during the winter months, and during the freeze-thaw cycle, and a strong interannual variation during the growing season. Overall, we documented a close relationship between the CO(2) and CH(4) emissions, implicating some regulatory commonality. We determined that the marsh was a N(2)O sink during the winter, but a significant source of N(2)O during the freeze-thaw cycle as the temperature increased, especially in early summer. During the thaw-freeze period, the N(2)O levels were positively correlated with the water depth. Additionally, water depth greatly governed the interannual variation of the N(2)O emissions from the marshes during the thaw-freeze period.     

The impact of urban growth on regional air quality surrounding the Langat River Basin, Malaysia

Studies of air quality were carried out in the towns of Kajang, Nilai and Banting in the Langat River Basin, southern region of Kuala Lumpur to determine the status and trend of air quality. The determination of air quality was based on several parameters such as suspended solids with diameters less than 10???m (PM₁₀) and gaseous pollutants of sulphur dioxide (SO₂), nitrogen dioxide (NO₂), ozone (O₃), and carbon monoxide (CO). Primary concentration data of air pollutants were compiled through fieldwork studies and combined with secondary data obtained from the regular monitoring data as collected by Alam Sekitar Malaysia Sdn. Bhd. (ASMA) on behalf of Malaysian Department of Environment (DOE) at their stations in Kajang and Nilai. Results showed that the average concentrations of PM₁₀, SO₂, NO₂, O_3, and CO at all sampling stations were still below the permissible values recommended by the Malaysian DOE. The level of gaseous pollutants of NO₂, O_3, and CO was recorded at statistically higher levels (p?<?0.05) than values recorded at the control station at Pangsun Recreational Area. These pollutants were suspected to have originated mainly from exhaust systems of motor vehicles. Data for the years 1996 to 2006 as obtained from ASMA showed long-term air quality trends of increasing O₃ and NO₂ concentrations in Kajang whilst concentrations of PM₁₀ recorded at both Kajang and Nilai stations were mostly expected coming from transboundary sources especially biomass burning and the development activities around the study areas.     

Experimental study of benzene,toluene, ethylbenzene,and xylene (BTEX) contributions in the air pollution of Tehran,Iran

Urbanization and development are associated with air pollution, including emissions of volatile organic compounds (VOCs) such as benzene, toluene, ethylbenzene, and xylene (BTEX). For this study, we measured and investigated the outdoor concentrations of BTEX in Tehran, Iran. National Institute for Occupational Safety and Health (NIOSH, 1996) methods were applied to measure the concentrations of BTEX in winter and spring of 2015 at 46 air monitoring stations. BETX concentrations were also measured at 19 monitoring stations in June and July of 2003. In 2003, BTEX compound pollutants were observed at greater concentration in the eastern, central, and southern zones of Tehran than in other zones. The average concentrations of the BTEX compounds were 238 parts per billion (ppb), 130 ppb, 69 ppb, and 118 ppb, respectively, for benzene, toluene, ethylbenzene, and xylene. The benzene to toluene (B/T) ratios ranged from 0.8 to 3.2, which indicated that the gasoline used in the city was of poor quality at that time. In 2015, the BTEX concentrations in District 19 (south of Tehran) were higher than in the eastern and central regions, which included restricted “traffic zones” and the extensive development of public transportation systems. In the restricted traffic zones, only public vehicles, such as buses, taxis, ambulances, etc., and other authorized vehicles are allowed to operate. By ameliorating the quality of gasoline, encouraging the use of late model private cars, and development of subway and public transportation during the years between 2003 and 2015, the BTEX concentrations have fallen to levels that comply with Iran's air quality standards. The 2015 measurements revealed that the average concentrations of the BTEX compounds were 5.3, 9.2, 1.5, and 2.6 ppb, respectively. The B/T ratio fluctuated from 0.39 to 0.76, demonstrating the remarkable role that vehicle traffic plays in BTEX pollution.     

成都市城区春节期间燃放烟花爆竹对空气质量的影响

利用空气质量自动监测系统分析了2013年春节期间成都市城区的SO2、NO2、CO、O3、PM10及PM2.5的浓度值,发现烟花爆竹的燃放对SO2、NO2、PM10及PM2.5的浓度有较大影响。     

Retention of gases by hexadecyltrimethylammonium-montmorillonite clays

Intercalated montmorillonite clays with different amounts of organic hexadecyltrimethylammonium (HDTMA) cations were studied to analyse their CO, CH(4), and SO(2) gas retentions. Equilibrium adsorption was measured by using a standard volumetric apparatus at 25 degrees C and 0.1 MPa. The solids were characterised by X-ray diffraction. The levels of adsorption of SO(2) by organo-montmorillonites (0.3595-1.6403 mmol/g) were higher than those of CO (up to 0.0202 mmol/g) and CH(4) (up to 0.0273 mmol/g) gases. HDTMA montmorillonites may be effective adsorbents for removing SO(2) and for its potential separation in the presence of CO and/or CH(4) molecules, which can be present in contaminated air.     

