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81.
Sónia?Roxo José?António?de?AlmeidaEmail author Filipa?Vieira?Matias Herlander?Mata-Lima Sofia?Barbosa 《Environmental monitoring and assessment》2016,188(3):129
This paper proposes a multistep approach for creating a 3D stochastic model of total petroleum hydrocarbon (TPH) grade in potentially polluted soils of a deactivated oil storage site by using chemical analysis results as primary or hard data and classes of sensory perception variables as secondary or soft data. First, the statistical relationship between the sensory perception variables (e.g. colour, odour and oil–water reaction) and TPH grade is analysed, after which the sensory perception variable exhibiting the highest correlation is selected (oil–water reaction in this case study). The probabilities of cells belonging to classes of oil–water reaction are then estimated for the entire soil volume using indicator kriging. Next, local histograms of TPH grade for each grid cell are computed, combining the probabilities of belonging to a specific sensory perception indicator class and conditional to the simulated values of TPH grade. Finally, simulated images of TPH grade are generated by using the P-field simulation algorithm, utilising the local histograms of TPH grade for each grid cell. The set of simulated TPH values allows several calculations to be performed, such as average values, local uncertainties and the probability of the TPH grade of the soil exceeding a specific threshold value. 相似文献
82.
Combining field and laboratory work, this study investigated the reproductive cycle, aggregative behavior, spawning periodicity,
development and early growth of the sea star Henricia lisa living at bathyal depths off eastern Canada. Marked differences were found between individuals from ~1,300 and ~600 m deep.
The former had a male biased sex ratio and an aperiodic reproductive cycle, whereas the latter displayed an equal sex ratio
and a biannual breeding pattern. Furthermore, the maximum size was larger and female fecundity roughly five times higher in
shallower compared to deeper populations. In the tanks, aggregative behavior was recorded twice a year during the summer and
winter breeding periods. The onset of aggregations and spawning coincided with a temperature of 3–4°C. Males spawned first
and females typically responded inside 30–60 min. Between 12 and 20 eggs were retained to be brooded under the arched arms
of the female, whereas the remainder were broadcasted and developed without parental care. The fertilized eggs underwent a
first cleavage after 12 h, reached the brachiolaria stage in 1 month, became juveniles within 3–4 months and reached ~ 4 mm
in diameter after 14–17 months of growth. The embryos and juveniles developed at the same rate whether brooded or not, and
development of winter cohorts was typically slower due to lower prevailing temperatures. This study of H. lisa provides the first evidence of lecithotrophy in a seasonally breeding deep-sea echinoderm and of brooding in a deep-sea asteroid. 相似文献
83.
This study examines the composition and activity of the planktonic community during the polar night in the high Arctic Kongsfjord,
Svalbard. Our results are the first published evidence of bioluminescence among zooplankton during the Arctic polar night.
The observations were collected by a bathyphotometer detecting bioluminescence, integrated into an autonomous underwater vehicle,
to determine the concentration and intensity of bioluminescent flashes as a function of time of day and depth. To further
understand community dynamics and composition, plankton nets were used to collect organisms passing through the bathyphotometer
along with traditional vertical net tows. Additionally, using a moored bathyphotometer closed to the sampling site, the bioluminescence
potential itself was shown not to have a diurnal or circadian rhythm. Rather, our results provide evidence for a diel vertical
migration of bioluminescent zooplankton that does not correspond to any externally detectable changes in illumination. 相似文献
84.
Pascal D. Leroy Ahmed Sabri Fran?ois J. Verheggen Fr��d��ric Francis Philippe Thonart Eric Haubruge 《Chemoecology》2011,21(3):113-122
In natural environment, semiochemicals are involved in many interactions between the different trophic levels involving insects,
plants and hosts for parasitoids or prey for predators. These volatile compounds act as messengers within or between insect
species, inducing particular behaviours, such as the localisation of a source of food, the orientation to an adequate oviposition
site, the selection of a suitable breeding site and the localisation of hosts or prey. In this sense, bacteria have been shown
to play an important role in the production of volatile compounds which ones act as semiochemicals. This review, focusing
on the semiochemically mediated interactions between bacteria and insects, highlights that bacterial semiochemicals act as
important messengers for insects. Indeed, in most of the studies reported here, insects respond to specific volatiles emitted
by specific bacteria hosted by the insect itself (gut, mouthparts, etc.) or present in the natural environment where the insect
evolves. Particularly, bacteria from the families Enterobacteriaceae, Pseudomonaceae and Bacillaceae are involved in many
interactions with insects. Because semiochemicals naturally produced by bacteria could be a very interesting option for pest
management, advances in this field are discussed in the context of biological control against insect pests. 相似文献
85.
Elaine S. Carvalho Rubén J. Sánchez Maria I. B. Tavares álano C. Lam?nica 《Journal of Polymers and the Environment》2010,18(4):661-667
The chemical modification of Acrylamidomethyl Cellulose Acetate Propionate (AMCAP) was carried out by radical addition of
acrylic acid. The structural modification was confirmed with the aid of FTIR, MS and NMR techniques. Thermal properties of
hydrophilic cellulose derivative (AMCAP–H2O2) such as glass transition (Tg 153 °C) and thermal stability (372.7 °C) were determined by DSC and TGA techniques, respectively. These thermal properties
confirmed the introduction of carboxylic groups into AMCAP structure, which causes an impact in their properties. The AMCAP–H2O2 shows minor contact angle compared to AMCAP, giving a more hydrophilic characteristic, due to acrylic acid addition into
the side chains of AMCAP polymer. 相似文献
86.
