Contribution of (222)Rn-bearing water to indoor radon and indoor air quality assessment in hot spring hotels of Guangdong, China

This study investigates the contribution of radon (²²²Rn)-bearing water to indoor ²²²Rn in thermal baths. The ²²²Rn concentrations in air were monitored in the bathroom and the bedroom. Particulate matter (PM, both PM₁₀ and PM_2.5) and carbon dioxide (CO₂) were also monitored with portable analyzers. The bathrooms were supplied with hot spring water containing 66-260 kBq m⁻³ of ²²²Rn. The results show that the spray of hot spring water from the bath spouts is the dominant mechanism by which ²²²Rn is released into the air of the bathroom, and then it diffuses into the bedroom. Average ²²²Rn level was 110-410% higher in the bedrooms and 510-1200% higher in the bathrooms compared to the corresponding average levels when there was no use of hot spring water. The indoor ²²²Rn levels were influenced by the ²²²Rn concentrations in the hot spring water and the bathing times. The average ²²²Rn transfer coefficients from water to air were 6.2 × 10⁻⁴-4.1 × 10⁻³. The 24-h average levels of CO₂ and PM₁₀ in the hotel rooms were 89% and 22% higher than the present Indoor Air Quality (IAQ) standard of China. The main particle pollutant in the hotel rooms was PM_2.5. Radon and PM₁₀ levels in some hotel rooms were at much higher concentrations than guideline levels, and thus the potential health risks to tourists and especially to the hotel workers should be of great concern, and measures should be taken to lower inhalation exposure to these air pollutants.     

Indoor and outdoor Radon concentration measurements in Sivas, Turkey, in comparison with geological setting

Indoor and soil gas Radon (²²²Rn) concentration measurements were accomplished in two stages in Sivas, a central eastern city in Turkey. In the first stage, CR-39 passive nuclear track detectors supplied by the Turkish Atomic Energy Authority (TAEA) were placed in the selected houses throughout Sivas centrum in two seasons; summer and winter. Before the setup of detectors, a detailed questionnaire form was distributed to the inhabitants of selected houses to investigate construction parameters and properties of the houses, and living conditions of inhabitants. Detectors were collected back two months later and analysed at TAEA laboratories to obtain indoor ²²²Rn gas concentration values. In the second stage, soil gas ²²²Rn measurements were performed using an alphameter near the selected houses for the indoor measurements. Although ²²²Rn concentrations in Sivas were quite low in relation with the allowable limits, they are higher than the average of Turkey. Indoor and soil gas ²²²Rn concentration distribution maps were prepared seperately and these maps were applied onto the surface geological map. In this way, both surveys were correlated with the each other and they were interpreted in comparison with the answers of questionnaire and the geological setting of the Sivas centrum and the vicinity.     

Development of an energy discriminate CR-39(®) nuclear track etch dosimeter for Radon-220 gas measurements

An energy discriminate CR-39^® nuclear track etch dosimeter for use in a ²²⁰Rn and ²²²Rn gas monitor has been developed and experimentally assessed. It utilises a thin film of Mylar^® C to attenuate the alpha particle energies to allow only the damage tracks created by the 8.785 MeV alpha particles emitted from ²¹²Po of the ²³²Th decay chain to be registered in the CR-39^® plaque, allowing for the direct measurement of ²²⁰Rn gas concentrations. The dosimeter was developed through a combination of experimental investigations and theoretical simulations using the Monte Carlo ion transport modelling program Stopping and Range of Ions in Materials (SRIM 2008). A film thickness of 54 μm has been shown to attenuate all alpha energies less then 7.7 MeV.     