Sensitivity analysis of ground-level ozone concentration to emission changes in two urban regions of southeast Texas

Air pollutant emission is one of the predominant factors affecting urban air quality such as ground-level ozone formation. This paper assesses the impact of changing emission inventory scenarios, based on combinations of point, mobile, area/non-road and biogenic sources, on the tropospheric ozone concentration in two southeast Texas urban areas, i.e. Houston-Galveston and Beaumont-Port Arthur, during the rapid ozone formation event (ROFE) on August 25, 2000. The EPA's Community Multiscale Air Quality (CMAQ) modeling system with 1999 national emission inventory (NEI99) estimates and updated SAPRC99 chemical mechanism are used in the sensitivity analysis for twelve different emission scenarios. Based on model results, it is found that the point source emission of NOx and VOC contributes the greatest ozone peak in the ROFE. Removing Texas point sources of VOC and NOx emission from the inventory results in a reduction in peak O3 concentration by 128 and 70 ppbv in Houston urban area, respectively. Similar but less drastic impact from point source is also observed in the Beaumont-Port Arthur area. The effect on peak ozone concentration due to mobile, area and non-road sources emissions are less significant compared to that of point source emission. Reducing VOC emission appears to be more effective than reducing NOx emission in lowering peak O3 concentration in the studied region. Although biogenic emission can contribute up to 37 ppbv of peak ozone level over a large area, the affected area is away from the urban region of concern, and should not be the main cause for O3 non-attainment in the two urban areas. Removing CO emission from mobile sources does not lead to significant reduction (< 1 ppbv) in ozone concentrations. The modeled data also show that the transport of O3 precursors from adjacent states can cause a significant ozone plume near Beaumont due to its proximity to the state border based on the conditions during the August 25, 2000 O3 episode.     

Evaluation of the temporal variations of air quality in Taipei City, Taiwan, from 1994 to 2003

Data collected from the five air-quality monitoring stations established by the Taiwan Environmental Protection Administration in Taipei City from 1994 to 2003 are analyzed to assess the temporal variations of air quality. Principal component analysis (PCA) is adopted to convert the original measuring pollutants into fewer independent components through linear combinations while still retaining the majority of the variance of the original data set. Two principal components (PCs) are retained together explaining 82.73% of the total variance. PC1, which represents primary pollutants such as CO, NO(x), and SO(2), shows an obvious decrease over the last 10 years. PC2, which represents secondary pollutants such as ozone, displays a yearly increase over the time period when a reduction of primary pollutants is obvious. In order to track down the control measures put forth by the authorities, 47 days of high PM(10) concentrations caused by transboundary transport have been eliminated in analyzing the long-term trend of PM(10) in Taipei City. The temporal variations over the past 10 years show that the moderate peak in O(3) demonstrates a significant upward trend even when the local primary pollutants have been well under control. Monthly variations of PC scores demonstrate that primary pollution is significant from January to April, while ozone increases from April to August. The results of the yearly variations of PC scores show that PM(10) has gradually shifted from a strong correlation with PC1 during the early years to become more related to PC2 in recent years. This implies that after a reduction of primary pollutants, the proportion of secondary aerosols in PM(10) may increase. Thus, reducing the precursor concentrations of secondary aerosols will be an effective way to lower PM(10) concentrations.     

Temporal‐spatial variations of air pollutants in Lanzhou,Gansu Province,China, during the spring–summer periods, 2014–2016

In this article, we analyzed the mass concentrations of particulate matter 2.5 micrometers (µm) or less in size (PM_2.5), particulate matter 10 µm or less in size (PM₁₀), sulfur dioxide (SO₂), nitrogen dioxide (NO₂), carbon monoxide (CO), and ozone (O₃) in Lanzhou, the capital of Gansu province, China. We analyzed monitoring data collected from five air quality monitoring stations during the spring–summer period from 2014 to 2016. Our comparison of contaminant concentrations and average diurnal, daily, monthly, and annual concentrations revealed that the average concentrations of PM_2.5 and PM₁₀ amounted to 128.57 and 46.4 micrograms per cubic meters (µg/m³), respectively, exceeding the Chinese National Ambient Air Quality Standard (NAAQS). We used the Pearson correlation coefficient to establish connections between particulate matter and gaseous pollutants. The results show significant differences in the concentration levels of airborne pollutants. The Pearson correlation coefficient between PM_2.5 and PM₁₀ had the highest coefficient of r = 0.842. A correlation between the two particulate matter sizes (PM_2.5 and PM₁₀) and SO₂ was PM_2.5 and SO₂ r = 0.313; PM₁₀ and SO₂ r = 0.279; and CO and the two particulate matter sizes, PM_2.5 and CO r = 0.304; and PM₁₀ and CO r = 0.203. The average monthly ratio for the study months of PM_2.5 to PM₁₀ was 0.361. In addition, we used the hybrid single particle Lagrangian integrated trajectory model for tracking sources and pathways of the air pollutants in Lanzhou.     

