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41.
Macar Oksal Kalefetoğlu Macar Tuğçe Çavuşoğlu Kültiğin Yalçın Emine 《Environmental science and pollution research international》2020,27(32):40253-40261
Environmental Science and Pollution Research - Cobalt (Co) is widely used in many industrial fields such as batteries and paints. Cobalt, a dangerous heavy metal, can be found in high... 相似文献
42.
Buse Tuğba Zaman Emine Gülhan Bakırdere Nursu Aylin Kasa Serenay Deniz Sabriye Sel Dotse Selali Chormey Sezgin Bakırdere 《Environmental monitoring and assessment》2018,190(7):437
This study describes the determination of trace levels of copper by slotted quartz tube atomic absorption spectrometry after dispersive liquid-liquid microextraction. A ligand synthesized from the reaction of salicylaldehyde and 1-naphthylamine was used to form coordinate copper complex prior to extraction. All parameters that influence the output of complex formation, extraction, and instrumental measurement were optimized to enhance the absorbance signal of copper. Under the optimum conditions, about 104-fold enhancement in sensitivity was recorded over the conventional flame atomic absorption spectrometer, corresponding to a 0.51 ng/mL detection limit. The percent relative standard deviation calculated for the lowest concentration (4.8%) indicated high precision for the experimental procedure. Accuracy and applicability of the optimum method were determined by performing spiked recovery tests on urine, lake water, and mineral water samples. Satisfactory recovery results were obtained between 82.2 and 106.3% at four different concentrations. Matrix matching method was also performed to increase the accuracy of quantification, and the percent recovery calculated for 175 ng/mL was 105.14%. 相似文献
43.
Demir S Saral A Ertürk F Kuzu SL Goncaloğlu BI Demir G 《Environmental science and pollution research international》2012,19(5):1503-1514
Introduction
The effect of diurnal changes in strengths of volatile organic compound (VOC) sources on the performances of positive matrix factorization (PMF) and principal component analysis (PCA) was investigated using ambient measurement results that were taken during daytime and nighttime hours between March 24 and May 14, 2011, within Davutpasa Campus of Yildiz Technical University (Istanbul, Turkey).Methods
Forty-five VOC species, ranging from C5 to C11 in volatility, were measured in the samples, 40 of which are included in the analyses. Ambient samples were grouped as daytime, nighttime, and all day datasets, and both PMF and PCA were applied to each dataset. A total of six source groups were extracted from each dataset: solvent use, general industrial paint use, gasoline and diesel vehicle exhausts, and biogenic as well as evaporative emissions. Estimated source contributions showed great diurnal variations.Results
The results suggested that extraction of possible sources by PCA depends greatly on the number of samples and the strength of the sources, while PMF produced stable results regardless of number of samples and source strengths.Conclusion
Although PMF was unable to resolve gasoline vehicle and evaporative emissions, it was found to be successful in explaining diurnal fluctuations in source strengths, while the performance of PCA depends on the strength of emission source. 相似文献44.
Hicran Altuğ Eftade O. Gaga Tuncay Döğeroğlu Özlem Özden Sermin Örnektekin Bert Brunekreef Kees Meliefste Gerard Hoek Wim Van Doorn 《Environmental science and pollution research international》2013,20(9):6455-6467
Health effects of ambient air pollution were studied in three groups of schoolchildren living in areas (suburban, urban and urban-traffic) with different air pollution levels in Eski?ehir, Turkey. This study involved 1,880 students aged between 9 and 13 years from 16 public primary schools. This two-season study was conducted from January 2008 through March 2009. Symptoms of asthma, rhinitis and eczema were determined by the International Study of Asthma and Allergies in Childhood questionnaire in 2008. Two lung function tests were performed by each child for summer and winter seasons with simultaneous ambient air measurements of ozone (O3), nitrogen dioxide (NO2) and sulfur dioxide (SO2) by passive sampling. Effects of air pollution on impaired lung function and symptoms in schoolchildren were estimated by multivariate logistic regression analyses. Girls with impaired lung function (only for the summer season evaluation) were more observed in suburban and urban areas when compared to urban-traffic area ([odds ratio (OR)?=?1.49; 95 % confidence interval (CI) 1.04–2.14] and [OR?=?1.69 (95 % CI 1.06–2.71)] for suburban vs. urban-traffic and urban vs. urban-traffic, respectively). Significant association between ambient ozone concentrations and impaired lung function (for an increase of 10 μg m?3) was found only for girls for the summer season evaluation [OR?=?1.11 (95 % CI 1.03–1.19)]. No association was found for boys and for the winter season evaluation. No association was found between any of the measured air pollutants and symptoms of current wheeze, current rhinoconjunctivitis and current itchy rash. The results of this study showed that increasing ozone concentrations may cause a sub-acute impairment in lung function of school aged children. 相似文献
45.