The concentrations of heavy metals and metals (Zn, Pb, Bi, Cd, Ni, Co, Fe, Mn, Mg, Cu, Cr, Ca, Sr, Na, Li, K) were measured in muscle of five species Cyprinus carpio (from I??kl? dam), Scardinius erythrophthalmus (from I??kl? dam), Tinca tinca (from I??kl? dam), C. carpio (from Karaca?ren dam), Carassius carassius (from Karaca?ren dam) caught from I??kl? and Karaca?ren. The highest metal was Na (466.95 μg/g) in C. carassius, while the lowest levels were Fe (0.37 μg/g) and Cu (0.37 μg/g) in C. carpio from I??kl? dam. The mean concentrations μg/g d.w. some of heavy metals in muscle of C. carpio (from I??kl? dam), S. erythrophthalmus (from I??kl? dam), T. tinca (from I??kl? dam), C. carpio (from Karaca?ren dam), C. carassius (from Karaca?ren dam) were as follows: Cd 2.00-2.10-1.95-2.06-2.27, Zn 4.36-2.64-13.13-13.33-24.47, Pb 1.65-1.24-1.90-2.37-2.41, Co 2.46-2.37-2.48-2.58-2.80, Mg 138.51-154.35-218.59-204.58-202.16, Fe 0.37-2.62-3.17-3.01-12.33, respectively. 相似文献
87.
Sediment quality guidelines (SQGs) can be derived using different approaches and are commonly used in environmental management,
reclamation, and risk assessment. The screening-level concentration (SLC) approach has been used in Ontario, Canada, to derive
lowest effect levels (LELs) and severe effect levels for use as SQGs. This approach was adopted by the Canadian Nuclear Safety
Commission (CNSC) to set guidelines for metals (As, Cr, Cu, Pb, Mo, Ni, Se, U, and V) and radionuclides (Ra-226, Pb-210, and
Po-210) in sediment at northern Saskatchewan uranium mining and milling operations. The SLC approach is based on total metal
and radionuclide concentrations in sediment, and corresponding benthic community composition data for a specific sampling
site. In this study, sediment chemistry (total metals and radionuclides) and benthic community data from northern Saskatchewan
uranium operations were compiled and examined. Results indicate that the CNSC-derived SQGs had limited relationships to observed
effects, or lack thereof, on benthic invertebrate communities near uranium operations in Saskatchewan. The LELs were found
to correctly align with effects at 95% of the sites that had effects, on a general basis, but on an element-specific basis
many of the elements had concentrations at effect sites below their LELs. Furthermore, concentrations of the evaluated elements
exceeded at least one LEL at 60% of the no-effect sites. The high number of exceedences of LELs at reference and no-effect
sites (false-positives) calls to question the appropriateness of the CNSC-derived SQGs. It is suggested that alternatives
to the SLC approach be explored. 相似文献
88.
A study of chemical and sedimentological parameters integrated with benthic foraminifera investigation was conducted along
the northern coast of Gabes Gulf. Thirty-two samples were studied and a total of 68 benthic foraminiferal species were identified.
Heavy metals enrichment factors and total hydrocarbon concentrations showed both metal and petrogenic pollution related mainly
to phosphogypsum, sewage, and fishing activities. Statistical analysis (bivariate correlation and hierarchical cluster analysis)
show a possible control of these pollutants on density, diversity, as well as the taxonomic composition of the benthic foraminiferal
assemblages. The extent to which the population was found less dense and less diversified corresponded to the degree to which
the sediment was contaminated. In these contaminated sites, an increase in relative abundance of opportunistic species such
Ammonia tepida and Haynesina germanica was found. Far from pollution, foraminiferal assemblages are dominated by species characteristic of Mediterranean shallow
water (Ammonia beccarii, Ammonia parkinsoniana, Elphidium crispum, Elphidium williamsoni, Elphidium advenum, Peneroplis planatus, Peneroplis pertesus). 相似文献
89.
Highways and main roads are a potential source of contamination for the surrounding environment. High traffic rates result in elevated heavy metal concentrations in road runoff, soil and water seepage, which has attracted much attention in the recent past. Nonetheless, investigations of pollutants in roadside soils are still a subject of major interest due to the rapid development of traffic systems and increasing traffic all over the world. The accumulation of the heavy metals Pb, Cd, Cu and Zn in soils along the oldest federal highway of the world has been studied by sampling a roadside transect of 125 by 10?m. In addition, heavy metal concentrations of Pb, Cd, Zn, Cu, Ni and Cr in soil solutions from different distances (2.5, 5 and 10?m) from the hard shoulder of the highway and from three soil depths (10, 30, and 50?cm) were investigated. The results show that heavy metal concentrations are up to 20 times increased compared to the geochemical background levels and a reference site of 800-m distance from the roadside. Soil matrix concentrations in the topsoil (0-10?cm) mostly exceeded the precautionary values of the German Federal Soil Protection and Contamination Ordinance (BBodSchV). The concentrations of Cd, Pb and Zn in the soil matrix tended to decrease with distance from the roadside edge, whereas the concentrations in the soil solution increased at a distance of 10?m onwards due to a lower soil pH. Because of both high pH values and a high sorption capacity of the soils, soil solution concentrations seldom exceeded the trigger values of the German Federal Soil Protection and Contamination Ordinance (BBodSchV) for transferring soil solution to groundwater. 相似文献