Evaluation of leaching characteristic and kinetic study of lithium from lithium aluminum silicate glass-ceramics by NaOH

The behavior and mechanism of Li leaching from lithium aluminum silicate glass-ceramics which can be used as a secondary source of Li using aqueous NaOH solution was investigated. The Li leaching efficiency is increased with increasing concentration of NaOH, specific surface area, and reaction temperature. When leached under optimum conditions, 2 mol/L NaOH, 53 μm particle undersize, 1:10 solid/liquid ratio, 250 r/min stirring speed, 100°C reaction temperature, 12 hr, the Li leaching efficiency was approximately 70%. However, when the leaching experiment was performed for 48 hr, the concentration of Li⁺ ions contained in the leach liquor decreased from 1160 to 236 mg/L. To investigate the origin of this phenomenon, the obtained leach residue was analyzed by X-ray diffraction, scanning electron microscopy, and energy-dispersive X-ray spectroscopy. These analyses show that zeolite was formed around the lithium aluminum silicate glass-ceramics, which affected the leaching of by adsorbing Li⁺ ions. In addition, using the shrinking-core model and the Arrhenius equation, the leaching reaction with NaOH was found to depends on the chemical reaction of the two reactants, with a higher than 41.84 kJ/mol of the activation energy.     

Carbon sinks and sources in China's forests during 1901-2001

This paper reports the annual carbon (C) balance of China's forests during 1901-2001 estimated using the Integrated Terrestrial Ecosystem C-budget model (InTEC). Annual carbon source and sink distributions are simulated for the same period using various spatial datasets including land cover and leaf area index (LAI) obtained from remote sensing, soil texture, climate, forest age, and nitrogen deposition. During 1901-1949, China's forests were a source of 21.0+/-7.8 Tg C yr(-1) due to disturbances (human activities). Its size increased to 122.3+/-25.3 Tg C yr(-1) during 1950-1987 due to intensified human activities in the late 1950s, early 1960s, 1970s and early 1980s. The forests became large sinks of 176.7+/-44.8 Tg C yr(-1) during 1988-2001, owing to large-scale plantation and forest regrowth in previously disturbed areas as well as growth stimulation by nondisturbance factors such as climatic warming, atmospheric CO(2) fertilization, and N deposition. From 1901 to 2001, China's forests were a small carbon source of 3.32 Pg C, about 32.9+/-22.3 Tg C yr(-1). The overall C balance in biomass from InTEC generally agrees with previous results derived from forest inventories of China's forests. InTEC results also include C stock variation in soils and are therefore more comprehensive than previous results. The uncertainty in InTEC results is still large, but it can be reduced if a detailed forest age map becomes available.     

Net primary productivity of China's terrestrial ecosystems from a process model driven by remote sensing

The terrestrial carbon cycle is one of the foci in global climate change research. Simulating net primary productivity (NPP) of terrestrial ecosystems is important for carbon cycle research. In this study, China's terrestrial NPP was simulated using the Boreal Ecosystem Productivity Simulator (BEPS), a carbon-water coupled process model based on remote sensing inputs. For these purposes, a national-wide database (including leaf area index, land cover, meteorology, vegetation and soil) at a 1 km resolution and a validation database were established. Using these databases and BEPS, daily maps of NPP for the entire China's landmass in 2001 were produced, and gross primary productivity (GPP) and autotrophic respiration (RA) were estimated. Using the simulated results, we explore temporal-spatial patterns of China's terrestrial NPP and the mechanisms of its responses to various environmental factors. The total NPP and mean NPP of China's landmass were 2.235 GtC and 235.2 gCm(-2)yr(-1), respectively; the total GPP and mean GPP were 4.418 GtC and 465 gCm(-2)yr(-1); and the total RA and mean RA were 2.227 GtC and 234 gCm(-2)yr(-1), respectively. On average, NPP was 50.6% of GPP. In addition, statistical analysis of NPP of different land cover types was conducted, and spatiotemporal patterns of NPP were investigated. The response of NPP to changes in some key factors such as LAI, precipitation, temperature, solar radiation, VPD and AWC are evaluated and discussed.     