Observations and modelling of thoron and its progeny in the soil-atmosphere-plant system

Samples of pasture vegetation, mainly Trifolium pratensis, were collected at the Botanic Garden of the University of Bologna during the period 1998-2000 and measured by gamma-spectrometry for determining thoron progeny. Concentrations of ²¹²Pb were between 1.5 and 20 Bq m⁻², with individual peaks up to 70 Bq m⁻². Soil samples were collected at the same location and physically characterised. Their chemical composition (particularly Th and U) was determined by X-ray fluorescence spectroscopy. Lead-212 on plants mainly originates from dry and wet deposition of this isotope generated in the lower atmosphere by the decay of its short-lived precursor ²²⁰Rn, which is produced in the upper soil layers as a member of the natural thorium decay chain and exhales into the atmosphere. Concentrations of ²²⁰Rn in the atmosphere depend on (1) the amount of Th present in soil, (2) the radon fraction which escapes from the soil minerals into the soil pore space, (3) its transport into the atmosphere, and (4) its redistribution within the atmosphere. The mobility of radon in soil pore space can vary by orders of magnitude depending on the soil water content, thus being the main factor for varying concentrations of ²²⁰Rn and ²¹²Pb in the atmosphere. We present a simple model to predict concentrations of thoron in air and its progeny deposited from the atmosphere, which takes into account varying soil moisture contents calculated by the OPUS code. Results of this model show close agreement with our observations.     

A survey of indoor workplace radon concentration in Japan

Radon ((222)Rn) concentration was measured at indoor workplaces in Japan to estimate effective dose to the public from (222)Rn and its progeny. Measurements were made from 2000 to 2003 at 705 sites in four categories of office, factory, school and hospital. Passive type Rn monitors equipped with two sheets of polycarbonate thin films for measuring radon concentrations were installed at observation sites and replaced every 3 months to observe seasonal variations in (222)Rn concentrations. The range of annual mean (222)Rn concentrations for all sites was 1.4-182 Bq m(-3), with the arithmetic mean and standard deviation were 20.8 and 19.5 Bq m(-3). Annual mean (222)Rn concentration observed at office, factory, school and hospital were 22.6, 10.1, 28.4 and 19.8 Bq m(-3), respectively. Seasonal variations in (222)Rn concentrations at offices, schools and hospitals were similar to those found in dwellings, and variations in factories were similar to those found in outdoor environments. (222)Rn concentration observed in every quarter period was found to decrease as follows: school>office>hospital>factory. The average effective dose to the public due to (222)Rn was estimated to be 0.41 mSv y(-1) weighted by the working population. Considering the (222)Rn exposure in indoor workplaces, effective dose to the general public is estimated to be in the range from approximately 0.42 to 0.52 mSv y(-1).     

Radon concentration in indoor occupational environments in Aomori Prefecture,Japan

The (222)Rn concentrations in indoor workplaces were measured in Aomori Prefecture, Japan, and the results are reported here. This survey was part of a program to measure background natural radiation dose rate in the prefecture where the first Japanese nuclear fuel cycling facilities are now under construction.The survey of the (222)Rn concentrations in indoor workplaces was carried out at 107 locations from 1996 to 1998. The (222)Rn concentrations were measured for approximately one year at each site with passive Rn detectors, which used a polycarbonate film for counting alpha-rays and could separate concentrations of (222)Rn from (220)Rn. Weeklong measurements of (222)Rn concentration and working level were carried out with active detectors to get the ratio of (222)Rn concentration during working hours to non-working hours as well as equilibrium factors in selected locations.Diurnal variation of (222)Rn concentration depended on building structure, air-conditioning, time of day and day of the week (week days or weekend). The (222)Rn concentration during working hours was generally lower than that in non-working hours. Although the annual average (222)Rn concentration in indoor occupational environments was higher than that in dwellings, radiation dose for Aomori Prefecture residents from Rn in the former was 14% of the total indoor dose by Rn because of the lower concentration in working hours and lower occupancy factor.     

