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101.
Wet scrubber is one of the most conventional types of air pollutant control devices (APCDs), which is specially designed to treat dust and acidic gases in the flue gas simultaneously. In spite of its outstanding ability to control them, however, wet scrubbers have been considered as potential contaminant sources that may increase PCDD/DF concentrations in the flue gas. In this study, we investigated the change of PCDD/DF concentrations at the inlets and outlets of seven wet scrubbers, and compared them with other published data. With a multi-regression analysis of dust concentrations and temperature at the inlets and outlets of given wet scrubbers, we developed an empirical model to understand factors dominating the change of PCDD/DF concentrations. As a result, we confirmed that the changes of PCDD/DF concentrations in wet scrubbers are closely related to their concentrations at the inlets, which would usually be determined by the type of APCDs installed upstream of the wet scrubber. 相似文献
102.
Magnesium-aluminum oxide (Mg-Al oxide) obtained by thermal decomposition of Mg-Al layered double hydroxide (Mg-Al LDH) effectively removed HCl from gaseous streams. HCl removal was greater in the presence of added water vapor at all temperatures examined and increased with decreasing temperature in both the presence and absence of added water vapor. Wet and dry removal of gaseous HCl were attributed to the production of MgCl2 . 6H2O and MgCl2 . 4H2O, respectively. For the wet scrubbing process, the reconstruction reaction of Mg-Al LDH from Mg-Al oxide was the primary mechanism for increased HCl removal. 相似文献
103.
Leaching of brominated flame retardants from TV housing plastics in the presence of dissolved humic matter 总被引:4,自引:0,他引:4
In this study, we investigated the contents of several brominated compounds in TV molding plastics, as well as their leaching characteristics in the presence of DHM. The PBDE content was about 3% of the sample weight, and deca-BDE was the most abundant homologue, accounting for over 80% of the total amount. TBBPA, PBPs and PBBs content was 8100, 4700 and 250 ng/g, respectively. Despite no detection of most of the lower brominated DEs in distilled water, most homologues could be detected in DHM solution, and their solubility increased according to the contact time; those of highly brominated compounds increased to 10 times their maximum solubility in distilled water. Especially, contrary to the relatively faster equilibrium in distilled water, BFR solubility in DHM solution was maintained even after 20 days. In addition, a modified first-order model adequately reflected rapid desorption for each compound in the initial period, but slow desorption afterwards. From an overall perspective, it is clear that hydrophobic BFRs can leach out to a great extent in the presence of DHM, which is a matter of great concern in E&E waste as the potential contaminant source of BFRs, especially in landfills and open dump sites that provide the perfect conditions for exposure of BFRs to abundant DHM. 相似文献
104.
105.
Masahiro Tokumura Yuko WadaYuri Usami Takako YamakiAtsushi Mizukoshi Miyuki NoguchiYukio Yanagisawa 《Chemosphere》2012,89(10):1238-1242
The photo-Fenton reaction was applied as a novel method for the removal of volatile organic compounds (VOCs) in the gas phase, and its effectiveness was experimentally examined. In conventional VOCs removal methods using a photocatalyst or ozone, VOCs are oxidized in the gas phase. Therefore, incompletely oxidized intermediates, which may have adverse effects on health, are likely to contaminate the treated air. On the other hand, in the VOCs removal method developed in this study, because the VOCs are oxidized in the liquid phase by the photo-Fenton reaction, any incompletely oxidized intermediates produced are confined to the liquid phase. As a result, the contamination of the treated air by these harmful intermediates can be prevented. Using a semi-batch process, it was found that the removal efficiency for toluene in a one-pass test (residence time of 17 s) was 61%, for an inlet toluene gas concentration of 930 ppbv, an initial iron ion concentration of 20 mg L−1, and an initial hydrogen peroxide concentration of 630 mg L−1. The removal efficiency was almost constant as long as H2O2 was present in the solution. Proton transfer reaction mass spectrometry analysis confirmed the absence of any incompletely oxidized intermediates in the treated air. 相似文献
106.
Masahiro Miura Atsushi Shimahata Toshio Nishikawa Masakazu Aoyama Kiyoshi Tada Junichi Horiuchi Masahiro Nakahara Chikara Sakai 《Journal of Material Cycles and Waste Management》2011,13(1):80-83
To prepare a substrate for microbial conversion of xylose into xylitol, the culm of Sasa senanensis was hydrolyzed with dilute sulfuric acid. When the reaction temperature was fixed at 121°C, an optimum yield of xylose was
obtained by treatment with 2% sulfuric acid for 1 h. An increase in the sulfuric acid concentration or a prolonged reaction
time resulted in a decrease in the xylose yield. A fermentable substrate with a relatively high xylose concentration (36.7
g l−1) was obtained by hydrolysis with 2% sulfuric acid with a liquid-to-solid ratio of 5 g g−1. During hydrolysis at elevated temperatures, certain undesired byproducts were also generated, such as degradation products
of solubilized sugars and lignin, which are potential inhibitors of microbial metabolism. These compounds were, however, successfully
removed from the hydrolysate by treatment with activated char. 相似文献
107.
