Aminobenzenesulfonamide functionalized SBA-15 nanoporous molecular sieve: A new and promising adsorbent for preconcentration of lead and copper ions

A rapid method for the extraction and monitoring of nanogram level of Pb²⁺ and Cu²⁺ ions using uniform silanized mesopor (SBA-15) functionalized with aminobenzenesulfonamide groups and flame atomic absorption spectrometry (FAAS) is presented. Aminobenzenesulfonamide functionalized SBA-15 was synthesized according to procedure in the literature and the presence of organic groups in the silica framework was demonstrated by FT-IR spectra. The functionalized product showed the BET surface area 110 m²/g and pore diameter 5.1 nm, based on adsorption-desorption of N₂ at 77 K. The effect of several variables such as (amount of adsorbent, stirring time, pH and presence of other ions in the medium) has been studied. Lead and copper were completely extracted at pH greater than 3 after stirring for 10 min. The maximum capacity of the adsorbent was found to be 191.3 ± 1.4 and 155.0 ± 1.0 μg of lead and copper ions/mg functionalized SBA-15, respectively. The preconcentration factor of the method was found to be 200. The detection limit of the technique was 3.4 and 0.4 ng/mL for Pb²⁺ and Cu²⁺, respectively. The applications of this methodology for real samples were examined by various water type, black tea and pepper samples.     

Control of TAME reactive distillation using Non-Dominated Sorting Genetic Algorithm-II

The control system performs poor in characteristics and even it becomes unstable, if improper values of the controller tuning constants are used. So it becomes necessary to tune the controller parameters to achieve good control performance with the proper choice of tuning constants. Many control problems involve simultaneous optimization of multiple variables that competing with each other. In this paper, the Non-Dominated Sorting Genetic Algorithm-II (NSGA-II) has been successfully applied to optimization of dynamic state of t-amyl-methyl-ether (TAME) reactive distillation process. This paper presents the tuning of Proportional-Integral-Derivative (PID) controllers by minimizing of two objective functions (overshoot and Integral of Absolute Error (IAE)) through the NSGA-II. Results show that genetic algorithm is more suitable method for optimal control of the TAME reactive distillation columns than traditional methods such as Tyreus-Luyben.     

Bioleaching of heavy metals from sewage sludge,direct action of Acidithiobacillus ferrooxidans or only the impact of pH?

Journal of Material Cycles and Waste Management - The bioleaching process comprises two mechanisms: direct action of the bacteria and indirect effect of low pH. In this work, the effect of bacteria...     

The evaluation of electrical energy per order (E(Eo)) for photooxidative decolorization of four textile dye solutions by the kinetic model

Photooxidative decolorization of four textile dyestuffs, C.I. Acid Orange 7 (AO7), C.I. Acid Orange 8 (AO8), C.I. Acid Orange 52 (AO52) and C.I. Acid Blue 74 (AB74), by UV/H2O2 was investigated in a laboratory scale photoreactor equipped with a 15 W low pressure mercury vapour lamp. The decolorization of the dyes was found to follow pseudo-first-order kinetics, and hence the figure-of-merit electrical energy per order (E(Eo)) is appropriate for estimating the electrical energy efficiency. The E(Eo) values were found to depend on the concentration of H2O2, concentration and basic structure of the dye. This study shows that these textile dyes can be treated easily and effectively with the UV/H2O2 process with E(Eo) values between 0.4 and 5 kW h m-3 order-1, depending on the initial concentrations of dyes and H2O2. The kinetic model, based on the initial rates of degradation, provided good prediction of the E(Eo) values for a variety of conditions.     