Radon mapping by retrospective measurements - an approach based on CDs/DVDs

This article points out the ability to map retrospective ²²²Rn concentrations by home stored CDs/DVDs. The method employs the high radon absorption ability of the polycarbonate material of CDs and DVDs and their track-etch properties. The principle steps for the application of the method are addressed. The possibility for individual a posteriori calibration is studied, demonstrating that better than 10% accuracy in retrospective measurements is potentially achievable. Results from retrospective measurements in three different regions are shown, demonstrating the potential of the method for large-scale radon mapping. Comparison with independently evaluated retrospective ²²²Rn concentrations in places with known radon history was made and very good correspondence was observed. The experience indicates that the method can be used for large scale retrospective radon mapping and its applications can be expanded towards mapping of radon concentrations in water and soil gas.     

A nationwide survey of outdoor radon concentration in Japan

Nationwide outdoor radon (222Rn) concentrations in Japan were measured to survey the environmental outdoor 222Rn level and to estimate the effective dose to the general public from 222Rn and its progeny. The 222Rn concentration was measured with a passive-type radon monitor. The 222Rn monitors were installed at about 700 points throughout Japan from 1997 to 1999. The annual mean 222Rn concentration in Japan was estimated from four quarters measurements of 47 prefectures in Japan. Nationwide outdoor mean 222Rn concentration was 6.1 Bq m(-3). This was about 40% of the indoor 222Rn concentration in Japan. The 222Rn concentration in Japan ranged from 3.3 Bq m(-3) in the Okinawa region to 9.8 Bq m(-3) in the Chugoku region, reflecting geological characteristics. Seasonal variation of outdoor 222Rn concentration was also found to be lowest in July to September, and highest in October to December. From the results of this 222Rn survey and previous indoor 222Rn survey program, the effective dose to the general public from 222Rn and its progeny was estimated to be 0.45 mSv y(-1).     

Rn concentration in public secondary schools in Galicia (Spain)

In the framework of a ²²²Rn screening campaign that was carried out in 58 public secondary schools in Galicia (NW Spain), the largest radon-prone area in the Iberian Peninsula, a positive correlation between indoor ²²²Rn concentration and outdoor gamma exposure rate was obtained. A new approach to the data acquisition in screening surveys was tested, improving the performances of this type of study and gathering useful data for future remedial actions. Using short-period detectors (charcoal canisters) firstly, in order to detect places showing ²²²Rn concentrations over 400 Bq m⁻³, the number of locations to be measured with long-period detectors (etched track detectors) is reduced. In this screening campaign, 34% of the schools surveyed presented at least one site exceeding the 400 Bq m⁻³ recommended action level established by the EU, and 15% had at least one site with ²²²Rn values over 800 Bq m⁻³. The maximum value recorded was 2084 ± 63 Bq m⁻³. These results are discussed and compared with data obtained in schools of several countries with similar geology. Seven schools were also studied for seasonal variations of ²²²Rn activity concentration. The results were not conclusive, and no significant correlation between season and ²²²Rn concentration was established. Finally, a continuous ²²²Rn concentration monitor was placed in the secondary school exhibiting a mean value of the ²²²Rn concentration very close to 400 Bq m⁻³. Maximum ²²²Rn concentration values were found to occur at times when the school was unoccupied.     

Seasonal variations of Rn concentrations in the air of a tunnel located in Nagano city

The seasonal variation of 222Rn concentrations in the air of tunnels constructed during World War II at Nagano City has been investigated. The determination of 222Rn concentrations in tunnel air was performed using a solid-state nuclear track detector technique. The monthly radon concentrations changed smoothly, decreasing towards winter and increasing towards summer, and it was found that the concentrations strongly correlate with the temperature difference between the inside and the outside of the tunnel. In the innermost areas of the tunnel, the maximum concentration was observed in July, its value being about 6500 Bq m (-3). The concentrations of radon in the tunnel air decrease exponentially towards the openings of the tunnel, which indicates that the radon concentration in the tunnel is basically governed by diffusion and mixing of radon gas with air. These observations lead to the conclusion that the seasonal variation of the radon concentration in the tunnel air is mainly caused by a convection current due to a stack effect induced by the temperature difference between the tunnel air and the outside air.     

