煤与瓦斯共采在错层位巷道布置中的机理研究及应用构想

为了完善现有煤与瓦斯共采技术，创新煤与瓦斯共采方法，对错层位巷道布置下的煤与瓦斯共采系统展开研究，利用相似模拟试验，分析错层位巷道布置覆岩运动情况，预测其开采围岩裂隙发育和瓦斯运移形式，提出了创新煤与瓦斯共采技术构想。研究结果表明:采空区覆岩三带高度随接续工作面的增加而增大，相邻采空区垮落矸石压实区呈现“O-L-O”形变化，多个相邻采空区覆岩出现大“O”形圈裂隙带；相邻采空区内瓦斯可实现相互运移，大“O”形圈裂隙带内赋存大量瓦斯气体；研究提出了地面钻井抽采瓦斯、走向高位瓦斯抽采巷和外错尾巷穿层钻孔3种煤与瓦斯共采技术，比传统巷道布置情况下的煤与瓦斯共采技术在安全、经济等方面更具优势。     

模糊综合评价法在钢铁企业安全投资合理性评价中的应用

为了对钢铁企业安全投资进行模糊综合评价,建立了钢铁企业安全投资的评价体系,确定各因素的权重。得出模糊综合评价矩阵,可对各因素进行评价分析;得出某钢铁企业安全投资现状分数为83.9分,等级为较好,需着重加强安全培训、劳保品、工业卫生等人因素方面的投资;在环境方面的投资较合理。     

The place of nature in conservation conflicts

Conservation conflicts are gaining importance in contemporary conservation scholarship such that conservation may have entered a conflict hype. We attempted to uncover and deconstruct the normative assumptions behind such studies by raising several questions: what are conservation conflicts, what justifies the attention they receive, do conservation-conflict studies limit wildlife conservation, is scientific knowledge stacked against wildlife in conservation conflicts, do conservation-conflict studies adopt a specific view of democracy, can laws be used to force conservation outcomes, why is flexibility needed in managing conservation conflicts, can conservation conflicts be managed by promoting tolerance, and who needs to compromise in conservation conflicts? We suggest that many of the intellectual premises in the field may defang conservation and prevent it from truly addressing the current conservation crisis as it accelerates. By framing conservation conflicts as conflicts between people about wildlife or nature, the field insidiously transfers guilt, whereby human activities are no longer blamed for causing species decline and extinctions but conservation is instead blamed for causing social conflicts. When the focus is on mitigating social conflicts without limiting in any powerful way human activities damaging to nature, conservation-conflict studies risk keeping conservation within the limits of human activities, instead of keeping human activities within the limits of nature. For conservation to successfully stop the biodiversity crisis, we suggest the alternative goal of recognizing nature's right to existence to maintenance of ecological functions and evolutionary processes. Nature being a rights bearer or legal person would imply its needs must be explicitly taken into account in conflict adjudication. If, even in conservation, nature's interests come second to human interests, it may be no surprise that conservation cannot succeed.     

300MW锅炉低NOx燃烧系统改造效果分析

针对日益严重的环境污染、锅炉热效率低等问题，阐述了燃煤锅炉炉内空间分级燃烧技术、煤粉浓淡高效分离技术改造项目和特点，提出了对燃烧器系统、一次风管道、二次风系统和空预器系统等系统进行具体的低氮改造措施。分析了300 MW燃煤锅炉低氮改造后的热经济性和安全性。经试验验证，1号锅炉低氮改造后，锅炉NOx 排放量大幅减少，排放浓度降到了280 mg／m3。     

大肠杆菌吸附-化学还原法用废含金催化剂制备金纳米线

采用大肠杆菌吸附-化学还原法,以大肠杆菌(ECCs)为模板、十六烷基三甲基溴化铵为保护剂、抗坏血酸为还原剂,由废含金催化剂制备金纳米线(AuNWs)。采用XRD,SEM,TEM等技术对AuNWs进行表征。研究了AuNWs对罗丹明6G(R6G)和4-巯基苯甲酸(4-MBA)的拉曼散射信号的增强效果。实验结果表明:在制备过程中加入微生物ECCs,可使金回收率提高约20百分点;当溶液pH小于4时,反应2 h后,有大量呈线状的AuNWs聚集沉降,金回收率可达99%1以上。表征结果显示,AuNWs呈多晶结构,晶格间距为0.23 nm。表面增强拉曼散射分析表明,AuNWs对R6G和4-MBA具有良好的拉曼光谱增强性能。     

Research on flow assurance of deepwater submarine natural gas pipelines: Hydrate prediction and prevention

