石墨烯类材料在水处理和地下水修复中的应用

作为一种性质优异的吸附材料,石墨烯类材料对有机物和重金属等多种水污染物均有出色的吸附能力,因此其在水处理和地下水修复工作中的应用前景在近几年备受关注.当前的研究总体上尚停留在实验室模拟阶段,在提高材料饱和吸附量的同时,研制出低成本、稳定性强、易于再生利用且环境友好的石墨烯类材料是今后的发展趋势.本文对石墨烯类材料的种类及制备方法进行了归纳总结,对他们在水处理和地下水修复中的应用研究情况进行了综述,对当前研究中存在的问题进行了分析,最后对未来的研究和应用前景进行了总结和展望.     

Highly time-resolved aerosol characteristics during springtime in Weizhou Island

A single particle aerosol mass spectrometer was deployed to measure the changes of single particle species and sizes during March 2015 in Weizhou Island of the Beibu Gulf, Guangxi province, South China. In this campaign, a total of 3,100,597 particles were sized, and 25.8%particles with both positive and negative mass spectrum were collected and 24.8%characterized in combination with the ART-2 a neural network algorithm. The distribution of sized particles was mainly in from 520 to 600 nm, and the diameters ranging from 340 to1000 nm accounted for above 90%. Eight types of particles were classified: Elemental Carbon containing(EC), Organic Carbon containing(OC), EC and OC combined containing particles,Na containing particles, K containing particles(K), Levoglucosan containing particles,mineral containing particles, and Heavy Metal containing particles(HM). EC, OC and K were the major containing particles, which accounted for 84.3% in the eight types particles. The relative ratio and size distribution of the three types were EC(48.1%, 620 nm), OC(12.7%,440 nm), and K(23.5%, 600 nm), respectively. The three types of particles were a bit increasing ratios compared with those in clean periods during haze pollution periods.Combined with the back-trajectory results from the Hysplit-4 model and local pollution sources revealed that the ambient air quality on the Weizhou Island may be influenced by biomass burning in the Indochina Peninsula(biomass burning in the Indochina Peninsula)from the transportation on higher level atmospheric layer and by mainland of south China located northeast of Weizhou Island on the ground.     

Polar organic tracers in PM2.5 aerosols from an inland background area in Southwest China: Correlations between secondary organic aerosol tracers and source apportionment

PM_(2.5) aerosol samples were collected over 12 hr and 24 hr intervals in an inland background area, Gongga Mountain National Nature Reserve(hereafter shortened to Gongga), during the summer of 2011. Polar organic tracers, inorganic ions and meteorological data were measured. The purpose of this work was to investigate the variation patterns, formation and sources of the secondary organic aerosol tracers in the studied atmosphere. The average concentrations of isoprene oxidation products, α-pinene oxidation products, β-caryophyllinic acid, sugars, sugar alcohols and anhydrosugars were 88.6 ± 106.1, 3.6 ± 5.7,0.13 ± 0.30, 13.6 ± 13.1, 31.9 ± 31.4 and 14.8 ± 10.7 ng/m3 respectively in all aerosol samples.The aged α-pinene second organic aerosol(SOA) tracers(i.e., 3-hydroxyglutraric acid(3 HGA), 3-hydroxy-2,2-dimethylglutaric acid(HDMGA), 3-acetylpentandioic acid(APDA) and 3-methyl-1,2,3-butanetricarboxylic acid(MBTCA)) correlated significantly with each other in the 24 hr PM2.5 aerosol samples, indicating that OH· is the major factor controlling the formation of these α-pinene SOA tracers. Using the positive matrix factorization(PMF) model and the tracer-based source apportionment method, we calculated that isoprene oxidation products, α-pinene oxidation products, sesquiterpene oxidation products, biomass burning, fungi spores and anthropogenic SOA accounted for 21.9% ± 5.5%, 8.4% ± 2.1%, 3.0% ± 0.7%, 5.2% ± 5.3%, 5.0% ± 6.2% and 31.4% ± 7.8% of organic carbon respectively during the sampling period.     