This study aims to investigate the treatment of paper mill effluents using electrocoagulation. Removal of lignin, phenol, chemical oxygen demand (COD) and biological oxygen demand (BOD) from paper mill effluents was investigated at various current intensities by using different electrodes (Al and Fe) and at various electrolysis times (1.0, 2.5, 5.0 and 7.5min). It was observed that the experiments carried out at 12V, an electrolysis time of 2min and a current intensity of 77.13mA were sufficient for the removal of these pollutants with each electrode. The removal capacities of the process using an Al electrode were 80% of lignin, 98% of phenol, 70% of BOD, and 75% of COD after 7.5min. Using an Fe electrode the removal capacities were 92%, 93%, 80% and 55%, respectively. In addition, it was found that removal of lignin, phenol, BOD and COD increased with increasing current intensity. In the experiments carried out at different current intensities, higher removal can be explained through a decrease in intra-resistance of solution and consequently an increase at the transfer speed of organic species to electrodes. It was also found that Al electrode performs higher efficiency than Fe electrode except for COD removal. However, the time required for removal of BOD was more than that of COD. The results suggest that electrocoagulation could be considered as an effective alternative to paper mill effluents treatment. 相似文献
46.
In this study, the relation between sulfur dioxide (SO2) and particulate matter (PM) concentrations periodically measured in the city of Afyon’s atmosphere with meteorological factors
such as precipitation, humidity, temperature, wind velocity, and inversion were investigated. The mean values of SO2 and PM concentrations measured during the winter months of October–March 1990–1999 were correlated with the meteorological
parameters of the same period. Simple and multiple linear regression analysis were utilized to evaluate the contribution of
meteorological variables. The statistical results show that the pollutants, i.e., SO2 and PM are dependent upon humidity, temperature, and inversion at the 1% significance level; while the dependence of both
pollutants with temperature is negative when those of humidity and inversion are positive. Two models in which temperature
and inversion are dependent with multiple variables are recommended for predicting the contribution of meteorological parameters
on SO2 and PM. In addition, the relationship between humidity, temperature, and inversion with pollutants is also determined using
nonlinear (polynomial) models. 相似文献
47.
Sezen Saçan Aysun Uğur Uğur Sunlu Baha Büyükışık Mehmet Aksu F. Sanem Sunlu 《Environmental monitoring and assessment》2010,161(1-4):575-582
Bottom sediments reflect in general the relative contamination of a sea area. Therefore, a great deal of monitoring work has been dedicated to the analysis of bottom sediments. Izmir Bay is a very important pollution centre in Turkish Aegean coast region due to a densely populated community, industrial complex and maritime transportation, and there are many streams flowing into the bay that pass through a number of industrial and agricultural areas. It had received the majority of domestic and industrial wastewaters until the wastewater treatment plant was constructed. It is well known that sediments play an important role as reservoirs of a fraction of the pollution in aquatic systems. Therefore, sediment samples were collected monthly from three stations which are located in the inner part of the bay during the period January to December 2003. Temporal variations and seasonal changes on their 210Po and 210Pb contents were examined, and the activity concentrations of 210Po and 210Pb were found to vary from 43±6 to 132±12 and 27±5 to 91±9 Bq kg???1 dry wt, respectively. The highest values of those natural radionuclides were measured at Kar??yaka Station because of the current systems of the bay. Seasonally, the 210Pb levels were found to increase during the winter time for all the stations. 相似文献
48.