The formation of hydrate will lead to serious flow assurance problems in deepwater submarine natural gas transmission pipelines. However, the accurate evaluation model of the hydrate blocking risk for submarine natural gas transportation is still lacking. In this work, a novel model is established for evaluating the hydrate risk in deepwater submarine gas pipelines. Based on hydrate growth-deposition mechanism, the mathematical model mainly consists of mass, momentum and energy conservation equations. Meantime, the model results are obtained by finite difference method and iterative technique. Finally, the model has been applied in the production of deepwater gas field (L Gas Field) in China, and the sensitivity analysis of relevant parameters has been carried out. The results show that: (a). The mathematical model can well predict the hydrate blockage risk in deepwater natural gas pipelines after verification. (b). Hydrate is easily formed at the intersection of horizontal pipeline and vertical riser, and the maximum blocking position often occurs in middle of the riser. (c). The hydrate blockage degree and length of hydrate formation region (HFR) decrease with the increase of gas transport rate. (d). The hydrate blockage degree and length of HFR decrease with the increase of gas transport temperature. (e). The hydrate blockage degree and length of HFR increase with the extension of horizontal pipeline. (f). Injecting inhibitors can effectively inhibit hydrate formation and blockage, but the improvement of transmission measures can significantly reduce the dosage of inhibitor. It is concluded that measures such as increasing gas transportation rate and temperature, shortening horizontal pipeline length, optimizing inhibitor injection point and injection rate can play a safe, economic and efficient role in hydrate preventing and controlling.     

A new leak location method based on leakage acoustic waves for oil and gas pipelines

In order to study a new leak detection and location method for oil and natural gas pipelines based on acoustic waves, the propagation model is established and modified. Firstly, the propagation law in theory is obtained by analyzing the damping impact factors which cause the attenuation. Then, the dominant-energy frequency bands of leakage acoustic waves are obtained through experiments by wavelet transform analysis. Thirdly, the actual propagation model is modified by the correction factor based on the dominant-energy frequency bands. Then a new leak detection and location method is proposed based on the propagation law which is validated by the experiments for oil pipelines. Finally, the conclusions and the method are applied to the gas pipelines in experiments. The results indicate: the modified propagation model can be established by the experimental method; the new leak location method is effective and can be applied to both oil and gas pipelines and it has advantages over the traditional location method based on the velocity and the time difference. Conclusions can be drawn that the new leak detection and location method can effectively and accurately detect and locate the leakages in oil and natural gas pipelines.     

欧盟空气质量监测现状及加强我国空气质量监测体系建设的建议

从欧盟空气质量监测政策和监测网络建设现状两个方面描述了欧盟空气质量监测发展现状。分析了我国空气污染现状和空气质量监测体系中存在的问题,并借鉴欧盟的经验,提出了加大政策支持和财政保障力度、逐步健全空气质量监测网络体系、加强空气质量监测技术研究、完善空气质量监测数据库、开展能力建设、提高公众参与度等加强我国空气质量监测体系建设的建议。     

Ti3C2纳米层状材料对废水中Cr（Ⅵ）的光催化去除性能

以Ti₃AlC₂为原料,采用HF刻蚀工艺制备出12种Ti₃C₂纳米层状材料,对其形貌进行了表征,并考察了以其作为光催化剂对废水中Cr（Ⅵ）的处理效果。实验结果表明：HF体积分数为80%、刻蚀时间为48 h时得到的MX-80-48的形貌较好;MX-80-48具有类似石墨烯的二维层状结构,纳米层厚度约20~50 nm,孔径2~10 nm,比表面积14.8 m²/g,在400~700 nm可见光范围内表现出强烈的吸光性;当Cr（Ⅵ）的初始质量浓度为40.00 mg/L、MX-80-48投加量为200 mg/L、pH=2、反应时间4 h（暗反应1 h+光照3 h）时,Cr（Ⅵ）去除率可达100%。     

加速溶剂同时萃取和净化-气相色谱-三重四极杆串联质谱测定土壤和沉积物中8种多溴联苯醚

建立了土壤和沉积物中8种多溴联苯醚(PBDEs,BDE-28、BDE-47、BDE-99、BDE-100、BDE-153、BDE-154、BDE-183和BDE-209)加速溶剂同时萃取和净化-气相色谱-三重四极杆串联质谱(ASE-GC-MS-MS)的分析方法。通过优化加速溶剂萃取与弗罗里硅土在线净化和串联质谱多反应监测模式的条件,较好地去除基质干扰,并提高了三重四极杆串联质谱定性的准确性及定量的灵敏性。该方法采用改进的色谱柱能同时分析包括高溴代联苯醚BDE-209在内的8种PBDEs,其浓度范围为1～100 ng/mL(BDE-209为10～1 000 ng/mL),线性良好,线性回归系数均大于0.997。方法检出限为0.004～0.1 ng/g,方法回收率为75%～110%,方法精密度为2.4%～15.6%。适于批量处理土壤和沉积物中含有多组分痕量PBDEs的样品。