Distribution and fractionation of phosphorus, cadmium, nickel, and lead in calcareous soils amended with composts

Composts improve organic carbon content and nutrients of calcareous soils but the accumulation and distribution of phosphorus and heavy metals among various fractions in soil may vary under the south Florida conditions. The accumulation of P, Cd, Ni, and Pb with depth and the distribution of water soluble, exchangeable, carbonate, Fe-Mn oxides, organic and residual forms of each element were investigated in soils amended with municipal solid waste (MSW) compost, co-compost and biosolids compost and inorganic fertilizer (as control). Total concentrations of P, Cd, Ni, and Pb were higher in the 0-22 cm soil layers and decreased considerably in the rock layers. These elements were in the decreasing order of P > Pb > Ni > Cd. Amounts of water soluble and exchangeable forms of P, Cd, Ni and Pb were negligible at 0-22 cm soil depths except for Cd in the 10-22 cm depth. Amending calcareous soil with either organic or inorganic amendments rendered phosphorus, nickle and lead in the residual form followed by Fe-Mn oxides form in the 0-10 and 10-22 cm soil layers. Cadmium was predominantly in the Fe-Mn oxides fraction followed by the residual and carbonate forms in both soil layers. A significant positive correlation was found between various organic carbon fractions and organic forms of P, Cd and Pb in the surface soil layer. Soil amended with MSW compost had higher concentration of Cd in the organic fraction whereas, co-compost and MSW compost amended soil had higher concentrations of organic Ni fraction in the 0-10 cm soil layer.     

Variation in sex steroids and phallus size in juvenile American alligators (Alligator mississippiensis) collected from 3 sites within the Kissimmee-Everglades drainage in Florida (USA)

This 3-year study was designed to examine variation in plasma sex steroids, phallus size, and the standard error (S.E.) associated with these endpoints in juvenile alligators collected from 3 sites within the Kissimmee-Everglades drainage (Florida, USA) with varying concentrations of sediment organochlorine contaminants. We hypothesized that decreased plasma sex steroid concentrations and phallus size would be observed in the higher contaminant site when compared to the intermediate and lower contaminant sites. Furthermore, we hypothesized that greater S.E. associated with these endpoints would be observed for the populations from more contaminated sites. We found that differences existed with females from the higher contaminant site exhibiting lower plasma estradiol-17beta (E2) and testosterone (T) concentrations. Males from the higher contaminant site exhibited smaller phallus sizes than males from the intermediate and lower contaminant sites. Smaller phallus size in this case differed from that reported in Lake Apopka male alligators [Gen. Comp. Endocrinol. 116 (1999) 356] in that a significant positive relationship between body size and phallus size existed. No difference among sites was observed in plasma T for males. Lower S.E. was associated with E2 and T concentrations in females from the higher contaminant site and in phallus size in males from the higher contaminant site. This pattern was opposite to what we had hypothesized. We concluded that variation in plasma E2 and T concentrations, phallus size, and the S.E. associated with these endpoints exists among the 3 sites with the patterns matching the patterns of organochlorine contamination, although S.E. patterns were opposite to what was predicted.     

Emission rates and comparative chemical composition from selected in-use diesel and gasoline-fueled vehicles

Emission samples for toxicity testing and detailed chemical characterization were collected from a variety of gasoline- and diesel-fueled in-use vehicles operated on the Unified Driving Cycle on a chassis dynamometer. Gasoline vehicles included normal particle mass (particulate matter [PM]) emitters (tested at 72 and 30 degrees F), "black" and "white" smokers, and a new-technology vehicle (tested at 72 degrees F). Diesel vehicles included current-technology vehicles (tested at 72 and 30 degrees F) and a high PM emitter. Total PM emission rates ranged from below 3 mg/mi up to more than 700 mg/mi for the white smoker gasoline vehicle. Emission rates of organic and elemental carbon (OC/EC), elements (metals and associated analytes), ions, and a variety of particulate and semi-volatile organic compounds (polycyclic aromatic hydrocarbons [PAH], nitro-PAH, oxy-PAH, hopanes, and steranes) are reported for these vehicles. Speciated organic analysis also was conducted on the fuels and lube oils obtained from these vehicles after the emissions testing. The compositions of emissions were highly dependent on the fuel type (gasoline vs. diesel), the state of vehicle maintenance (low, average, or high emitters; white or black smokers), and ambient conditions (i.e., temperature) of the vehicles. Fuel and oil analyses from these vehicles showed that oil served as a repository for combustion byproducts (e.g., PAH), and oil-burning gasoline vehicles emitted PAH in higher concentrations than did other vehicles. These PAH emissions matched the PAH compositions observed in oil.     

