Effects of temperature and SO3 on re-emission of mercury from activated carbon under flue gas conditions

Mercury(Hg) is a toxic and bio-accumulating heavy metal that is predominantly released via the combustion of coal. Due to its toxicity, the Environmental Protection Agency(EPA)has introduced Mercury and Air Toxics Standards(MATS) Rule regarding allowable Hg emissions. In order to reduce emissions, power plants have widely adopted activated carbon(AC) injection. AC injection has proven to be an effective method to reduce Hg emissions, but the re-emission of previously adsorbed Hg during unit operation, likely due to changing temperature or flue gas composition, could be problematic. This study specifically examined the effects of temperature and sulfur trioxide(SO3) concentration,by ramping temperature and SO3 concentration independently and simultaneously, on AC samples that are already exposed to flue gas and saturated in presence of Hg, sulfur dioxide(SO2) and nitric oxide(NO). Of these two suspected factors to cause re-emission,temperature had the greater impact and resulted in re-emission of both elemental and oxidized Hg with a greater fraction of oxidized Hg, which can be attributed to elemental Hg being more strongly bonded to the AC surface. Surprisingly, exposing the samples to increasing concentrations of SO3 had nearly no effect under the conditions examined in this study, possibly as a result of the samples being already saturated with sulfur prior to the SO3 ramp tests to simulate transient conditions in the plant.     

NEW DIRECTIONS IN FLOODPLAIN MANAGEMENT1

ABSTRACT: Over the last 30 years, average annual riverine flood damages have exceed $2 billion. Damages associated with the Mississippi River Flood of 1993 exceeded $12 billion and these costs do not include the non-quantifiable, human impacts of this disaster. In a report submitted to the White House in June 1994, a federal interagency floodplain management review committee proposed better ways to manage the nation's floodplains. The committee indicated that the 1993 Mississippi River flood was the result of a significant hydrometeorological event, that federal flood control efforts in the Mississippi basin had prevented nearly $20 billion in potential damages, and that, in spite of federal flood damage reduction efforts, throughout the nation people and property remain at risk to inevitable future flooding. It recommended that the division of decision and cost-sharing responsibilities among federal, state and local governments be more clearly defined, and that the nation adopt a strategy of, sequentially, avoiding inappropriate use of the flood-plain, minimizing vulnerability to damage through both nonstruc-tural and structural means, and mitigating damages as they occur. The report did not call for abandonment of human use of the flood-plain but argued for full consideration of the economic, social and environmental costs and benefits of all future floodplain activity.     

Effects of Disturbance on Nitrogen Export from Forested Lands of the Chesapeake Bay Watershed

The objective of this research project is to develop, test, validate, and demonstrate an analytical framework for assessing regional-scale forest disturbance in the mid-Atlantic region by linking forest disturbance and forest nitrogen export to surface waters at multiple spatial scales. It is hypothesized that excessive nitrogen (N) leakage (export) from forested watersheds is a potentially useful, integrative "indicator" of a negative change in forest function which occurs in synchrony with changes in forest structure and species composition. Our research focuses mainly on forest disturbance associated with recent defoliations by the gypsy moth larva (Lymantria dispar) at spatial scales ranging from small watersheds to the entire Chesapeake Bay watershed. An approach for assessing the magnitude of forest disturbance and its impact on surface water quality will be based on an empirical model relating forest N leakage and gypsy moth defoliation that will be calibrated using data from 25 intensively-monitored forested watersheds in the region and tested using data from more than 60 other forested watersheds in Virginia. Ultimately, the model will be extended to the region using spatially-extensive data describing: 1) the spatial distribution of dominant forest types in the mid-Atlantic region based on both remote sensing imagery and plot-scale vegetation data; 2) the spatial pattern of gypsy moth defoliation of forested areas from aerial mapping; and 3) measurements of dissolved N concentrations in streams from synoptic water quality surveys.     

Reactive nitrogen and the world: 200 years of change

This paper examines the impact of food and energy production on the global N cycle by contrasting N flows in the late-19th century with those of the late-20th century. We have a good understanding of the amounts of reactive N created by humans, and the primary points of loss to the environment. However, we have a poor understanding of nitrogen's rate of accumulation in environmental reservoirs, which is problematic because of the cascading effects of accumulated N in the environment. The substantial regional variability in reactive nitrogen creation, its degree of distribution, and the likelihood of increased rates of reactive-N formation (especially in Asia) in the future creates a situation that calls for the development of a Total Reactive Nitrogen Approach that will optimize food and energy production and protect environmental systems.     

