Degradation of 14C-chlorpyrifos was studied in a marine ecosystem for 60 days and in marine sediment under moist and flooded conditions using a continuous flow system allowing a total 14C-mass balance for a period of 40 days. In the marine ecosystem, 14C-chlorpyrifos underwent rapid degradation and very little (1-2%) 14C-residues of the applied activity were detected after two months in sediments. Clams were major component of the ecosystem and played a significant role in degradation of the insecticide. In the continuous flow system chlorpyrifos did not undergo substantial mineralization. Volatilization accounted for 0.8-1% loss during first ten days of application. The amounts of extractable 14C-activity were higher in flooded sediments than in moist sediment. More bound residues were formed under moist conditions. TCP (3,5,6-trichloro-2-pyridinol) was the major degradation product formed under both moist and flooded conditions, its formation being higher in the latter conditions. These studies underline the role of clams in degradation of chlorpyrifos and lack of microbial degradation. In absence of clams, chlorpyrifos underwent abiotic degradation in marine sediment with formation of bound residues. 相似文献
The utilization of water quality analysis to inform optimal decision-making is imperative to achieve sustainable management of river water quality. A multitude of research works in the past has focused on river water quality modeling. Despite being a precise statistical regression technique that allows for fitting separate models for all potential combinations of predictors and selecting the optimal subset model, the application of best subset method in river water quality modeling is not widely adopted. The current research aims to validate the use of best subset method in evaluating the water quality parameters of the Godavari River, one of the largest rivers in India, by developing regression equations for different combinations of its physicochemical parameters. The study involves in formulating best subset regression equations to estimate the concentrations of river water quality parameters while also identifying and quantifying their variations. A total of 17 water quality parameters are analyzed at 13 monitoring sites using 13 years (1993–2005) of observed data for the monsoon (June–October) period and post-monsoon (November–February) period. The final subset model is selected among model combinations that are developed for each year's dataset through widely used statistical criteria such as R2, F value, adjusted R2a, AICc, and RSS. The final best subset model across all parameters exhibits R2 values surpassing 0.8, indicating that the models possess the ability to account for over 80% of the variations in the concentrations of dependent parameters. Therefore, the findings demonstrated the appropriateness of this method in evaluating the water quality parameters in extensive rivers. This work is very useful for decision-making and in the management of river water quality for its sustainable use in the study area. 相似文献
Environmental Science and Pollution Research - Multi-drug resistance (MDR) in bacteria is regarded as an emerging pollutant in different food production avenues including aquaculture. One hundred... 相似文献
Environmental Science and Pollution Research - Oxygen plays a crucial role in coal spontaneous combustion (CSC), and the magnitude of oxygen concentration determines the oxidation reaction... 相似文献
China’s pilot free trade zone (PFTZ) is an important national strategy to achieve high-quality development, so it is necessary to discuss the effect of PFTZ implementation on green total factor productivity (GTFP). Based on the data from 279 cities in China from 2004 to 2018, this study takes the establishment of PFTZ as a quasi-natural experiment and uses the difference-in-differences (DID) method to systematically evaluate the effect of PFTZ on urban GTFP. The empirical results of this paper are shown as follows: Firstly, the construction of PFTZ has a significant effect on urban GTFP, and this effect has increased gradually over time. Secondly, the construction of PFTZ mainly promotes the urban GTFP by increasing the level of science and technology innovation, reducing government intervention and improving the level of human capital. Thirdly, the effect of PFTZ construction on GTFP is more pronounced in regions with earlier waves of PFTZ and in western regions where environmental concerns are higher. In addition, there is a significant positive linkage between the construction of the PFTZ and the Belt and Road Initiative to improve the urban GTFP. The findings of this paper enrich the relevant literature on PFTAs and sustainable development and provide a theoretical basis for further promotion of PFTZ construction.