Emergy Assessment of a Wheat-Maize Rotation System with Different Water Assignments in the North China Plain

Sustainable water use is seriously compromised in the North China Plain (NCP) due to the huge water requirements of agriculture, the largest use of water resources. An integrated approach which combines the ecosystem model with emergy analysis is presented to determine the optimum quantity of irrigation for sustainable development in irrigated cropping systems. Since the traditional emergy method pays little attention to the dynamic interaction among components of the ecological system and dynamic emergy accounting is in its infancy, it is hard to evaluate the cropping system in hypothetical situations or in response to specific changes. In order to solve this problem, an ecosystem model (Vegetation Interface Processes (VIP) model) is introduced for emergy analysis to describe the production processes. Some raw data, collected by investigating or observing in conventional emergy analysis, may be calculated by the VIP model in the new approach. To demonstrate the advantage of this new approach, we use it to assess the wheat-maize rotation cropping system at different irrigation levels and derive the optimum quantity of irrigation according to the index of ecosystem sustainable development in NCP. The results show, the optimum quantity of irrigation in this region should be 240–330 mm per year in the wheat system and no irrigation in the maize system, because with this quantity of irrigation the rotation crop system reveals: best efficiency in energy transformation (transformity = 6.05E + 4 sej/J); highest sustainability (renewability = 25%); lowest environmental impact (environmental loading ratio = 3.5) and the greatest sustainability index (Emergy Sustainability Index = 0.47) compared with the system in other irrigation amounts. This study demonstrates that application of the new approach is broader than the conventional emergy analysis and the new approach is helpful in optimizing resources allocation, resource-savings and maintaining agricultural sustainability.     

Farmland damage and its impact on the overlapped areas of cropland and coal resources in the eastern plains of China

The subsidence caused by coal mining in areas where cropland and coal resources overlap in the eastern plains of China with high ground water levels has caused large amounts of water to collect in cropland, significant damage to cropland, and a sharp contradiction between people and land distribution within this region. Systematic analysis and calculation were conducted on these areas by using GIS spatial overlay analysis technology, subsidence and occupied cropland estimation models, and crop yield reduction prediction model to reveal the overlapped characteristics and extent of farmland damage, as well as to evaluate the effects of farmland damage to grain yield, farmland landscape, agricultural population, and dynamical equilibrium of the total cultivated land. Results showed that the overlapped areas of cropland and coal resources on the eastern plains of China occupied an area covering 1.33 × 10⁵ km², which accounted for 31.93% of the total cropland area. In 2020, the accumulative total area of destroyed cropland reached 3.83 × 10³ km², thus reducing grain yield by 9.63 × 10⁸ kg, and increasing the number of landless farmers to 1.91 × 10⁶. Furthermore, the quality and production capacity of cultivated land decreased, farmland landscape patterns changed, land patterns and structures were adjusted, the dynamical equilibrium of the total cultivated land was difficult to guarantee, and social instability increased in coal mining subsidence areas. These findings provided a scientific basis for relevant government departments to enact countermeasures for the coordinative production of coal and grain.     

Energy recovery from municipal solid waste in Nigeria and its economic and environmental implications

An assessment of potential biomass resources in Nigeria for the production of methane and power generation is presented in this paper. Nigeria, as an underdeveloped and populous country, needs an uninterrupted source of energy. The country's energy problems have crippled large sectors of the economy. The percentage of people connected to the national grid is 40%. These 40% experience electricity supply failure on average 10–12 hours daily. Energy generation from municipal solid waste (MSW) is an effective MSW management strategy. Yearly waste generation has increased from 6,471 gigagrams (Gg) in 1959 to 26,600 Gg in 2015. This amount is projected to reach 36,250 Gg per year by 2030. Methane emission for 2015 was 491 Gg, and it is projected to reach 669 Gg in 2030. These values translate to 3.48 × 10⁹ kilowatt hours (kWh) of electricity for 2015, with a projected 4.74 × 10⁹ kWh by 2030. The revenue to be derived from the electricity that is generated could have been US$365.04 × 10⁶ for 2015, and it is estimated that it will reach US$473.82 × 10⁶ by 2030. It was found that methane emissions from MSW increased with time, and capturing this gas for energy production will lead to a sustainable waste management.     