Methane production from food waste leachate in laboratory-scale simulated landfill

Due to the prohibition of food waste landfilling in Korea from 2005 and the subsequent ban on the marine disposal of organic sludge, including leachate generated from food waste recycling facilities from 2012, it is urgent to develop an innovative and sustainable disposal strategy that is eco-friendly, yet economically beneficial. In this study, methane production from food waste leachate (FWL) in landfill sites with landfill gas recovery facilities was evaluated in simulated landfill reactors (lysimeters) for a period of 90 d with four different inoculum–substrate ratios (ISRs) on volatile solid (VS) basis. Simultaneous biochemical methane potential batch experiments were also conducted at the same ISRs for 30 d to compare CH₄ yield obtained from lysimeter studies. Under the experimental conditions, a maximum CH₄ yield of 0.272 and 0.294 L/g VS was obtained in the batch and lysimeter studies, respectively, at ISR of 1:1. The biodegradability of FWL in batch and lysimeter experiments at ISR of 1:1 was 64% and 69%, respectively. The calculated data using the modified Gompertz equation for the cumulative CH₄ production showed good agreement with the experimental result obtained from lysimeter study. Based on the results obtained from this study, field-scale pilot test is required to re-evaluate the existing sanitary landfills with efficient leachate collection and gas recovery facilities as engineered bioreactors to treat non-hazardous liquid organic wastes for energy recovery with optimum utilization of facilities.     

基于生命周期评价法的条斑紫菜养殖加工产业碳足迹分析

应用生命周期评价法（LCA）对条斑紫菜养殖加工行业进行了全周期的碳足迹分析，明确了各环节中碳排放源的种类和数量。结果表明，100亩条斑紫菜养殖加工过程中碳排放总量为1.25×10⁵~2.47×10⁵ kg CO₂，远高于条斑紫菜100亩养殖形成的可移出碳汇量（9.43×10³ kg CO₂）。基于全产业链的分析，条斑紫菜产业尚不是一个碳汇产业。养殖阶段碳排放量最大，排放源主要来自石油化工材料的大量使用。二次加工阶段碳排放量仅次于养殖阶段，排放源主要来自纸壳包装和塑料包装的大量使用。在一次加工阶段，热源的使用是影响该阶段碳排放的主要影响因素，生物质燃料是碳排放量最低的热源形式。     

The effect of spent bleaching earth ageing process on its physicochemical and microbial composition and its potential use as a source of fatty acids and triterpenes

This study was aimed at investigating the physicochemical and microbiological changes that took place during the ageing process of spent bleaching earth in the presence of autochthonous microorganisms. Research material included fresh spent bleaching earth (SBE₀) and the same material after 3 years of storage at the constant temperature of 20 °C, without aeration and moistening (SBE₃). Changes in the chemical composition of analysed waste material were observed during its ageing process point to a spontaneous bioconversion of fat substance towards formation and/or release of free saturated fatty acids C16:0 and C18:0 (14.3 g 100 g^?1 D.M.), triterpenes (8.48 g 100 g^?1 D.M.), cholesterol (3.29 g 100 g^?1 D.M.), small quantities of carbohydrates and esters (0.80 g 100 g^?1 D.M.). This process was accompanied by other changes in physicochemical parameters of the waste material, such as colour, odour and viscosity, decrease in fat content from 28.27 to 24.6 % and that of soluble forms of metals (Mo, Cu, Fe, Zn, Ni, Cr and Mn), ranging from 25 to 75 %, and an increase in pH, from 3.85 to 4.2. At the same time, changes in the microbial consortium were observed.     

