Contamination by organochlorine compounds in the edible tissue of four sturgeon species from the Caspian Sea (Iran)

This study focused on accumulation of organochlorine compounds (OCs), including dichloro-diphenyl-trichloroethanes (DDTs), hexachlorobenzene (HCB), hexachlorocyclohexanes (HCHs), and polychlorinated biphenyls (PCBs) accumulation in the muscle of four sturgeon (Persian sturgeon, Acipenser persicus; Stellate sturgeon, Acipenser stellatus; Ship sturgeon, Acipenser nudiventris and Beluga sturgeon, Huso huso) from the southern Caspian Sea. The DDT group was prominent in all of the sturgeon muscle tested constituting almost half or more of the total organochlorine content. Contaminant concentration generally followed this order: DDTs>PCBs>HCHs>HCB. The OCs concentrations in Beluga sturgeon (H. huso) were the highest and over four times higher than in the next highest species (A. nudiventris). From an ecotoxicological point of view, the concentrations of OCs in experimental fishes do not reflect a comparatively clean and pollution-free environment; however, results from this study shown that the inflow of organic pollutants into the Caspian Sea has been reduced when compared with prior studies. Levels of measured OCs in sturgeon were relatively low, but the level of some OCs in some of the specimens tested exceeded the guidelines for food; therefore, the maximum allowable daily consumption rate for sturgeon from this watershed may be limited by DDTs and PCBs content for high risk populations.     

Anaerobic co-digestion of wine/fruit-juice production waste with landfill leachate diluted municipal sludge cake under semi-continuous flow operation

Anaerobic co-digestion of four organic waste streams; a thickened waste activated sludge (TWAS) and screen cake (SC) from a fruit-juice/winery wastewater treatment plant along with municipal sludge cake (MC) and landfill leachate (LL) was evaluated. A total of eight semi-continuously-fed single and co-digesters were operated side-by-side at sludge retention times (SRT) of 20 and 10 days. Co-digestion of industrial waste streams (TWAS and SC) with MC and LL resulted in increased operational stability compared to the single digestion of industrial TWAS at the higher organic loading (10 d SRT). Although digester operational temperature had no statistically significant effect on organics removal and biogas production, mesophilic digesters had consistently higher total coliform densities (8838–37,959 most probable number or MPN/g-dry weight) compared to the thermophilic digesters (41–6723 MPN/g-dry weight) at both SRTs. Coliform analysis results also proved that most of the thermophilic digestates could be classified as Class A biosolids according to regulations. Furthermore, addition of industrial TWAS to co-digesters enhanced the dewaterability of the digested streams. A cost-benefit analysis confirmed the benefits and indicated that a full-scale co-digester utilizing all four waste streams can decrease the total capital and operational cost by 22% ($10.52 million).     

Environmental protection stability of river bed and banks using convex, concave, and linear bed sills

River bed scourings are a major environmental problem for fish and aquatic habitat resources. In this study, to prevent river bed and banks from scouring, different types of bed sills including convex, concave and linear patterns were installed in a movable channel bed in a laboratory flume. The bed sills were tested with nine different arrangements and under different flow conditions. To find the most effective bed sill pattern, the scouring depth was measured downstream of the bed sill for a long experimental duration. The scour depth was measured at the middle and at the end of each experimental test for different ratios of the arch radius to the channel width $(r/\emph{w})$ . The experimental results indicated that the convex pattern with $r/\emph{w}=0.35$ produced minimum bed scouring depth at the center line whereas the concave pattern with $r/\emph{w}=0.23$ produced the minimum scour depth at the wall banks. Therefore, the convex pattern was the most effective configuration for prevention of scouring at the center line of the river while the concave pattern was very effective to prevent scouring at the river banks. These findings can be suggested to be used in practical applications.     

Petroleum pollution in mangrove forests sediments from Qeshm Island and Khamir Port—Persian Gulf, Iran

The concentrations of total polycyclic aromatic hydrocarbons (?PAHs) and 22 individual PAH compounds in 42 surface sediments collected from the mangrove forest of Qeshm Island and Khamir Port (Persian Gulf) were analyzed. ?PAHs concentrations ranged from 259 to 5,376 ng?g^?1 dry weight with mean and median values of 1,585 and 1,146 ng?g^?1, respectively. The mangrove sediments had higher percentages of lower molecular weight PAHs and the PAH profiles were dominated by naphthalene. Ratio values of specific PAH compounds were calculated to evaluate the possible source of PAH contamination. This ratios suggesting that the mangrove sediments have a petrogenic input of PAHs. Sediment quality guidelines were conducted to assess the toxicity of PAH compounds. The levels of total PAHs at all of stations except one station, namely Q₆, were below the effects range low. Also, concentrations of naphthalene in some stations exceeded the effects range median.     

Predicting saltwater intrusion into aquifers in vicinity of deserts using spatio-temporal kriging

The primary objective of this study was to provide a detailed framework to use the spatio-temporal kriging to model the spatio-temporal variations of salinity data and predict saltwater intrusion into freshwater aquifers in the vicinity of deserts. EC data, measured in extraction wells in the Mahvelat plain located in the Northeastern part of Iran, available from 2007 to 2013, were used to demonstrate the developed framework. The source of data was not a well-designed measurement network. Therefore, to homogenize the data, spatial analysis was used to find EC distribution in the area in each year of study. To conduct the spatial analysis, a guideline and a systematic process were developed to select an appropriate kriging method and optimize its parameters. This process can be applied to different variables. After spatial analysis of EC data for all the years of the analysis period using empirical Bayesian kriging (EBK) method with manually optimized parameters, spatio-temporal and corresponding variogram analysis was conducted using R software. This process was based on a separable product-sum model applied to the data from 2007 to 2012. The data of 2013 and the data available for the years 1999 and 2006 were used for evaluating the performance of the spatio-temporal model. The EC distribution maps, developed for different years until 2021, show a high level of EC in the north, south, and west of the study area and growing saltwater intrusion into the central freshwater aquifer. This result can be attributed to the over-exploitation of the aquifer and hydraulic head and gradient distribution in the area. The framework provided in this study for spatio-temporal analysis of unstructured EC data is useful for groundwater managers in making proper decisions.     

Fish Bone as a Low-Cost Adsorbent for Dye Removal from Wastewater: Response Surface Methodology and Classical Method

This research studied the application of fish bone as a low-cost adsorbent for the removal of two basic dyes (C.I. Basic Blue 41 and C.I. Basic Yellow 28) from textile wastewaters. The surface morphology and functional groups of the fish bone was studied by scanning electron microscopy and Fourier transform infrared, respectively. The experiments were designed in two methods: classical method and response surface methodology (RSM). The effect of operating parameters including pH, initial dye concentration, adsorbent dosage, and inorganic salts was investigated by both methods. The optimum conditions to satisfy 75 % of dye removal for both dyes were predicted by RSM method and the results were very close to the experimental values. So, it was concluded that the fish bone can be used as a low-cost adsorbent for dye removal from effluents.