基于能值生态足迹的海岛可持续性评估——以舟山为例

基于能值理论,结合生态足迹方法,构建能值生态赤字/盈余、渔业足迹强度(D)、社会发展压力指数(I)和经济协调指数(Q)参数评价海岛可持续性,选取典型海岛城市浙江省舟山市作为案例研究。结果显示:2003—2017年舟山能值足迹、能值承载力均呈上升趋势;人均能值生态足迹共增加15.78 hm²,增幅为63.26%;人均能值承载力增加5.20×10² hm²,增幅为82.86%;其中,化石能源用地能值足迹增加最多,社会经济承载力增加最多,而自然承载力却有所下降。能值生态赤字/盈余和经济协调指数不能完全反映区域可持续性,区域渔业足迹强度的不断增加表明当前的渔业经济模式不满足可持续发展要求,社会发展压力指数增大也进一步表明舟山的发展状况偏离了可持续性的轨道。     

Potential Environmental Benefits from Increased Use of Bioenergy in China

Because of its large population and rapidly growing economy, China is confronting a serious energy shortage and daunting environmental problems. An increased use of fuels derived from biomass could relieve some demand for nonrenewable sources of energy while providing environmental benefits in terms of cleaner air and reduced emissions of greenhouse gases. In 2003, China generated about 25.9 × 10⁸ metric tons of industrial waste (liquid + solid), 14.7 × 10⁸ metric tons/year (t/y) of manure (livestock + human), 7.1 × 10⁸ t/y of crop residues and food-processing byproducts, 2 × 10⁸ t/y of fuelwood and wood manufacturing residues, and 1.5 × 10⁸ t/y of municipal waste. Biofuels derived from these materials could potentially displace the use of about 4.12 × 10⁸ t/y of coal and 3.75 × 10⁶ t/y of petroleum. An increased bioenergy use of this magnitude would help to reduce the emissions of key air pollutants: SO₂ by 11.6 × 10⁶ t/y, NO_X by 1.48 × 10⁶ t/y, CO₂ by 1.07 × 10⁹ t/y, and CH₄ by 50 × 10⁶ t/y. The reduced SO₂ emissions would be equivalent to 54% of the national emissions in 2003, whereas those for CO₂ are 30%. It is important to recognize, however, that large increases in the use of biomass fuels also could result in socioeconomic and environmental problems such as less production of food and damage caused to natural habitats.     

基于能值分析的苏州市城市生态系统可持续发展评估

本文利用能值分析的方法,分析了苏州城市生态系统的各种生态流,并建立了苏州城市生态系统可持续发展能值评价指标体系,评估其可持续发展程度,并对其能值指标的发展进行了预测。研究结果显示,2007年苏州市系统利用总能值达到616.71×1021sej,能值自给率仅为35.5%,环境负载率达到61.67。与其他国家和地区能值指标对比得出,苏州市是一个高度外向型生态经济系统,其系统的发展高度依赖于外界资源的输入,面对现在不稳定的世界经济发展和外部环境,苏州市必须加大系统自身的供给能力,提高系统自身的稳定性;发展循环经济,降低系统环境负载率;加强高科技和人才投入,提高系统可持续发展潜力。     

