Passive sampling in combination with thermal desorption and gas chromatography as a tool for self-assessment of chemical exposure

Diffusive samplers for monitoring of air quality are user-friendly devices that can normally be operated by the user himself. Hence these samplers are suitable for self-assessment. Practical and work organisational aspects of self-assessment of chemical exposure were studied in different occupational settings. It was found that the diffusive sampler used in these studies, the Perkin-Elmer tube in combination with thermal desorption, worked well for the purpose and could be correctly handled by the individuals using it. The results from self-assessments agreed well with expert measurements carried out by an occupational hygienist. However, in order to obtain a sustainable system of self-assessment strong organizational support is needed.     

Parental concern about children's traffic safety in residential neighborhoods

One hundred and five parents and nonparents responded to a questionnaire consisting of evaluative ratings (general evaluation, social status and safety concern) of six familiar residential neighborhoods; ratings of the traffic accident risk children in the age ranges 2–4, 5–6, 7–9 and 10–12 years run in these neighborhoods; and, finally, ratings of the strengths attributed to factors as causes of traffic accidents (environment, children, parents, drivers and chance). Across neighborhoods and age ranges of children, risk perceptions were found to be related to the rated strengths of the causes. Low-traffic volume neighborhoods were perceived as less risky and were attributed as less strong causes than high-traffic volume neighborhoods were. Perceived risk increased with age of child to a maximum, then decreased. The same relationship with age was found for the attributed causes environment and drivers. The strength of parents as cause was rated to decrease while the strength of child as cause was rated to increase with age. Chance was rated as the weakest cause and the rated strength did not vary across neighborhoods or age. Neither parentship nor gender, singly or in combination, had any clear effects. For parents and nonparents alike the general evaluation of the neighborhoods was influenced by safety concern but not by the particular aspect investigated, i.e. perceived traffic accident risk to children.     

Impact of air pollution on floral morphology of Cassia siamea Lamk

Cassia siamea plants growing at two different sites (polluted and non-polluted) on two important roads of Agra city exhibited significant differences in their flowering phenology and floral morphology. The flowering in plants growing at polluted site is delayed and there was a marked reduction in flowering density, flowering period, size of floral parts, pollen fertility, fruit and seed-set. SEM observations revealed the presence of well developed glandular structures and reduction in the number and size of large stomata on the anther surface at polluted site. These changes were found to be closely associated with the extent of air pollution caused mainly by significant in the number of automobiles.     

UVR-induced photoinhibition of summer marine phytoplankton communities from Patagonia

During austral summer 2006, experiments were carried out to evaluate the effects of ultraviolet radiation (UVR, 280–400 nm) on carbon fixation of natural phytoplankton assemblages from Patagonia (Argentina). Surface water samples were collected (ca. 100 m offshore) at mid morning using an acid-cleaned (1 N HCl) dark container. The short-term impact of UVR (measured as radiocarbon incorporation) was immediately assessed by exposing samples to three artificial illumination treatments: PAR (400–700 nm), PAR + UV-A (320–700 nm), and PAR + UV-A + UV-B (280–700 nm). Pico-nanoplankton characterized the assemblages, and taxon-specific pigment fingerprinting combined with CHEMTAX and supplemented with microscopic observations showed varied proportions of diatoms, chlorophytes, and cyanobacteria throughout January–February 2006. Photosynthetic efficiency, as assessed through assimilation numbers, was high [between 4.4 and 10.4 μg C (μg chl-a)⁻¹ h⁻¹], and it was probably favored by the supply of inorganic nutrients from the Chubut River. UVR-induced photoinhibition appeared to be related to the taxonomic composition: in general, higher photoinhibition was observed when diatoms dominated, whereas this was lower when samples were dominated by chlorophytes. Our data suggest that xanthophyll pigments might have provided only limited protection in these already highlighted acclimated assemblages.     

Fast removal of heavy metals from water and soil samples using magnetic Fe3O4 nanoparticles

Environmental Science and Pollution Research - Heavy metal discharge from anthropogenic sources on open soil surfaces and in natural water bodies poses serious environmental and health concerns. In...     

Hydrochemical profile for assessing the groundwater quality of Sambhar lake City and its Adjoining area

Quality assessment of water is essential to ensure sustainable safe use of it for drinking, agricultural, and industrial purposes. For the same purpose the study was conducted for the samples of water of Sambhar lake city and its adjoining areas. The standard methods of APHA were used to analysis 15 samples collected from hand pumps and tube wells of the specified area. The analytical results show higher concentration of total dissolved solids, electrical conductivity sodium, nitrate, sulfate, and fluoride, which indicate signs of deterioration but values of pH, calcium, magnesium, total hardness, and carbonate are within permissible limits as per WHO standards. From the Hill-piper trilinear diagram, it is observed that the majority of groundwater from sampling stations are sodium?Cpotassium?Cchloride?Csulfate type water. The values of sodium absorption ratio and electrical conductivity of the groundwater were plotted in the US salinity laboratory diagram for irrigation water. Only the one sample fall in C₃S₁ quality with high salinity hazard and low sodium hazard. Other samples fall in high salinity hazard and high sodium hazard. Chemical analysis of groundwater shows that mean concentration of cation is in order sodium > magnesium > calcium > potassium while for the anion it is chloride > bicarbonate > nitrate > sulfate.     

Impact and adaptation opportunities for European agriculture in response to climatic change and variability

Climate change, involving changes in mean climate and climatic variability, is expected to severely affect agriculture and there is a need to assess its impact in order to define the appropriate adaptation strategies to cope with. In this paper, we projected a scenario of European agriculture in a +2°C (above pre-industrial levels) world in order to assess the potential effect of climatic change and variability and to test the effectiveness of different adaptation options. For this purpose, the outputs of HadCM3 General Circulation Model (GCM) were empirically downscaled for current climate (1975–2005) and a future period (2030–2060), to feed a process-based crop simulation model, in order to quantify the impact of a changing climate on agriculture emphasising the impact due to changes in the frequency of extreme events (heat waves and drought). The same climatic dataset was used to compare the effectiveness of different adaptations to a warmer climate strategies including advanced or delayed sowing time, shorter or longer cycle cultivar and irrigation. The results indicated that both changes in mean climate and climate variability affected crop growth resulting in different crop fitting capacity to cope with climate change. This capacity mainly depended on the crop type and the geographical area across Europe. A +2°C scenario had a higher impact on crops cultivated over the Mediterranean basin than on those cultivated in central and northern Europe as a consequence of drier and hotter conditions. In contrast, crops cultivated in Northern Europe generally exhibited higher than current yields, as a consequence of wetter conditions, and temperatures closer to the optimum growing conditions. Simple, no-cost adaptation options such as advancement of sowing dates or the use of longer cycle varieties may be implemented to tackle the expected yield loss in southern Europe as well as to exploit possible advantages in northern regions.