Estimating Floodwater Depths from Flood Inundation Maps and Topography

Information on flood inundation extent is important for understanding societal exposure, water storage volumes, flood wave attenuation, future flood hazard, and other variables. A number of organizations now provide flood inundation maps based on satellite remote sensing. These data products can efficiently and accurately provide the areal extent of a flood event, but do not provide floodwater depth, an important attribute for first responders and damage assessment. Here we present a new methodology and a GIS‐based tool, the Floodwater Depth Estimation Tool (FwDET), for estimating floodwater depth based solely on an inundation map and a digital elevation model (DEM). We compare the FwDET results against water depth maps derived from hydraulic simulation of two flood events, a large‐scale event for which we use medium resolution input layer (10 m) and a small‐scale event for which we use a high‐resolution (LiDAR; 1 m) input. Further testing is performed for two inundation maps with a number of challenging features that include a narrow valley, a large reservoir, and an urban setting. The results show FwDET can accurately calculate floodwater depth for diverse flooding scenarios but also leads to considerable bias in locations where the inundation extent does not align well with the DEM. In these locations, manual adjustment or higher spatial resolution input is required.     

INTEGRATING SOCIAL BENEFIT COST ACCOUNTING INTO WATERSHED RESTORATION AND PROTECTION PROGRAMS1

ABSTRACT: Successful watershed management requires consideration of multiple objectives and the efficient use of scarce public and private resources. One way to address these multi-faceted issues is through Social Benefit-Cost Accounting (SBCA). SBCA is a systematic method of addressing complex social and economic issues relevant to proposed watershed management projects. Benefits of using this technique include: benefits and costs of watershed projects are better understood; politically sensitive issues tend to be put into perspective; and stakeholders' interests are placed on a level playing field. An example from Bogota, Colombia demonstrates how SBCA can be used to value the benefits and costs of a proposed project. By addressing the benefits and costs to all stakeholders, the design of watershed management programs can be improved to achieve goals in a cost-effective manner.     

Biological and environmental influences on the trophic ecology of leatherback turtles in the northwest Atlantic Ocean

Understanding the causes and consequences of variability in trophic status is important for interpreting population dynamics and for identifying important habitats for protected species like marine turtles. In the northwest Atlantic Ocean, many leatherback turtles (Dermochelys coriacea) from distinct breeding stocks throughout the Wider Caribbean region migrate to Canadian waters seasonally to feed, but their trophic status during the migratory and breeding cycle and its implications have not yet been described. In this study, we used stable carbon and nitrogen isotope analyses of bulk skin to characterize the trophic status of leatherbacks in Atlantic Canadian waters by identifying trophic patterns among turtles and the factors influencing those patterns. δ¹⁵N values of adult males and females were significantly higher than those of turtles of unknown gender (i.e., presumed to be subadults), and δ¹⁵N increased significantly with body size. We found no significant differences among average stable isotope values of turtles according to breeding stock origin. Significant inter-annual variation in δ¹⁵N among cohorts probably reflects broad-scale oceanographic variability that drives fluctuations in stable isotope values of nutrient sources transferred through several trophic positions to leatherbacks, variation in baseline isotope values among different overwintering habitats used by leatherbacks, or a combination of both. Our results demonstrate that understanding effects of demographic and physiological factors, as well as oceanographic conditions, on trophic status is key to explaining observed patterns in population dynamics and for identifying important habitats for widely distributed, long-lived species like leatherbacks.     