Phosphorus resources,their depletion and conservation,a review

Yearly, about 22 × 10¹² g phosphorus (P) from mined fossil phosphate resources are added to the world economy. The size of remaining fossil phosphate resources is uncertain but practically finite. Thus, fossil P resources may become depleted by ongoing mining. Despite calls for resource conservation, fossil P resources have been depleted at an increasing rate. Geographically, fossil P supply and demand are distributed in an increasingly uneven way, which has geopolitical consequences and may well affect security of supply. Current use of P gives rise to negative environmental impacts due to P losses from the economy and contaminants derived from fossil P resources. There may also be negative impacts on human health. Reducing the demand for fossil phosphorus may reduce environmental burdens and may improve the future security of supply. Technically speaking, there is much scope for the reduction of current demand for fossil P resources. Limiting consumption of P to essential uses, increased efficiency of agricultural use and increased recycling of P may substantially contribute to the reduction of demand for fossil P resources. Recycling of P has to face concerns regarding the efficiency of P recovery, pathogenic organisms and contaminating substances. Much work remains to be done to effectively address those concerns.     

Using a Mass Balance Model to Evaluate Groundwater Budget of Seawater‐Intruded Island Aquifers1

Jang, Cheng‐Shin, Chen‐Wuing Liu, Shih‐Kai Chen, and Wen‐Sheng Lin, 2011. Using a Mass Balance Model to Evaluate Groundwater Budget of Seawater‐Intruded Island Aquifers. Journal of the American Water Resources Association (JAWRA) 48(1): 61‐73. DOI: 10.1111/j.1752‐1688.2011.00593.x Abstract: The study developed a mass balance model to evaluate the groundwater budget of seawater‐intruded island aquifers using limited available data. The Penghu islands were selected as a study area. As sparse observed data were available in the islands, methods of combining water and chloride balances were used to determine the amounts of groundwater pumping, seawater intrusion, aquifer storages, and safe yields in the shallow and deep aquifers. The groundwater budget shows that seawater intrusion to freshwater aquifers was 1.38 × 10⁶ and 0.29 × 10⁶ m³/year in the shallow and deep aquifers, respectively, indicating that the seawater intrusion is severe in the both aquifers. The safe yield of the shallow aquifer was 14.56 × 10⁶ m³/year in 2005 which was four times higher than that of the deep aquifer (3.70 × 10⁶ m³/year). However, the annual pumping amounts in the shallow and deep aquifers were 4.77 × 10⁶ and 3.63 × 10⁶ m³/year, respectively. Although the safe yield of the shallow aquifer is enough for all water resources demands, only 55% of exploitation amount was extracted from the shallow aquifer due to its poor water quality. Groundwater exploitation in the deep aquifer should be significantly reduced and regulated by a dynamic management of pumping scheme because the annual pumping amounts are close to the safe yield and seawater intrusion occurs continually. Additionally, to alleviate further aquifer salination, at least half of the current annual groundwater abstraction should be reduced.     

EMERGY-based environmental systems assessment of a multi-purpose temperate mixed-forest watershed of the southern Appalachian Mountains, USA

Emergy (with an 'm') synthesis was used to assess the balance between nature and humanity and the equity among forest outcomes of a US Forest Service ecosystem management demonstration project on the Wine Spring Creek watershed, a high-elevation (1600 m), temperate forest located in the southern Appalachian mountains of North Carolina, USA. EM embraces a holistic perspective, accounting for the multiple temporal and spatial scales of forest processes and public interactions, to balance the ecological, economic, and social demands placed on land resources. Emergy synthesis is a modeling tool that allows the structure and function of forest ecosystems to be quantified in common units (solar emergy-joules, sej) for easy and meaningful comparison, determining 'system-value' for forcing factors, components, and processes based on the amount of resources required to develop and sustain them, whether they are money, material, energy, or information. The Environmental Loading Ratio (ELR), the units of solar emergy imported into the watershed via human control per unit of indigenous, natural solar emergy, was determined to be 0.42, indicating that the load on the natural environment was not ecologically damaging and that excess ecological capacity existed for increasing non-ecological activities (e.g. timbering, recreation) to achieve an ELR of 1.0 (perfect ecological-economic balance). Three forest outcomes selected to represent the three categories of desired sustainability (ecological, economic, and social) were evaluated in terms of their solar emergy flow to measure outcome equity. Direct economic contribution was an order of magnitude less (224 x 10(12)solar emergy-joules (sej) ha(-1)) than the ecological and social contributions, which were provided at annual rates of 3083 and 2102 x 10(12)sejha(-1), respectively. Emergy synthesis was demonstrated to holistically integrate and quantify the interconnections of a coupled nature-human system allowing the goals of ecological balance and outcome equity to be measured quantitatively.     