Inverse modeling of Asian Rn flux using surface air Rn concentration

When used with an atmospheric transport model, the ²²²Rn flux distribution estimated in our previous study using soil transport theory caused underestimation of atmospheric ²²²Rn concentrations as compared with measurements in East Asia. In this study, we applied a Bayesian synthesis inverse method to produce revised estimates of the annual ²²²Rn flux density in Asia by using atmospheric ²²²Rn concentrations measured at seven sites in East Asia. The Bayesian synthesis inverse method requires a prior estimate of the flux distribution and its uncertainties. The atmospheric transport model MM5/HIRAT and our previous estimate of the ²²²Rn flux distribution as the prior value were used to generate new flux estimates for the eastern half of the Eurasian continent dividing into 10 regions.The ²²²Rn flux densities estimated using the Bayesian inversion technique were generally higher than the prior flux densities. The area-weighted average ²²²Rn flux density for Asia was estimated to be 33.0 mBq m⁻² s⁻¹, which is substantially higher than the prior value (16.7 mBq m⁻² s⁻¹). The estimated ²²²Rn flux densities decrease with increasing latitude as follows: Southeast Asia (36.7 mBq m⁻² s⁻¹); East Asia (28.6 mBq m⁻² s⁻¹) including China, Korean Peninsula and Japan; and Siberia (14.1 mBq m⁻² s⁻¹). Increase of the newly estimated fluxes in Southeast Asia, China, Japan, and the southern part of Eastern Siberia from the prior ones contributed most significantly to improved agreement of the model-calculated concentrations with the atmospheric measurements. The sensitivity analysis of prior flux errors and effects of locally exhaled ²²²Rn showed that the estimated fluxes in Northern and Central China, Korea, Japan, and the southern part of Eastern Siberia were robust, but that in Central Asia had a large uncertainty.     

Dynamics, deterministic nature and correlations of outdoor (222)Rn and (220)Rn progeny concentrations measured at Bacău, Romania

The long-term variation, nature and correlations of outdoor ²²²Rn and ²²⁰Rn progeny concentrations measured during the period 1994-2009 were investigated. The time series of data were obtained within the framework of the monitoring program performed by the Environmental Radioactivity Monitoring Station (ERMS) Bac?u, a component part of the National Environmental Radioactivity Survey Network (NERSN), coordinated by National Environmental Protection Agency (NEPA). The measuring method is based on the total beta measurements of atmospheric aerosol filters, using a low background total beta counter and (⁹⁰Sr/Y) reference standard. Analysis of the time series of progeny concentrations in the low atmosphere makes evident different patterns of variation of these concentrations: diurnal, seasonal and annual. A possible relationship of progeny concentration increase with global warming is emphasized. In order to find the dominant frequency of the physical processes determining progeny concentration variability the power spectrum has been used. The deterministic nature of the time series of concentrations has been studied making use of the autocorrelation function and stationarity of the original data and of their phase randomized time series. Also, the correlations with meteorological parameters have been investigated using Pearson’s correlation coefficient with corresponding level of significance.     

Bronchial Rn dose survey for residences

The bronchial dosimeter for Rn progeny proposed by Yu and Guan in 1998 was employed to survey the bronchial dose from Rn progeny in 30 residences in Hong Kong. An average bronchial deposition fraction of Rn progeny was obtained as 0.0334, which gave an average dose conversion factor (DCF) of 8.5 mSv WLM-1. The mean values of potential alpha energy concentration (PAEC) deposited in the tracheobronchial region (PAECT-B), total PAEC in air (PAECT), annual effective dose (E), concentration of Rn gas (RC) and annual dose conversion factor (ADCF) for all the residential sites combined were 0.11 +/- 0.05, 3.1 +/- 1.4 mWL, 1.2 +/- 0.5 mSv yr-1, 23 +/- 10 Bq m-3 and 0.055 +/- 0.020 (mSv yr-1 per Bqm-3), respectively, with air-conditioned sites (AC sites) and non-AC sites having significantly different mean ADCF values. The indoor relative humidity affected PAECT and RC with high confidence levels (> 95%).     

