首页 | 本学科首页   官方微博 | 高级检索  
文章检索
  按 检索   检索词:      
出版年份:   被引次数:   他引次数: 提示:输入*表示无穷大
  收费全文   834篇
  免费   82篇
  国内免费   364篇
安全科学   87篇
废物处理   33篇
环保管理   48篇
综合类   635篇
基础理论   143篇
污染及防治   223篇
评价与监测   38篇
社会与环境   43篇
灾害及防治   30篇
  2024年   7篇
  2023年   18篇
  2022年   68篇
  2021年   60篇
  2020年   68篇
  2019年   58篇
  2018年   49篇
  2017年   58篇
  2016年   55篇
  2015年   63篇
  2014年   58篇
  2013年   68篇
  2012年   89篇
  2011年   89篇
  2010年   62篇
  2009年   60篇
  2008年   53篇
  2007年   39篇
  2006年   40篇
  2005年   23篇
  2004年   35篇
  2003年   24篇
  2002年   19篇
  2001年   14篇
  2000年   11篇
  1999年   21篇
  1998年   6篇
  1997年   12篇
  1996年   12篇
  1995年   10篇
  1994年   8篇
  1993年   4篇
  1992年   6篇
  1991年   6篇
  1989年   2篇
  1988年   2篇
  1985年   1篇
  1983年   1篇
  1981年   1篇
排序方式: 共有1280条查询结果,搜索用时 15 毫秒
101.
改性硅藻土用于巢湖水脱磷研究   总被引:5,自引:1,他引:4  
采用改性硅藻土强化混凝处理巢湖水,以达到除磷的目的.研究了改性硅藻土除磷最适操作条件,并将改性硅藻土同几种常规混凝剂的处理效果和其经济性进行了对比.结果表明:改性硅藻土和水的混合搅拌速度梯度为260 s-1左右,絮凝反应速度梯度为20 s-1左右,絮凝时间15 min,沉淀时间1 h,改性硅藻土投加量50~100 mg...  相似文献   
102.
厌氧-局部循环供氧生物膜技术处理农村污水   总被引:1,自引:0,他引:1  
通过模拟农村生活污水水质和间歇进水特点,利用“厌氧-局部循环供氧生物膜”技术,研究该工艺对有机物、氮、磷的去除效果.厌氧池和局部循环供氧池有效容积比为1∶1.6,曝气装置位于局部循环供氧池中间底部,环形导流板将局部循环供氧池分隔成中间好氧区和四周缺氧区,斜管沉淀池前置到厌氧池与局部循环供氧池之间,出水端设置循环水池.装置连续稳定运行12个月,平均进水量为140 L/d,生物反应区HRT为1.3d.监测结果表明,出水COD、BOD、NH3-N、TN和TP平均浓度分别在40.31、3.38、2.69、11.98和0.75 mg/L,达到了国家城镇污水处理厂污染物排放指标(GB-18918-2002)中的一级排放标准.研究表明,厌氧-局部循环供氧技术是一种适合农村分散污水处理的新工艺,可有效减轻农业面源污染.  相似文献   
103.
基于星座图法的湖北省农业功能分区   总被引:2,自引:0,他引:2  
农业功能分区是准确把握县域农业功能定位、推动区域农业功能拓展和向现代农业转型的基础工作。旨在探索运用一种新的分类方法即星座图法在农业功能分区中的应用。剖析现代农业的功能定位问题,从农产品供应、就业与社会保障、生态调节和文化传承与休闲4大类综合功能选取30个定量指标和2个定性指标,构建了湖北省农业功能分区指标体系。采用星座图法,根据星座图中各星点的位置,确定各县(市)单项功能的分等类型;并以此为基础结合分区单元的实际地理位置和社会经济及环境现状,作出湖北省农业功能分区方案。分区结果以县级行政区域为分区单元,按照农业功能分区的基本原则,湖北省分4个农业主导功能区,各主导功能区分为3个二级区共12个二级农业功能区  相似文献   
104.
