有序介孔碳载金/L-赖氨酸/纳米金修饰电极的制备及其对邻苯二酚、对苯二酚的检测响应研究

通过化学还原的方法合成有序介孔碳负载纳米金粒子,并构筑有序介孔碳载金/L-赖氨酸/纳米金复合膜修饰玻碳电极;利用扫描电镜观察介孔碳和介孔碳复合膜的微观结构,并用循环伏安法、电化学阻抗谱表征自组装电极的过程.在此基础上用差分脉冲伏安法研究对苯二酚和邻苯二酚混合物在该电极上的电催化氧化,研制了一种基于有序介孔碳载金/L-赖氨酸/纳米金复合膜修饰电极分别检测对苯二酚和邻苯二酚的传感器.在最优的实验条件下,该传感器在对苯二酚和邻苯二酚浓度为1×10-6～8×10-4mol·L-1的范围内具有良好的线性关系,检出限分别为3×10-7mol·L-1、7×10-7mol·L-1.     

地质雷达在监测地下水石油烃污染中的应用

随着我国工业迅速发展,石油烃污染威胁地下水安全问题逐渐暴露出来。地质雷达作为一种非破坏性的原位探测技术在国外已广泛应用于地下水监测,由于石油烃在地质雷达图谱上通常显示出高阻异常特征,这为探测地下水中的石油烃污染提供了可能。简述了地质雷达探测石油烃的原理,探测效果的影响因素,并列举了部分国外实例,证实了地质雷达探测地下水石油烃污染的可行性。     

Interface-mediated synthesis of monodisperse ZnS nanoparticles with sulfate-reducing bacterium culture

We have created a new method of ZnS nanospheres synthesis. By interface-mediated precipitation method (IMPM), monodisperse ZnS nanoparticles was synthesized on the particle surface of sulfate-reducing bacterium nutritious agar culture. Sulfate-reducing bacterium (SRB) was used as a sulfide producer because of its dissimilatory sulfate reduction capability, meanwhile produced a variety of amino acids acting as templates for nanomaterials synthesis. Then zinc acetate was dispersed into nutritious agar plate. Subsequently agar plate was broken into particles bearing much external surface, which successfully mediated the synthesis of monodisperse ZnS nanoparticles. The morphology of monodisperse ZnS nanospheres and SRB were examined by scanning electron microscopy (SEM), and the microstructure was investigated by X-ray diffraction (XRD). The thermostability of ZnS nanoparticles was determined by thermo gravimetric-differential thermo gravimetric (TG-DTG). The maximum absorption wavelengh was analysed with an ultraviolet-visible spectrophotometer within a range of 199–700 nm. As a result, monodisperse ZnS nanoparticles were successfully synthesized, with an average diameter of 80 nm. Maximum absorption wavelengh was 228 nm, and heat decomposed temperature of monodisperse ZnS nanoparticles was 596°C.     

Interface-mediated synthesis of monodisperse ZnS nanoparticles with sulfate-reducing bacterium culture

We have created a new method of ZnS nanospheres synthesis. By interface-mediated precipitation method (IMPM), monodisperse ZnS nanoparticles was synthesized on the particle surface of sulfate-reducing bacterium nutritious agar culture. Sulfate-reducing bacterium (SRB) was used as a sulfide producer because of its dissimilatory sulfate reduction capability, meanwhile produced a variety of amino acids acting as templates for nanomaterials synthesis. Then zinc acetate was dispersed into nutritious agar plate. Subsequently agar plate was broken into particles bearing much external surface, which successfully mediated the synthesis of monodisperse ZnS nanoparticles. The morphology of monodisperse ZnS nanospheres and SRB were examined by scanning electron microscopy (SEM), and the microstructure was investigated by X-ray diffraction (XRD). The thermostability of ZnS nanoparticles was determined by thermo gravimetric-differential thermo gravimetric (TG-DTG). The maximum absorption wavelengh was analysed with an ultravioletvisible spectrophotometer within a range of 199-700 nm. As a result, monodisperse ZnS nanoparticles were successfully synthesized, with an average diameter of 80 nm. Maximum absorption wavelengh was 228 nm, and heat decomposed temperature of monodisperse ZnS nanoparticles was 596℃.     

关于加强我国污染场地环境管理政策建议探讨

本文在综述当前我国污染场地环境管理现状基础上,探讨了加强污染场地环境管理相关政策建议,以期为我国进一步完善污染场地环境管理提供决策参考。具体建议：强化污染场地信息管理;把握和贯彻基于风险的管理理念;搞好标准建设工作;重视复合绿色修复技术的研发;逐步开创适宜的融资机制和模式;建立合理有效的公众参与和信息公开制度。     

基于单颗粒质谱信息气溶胶分类方法的研究进展

气溶胶质谱仪在对气溶胶颗粒的监测过程中会产生大量单颗粒的化学成分和粒径信息,基于这些质谱数据能够推测颗粒的来源。而对气溶胶来源的分析,很大程度上是由颗粒的种类决定的,故对海量数据的分类就成为不可忽略的步骤。针对气溶胶质谱仪采集到的数据,概述了用于气溶胶分类的多种方法的理论核心、分类步骤及各自的优缺点等。据此可为今后气溶胶分类方法的研究提供建设性意见。     

浅谈可燃气体报警器检定装置计量标准的建立

从计量标准的相关概念出发．强调了建立可燃气体报警器计量检定装置（计量标准）的目的和重要性。从计量标准的工作原理、计量标准器及配套设备构成、计量标准的测量范围、重复性、稳定性、不确定度等计量技术角度对可燃气体报警器检定装置的建立进行了阐述。     

导热检测法测定硝酸异丙酯浓度试验研究

硝酸异丙酯是云爆剂（FAE）的一种重要组成成分,具有易挥发和相容性差的特点。因此,准确测定弹药库房和弹药包装筒内的C3H7NO3浓度,对于保证仓库、弹药和人员安全具有重要意义。从气相色谱的导热检测原理出发,确定了测定C3H7NO3浓度的色谱条件,通过试验测量计算了C3H7NO3的校正因子,从而建立了一种C3H7NO3浓度测量的新方法。     

北京房山区自驾车旅游经济发展战略研究

自驾车旅游是旅游经济发展的重要组成部分,也是新兴的旅游热点之一,自驾旅游经济发展已初见端倪,但市场仍待开发。特别是自驾旅游基地,作为自驾经济的核心发展部分,其建设和发展是自驾旅游经济发展的重中之重。本文通过对在北京房山区自驾车旅游市场的旅游者结构、空间分布特征、需求特征等方面的调查,掌握影响房山自驾车旅游市场的因素,以期提高自驾车旅游市场质量,为房山区自驾旅游经济的发展提供依据和指导。研究指出,北京房山区应发展自驾游露营基地、加强旅游交通导引建设、完善旅游智能交通系统、全面推进自驾旅游的推广与营销。     

农业废物好氧堆肥中氨氧化细菌的群落结构

应用聚合酶链式反应-变性梯度凝胶电泳（PCR-DGGE）技术对农业废物好氧堆肥过程中氨氧化细菌（ammonia-oxidizingbacteria,AOB）种群结构随时间的变化情况进行了研究,结果表明,AOB群落的Shannon-Weaver指数初始值为2.58,堆肥结束时为2.02,多样性整体呈下降趋势.通过对部分优...