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101.
K. K. Sharma Irani Mukherjee Balwinder Singh Kousik Mandal Sanjay K. Sahoo Hemanta Banerjee Tirthankar Banerjee Sankhajit Roy Paresh G. Shah Hemlatta K. Patel Anil R. Patel S. Naseema Beevi Thomas George Thomas B. Mathew Geeta Singh Rajbir Noniwal Sunita Devi 《Environmental monitoring and assessment》2014,186(12):8453-8461
Supervised field trials were conducted at four different agro-climatic locations of India to evaluate the dissipation pattern and risk assessment of spiromesifen on tomato. Spiromesifen 240 SC was sprayed on tomato at 150 and 300 g a.i.?ha?1. Samples of tomato fruits were drawn at 0, 1, 3, 5, 7, 10 and 15 days after treatment and soil at 15 days after treatment. Quantification of residues was done on gas chromatograph–mass spectrophotometer in selective ion monitoring mode in the mass range of 271–274 (m/z). The limit of quantification of the method was found to be 0.05 mg kg?1, while the limit of determination was 0.015 mg kg?1. Residues were found below the LOQ of 0.05 mg kg?1 in 10 days at both the doses of application at all the locations. Spiromesifen dissipated with a half-life of 0.93–1.38 days at the recommended rate of application and 1.04–1.34 days at the double the rate of application. Residues of spiromesifen in soil were detectable level (<0.05 mg kg?1) after 15 days of treatment. A preharvest interval (PHI) of 1 day has been recommended on tomato on the basis of data generated under All India Network Project on Pesticide Residues. Spiromesifen 240 SC has been registered for its use on tomato by Central Insecticide Board and Registration Committee, Ministry of Agriculture, Government of India. The maximum residue limit (MRL) of spiromesifen on tomato has been fixed by Food Safety Standard Authority of India, Ministry of Health and Family Welfare, Government of India as 0.3 μg/g after its risk assessment. 相似文献
102.
Vinay Kumar Yadav Sahdeo Prasad Devendra K. Patel Altaf Husain Khan Madhu Tripathi Yogeshwer Shukla 《Environmental monitoring and assessment》2010,168(1-4):173-178
Inhalation of emissions from petrol and diesel exhaust particulates is associated with potentially severe biological effects. In the present study, polycyclic aromatic hydrocarbons (PAHs) were identified from smokes released by the automobile exhaust from petrol and diesel. Intensive sampling of unleaded petrol and diesel exhaust were done by using 800-cm3 motor car and 3,455-cm3 vehicle, respectively. The particulate phase of exhaust was collected on Whatman filter paper. Particulate matters were extracted from filter paper by using Soxhlet. PAHs were identified from particulate matter by reverse phase high performance liquid chromatography using C18 column. A total of 14 PAHs were identified in petrol and 13 in case of diesel sample after comparing to standard samples for PAH estimation. These inhalable PAHs released from diesel and petrol exhaust are known to possess mutagenic and carcinogenic activity, which may present a potential risk for the health of inhabitants. 相似文献
103.
Abhinav Srivastava Vinod P. Sharma Ranu Tripathi Rakesh Kumar Devendra K. Patel Pradeep Kumar Mathur 《Environmental monitoring and assessment》2010,168(1-4):397-406
Cadmium and lead are important environmental pollutants with high toxicity to animals and human. Soils, though have considerable metal immobilizing capability, can contaminate food chain via plants grown upon them when their built-up occurs to a large extent. Present experiment was carried out with the objective of quantifying the limits of Pb and Cd loading in soil for the purpose of preventing food chain contamination beyond background concentration levels. Two separate sets of pot experiment were carried out for these two heavy metals with graded levels of application doses of Pb at 0.4–150 mg/kg and Cd at 0.02–20 mg/kg to an acidic light textured alluvial soil. Spinach crop was grown for 50 days on these treated soils after a stabilization period of 2 months. Upper limit of background concentration levels (C ul) of these metals were calculated through statistical approach from the heavy metals concentration values in leaves of spinach crop grown in farmers’ fields. Lead and Cd concentration limits in soil were calculated by dividing C ul with uptake response slope obtained from the pot experiment. Cumulative loading limits (concentration limits in soil minus contents in uncontaminated soil) for the experimental soil were estimated to be 170 kg Pb/ha and 0.8 kg Cd/ha. Based on certain assumptions on application rate and computed cumulative loading limit values, maximum permissible Pb and Cd concentration values in municipal solid waste (MSW) compost were proposed as 170 mg Pb/kg and 0.8 mg Cd/kg, respectively. In view of these limiting values, about 56% and 47% of the MSW compost samples from different cities are found to contain Pb and Cd in the safe range. 相似文献
104.