Assessment of the aquatic biodiversity of a threatened coastal lagoon at Bimini, Bahamas

Coastal biodiversity is threatened worldwide by both direct and indirect anthropogenic activities. To more effectively manage and protect coastal biodiversity, accurate assessments of genetic, species, and ecosystem level diversity are required. We present the results from an assessment of the aquatic species diversity of a small (3?km²), shallow, mangrove-fringed Bahamian lagoon (the North Sound) subject to ongoing anthropogenic development. The assessment was conducted through a collation of field observations and data in published literature. We found that eight angiosperm species, 30 macroalgal species, and 370 animal species (including 95 fishes, 69 arthropods, 56 birds, and 45 mollusks) were documented within the lagoon. At least 11 of these species are of conservation concern, such as the critically endangered smalltooth sawfish (Pristis pectinata) and hawksbill turtle (Eretmochelys imbricata). Comparisons of community similarity indicated that the North Sound has a relatively distinct fauna and flora, but available data suggest that the species found there are most similar to those found in nearby habitats in Cuba. The lagoon forms a key nursery habitat for many species, including lemon sharks (Negaprion brevirostris), Caribbean spiny lobsters (Panulirus argus), and queen conch (Strombas gigas). Recently, the lagoon was included as part of a new marine protected area (MPA), but much of the habitat has already experienced considerable anthropogenic disturbance and the MPA boundaries have yet to be established. We have therefore analyzed the lagoon biodiversity and expect the data presented here to serve as a baseline for future comparisons.     

Halton iterative partitioning: spatially balanced sampling via partitioning

A new spatially balanced sampling design for environmental surveys is introduced, called Halton iterative partitioning (HIP). The design draws sample locations that are well spread over the study area. Spatially balanced designs are known to be efficient when surveying natural resources because nearby locations tend to be similar. The HIP design uses structural properties of the Halton sequence to partition a resource into nested boxes. Sample locations are then drawn from specific boxes in the partition to ensure spatial diversity. The method is conceptually simple and computationally efficient, draws spatially balanced samples in two or more dimensions and uses standard design-based estimators. Furthermore, HIP samples have an implicit ordering that can be used to define spatially balanced over-samples. This feature is particularly useful when sampling natural resources because we can dynamically add spatially balanced units from the over-sample to the sample as non-target or inaccessible units are discovered. We use several populations to show that HIP sampling draws spatially balanced samples and gives precise estimates of population totals.     

Rural organizations and adaptation to climate change and variability in rural Kenya

Numerous studies have shown that collective action affects the type and efficiency of short- and long-term adaptation to climate change. This empirical study contributes to the body of the literature on collective action and adaptive capacity by demonstrating how organizations frame responses to climate variability and change in rural Kenya by promoting local rural institutions. By analyzing interviews, role-playing games, and household surveys, we ask how local rural organizations shape coping strategies to climate variability and how they may structure future adaptations to climate change. We also investigate what types of households participate in those organizations and how their participation may impact their vulnerability to climate change and variability. Our analysis shows that in places rendered especially vulnerable to climate change by arid climatic conditions, the disengagement of governmental services, and a limited access to income-generating activities, local rural organizations increase livelihood security. Those organizations reduce local vulnerabilities and enhance collective action. In contrast to common diversification and livelihood security strategies which rely on the access to urban or peri-urban structures, local rural institutions and organizations allow for rural and grassroots sustainable adaptation strategies. In that respect, they constitute a resilient and mostly untapped resource for visibly strengthening livelihood security and adaptive capacities in rural Kenya.     

Use of industrial byproducts to filter phosphorus and pesticides in golf green drainage water

Golf courses are vulnerable to phosphate (PO) and pesticide loss by infiltration of the sandy, porous grass rooting media used and through subsurface tile drainage. In this study, an effort was made to remove PO, chlorothalonil, mefenoxam, and propiconazole in a golf green's drainage water with a filter blend comprised of industrial byproducts, including granulated blast furnace slag, cement kiln dust, silica sand, coconut shell-activated carbon, and zeolite. To test this filter media, two 6-h storm events were simulated by repeat irrigation of the golf green after PO and pesticide application. Drainage flows ranged from 0.0034 to 0.6433 L s throughout the course of the simulations. A significant decrease in the chlorothalonil load for the experimental run (with filter media) was observed compared with the control (without filter media) ( < 0.05). In general, percent reductions in chlorothalonil were very high (>80%) near peak flows. In contrast, filter media was not effective in removing PO, mefenoxam, or propiconazole ( > 0.05). Instead, it appears that the filter blend added PO to the effluent above flow rates of 0.037 L s. Overall, flow rate, the amount of filter media used, and contaminant properties may have influenced the filter media's ability to remove contaminants. More research is needed to determine the optimal blend and configuration for the filter media to remove significant amounts of all contaminants investigated.