Effects of TiO2 nanoparticles on the aquatic plant Spirodela polyrrhiza: Evaluation of growth parameters, pigment contents and antioxidant enzyme activities

Plants are essential components of all ecosystems and play a critical role in environmental fate of nanoparticles. However, the toxicological impacts of nanoparticles on plants are not well documented. Titanium dioxide nanoparticles (TiO₂-NPs) are produced worldwide in large quantities for a wide range of purposes. In the present study, the uptake of TiO₂-NPs by the aquatic plant Spirodela polyrrhiza and the consequent effects on the plant were evaluated. Initially, structural and morphological characteristics of the used TiO₂-NPs were determined using XRD, SEM, TEM and BET techniques. As a result, an anatase structure with the average crystalline size of 8nm was confirmed for the synthesized TiO₂-NPs. Subsequently, entrance of TiO₂-NP_S to plant roots was verified by fluorescence microscopic images. Activity of a number of antioxidant enzymes, as well as, changes in growth parameters and photosynthetic pigment contents as physiological indices were assessed to investigate the effects of TiO₂-NPs on S. polyrrhiza. The increasing concentration of TiO₂-NPs led to the significant decrease in all of the growth parameters and changes in antioxidant enzyme activities. The activity of superoxide dismutase enhanced significantly by the increasing concentration of TiO₂-NPs. Enhancement of superoxide dismutase activity could be explained as promoting antioxidant system to scavenging the reactive oxygen species. In contrast, the activity of peroxidase was notably decreased in the treated plants. Reduced peroxidase activity could be attributed to either direct effect of these particles on the molecular structure of the enzyme or plant defense system damage due to reactive oxygen species.     

Comparison of energy produced from waste by removing its different components: A case study of the waste landfill in Tehran

In developing and populated cities such as Tehran, a massive amount of municipal solid waste (MSW), both wet and dry, is transferred to landfills daily. Combustion is one of the most common methods of using mixed waste energy from the past to the present. The Dulong formula is widely used to calculate the energy released from MSW combustion. According to the constituent components of Tehran MSW, removing food waste leads to an increase in energy potential, which will be a suitable condition for energy production. In this work, the energy derived from the combustion of mixed and separated dry MSW generated in Tehran was calculated using the experimental Dulong formula and tables in Integrated Solid Waste Management (Tchobanoglous et al. 1993, McGraw‐Hill). The Dulong formula indicates that the use of Tehran mixed MSW (without separating materials for recycling) as a fuel source yields 8,966.40 KJ/kg while the use of Tchobanoglous et al. (1993) tables can generate 8,236 kJ/kg. By removing food waste and recyclable materials, the potential of energy production changes to 22,047 kJ/kg using the Dulong formula and 16,207 kJ/kg and the Tchobanoglous et al. (1993) tables. It indicates increase by 1.46 times and 46%, respectively. Regarding the 200‐ton capacity of the Tehran waste incinerator, the Dulong formula indicated generation of 4,409 MJ/day energy, and the Tchobanoglous et al. table presents 3,241 MJ/day. Therefore, considering that Tehran generates more than 4,000 tons of reject waste daily, it can easily be converted to energy rather than landfilled. This can alleviate the problem of buying land and construction of landfills and leachate generation.     

Effects of Zr substitution on soot combustion over cubic fluorite-structured nanoceria: Soot-ceria contact and interfacial oxygen evolution

Ceria is widely used as a catalyst for soot combustion, but effects of Zr substitution on the reaction mechanism is ambiguous. The present work elucidates effects of Zr substitution on soot combustion over cubic fluorite-structured nanoceria. The nanostructured CeO₂, Ce_0.92Zr_0.08O₂, and Ce_0.84Zr_0.16O₂ composed of 5–6 nm crystallites display T_m-CO2 (the temperature at maximum CO₂ yield) at 383, 355, and 375°C under 10 vol.% O₂/N₂, respectively. The size of agglomerate decreases from 165.5 to 51.9–57.3 nm, which is beneficial for the soot-ceria contact. Moreover, Zr increases the amount of surface oxygen vacancies, generating more active oxygen (O₂^? and O^?) for soot oxidation. Thus, the activities of Ce_0.92Zr_0.08O₂ and Ce_0.84Zr_0.16O₂ in soot combustion are better than that of CeO₂. Although oxygen vacancies promote the migration of lattice O^2?, the enriched surface Zr also inhibits the mobility of lattice O^2?. Therefore, the T_m-CO2 of Ce_0.84Zr_0.16O₂ is higher than that of Ce_0.92Zr_0.08O₂. Based on reaction kinetic study, soot in direct contact with ceria preferentially decomposes with low activation energy, while the oxidation of isolated soot occurs through diffusion with high activation energy. The obtained findings provide new understanding on the soot combustion over nanoceria.