两性聚电解质絮凝剂的合成及特性粘数

研究了两性聚电解质絮凝剂的合成方法对其特性粘数的影响,发现单体配比、pH及聚合引发剂品种和剂量均对两性聚电解质絮凝剂的特性粘数有明显作用。     

胶州湾污染物COD的三维扩散与输运研究

笔者较系统地对环胶州湾工业污染源、生活污染源和海水养殖污染源进行收集和分析,给出影响胶州湾海域环境的主要污染源强的大小及分布;在三维潮流模拟的基础上,建立了一个三维保守污染物COD输运的对流扩散数值模型;模拟所得的COD污染物分布结果与胶州湾的实际监测资料符合良好。      

茨榆山乡上窝铺泥石流灾害特征及防治对策

秦皇岛北部山区泥石流地质灾害隐患威胁着当地居民的生命财产安全,严重阻碍了乡村经济的快速发展。以青龙满族自治县茨榆山乡上窝铺泥石流为例,通过实地调查与数据分析,确定了泥石流成因、类型、活动状况、危害性、危险区范围;获取了泥石流流体重度规律、泥石流流速、泥石流流量、一次性固体冲出物主要力学参数特征;根据泥石流的特点及主要参数,提出监测预警方案及工程治理方案。     

Screening of flocculant-producing microorganisms and flocculating activity

A strain saccharomycete STSM-I with high flocculanting activity was isolated from activated sludge with conventional methods.The high production rate and the low cost STSM-I medium was obtained by selecting different kinds of media, carbon source, nitrogen source and inorganic salt ion. The best flocculant-producing conditions were found by changing medium initial pH, culture temperature and ventilation flow. The best flocculating effect was obtained by changing positive ion types, density and concentration of flocculant.     

云南近46年降水与气温变化趋势的特征分析

利用云南1961-2007年降水与气温资料进行线性趋势分析和突变检验。结果表明,近46年来云南年均降水量是趋于减少的,其中夏季降水量减少较为明显,减少率为4.5 mm/10a,且夏季降水在1971年前后发生了由多到少的突变。从降水的季节变化特征及异常值统计结果来看,云南雨季平均降水量是趋于减少的,而干季平均降水量趋于增加;从降水的地域分布来看,滇南地区降水呈缓慢减少趋势;滇中降水呈缓慢减少后略升状态;滇西北降水呈略升趋势;滇东北降水为明显下降趋势。近46年云南年平均气温是升高的,从全省气温变化的季节特征及异常值统计结果来看,春夏秋冬四季增温都明显,但冬季气温增加最为显著,增加率为0.27℃/10a,冬季平均气温在1995年出现了一次由冷到暖的突变。滇中及以东地区的气温变化增暖趋势明显,滇西地区气温也为增暖的变化趋势。     

The land ecological evolutional patterns in the source areas of the Yangtze and Yellow Rivers in the past 15 years, China

Based on land ecological classification of the source regions of the Yangtze and Yellow Rivers and field investigation, two phases of TM remote sensing data obtained in 1986 and 2000 were compared. From spatial variations and type transformation trends, the spatial changes and evolutional patterns of land ecosystem in the source regions of the two rivers were analyzed using the analytical method of landscape ecological spatial patterns. Results show that middle and high-cover high-cold steppe areas degraded considerably by 15.82%, high-cover high-cold meadow areas by 5.15%, while high-cold swamp meadow areas decreased by 24.36%. Lake water area was reduced by 7.5%, especially the lakes in the source region of the Yangtze River. Land desertification is developing rapidly and the average of desertified land area has increased by 17.11%. Desertified land in the source region of Yellow River is expanding at an annual rate of 1.83%. Analysis of the evolutional pattern of land ecotypes shows that the general tendencies of spatial evolution in the regions are coverage reduction and desertification of high-cold steppe, cover reduction and steppification of high-cold meadows, and desiccation of swamp meadows. As a result, land ecological spatial distribution pattern in the region is changing and the state of eco-environment declining.     

Assessment of Traffic Noise Pollution from 1989 to 2003 in Lanzhou City

On the basis of the continuous traffic noise data observed at 142 sites distributed in 52 roads from 1989 to 2003, the characteristics of traffic noise and effect factors were analyzed through traffic noise indices, such as Lep, L10, L50, L90, TNI, and Pn. Our findings allow us to reach a number of conclusions as follows: Firstly, traffic noise pollution was serious, and its fluctuant characteristic was obvious, resulting in a great intrusion to public in Lanzhou City during last 15 years. Secondly, traffic noise made a distinction between trunk lines and secondary lines, west-east direction roads and north-south direction roads. Thirdly, spatial character and time rule of traffic noise were obvious. In addition, traffic volume, traffic composition, road condition, and traffic management were identified as the key factors influencing traffic noise in this city.