Sezgin Hacısalihoğlu 《Environmental monitoring and assessment》2010,165(1-4):255-262
The main goal of this research was soil-loss determination and comparison of the plot measurement results with simulation model (universal soil loss equation (USLE)) results in different land use and slope classes. The research took place in three different land-use types (Scotch pine forest, pasture land, and agricultural land) and in two different slope classes (15–20%, 35–40%). Within six measurement stations (for each land-use type and slope class-one station), totally 18 measurement plots have been constituted, and soil-loss amount measurements have been investigated during the research period (3 years along). USLE simulation model is used in these measurement plots for calculation the soil-loss amounts. The results pointed out that measured (in plots) and simulated (with USLE) soil-loss amounts differ significantly in each land-use type and slope class. 相似文献
49.
Nevzat Damla Uğur Cevik Ali Ihsan Kobya Ahmet Celik Necati Celik 《Environmental monitoring and assessment》2010,170(1-4):457-466
The activity concentrations of 226Ra, 232Th, and 40K in lime and gypsum samples used as building materials in Turkey were measured using gamma spectrometry. The mean activity concentrations of 226Ra, 232Th, and 40K were found to be 38 ± 16, 20 ± 9, and 156 ± 54 Bq kg???1 for lime and found to be 17 ± 6, 13 ± 5, and 429 ± 24 Bq kg???1 for gypsum, respectively. The radiological hazards due to the natural radioactivity in the samples were inferred from calculations of radium equivalent activities (Raeq), indoor absorbed dose rate in the air, the annual effective dose, and gamma and alpha indices. These radiological parameters were evaluated and compared with the internationally recommended limits. The experimental mass attenuation coefficients (μ/ρ) of the samples were determined in the energy range 81–1,332 keV. The experimental mass attenuation coefficients were compared with theoretical values obtained using XCOM. It is found that the calculated values and the experimental results are in good agreement. 相似文献
50.
Delta-aminolevulinate dehydratase (ALAD) activity has been used in prokaryotes and eukaryotes as a biomarker for environmental
lead (Pb) exposure and toxicity. Microorganisms are sensitive indicators of toxicity at the fundamental level of ecological
organization, but bacterial biomarker studies are focused on the Pseudomonas strains in Group I and E coli. The objectives of the present work were to determine if Burkholderia gladioli belonging to group II, due to its 16SrRNA similarity, can be used as biomarker in metal contamination and compare its possible
usage with Pseudomonas aeruginosa and Citrobacter freundii (previously known as Esherichia freundii) and Bacterium freundii which are classified in Group I. In this study, ALAD activity in an environmental strains of Burkholderia gladioli, Pseudomonas aeruginosa, Citrobacter freundii were investigated to evaluate potential inhibition by Pb and other toxic metals. When the ALAD activity of Burkholderia gladioli was tested, Co and Pb decreased activity by 27 and 71%, respectively. In addition to these findings, Zn increased the activity
up to 26%. These effects were found to be statistically meaningful (p < 0.05). It was determined that the increase of lead concentration inhibites the ALAD activity at each of the three strains.
There was a statistically significant dose–response relationship between ALAD activity in cells of Burkholderia gladioli and Pb (Pearson correlation coefficent = −0.665; r
2 = 0.665, and p < 0.001). The strongest ALAD inhibition which was measured was 90% at Burkholderia gladioli when protein extracts were incubated with 750 μM of Pb. The relationship between Pb and ALAD activity was statistically described
by [ALAD Activity] = 0.476−0.000597 × [Pb]. According to the obtained results, we suggest that the ALAD of Burkholderia gladioli can be used as a biomarker for lead contamination in the environment. 相似文献