流域水生态系统服务价值评估研究——以黄山市新安江为例

为全面认识新安江水资源价值,本文对河流生态系统的各项服务功能开展了定量评价。本文按照联合国千年评估对生态系统的划分方法(供给、调节、文化与支持4项服务),结合新安江流域水生态系统的特征和结构,建立了15项评估指标体系。以2013年为基准年,对新安江水生态系统服务功能及其生态经济价值进行评价。结果显示:新安江水生态系统服务总价值为73.72亿元,其中,提供产品功能价值9.58亿元、调节功能价值11.77亿元、支持功能价值24.13亿元、文化服务功能价值28.24亿元,分别占总价值的13.0%、16.0%、32.7%、38.3%。新安江单位面积提供的生态系统服务价值为0.41亿元/km~2,高于黄山市单位面积GDP产值0.28亿元/km~2。研究认为,新安江流域水生态系统对支持和保护当地经济发展具有重要作用,研究结果以期为新安江水资源有效管理和区域生态环境保护及水环境补偿提供生态学依据。     

Environmental Impact Assessment of Sand Mining from the Small Catchment Rivers in the Southwestern Coast of India: A Case Study

In the past few decades, the demand for construction grade sand is increasing in many parts of the world due to rapid economic development and subsequent growth of building activities. This, in many of the occasions, has resulted in indiscriminate mining of sand from instream and floodplain areas leading to severe damages to the river basin environment. The case is rather alarming in the small catchment rivers like those draining the southwestern coast of India due to limited sand resources in their alluvial reaches. Moreover, lack of adequate information on the environmental impact of river sand mining is a major lacuna challenging regulatory efforts in many developing countries. Therefore, a scientific assessment is a pre-requisite in formulating management strategies in the sand mining-hit areas. In this context, a study has been made as a case to address the environmental impact of sand mining from the instream and floodplain areas of three important rivers in the southwestern coast of India namely the Chalakudy, Periyar and Muvattupuzha rivers, whose lowlands host one of the fast developing urban-cum-industrial centre, the Kochi city. The study reveals that an amount of 11.527 million ty⁻¹ of sand (8.764 million ty⁻¹ of instream sand and 2.763 million ty⁻¹ of floodplain sand) is being mined from the midland and lowland reaches of these rivers for construction of buildings and other infrastructural facilities in Kochi city and its satellite townships. Environmental Impact Assessment (EIA) carried out as a part of this investigation shows that the activities associated with mining and processing of sands have not only affected the health of the river ecosystems but also degraded its overbank areas to a large extent. Considering the degree of degradation caused by sand mining from these rivers, no mining scenario may be opted in the deeper zones of the river channels. Also, a set of suggestions are made for the overall improvement of the rivers and its biophysical environment.     