Present status of Rn in groundwater in Extremadura

Radon-222 was measured in groundwater sources of Extremadura (Spain), analyzing 350 samples from private and public springs, wells, and spas by liquid scintillation counting (LSC) and gamma spectrometry. The ²²²Rn activity concentrations ranged from 0.24 to 1168 Bq L⁻¹. The statistical analysis showed a log-normal distribution with a mean of (111 ± 7) Bq L⁻¹ and a median of (36 ± 3) Bq L⁻¹. A hydrogeological study revealed correlations between the activity concentration and the aquifer material's characteristics. A map of ²²²Rn in groundwater was elaborated and compared with the natural gamma radiation map for this region. About 35% of the samples showed ²²²Rn activity concentrations above the Euratom recommended limit of 100 Bq L⁻¹. Three uranium series radionuclides (²³⁸U, ²³⁴U, and ²²⁶Ra) were also assayed by alpha-particle spectrometry, estimating the annual effective dose due to the presence of these natural radionuclides in drinking water.     

222Rn and 220Rn concentrations in soil gas of Karkonosze-Izera Block (Sudetes, Poland)

Soil gas 222Rn and 220Rn concentrations were measured at 18 locations in the Karkonosze-Izera Block area in southwestern Poland. Measurements were carried out in surface air and at sampling depths of 10, 40 and 80 cm. Surface air 222Rn concentrations ranged from 4 to 2160 Bq m(-3) and 220Rn ranged from 4 to 228 Bq m(-3). The concentrations for 10 and 40 cm varied from 142 Bq m(-3) to 801 kBq m(-3) and 102 Bq m(-3) to 64 kBq m(-3) for 222Rn and 220Rn, respectively. At 80 cm 222Rn concentrations ranged from 94 Bq m(-3) to >1 MBq m(-3). The 220Rn concentrations at 80 cm varied from 45 Bq m(-3) to 48 kBq m(-3). The concentration versus depth profiles for 222Rn differed for soils developed on fault zones, uranium deposits or both. Atmospheric air temperature and soil gas 222Rn and 220Rn were negatively correlated. At sampling sites with steep slopes, 220Rn concentrations decreased with depth.     

A Monte Carlo study of radon detection in cylindrical diffusion chambers

The functioning of radon diffusion chambers was studied using the Monte Carlo code RAMMX developed here. The alpha particles from radon are assumed randomly produced in the volume of the cylinder, and those from the progeny are assumed to originate randomly at the cylindrical surface. The energy spectrum, the distribution of incident angles, and the distribution of path lengths of the alpha particles on the detector were obtained. These quantities vary depending on input parameters such as initial alpha particle energy, radius and depth of the diffusion chamber, detector size and atmospheric pressure. The calculated energy spectrum for both ²²²Rn and ²²⁰Rn was compared with experiment, permitting the identification of each peak and its origin, and a better understanding of radon monitoring. Three aspects not considered in previous calculations are progeny alphas coming from surfaces of the monitor, taking into account the atmospheric pressure, and including the isotope ²²⁰Rn.     

Estimation of 222Rn release from the phosphogypsum board used in housing panels

Phosphogypsum board is a popular construction material used for housing panels in Korea. Phosphogypsum often contains (226)Ra which decays into (222)Rn through an alpha transformation. (222)Rn emanated from the (226)Ra-bearing phosphogypsum board has drawn the public concern due to its potential radiological impacts to indoor occupants. The emanation rate of (222)Rn from the board is estimated in this paper. A mathematical model of the emanation rate of (222)Rn from the board is presented and validated through a series of experiments. The back diffusion effect due to accumulation of (222)Rn-laden air was incorporated in the model and found to have a strong impact on the (222)Rn emanation characteristics.     