Obtaining the cooperation of citizens to participate in separate waste collection is essential to create a recycling-oriented society. In this research, the degree of change in the citizen participation rate, which occurs when the contents of political measures such as the raising of awareness, provision of information, and the conditions of collection services were changed, was estimated together with the effect on the reduction in environmental load. A questionnaire survey was conducted, targeted at residents of Itabashi Ward, while logistic regression analyses were also conducted to create predictive models for recycling behavior, and sensitivity analyses of the models were carried out to estimate the increase in citizen participation rate achievable through the implementation of various political measures. It was found that the effect of "thorough perception of information" was the largest, followed by "minimization of evaluation of trouble" and "thorough perception of efficacy of measures." The effect of the improvement in the citizen participation rate on the reduction in environmental load was also evaluated quantitatively by life cycle inventory analyses. It was indicated that "maximization of perception of information" had the greatest effect. However, the reduction effect with "paper packs" and "PET bottles" was relatively small compared with that of "bottles/cans." 相似文献
108.
Hirofumi Sakanakura Masahiro Osako Akiko Kida Shin-ichi Sakai 《Journal of Material Cycles and Waste Management》2011,13(1):56-67
The objective of this study was to design a procedure for an environmental availability test under both acidic and alkaline
conditions for solid wastes and recycled materials and products. The procedure was designed on the basis of the Dutch availability
test NEN 7371. Bottom ash from a municipal solid waste incinerator and copper slag were used as test materials. The influences
of the type and intensity of liquid stirring apparatus and the open area ratio of the top of the leaching vessel were investigated
experimentally, and partial least-squares modeling was applied as multivariate data analysis for the simultaneous evaluation
of the three leaching conditions. Interlaboratory validation was then carried out with the participation of seven laboratories
in accordance with JIS Z 8402-2/ISO 5725-2. Both repeatability and reproducibility were found to be acceptable, but precise
calibration of the pH electrode is required. The proposed procedure will provide sufficient accuracy as a standard test method. 相似文献
109.
Effect of the carbon coating in Fe-C-TiO(2) photocatalyst on phenol decomposition under UV irradiation via photo-Fenton process 总被引:1,自引:0,他引:1
Fe-C-TiO(2) photocatalysts which contained the residue carbon (0.2-3.3 mass%) were prepared from a mixture of TiO(2) and FeC(2)O(4) through the heating at 673-1173 K in Ar. These photocatalysts did not show a high adsorption of phenol, but they were active in photo-Fenton reactions during decomposition of phenol under UV irradiation with addition of H(2)O(2). It was proved that Fe(2+) governed the photoactivity of Fe-C-TiO(2) photocatalysts, it decreased with heat-treatment temperature above 773 K. For comparison, Fe-TiO(2) photocatalyst was prepared by heating TiO(2) and FeC(2)O(4) at 823 K in air for 3h. Phenol decomposition was going much slower on Fe-TiO(2) photocatalyst in comparison with Fe-C-TiO(2), of which mechanism was different, on the former phenol was decomposed by the radical reaction, on the latter through a complex reaction with iron and intermediates of phenol decomposition. Therefore carbon-coating TiO(2) was found to be advantageous for mounting iron and its application for the phenol decomposition via photo-Fenton process. 相似文献
110.
Naoko NAKAGAWA Masahiro OTAKI Shinji MIURA Hironobu HAMASUNA Katsuyoshi ISHIZAKI 《环境科学学报(英文版)》2006,18(6):1088-1093
Sustainable sanitation is an approach for more ecological and sustainable water resources management. In this paper, we proposed one of the new integrated waste treatment systems: an "sustainable sanitation system" that includes separation of the black water from water system by a non-flushing toilet (bio-toilet), and a gray water treatment based on a biological and ecological concept. Sustainable sanitation system also converts the domestic waste to soil conditioners and fertilizers, for farmland use. As one of the case studies, Environmentally Symbiotic Housing in which people actually live using the bio-toilet for the black water treatment and the household wastewater treatment facility for the gray water was introduced. The availability of this system was investigated by analyzing the sawdust used in the bio-toilet and the quality of the effluent in the household wastewater treatment facility. As the result, the water content of the sawdust did not exceed 60% in any of the sampling points and the BOD and COD of the effluent of the household wastewater treatment facility were below 10 and 20 mg/L respectively, due to the low loading. Compared to the pollution load on the water environment created by the conventional system, it was found that the effluent of the house has a lower load than the tertiary treatment and the volume of the water consumption is 75% of the conventional system. 相似文献