A double‐edged sword: The moderating role of conscientiousness in the relationships between work stressors,psychological strain,and job performance

Although conscientiousness was commonly viewed as a type of personal resource to help individuals reduce strain or mitigate the impacts of stressors, empirical research demonstrated mixed results. Based on the personal resource allocation perspective, we posited that rather than functioning as personal resource per se, conscientiousness may act as a key factor influencing how individuals allocate their personal resources. The current study examined the moderating roles of conscientiousness in the relationships that work stressors (i.e., challenge stressors and hindrance stressors) have with employee psychological strain and job performance by using multi‐source, time‐lagged data collected from 250 employees working at two companies. The results showed that both challenge stressors and hindrance stressors were positively related to psychological strain. Conscientiousness moderated the relationships between both stressors and psychological strain, such that the positive relationships were stronger for individuals with high conscientiousness. Conscientiousness also moderated the relationship between challenge stressors and performance, such that the relationship was positive for individuals with high conscientiousness but negative for those with low conscientiousness. Altogether, the findings suggest that conscientiousness acts as a double‐edged sword that both promotes performance and exacerbates the stress reaction of employees when they are confronted with stressful situations. Copyright © 2014 John Wiley & Sons, Ltd.     

Nitrogen to phosphorus ratios of two understory plant species in response to nitrogen and phosphorus addition in tropical forest of southern China北大核心CSCD

The secondary tropical forests in southern China have suffered from frequent human disturbance and increasing high N deposition. In order to explore the nutrient limitation status in secondary tropical forests of South China, this 3-year field experiment of nitrogen (+N) and phosphorus (+P) addition investigated nitrogen (N) and phosphorus (P) concentrations of the aboveground tissue (leaf and branch) of two widely distributed understory native species Clerodendrum cyrtophyllum and Uvaria microcarpa in a secondary tropical forest of South China. The results showed that: 1) the N and P concentrations of the two species were significantly different (P < 0.001); N and P concentrations of different tissues in the same species were different; N&P addition greatly affected N and P concentrations in branch rather than new leaf and older leaf. 2) +N treatment had no significant effect on N or P concentrations of either species, but significantly decreased N:P ratios (P = 0.001), at the level of 9% for C. cyrtophyllum and 50% for U. microcarpa, respectively. 3) +P treatment had no significant effect on tissue N concentrations, but significantly increased plant P concentrations (P < 0.001), at 54% for C. cyrtophyllum and 88% for U. microcarpa, respectively; +P treatment significantly decreased plant N:P ratios (P < 0.001), at 28% and 60%, respectively. 4) The alterations of P concentrations of two species had significantly negative correlations with N:P alterations under +N/+P treatment (P < 0.001), suggesting that the alteration of P concentrations in plant tissue was the major driver for N:P alteration. Our results show that N and P addition would affect tissue N and P concentrations of the two species, with +P treatment having relatively greater effect on nutrient concentrations than +N treatment; the branch is more sensitive than new or older leaf in response to nutrient addition. Therefore, P availability may be the limiting factor for plant growth in the tropical forests.     

Temporal variability of atmospheric particulate matter and chemical composition during a growing season at an agricultural site in northeastern China

This study presents the observations of PM_(10) and PM_(2.5) concentrations at an agricultural site from April to October 2012 in Dehui city,China.Ambient air was sampled by filter-based samplers and online PM monitors.The filter samples were analyzed to determine the abundance of ionic/inorganic elements,organic carbon(OC) and elemental carbon(EC).The daily PM_(10) concentrations varied significantly over the monitoring period,with an average of168 ± 63(in the range of 52-277) μg/m~3 during the land preparation/planting period(26 April-15 June),85 ± 65(36-228) μg/m~3 during the growing season(16 June-25 September),and 207 ±88(103-310) μg/m~3 during the harvest period(26 September-31 October).PM_(2.5) accounted for44%,56%and 66%of atmospheric PM_(10) during these periods,respectively.The PM_(10) diurnal variation showed a distinct peak from 16:00 to 21:00(LST) during the growing and harvesting seasons,while a gradual increase throughout the daytime until 17:00 was observed during tilling season.Mineral dust elements(Al,Ca,Fe,and Mg) dominated the PM_(10) chemical composition during the tilling season;OC,NO_3~-,SO_4~(2-) and NH_4~+ during the growing season;and carbonaceous species(i.e.,OC and EC) during the harvesting season.Our results indicate that the soil particles emitted by farm tillage and organic matter released from straw burning are the two most significant sources of PM_(10) emissions contributing to the recurring high pollution events in this region.Therefore,development of agricultural PM inventories from soil tillage and straw burning is prioritized to support air quality modeling.