单波  陈杰  肖岩 《环境工程学报》2013,7(2):649-656
胶合竹材GluBam的甲醛释放情况是现代竹结构住宅环保性的一个重要方面,也是竹结构住宅推广中最受关注的指标之一。采用1 m3气候箱对温度、相对湿度和封边情况与GluBam的甲醛释放量和释放速率的相关关系进行了测试,并以一阶单衰减模型为基础提出了GluBam的甲醛释放分析模型。测试和分析结果表明:GluBam板材在各模拟条件下甲醛浓度峰值均小于规范要求;初始甲醛释放量E0和衰减率常数k可以用来评价GluBam的甲醛释放特征;GluBam的醛释放量和释放速率随环境温度和湿度增加而显著增大,且温度因素的影响更大;封边处理可以有效降低GluBam板材的甲醛释放量。  相似文献   
105.
Parks with various types of vegetations played an important role in ameliorating air quality in urban areas. However, the attenuation effect of urban vegetation on levels of air pollution was rarely been experimentally estimated. This study, using seasonal monitoring data of total suspended particles (TSP), sulfur dioxide (SO(2)) and nitrogen dioxide (NO(2)) from six parks in Pudong District, Shanghai, China, demonstrated vegetations in parks can remove large amount of airborne pollutants. In addition, crown volume coverage (CVC) was introduced to characterize vegetation conditions in parks and a mixed-effects model indicated that CVC and the pollution diffusion distance were key predictors influencing pollutants removal rate. Therefore, it could be estimated by regression analysis that in summer, urban vegetations in Pudong District could contribute to 9.1% of TSP removal, 5.3% of SO(2) and 2.6% of NO(2). The results could be considered for a better park planning and improving air quality.  相似文献   
106.
The effects of TiO2 nanoparticles on the transport of Cu through four different soil columns were studied. For two soils (HB and DX), TiO2 nanoparticles acted as a Cu carrier and facilitated the transport of Cu. For a third soil (BJ) TiO2 nanoparticles also facilitated Cu transport but to a much lesser degree, but for a fourth soil (HLJ) TiO2 nanoparticles retarded the transport of Cu. Linear correlation analysis indicated that soil properties rather than sorption capacities for Cu primary governed whether TiO2 nanoparticles-facilitated Cu transport. The TiO2-associated Cu of outflow in the Cu-contaminated soil columns was significantly positively correlated with soil pH and negatively correlated with CEC and DOC. During passage through the soil columns 46.6-99.9% of Cu initially adsorbed onto TiO2 could be “stripped” from nanoparticles depending on soil, where Cu desorption from TiO2 nanoparticles increased with decreasing flow velocity and soil pH.  相似文献   
107.
A new imidacloprid (IMI) degrading bacterium Z-9 (deposited number CGMCC 6648) was isolated and identified as Pseudoxanthomonas indica by 16S rRNA gene analysis. Two metabolites were identified as olefin and 5-hydroxy IMI by liquid chromatography-mass spectrometry and nuclear magnetic resonance analysis. P. indica CGMCC 6648 degraded 70.1% of IMI (1.22 mmol L?1) and formed 0.93 mmol L?1 5-hydroxy IMI and 0.05 mmol L?1 olefin IMI in 6 days and in the presence of 100 mmol L?1 glucose. The half-life of IMI degradation was 3.6 days. P. indica CGMCC 6648 transforms IMI via a co-metabolism mechanism and different carbohydrates have significant effects on 5-hydroxy IMI formation, whereas different organic acids have substantial effects on olefin IMI production. Lactose is the best co-substrate for IMI degradation and 5-hydroxy IMI formation with 0.77 mmol L?1 degraded and 0.67 mmol L?1 formed in 48 h, respectively. Pyruvate is the best co-substrate for olefin IMI formation with 0.17 mmol L?1 produced in 96 h for all carbon sources tested. Pyruvate significantly stimulates the conversion of 5-hydroxy IMI to olefin IMI, whereas glucose slightly inhibits this reaction. P. indica CGMCC 6648 rapidly degrades IMI and forms olefin IMI, which may enhance its potential for biodegradation of IMI and increase its insecticidal activity, which can decrease the IMI dosage required.  相似文献   
108.