TOTAL SOLUTES LOADS AND GEOCHEMICAL YIELDS IN THE SASKATCHEWAN RIVER BASIN1

ABSTRACT: River solute loads have seldom been measured in very large, complex drainage basins, nor have the methods of calculating loads been critically examined. For sites in the Saskatchewan River Basin, Canada, rating curves were poor predictors of solute loads because correlations between discharge and total solutes concentration were weak (R² < 0.05 in most cases) and suffered from hysteresis. In contrast, the interval method produced reliable estimates in all seasons and sites tested, and was little affected by sampling schedule. The limit of precision (SE) for estimates of mean annual or seasonal solute load was 10–15 percent of the mean (5 percent in very small basins), reached with 10 years or more of data. Two-thirds or more of total annual solute load was transported during the open-water season, but the proportion carried during winter increased from 8 percent to 34 percent from the upstream to the downstream end of the basin, due to reservoirs retaining and mixing water. Annual loads of total solutes varied from 6.2 × 10⁴ tonnes in foothills tributaries to almost 4.0 × 10⁶ tonnes in the Saskatchewan River near the mouth. But, on an areal basis, the mountain and foothills region was the dominant solute source, producing 43–97 tonnes/km²/yr, compared with only 3–22 tonnes/km²/yr for prairie rivers. This difference is a consequence of greater rainfall and, hence, more rapid erosion in the mountains.     

Wind‐Powered Desalination: An Estimate of Saline Groundwater in the United States1

James Androwski, Abraham Springer, Thomas Acker, and Mark Manone, 2011. Wind‐Powered Desalination: An Estimate of Saline Groundwater in the United States. Journal of the American Water Resources Association (JAWRA) 47(1):93‐102. DOI: 10.1111/j.1752‐1688.2010.00493.x Abstract: Increasing scarcity of freshwater resources in many regions of the world is leading water resource managers to consider desalination as a potential alternative to traditional freshwater supplies. Desalination technologies are energy intensive and expensive to implement making desalination using renewable energy resources a potentially attractive option. Unfortunately, saline groundwater resources are not well characterized for many regions hindering consideration of such technologies. In this assessment, we estimate the saline groundwater resources of the principal aquifers of the United States using a geographic information system and correlate these resources to wind resources potentially sufficient to supply the energy demand of desalination equipment. We estimate that 3.1 × 10¹⁴ m³ saline groundwater, total volume, are contained in 28 of the country’s principal aquifers known to contain saline groundwater. Of this volume, 1.4 × 10¹⁴ m³ saline groundwater are co‐located with wind resources sufficient for electrical generation to desalinate groundwater.     

A Method and Rationale for Deriving Nutrient Criteria for Small Rivers and Streams in Ohio

A mechanistic understanding of the effects of nutrient enrichment in lotic systems has been advanced over the last two decades such that identification of management thresholds for the prevention of eutrophication is now possible. This study describes relationships among primary nutrients (phosphorus and nitrogen), benthic chlorophyll a concentrations, daily dissolved oxygen (DO) concentrations, and the condition of macroinvertebrate and fish communities in small rivers and streams in Ohio, USA. Clear associations between nutrients, secondary response indicators (i.e., benthic chlorophyll and DO), and biological condition were found, and change points between the various indicators were identified for use in water quality criteria for nutrients in small rivers and streams (<1300 km²). A change point in benthic chlorophyll a density was detected at an inorganic nitrogen concentration of 0.435 mg/l (±0.599 SD), and a total phosphorus (TP) concentration of 0.038 mg/l (±0.085 SD). Daily variation in DO concentration was significantly related to benthic chlorophyll concentration and canopy cover, and a change point in 24-h DO concentration range was detected at a benthic chlorophyll level of 182 mg/m². The condition of macroinvertebrate communities was related to benthic chlorophyll concentration and both minimum and 24-h range of DO concentration. The condition of fish communities was best explained by habitat quality. The thresholds found in relationships between the stressor and the response variables, when interpreted in light of the uncertainty surrounding individual change points, may now serve as a framework for nutrient criteria in water quality standards.     