Dey RK Swain SK Mishra S Sharma P Patnaik T Singh VK Dehury BN Jha U Patel RK 《Environmental monitoring and assessment》2012,184(5):3279-3291
The present investigation reports the assessment of hydrochemical/geochemical processes controlling the concentration of fluoride
in groundwater of a village in India (Boden block, Orissa). Boden block is one of the severely affected fluoride-contaminated
areas in the state of Orissa (India). The sampling and subsequent analysis of water samples of the study area was carried
out following standard prescribed methods. The results of the analysis indicate that 36.60% groundwater F− concentration exceeds the limit prescribed by the World Health Organization for drinking water. The rock interaction with
groundwater containing high concentration of HCO3− and Na+ at a higher pH value of the medium could be one of the important reasons for the release of F− from the aquatic matrix into groundwater. Geochemical classification of groundwater based on Chadha rectangular diagram shows
that most of the groundwater samples having fluoride concentration more than 1.5 mg L−1 belongs to the Na-K-HCO3 type. The saturation index values evaluated for the groundwater of the study area indicated that it is oversaturated with
respect to calcite, whereas the same is undersaturated with respect to fluorite content. The deficiency of calcium ion concentration
in the groundwater from calcite precipitation favors fluorite dissolution leading to excess of fluoride concentration. The
risk index was calculated as a function of fluoride level in drinking water and morbidity of fluorosis categorizes high risk
for villages of Amera and Karlakote panchayat of Boden block. 相似文献
105.
The aim of this study is to determine the possibility of using Rinodina sophodes (Ach.) Massal., a crustose lichen as polycyclic aromatic hydrocarbons (PAHs) bioaccumulator for evaluation of atmospheric
pollution in tropical areas of India, where few species of lichens are able to grow. PAHs were identified, quantified and
compared to evaluate the potential utility of R. sophodes. The limit of detection for different PAHs was found to be 0.008–0.050 μg g − 1. The total PAHs in different sites were ranged between 0.189 ± 0.029 and 0.494 ± 0.105 μg g − 1. The major sources of PAHs were combustion of organic materials, traffic and vehicular exhaust (diesel and gasoline engine).
Significantly higher concentration of acenaphthylene and phenanthrene indicates road traffic as major source of PAH pollution
in the city. Two-way ANOVA also confirms that all PAHs content showed significant differences between all sampling sites (P
1%). This study establishes the utility of R. sophodes in monitoring the PAHs accumulation potentiality for development of effective tool and explores the most potential traits
resistant to the hazardous environmental conditions in the tropical regions of north India, where no such other effective
way of biomonitoring is known so far. 相似文献
106.
A field experiment was conducted at Anand Agricultural University, Anand during Sept-Dec, 2009 to study the rate of degradation of flubendiamide in/on brinjal fruits following foliar application of Fame 480 SC at 90 (standard dose) and 180 (double dose) g a.i. ha(?-1). The residues estimated using HPLC revealed persistence of flubendiamide in/on brinjal till 3rd and 7th day after the last spray at standard and double dose, respectively. The residues of flubendiamamde were reported as parent compound, and no desiodo metabolite was detected. The initial deposits of 0.17 and 0.42 μg g(?-1) in/on brinjal fruits reached below determination level of 0.05 μg g(?-1) on the 5th and 10th day at standard and double dose, respectively. The half life of flubendiamide on brinjal fruits ranged from 2.68 to 2.55 days. Soil samples analyzed on the 15th day after the last spray revealed residues at below determination level (0.05 μg g(?-1)) at either dose of application. 相似文献
107.