Soil gas (²²²Rn, CO₂, ⁴He) behaviour over a natural CO₂ accumulation, Montmiral area (Drôme, France): geographical, geological and temporal relationships

The south east basin of France shelters deep CO₂ reservoirs often studied with the aim of better constraining geological CO₂ storage operations. Here we present new soil gas data, completing an existing dataset (CO₂, ²²²Rn, ⁴He), together with mineralogical and physical characterisations of soil columns, in an attempt to better understand the spatial distribution of gas concentrations in the soils and to rule on the sealed character of the CO₂ reservoir at present time.Anomalous gas concentrations were found but did not appear to be clearly related to geological structures that may drain deep gases up to the surface, implying a dominant influence of near surface processes as indicated by carbon isotope ratios. Coarse grained, quartz-rich soils favoured the existence of high CO₂ concentrations. Fine grained clayey soils preferentially favoured the existence of ²²²Rn but not CO₂. Soil formations did not act as barriers preventing gas migrations in soils, either due to water content or due to mineralogical composition. No abundant leakage from the Montmiral reservoir can be highlighted by the measurements, even near the exploitation well. As good correlation between CO₂ and ²²²Rn concentrations still exist, it is suggested that ²²²Rn migration is also CO₂ dependent in non-leaking areas - diffusion dominated systems.     

Natural radionuclide content in building materials and gamma dose rate in dwellings in Cuba

An extensive research project to investigate the radioactive properties of Cuban building materials was carried out because there is a lack of information on the radioactivity of such materials in Cuba. In the framework of this project 44 samples of commonly used raw materials and building products were collected in five Cuban provinces. The activity concentrations of natural radionuclides were determined by gamma ray spectrometry using a p-type coaxial high purity germanium detector and their mean values were in the ranges: 9-857Bqkg(-1) for (40)K; 6-57Bqkg(-1) for (226)Ra; and 1.2-22Bqkg(-1) for (232)Th. The radium equivalent activity in the 44 samples varied from 4Bqkg(-1) (wood) to 272Bqkg(-1) (brick). A high pressure ionisation chamber was used to measure the indoor absorbed dose rate in 543 dwellings and workplaces in five Cuban provinces. The average absorbed dose rates in air ranged from 43nGyh(-1) (Holguín) to 73nGyh(-1) (Camagüey) and the corresponding population-weighted annual effective dose due to external gamma radiation was estimated to be 145+/-40microSv. This value is 51% lower than the effective dose due to internal exposure from inhalation of decay products of (222)Rn and (220)Rn and it is 16% higher than the calculated value for the typical room geometry of a Cuban house.     

Doses of external exposure in Jordan house due to gamma-emitting natural radionuclides in building materials

The use of building materials containing naturally occurring radionuclides as ⁴⁰K, ²³²Th, and ²³⁸U and their progeny results in external exposures of the residents of such buildings. In the present study, indoor dose rates for a typical Jordan concrete room are calculated using Monte Carlo method. Uniform chemical composition of the walls, floor and ceiling as well as uniform mass concentrations of the radionuclides in walls, floor and ceiling are assumed.Using activity concentrations of natural radionuclides typical for the Jordan houses and assuming them to be in secular equilibrium with their progeny, the maximum annual effective doses are estimated to be 0.16, 0.12 and 0.22 mSv a⁻¹ for ⁴⁰K, ²³²Th- and ²³⁸U-series, respectively. In a total, the maximum annual effective indoor dose due to external γ-radiation is 0.50 mSv a⁻¹. Additionally, organ dose coefficients are calculated for all organs considered in ICRP Publication 74. Breast, skin and eye lenses have the maximum equivalent dose rate values due to indoor exposures caused by the natural radionuclides, while equivalent dose rates for uterus, colon (LLI) and small intestine are found to be the smallest. More specifically, organ dose rates (nSv a⁻¹ per Bq kg⁻¹) vary from 0.044 to 0.060 for ⁴⁰K, from 0.44 to 0.60 for radionuclides from ²³⁸U-series and from 0.60 to 0.81 for radionuclides from ²³²Th-series.The obtained organ and effective dose conversion coefficients can be conveniently used in practical dose assessment tasks for the rooms of similar geometry and varying activity concentrations and local-specific occupancy factors.