Experimental investigation of the CO2 sealing efficiency of caprocks

Using a combination of experimental (petrophysical and mineralogical) methods, the effects of high-pressure CO₂ exposure on fluid transport properties and mineralogical composition of two pelitic caprocks, a limestone and a clay-rich marl lithotype have been studied. Single and multiphase permeability tests, gas breakthrough and diffusion experiments were conducted under in situ p/T conditions on cylindrical plugs (28.5 mm diameter, 10–20 mm thickness).The capillary CO₂ sealing efficiency of the initially water-saturated sample plugs was found to decrease in repetitive gas breakthrough experiments on the same sample from 0.74 to 0.41 MPa for the limestone and from 0.64 to 0.43 MPa for the marl. Helium breakthrough experiments before and after the CO₂ tests showed a decrease in capillary threshold (snap-off) pressure from 1.81 to 0.62 MPa for the limestone.Repetitive CO₂ diffusion experiments on the marlstone revealed an increase in the effective diffusion coefficient from 7.8 × 10^?11 to 1.2 × 10^?10 m².Single-phase (water) permeability coefficients derived from steady-state permeability tests ranged between 7 and 56 nano-Darcy and showed a consistent increase after each CO₂ test cycle. Effective gas permeabilities were generally one order of magnitude lower than water permeabilities and exhibit the same trend. XRD measurements performed before and after exposure to CO₂ did not reveal any distinct change in the mineral composition for both samples. Similarly, no significant changes were observed in specific surface areas (determined by BET) and pore-size distributions (determined by mercury injection porosimetry). High-pressure CO₂ sorption experiments on powdered samples revealed significant CO₂ sorption capacities of 0.27 and 0.14 mmol/g for the marlstone and the limestone, respectively.The changes in transport parameters in the absence of detectable mineral alterations may be explained by carbonate dissolution and further precipitation along a pH profile across the sample plug which would not be subject to quantitative mineral alteration.     

《大气污染防治行动计划》实施环境效果模拟

本研究利用2010年污染源普查数据和MEIC排放清单建立全国大气污染物高时空分辨率排放清单,在此基础上利用2012年环境统计数据对其进行修订建立2012年全国大气污染物高时空分辨率排放清单;结合《大气污染防治行动计划》(以下简称《计划》)研究工作,测算了《计划》实施后在污染源综合治理、落后产能淘汰、能源结构调整方面对SO2、NOx、颗粒物、VOCs的减排量,同时对污染物新增量进行了预测,建立了《计划》实施后全国大气污染物高时空分辨率排放清单;利用CMAQ空气质量模型模拟分析了《计划》实施的空气质量改善效果。结果表明:《计划》实施后,将可以减少641万吨SO2、859万吨NOx、547万吨颗粒物(不含扬尘污染控制)、627万吨VOCs,全国、京津冀、长三角及珠三角区域PM2.5年均浓度将分别比2012年下降22.08%、33.99%、23.98%、24.04%。如果《计划》要求全部落实,可以实现空气质量改善目标。     

Multivariate approach for surface water quality mapping with special reference to nitrate enrichment in Sugadaira,Nagano Prefecture (Japan)

The hydrochemical study of the surface water along with land-use/land-cover study of its catchment area is useful for determining its suitability for support to aquatic ecosystem and agricultural purposes. The surface water quality around the wetland in Sugadaira region, Japan, is being affected both by complex hydrogeochemical processes and by anthropogenic activity, mainly intensive agricultural practices. Statistical analysis was carried out in this study using surface water chemistry data to enable hydrochemical evaluation of the water quality based on the ionic constituents, water types, and factors controlling water quality. Results show that the general trend of various ions was found to be Ca²⁺ > Mg²⁺ > Na⁺ > K⁺ and HCO₃ ⁻ > NO₃ ⁻ > SO₄ ²⁻ > Cl⁻. Spatial distribution of water chemistry shows that enrichment of NO₃ ⁻ has taken place along one side of the wetland that is exposed directly to human settlement and agricultural practices. This study is vital considering that pollution in a wetland indicates that poor health of water resources in the region not only makes the situation alarming but also calls for immediate attention.     

