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Banana peels were employed for the removal of metribuzin from aqueous solution. Sorption in the batch mode was optimized regarding pH, contact time, sorbent dose, initial pesticide concentrations, and temperature. The sorption data were fitted to pseudo-first-order, pseudo-second-order, intraparticle diffusion, Elovich, and liquid film diffusion model, the pseudo-second-order exhibiting best fit (R2 = 0.9803). Of the four most common sorption isotherm models (Langmuir, Freundlich, Tempkin, and Dubinin–Radushkevich), the data followed the Langmuir isotherm with highest correlation. The maximum adsorption capacity was found to be 167 mg g?1. Gibbs free energy, enthalpy, and entropy showed that the sorption was exothermic and spontaneous. 相似文献
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This paper presents an agent-based approach for error detection in incident management organizations. The approach consists of several parts. First, a formal approach for the specification and hierarchical verification of both traces and properties. Incomplete traces are enriched by enrichment rules. Furthermore, a classification mechanism is presented for the different properties in incident management that is based on psychological literature. Classification of errors provides insight in the functioning of the agents involved with respect to their roles. This insight enables the provision of dedicated training sessions and allows software support to give appropriate warning messages during incident management. 相似文献
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There must be a change in attitude towards end-of-life products. The view that these products pose a liability must be changed. Secondary material is valuable as raw material. Thus, activities encouraging changes in opinion are important.Two major EU directives guide the recycling process; the Directive of End-of-Life Vehicles (ELV) and the Directive of Waste Electrical and Electronic Equipment (WEEE). Both focus on the input of the recycling system, not on what is coming out of the system.The WEEE Directive is the legislation on the European level that governs the handling and processing of these types of products. The WEEE Directive is not only aimed at stricter handling and reduction of hazardous materials but also encourages EU member states to support technical development in order to facilitate increased recycling.In order to properly address these issues a mind-set, material hygiene, has been introduced. The basic idea is to act, in every life cycle phase of the product, towards highest possible efficiency in recycling. The outcome of useful material is in focus.A study on dishwashers is made with copper outcome as target. The results are based on Swedish conditions but general conclusions can be made. Limited design efforts can raise the outcome of valuable materials, if the recycling process is organized in an optimal manner.A theoretical concept of disassembly structures is used to draw general conclusions on the case study.Increasing product recycling suitability is one side of the problem; another is increasing effectiveness of handling and processing of end-of-life products.The purpose of this paper is to introduce the concept of “material hygiene” and based on that demonstrate a method for grading structural properties in a recycling perspective. The findings presented in this paper are based on a field study in which a number of dishwashers were disassembled and analyzed. 相似文献
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E. Joanne Verweij Martine C. de Vries Esther J. Oldekamp Alex J. Eggink Dick Oepkes Femke Slaghekke Jochem K. H. Spoor Jan A. Deprest Jena L. Miller Ahmet A. Baschat Philip L. J. DeKoninck 《黑龙江环境通报》2021,41(8):949-956
Since the completion of the Management of Myelomeningocoele Study, maternal-fetal surgery for spina bifida has become a valid option for expecting parents. More recently, multiple groups are exploring a minimally invasive approach and recent outcomes have addressed many of the initial concerns with this approach. Based on a previously published framework, we attempt to delineate the developmental stage of the surgical techniques. Furthermore, we discuss the barriers of performing randomized controlled trials comparing two surgical interventions and suggest that data collection through registries is an alternative method to gather high-grade evidence. 相似文献
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Guus J.M. Velders Jan Matthijsen 《Atmospheric environment (Oxford, England : 1994)》2009,43(25):3858-3866
The extent of the exceedance of the EU limit values for nitrogen dioxide (NO2) and particulate matter (PM10) concentrations within the Netherlands is expected to decrease significantly, in the coming years. Whether limit values will actually be exceeded, in the next decade, depends not only on European, national and local policies, but also on the effects of inevitable interannual meteorological fluctuations. An analysis of model calculations and measurements yields variations (1 sigma) in the annual average concentration of about 5% for NO2 and 9% for PM10, due to meteorological fluctuations. These deviations from long-term average concentrations affect assessments of future levels, set against limit values. For instance, an NO2 concentration of 39 μg m?3, estimated for a given year with long-term average meteorology, indicates that it is likely (chance >66%) that the limit value of 40 μg m?3 will not be exceeded in that particular year. At the same time, the estimation also indicates, for example, that this situation is unlikely (change <33%) to continue for three years in a row. However, with an estimated concentration of 38 μg m?3, it is likely that the limit value will not be exceeded for three years in a row. The limit value for the daily average PM10 concentration is equivalent to an annual average of about 32 μg m?3. This threshold is unlikely to be exceeded for three years in a row, when an annual average concentration of 29 μg m?3 is estimated. Interannual variations in concentrations of NO2 and PM10 are linked to large-scale meteorological fluctuations. Therefore, similar results can be expected for other European countries. 相似文献