As one of China’s great metropolises, Taiyuan is affected by heavy chemical industry and manufacture of chemical products, and faces pollution from polychlorinated biphenyls (PCBs). Therefore, this study was conducted to determine the PCB concentrations in various environmental media in Taiyuan. We collected 15 soil samples, 34 respirable particulate matter (PM) samples (17 of PM2.5 and 17 of PM10) from urban areas of Taiyuan, and measured a total of 144 PCB congeners (including some coeluting PCB congeners). The total PCB concentrations were 51–4.7 × 103 pg g−1 in soil, 27–1.4 × 102 pg m−3 in PM2.5 and 16–1.9 × 102 pg m−3 in PM10. Of the PCB homologues, the dominant PCBs detected in the various media were all tri-CBs. Soil was relatively the most polluted media. Furthermore, principal-component analysis revealed that the major PCB source in Taiyuan may be associated with the main commercial PCB through long-range transmission. Toxic equivalency (TEQ) concentrations (based on ten dioxin-like PCBs) ranged from N.D. to 5.9 × 10−3 pg-WHO TEQ g−1 in soil, 2.0 × 10−4–3.4 × 10−3 pg-WHO TEQ m−3 and 1.0 × 10−4–1.2 × 10−3 pg-WHO TEQ m−3 in PM2.5 and PM10, respectively. In previous studies, PCBs were not a severe component of contaminant in Taiyuan; however, this study suggested there is a potential threat of human exposure to PCBs for residents of Taiyuan.  相似文献   
109.
Removal of 2-chlorophenol from water using rice-straw derived ash (RSDA) was evaluated in this study to compare with commercial activated carbon. RSDA was obtained by burning rice-straw at 400 °C and 700 °C for 1 h. This ash can provide a better adsorbent for 2-chlorophenol. The adsorption capacities of RSDA at 400 °C and 700 °C are 37 and 52 mg g?1 at pH 4, respectively, and decrease to 9.0 and 40 mg g?1 at pH 10. Adsorption of either neutral or anionic 2-cholorphenol by the RSDA are shown as L-shaped nonlinear isotherms, suggesting surface adsorption rather than partitioning is occurring. At higher-burning temperatures, the surface area, porosity, point of zero charge and aromaticity of the resultant RSDA increase, but the oxygen content and surface acidity decrease. The combined effects result in a higher 2-chlorophenol adsorption of RSDA at 700 °C, which shows a slight pH effect on the adsorption of 2-chlorophenol, due to the lower content of oxygen-containing functional groups. Oxygen-containing functional groups contribute to surface acidity and H-bonding sites for adsorbed water, which compromises the interaction between 2-chlorophenol and the adsorbents. Thus, it suggests that rice-straw derived carbon (RSDC) can be used as an effective low-cost substitute material for activated carbon for removal of chlorophenols from wastewater.  相似文献   
110.
周珊  康君行  黄骏雄 《环境化学》2001,20(2):191-195
用固相微苹取(SPME)-气相色谱/质谱联用法测定饮用水中苯类化合物,以100μm PDMS(聚二甲基硅氧烷)萃取针提取、浓缩、分离与测定九种目标化合物.萃取时间经优化选定为8min,而热解析时间设定为2min. 本方法的相对标准偏差小于5%,线性范围宽(20ng·ml-1-10000ng·ml-1),多数化合物的检测限低于5μg·l-1.饮用水样品检测显示,样品加标回收率范围在84%至110%内.  相似文献   
设为首页 | 免责声明 | 关于勤云 | 加入收藏

Copyright©北京勤云科技发展有限公司  京ICP备09084417号