Asirvatham Ramesh Kumar Patel Riyazuddin 《Environmental monitoring and assessment》2011,176(1-4):647-662
Chromium species (Cr(III), Cr(VI), and Cr(III)-organic) in groundwater of a tannery contaminated area were monitored during pre- and post-monsoon seasons for a period of 3 years (May 2004 to January 2007). The objectives of the study were (1) to investigate the temporal variation of chromium species and other matrix constituents and (2) to study the redox processes associated with the temporal variation of chromium species. Samples were collected from 15 dug wells and analyzed for chromium species and other constituents. The results showed that the groundwater was relatively more oxidizing during post-monsoon periods than the pre-monsoon periods. Except one sample, the concentration of chromium species were found in the order of Cr(VI)>Cr(III)>Cr(III)-organic complexes during all the pre- and post-monsoon periods. In most of the wells, the concentrations of Cr(III), Cr(VI), and Cr(III)-organic decreased during post-monsoon periods compared to their pre-monsoon concentrations. However, the Cr(VI)/CrTotal ratio still increased and the Cr(III)/CrTotal ratio decreased during post-monsoon periods in most of the samples. The possible mechanisms for the temporal variation of chromium species were (1) Fe(II) reduction of Cr(VI) vs oxidation of Fe(II) by dissolved oxygen and (2) oxidation of Cr(III) by Mn(IV). 相似文献
108.
Removal efficiency of fluoride by novel Mg-Cr-Cl layered double hydroxide by batch process from water 总被引:1,自引:0,他引:1
Sandip Mandal Swagatika Tripathy Tapswani Padhi Manoj Kumar Sahu Raj Kishore Patel 《环境科学学报(英文版)》2013,25(5):993-1000
The fluoride ion removal from aqueous solution using synthesized Mg-Cr-Cl layered double hydroxide has been reported.Mg-Cr-Cl was characterized by X-ray powder diffraction,Fourier-transform infrared,thermo-gravimetric analysis,differential thermal analysis,and scanning electron microscope.Adsorption experiments were carried out in batch mode as a function of adsorption dosages,contact time,pH,and initial fluoride concentration to get optimum adsorption capacity.The adsorption kinetic study showed that the adsorption process followed first order kinetics.The fluoride removal was 88.5% and 77.4% at pH 7 with an adsorbent dose of 0.6 g/100 mL solution and initial fluoride concentration of 10 mg/L and 100 mg/L,respectively.The equilibrium was established at 40 min.Adsorption experiment data were fitted well with Langmuir isotherm with R 2 = 0.9924.Thermodynamic constants were also measured and concluded that the adsorption process was spontaneous and endothermic in nature.The removal percentage decreased slowly with increasing pH.This process is suitable for industrial effluents.The regeneration of the material is not possible. 相似文献
109.
Shyamal Dhananjay Singh Sawai Ankita Kazmi Absar Ahmad 《Journal of Material Cycles and Waste Management》2022,24(3):835-851
Journal of Material Cycles and Waste Management - Improper management of solid waste creates health problems and degrades the environment (air, water, and soil). The Indian state Uttarakhand is... 相似文献
110.
Dhama Kuldeep Patel Shailesh Kumar Kumar Rakesh Masand Rupali Rana Jigyasa Yatoo Mohd. Iqbal Tiwari Ruchi Sharun Khan Mohapatra Ranjan K. Natesan Senthilkumar Dhawan Manish Ahmad Tauseef Emran Talha Bin Malik Yashpal Singh Harapan Harapan 《Environmental science and pollution research international》2021,28(26):34211-34228
Environmental Science and Pollution Research - Disinfectants and sanitizers are essential preventive agents against the coronavirus disease 2019 (COVID-19) pandemic; however, the pandemic crisis... 相似文献