Integrating emergy evaluation and geographic information systems for monitoring resource use in the Abruzzo region (Italy)

This paper presents an application of an environmental accounting method, namely emergy evaluation, developed for the monitoring and assessment of environmental resource use by local communities in the Abruzzo Region (Italy). Once quantified and classified according to their origin (renewable or non-renewable, local or external), emergy flows were elaborated through a geographic information system (GIS) that allowed us to represent their spatial distribution throughout the region. Outcomes took the form of patterns in which different emergy intensities, namely empower (unit: seJ yr^?1), were represented through a graduated grey-scale and visualized on a cartographic basis. The concentration of emergy flows, depending on the activity of local communities, showed variable levels of environmental load in different areas. In particular, spatial zones with homogeneous values of empower density (unit: seJ yr^?1 km^?2) – high, medium and low – were detected in order to identify areas with a similar “thermodynamic” nature, emergy being a thermodynamics based function. This allowed for the representation, at a glance, of a kind of geography that mirrors the behavior of a population settled in an area as additional information for investigating the effects of the use of urban structures and functions and improving our understanding of regional systems. A combined use of emergy evaluation and GIS could thus provide a complementary view of a territorial system and inform policy makers for planning specific strategies of future development.     

Responses of Soil CO<Subscript>2</Subscript> Efflux to Precipitation Pulses in Two Subtropical Forests in Southern China

This study was designed to examine the responses of soil CO₂ efflux to precipitation pulses of varying intensities using precipitation simulations in two subtropical forests [i.e., mixed and broadleaf forests (MF and BF)] in southern China. The artificial precipitation event was achieved by spraying a known amount of water evenly in a plot (50 × 50 cm²) over a 30 min period, with intensities ranging from 10, 20, 50 and 100 mm within the 30 min. The various intensities were simulated in both dry season (in December 2007) and wet (in May 2008) season. We characterized the dynamic patterns of soil CO₂ efflux rate and environmental factors over the 5 h experimental period. Results showed that both soil moisture and soil CO₂ efflux rate increased to peak values for most of the simulated precipitation treatments, and gradually returned to the pre-irrigation levels after irrigation in two forests. The maximum peak of soil CO₂ efflux rate occurred at the 10 mm precipitation event in the dry season in BF and was about 3.5 times that of the pre-irrigation value. The change in cumulative soil CO₂ efflux following precipitation pulses ranged from −0.68 to 1.72 g CO₂ m⁻² over 5 h compared to the pre-irrigation levels and was generally larger in the dry season than in the wet season. The positive responses of soil CO₂ efflux to precipitation pulses declined with the increases in precipitation intensity, and surprisingly turned to negative when precipitation intensity reached 50 and 100 mm in the wet season. These findings indicated that soil CO₂ efflux could be changed via pulse-like fluxes in subtropical forests in southern China as fewer but extreme precipitation events occur in the future.     

Phenol degradation using combined effects of hydrodynamic cavitation and oxidant: Doehlert matrix

Hydrodynamic cavitation (HC)-based treatments have been proposed for the degradation of phenol as a toxic pollutant. The present work aimed to optimize the degradation of phenol using HC by means of Doehlert experimental design, which has not been previously addressed. Initially, operational parameters of hydraulic characteristics of the pump, inlet pressure, solution pH, and initial concentration were optimized; later, the effects of pH solution and H₂O₂ loading or initial pollutant concentration on phenol degradation were explored using the Doehlert experimental design. It was observed that phenol degradation is strongly dependent on the pH of the solution. Also, the acidic condition favors the formation of hydroxyl radicals and thus, the degradation of phenol. Based on the Doehlert matrix, the 94.1% phenol degradation and 68.60% total organic carbon (TOC) were obtained in 180 min at 304.5 mg/L of hydrogen peroxide at an initial concentration of 20 mg/L, 2.0 pH, and 90 psi inlet pressure, providing a cavitational yield of 6.33 × 10⁻⁶ mg/J and minimum treatment cost of US$/L 0.13. Overall, it has been observed that HC can be a promising route for the removal of pollutants (phenol) effectively using hydrogen peroxide as an additive.