Impacts on air pollution in urban areas

Environmental management involves controlling various forms of pollution to levels that do not pose a threat to the health of the people and the environment in general. This paper presents a framework to analyze sources of local air pollution in cities. Using an OLS model, an investigation is performed of the relationship among the concentrations of air pollutants [more precisely, concentrations of sulfur dioxide (SO₂), dust, nitric oxide (NO), nitrogen dioxide (NO₂), carbon oxide (CO) and ozone (O₃)], economic activities, and meteorology. Time series analysis leads to a model, that explains a high degree of the variance in the air pollution data. The model is applied to daily time series from three measurement stations in innsbruck, Austria. Estimation results of the model generally fit with the expected relations. Space heating influences SO₂, dust, and NO, while NO₂ levels are primarily affected by traffic. These results also indicate interdependent relations among the pollutants NO, NO₂, O₃, and CO; O₃ levels depend on temperature and sunshine.     

2017～2018年荆州城区空气质量分布及重污染天气特征分析

利用2017年1月至2018年12月荆州城区3个国家环境空气质量监测点的污染物监测数据和荆州国家气象站地面气象要素观测数据,采用统计学方法,对荆州城区空气质量分布及重污染过程天气特征进行了初步分析,结果表明:空气污染综合指数冬季最高,春秋季次之,夏季最低;PM2.5、PM10、 CO和NO2的浓度在上午和傍晚至上半夜其...     

Air quality impact of carbon monoxide emission from diesel engine electric power generators

An emissions inventory and the AERMOD View dispersion model were used to estimate the concentrations and the potential effects of carbon monoxide (CO) from diesel engine electric power generators operated by and providing electricity to a textile factory in Nigeria on its host air shed. The CO emissions from simultaneous operations of all of the electric power generators in the factory resulted in: 1‐hr average CO emissions of 4.2 to 54.5 micrograms per cubic meters (μg/m³) and 24‐hr average CO emissions of 0.3 to 20.9 μg/m³. The estimated 1‐hr averaging period maximum ground‐level concentrations of CO were deposited within the factory, while the 24‐hr maximum ground‐level concentrations are estimated at a distance 90 meters (m) from the factory in a southeast direction. The ground‐level concentrations of CO emanating from the textile factory are within the stipulated ambient air quality standards.     

Performance of lime-BHA solidified plating sludge in the presence of Na2SiO3 and Na2CO3

This research investigated the performance of lime-BHA (black rice husk ash) solidified plating sludge with 2 wt% NaO from Na(2)SiO(3) and Na(2)CO(3) at the level of 0, 30 and 50 wt%. The sludge was evaluated for strength development, leachability, solution chemistry and microstructure. The lime-BHA solidified plating sludge with Na(2)SiO(3) and Na(2)CO(3) had higher early strength when compared to the control. The addition of Na(2)SiO(3) and Na(2)CO(3) increased the OH(-) concentration and decreased the Ca(2+) and heavy metal ions in solution after the first minute. The XRD patterns showed that the addition of Na(2)SiO(3) resulted in the formation of calcium silicate hydrates, while the addition of Na(2)CO(3) resulted in CaCO(3). The heavy metals from the plating sludge, especially Zn, were immobilized in calcium zincate and calcium zinc silicate forms for the lime-BHA with and without Na(2)SiO(3) solidified wastes, while samples with Na(2)CO(3) contained Zn that was fixed in the form of CaZnCO(3). The cumulative leaching of Fe, Cr and Zn from the lime-BHA solidified plating sludge decreased significantly when activators were added, especially Na(2)CO(3).     

Real-time, high-resolution quantitative measurement of multiple soil gas emissions: selected ion flow tube mass spectrometry

A new technique is presented for the rapid, high-resolution identification and quantification of multiple trace gases above soils, at concentrations down to 0.01 microL L(-1) (10 ppb). The technique, selected ion flow tube mass spectrometry (SIFT-MS), utilizes chemical ionization reagent ions that react with trace gases but not with the major air components (N2, O2, Ar, CO2). This allows the real-time measurement of multiple trace gases without the need for preconcentration, trapping, or chromatographic separation. The technique is demonstrated by monitoring the emission of ammonia and nitric oxide, and the search for volatile organics, above containerized soil samples treated with synthetic cattle urine. In this model system, NH3 emissions peaked after 24 h at 2000 nmol m(-2) s(-1) and integrated to approximately 7% of the urea N applied, while NO emissions peaked about 25 d after urine addition at approximately 140 nmol m(-2) s(-1) and integrated to approximately 10% of the applied urea N. The monitoring of organics along with NH3 and NO was demonstrated in soils treated with synthetic urine, pyridine, and dimethylamine. No emission of volatile nitrogen organics from the urine treatments was observed at levels >0.01% of the applied nitrogen. The SIFT method allows the simultaneous in situ measurement of multiple gas components with a high spatial resolution of < 10 cm and time resolution <20 s. These capabilities allow, for example, identification of emission hotspots, and measurement of localized and rapid variations above agricultural and contaminated soils, as well as integrated emissions over longer periods.