美国1961～2000年氮使用量的变化及未来趋势预测

从1961～1997年,因人类活动而输入到美国的氮翻了一番,特别是在上个世纪60年代和70年代,其增长量最大.尽管无机氮肥的使用量增长最大,但矿物燃料燃烧所造成的NOx排放,也有明显的增加.1961年,美国农业生产系统中的生物固氮量是活性氮的最大来源;到了1997年,尽管生物固氮量也有增加,但相比而言,无机氮肥的使用和NOx的排放增加得更快,成为两个最大的氮源.1961～1997年,在输入到美国的活性氯中,有2/3发生了脱氮反应或者是被贮存在土壤与生物群落之中,有1/3输出到境外.在输出到境外的这部分氮中,通过河流流到海洋中的分量最大,其次是通过粮食和饲料出口而到其它国家以及通过大气平流传输到了海洋中.动物性蛋白的消费是美国农业系统中氮使用的主要驱动因子,如果饮食方式或农业生产方式不发生改变,在未来30年的时间里,美国肥料的使用量将继续增长,流向海洋中的氮通量将可能再增长30%,但也有可能出现下降.     

Nitrogen use in the United States from 1961-2000 and potential future trends

Nitrogen inputs to the US from human activity doubled between 1961 and 1997, with most of the increase in the 1960s and 1970s. The largest increase was in use of inorganic N fertilizer, but emissions of NOx from fossil-fuel combustion also increased substantially. In 1961, N fixation in agricultural systems was the largest single source of reactive N in the US. By 1997, even though N fixation had increased, fertilizer use and NOx emissions had increased more rapidly and were both larger inputs. In both 1961 and 1997, two thirds of reactive N inputs were denitrified or stored in soils and biota, while one third was exported. The largest export was in riverine flux to coastal oceans, followed by export in food and feeds, and atmospheric advection to the oceans. The consumption of meat protein is a major driver behind N use in agriculture in the US Without change in diet or agricultural practices, fertilizer use will increase over next 30 years, and fluxes to coastal oceans may increase by another 30%. However, substantial reductions are possible.     

Nitrogen footprints: Regional realities and options to reduce nitrogen loss to the environment

Ambio - Nitrogen (N) management presents a sustainability dilemma: N is strongly linked to energy and food production, but excess reactive N causes environmental pollution. The N footprint is an...     

Streamflow,Sediment Transport,and Geomorphic Change during the 2011 Flood on the Missouri River Near Bismarck–Mandan,ND

Geomorphic change from extreme events in large managed rivers has implications for river management. A steady‐state, quasi‐three‐dimensional hydrodynamic model was applied to a 29‐km reach of the Missouri River using 2011 flood data. Model results for an extreme flow (500‐year recurrence interval [RI]) and an elevated managed flow (75‐year RI) were used to assess sediment mobility through examination of the spatial distribution of boundary or bed shear stress (τ_b) and longitudinal patterns of average τ_b, velocity, and kurtosis of τ_b. Kurtosis of τ_b was used as an indicator of planform channel complexity and can be applied to other river systems. From differences in longitudinal patterns of sediment mobility for the two flows we can infer: (1) under extreme flow, the channel behaves as a single‐thread channel controlled primarily by flow, which enhances the meander pattern; (2) under elevated managed flows, the channel behaves as multithread channel controlled by the interaction of flow with bed and channel topography, resulting in a more complex channel; and (3) for both flows, the model reach lacks a consistent pattern of deposition or erosion, which indicates migration of areas of erosion and deposition within the reach. Despite caveats and limitations, the analysis provides useful information about geomorphic change under extreme flow and potential implications for river management. Although a 500‐year RI is rare, extreme hydrologic events such as this are predicted to increase in frequency.     

Sublethal toxicity of nano-titanium dioxide and carbon nanotubes in a sediment dwelling marine polychaete

The ecotoxicology of manufactured nanoparticles (MNPs) in estuarine environments is not well understood. Here we explore the hypothesis that nanoTiO₂ and single walled nanotubes (SWNT) cause sublethal impacts to the infaunal species Arenicola marina (lugworm) exposed through natural sediments. Using a 10 day OECD/ASTM 1990 acute toxicity test, no significant effects were seen for SWNT up to 0.03 g/kg and no uptake of SWNTs into tissues was observed. A significant decrease in casting rate (P = 0.018), increase in cellular damage (P = 0.04) and DNA damage in coelomocytes (P = 0.008) was measured for nanoTiO₂, with a preliminary LOEC of 1 g/kg. Coherent anti-stokes Raman scattering microscopy (CARS) located aggregates of TiO₂ of >200 nm within the lumen of the gut and adhered to the outer epithelium of the worms, although no visible uptake of particles into tissues was detected.